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Au [email protected] @ZnIn 2 S 4 nanosheets with significantly enhanced visible-light photocatalytic H 2 evolution: The effect of different Au positions on the transfer of electron-hole pairs

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Applied Catalysis B: Environmental 2021年 282卷

作者： Siman Mao Jian-Wen Shi Guotai Sun Dandan Ma Chi He Zengxin Pu Kunli Song Yonghong Cheng State Key Laboratory of Electrical Insulation and Power Equipment Center of Nanomaterials for Renewable Energy School of Electrical Engineering Xi'an Jiaotong University Xi'an 710049 China State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'an Jiaotong University Xi'an 710049 Shaanxi China

Herein, a new type of photocatalysts, Au [email protected] @ZnIn 2 S 4 nanosheets ( [email protected] @ZIS), is elaborately designed for the photocatalytic H 2 evolution from water splitting, where Au nanodots (NDs) are anchored in the pore space of thiol-functionalized UiO66 metal-organic framework (MOF) and ZnIn 2 S 4 nanosheets are wrapped around the UiO66 MOF containing Au NDs. It is found that the different Au positions have a grateful effect on the transfer of photogenerated charge carriers. In [email protected] @ZIS, the photoexcited electrons transfers from ZnIn 2 S 4 to UiOS and then to Au NDs, establishing a smooth transmission channel of electrons. As expected, the optimal sample (Au 4 @ [email protected] 40 ) presents a high photocatalytic H 2 production rate of 391.6 μmol/h (10 mg of catalyst) under visible light irradiation, which is 435.1, 61.2 and 10.2 times higher than that of the pure UiOS, ZnIn 2 S 4 and [email protected] , respectively.

关键词： Photocatalysis Hydrogen evolution Metal-organic framework Thiol- functionalization Au nanodots

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Surface Adsorbed Hydroxyl: A Double-Edged Sword in Electrochemical CO2Reduction over Oxide-Derived Copper

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Angewandte Chemie 2023年第31期135卷

作者： Daixing Wei Yiqing Wang Prof. Chung-Li Dong Ta Thi Thuy Nga Yuchuan Shi Jialin Wang Xiaoli Zhao Prof. Fan Dong Prof. Shaohua Shen International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China Department of Physics Tamkang University New Taipei City 25137 Taiwan Research Center for Environmental and Energy Catalysis Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of China Chengdu 611731 China

Oxide-derived Cu (OD−Cu) featured with surface located sub-20 nm nanoparticles (NPs) created via surface structure reconstruction was developed for electrochemical CO 2 reduction (ECO 2 RR). With surface adsorbed hydroxyls (OH ad ) identified during ECO 2 RR, it is realized that OH ad , sterically confined and adsorbed at OD−Cu by surface located sub-20 nm NPs, should be determinative to the multi-carbon (C 2 ) product selectivity. In situ spectral investigations and theoretical calculations reveal that OH ad favors the adsorption of low-frequency *CO with weak C≡O bonds and strengthens the *CO binding at OD−Cu surface, promoting *CO dimerization and then selective C 2 production. However, excessive OH ad would inhibit selective C 2 production by occupying active sites and facilitating competitive H 2 evolution. In a flow cell, stable C 2 production with high selectivity of ∼60 % at −200 mA cm −2 could be achieved over OD−Cu, with adsorption of OH ad well steered in the fast flowing electrolyte.

关键词： CO2 Reduction Electrochemistry Oxide-Derived Copper Reaction Mechanisms Surface Adsorbed Hydroxyls

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Efficiency enhancement in photoelectrochemical water splitting: Defect passivation and boosted charge transfer kinetics of zinc oxide nanostructures via chalcopyrite/chalcogenide mix sensitization

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Physical Review Materials 2021年第12期5卷 125403-125403页

作者： Cigdem Tuc Altaf Nazrin Abdullayeva Ozlem Coskun Alihan Kumtepe İpek Deniz Yildirim Emre Erdem Maochang Liu Ali Bozbey Ertan Agar Mehmet Sankir Nurdan Demirci Sankir Micro and Nanotechnology Graduate Program TOBB University of Economics and Technology Sogutozu Caddesi No 43 Sogutozu 06560 Ankara Turkey Faculty of Engineering and Natural Sciences Sabanci University Orhanli Tuzla 34956 Istanbul Turkey International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an Shaanxi 710049 People's Republic of China Department of Electrical and Electronics Engineering TOBB University of Economics and Technology Sogutozu Caddesi No 43 Sogutozu 06560 Ankara Turkey Department of Mechanical Engineering Energy Engineering Graduate Program University of Massachusetts Lowell Lowell Massachusetts 01854 USA Department of Materials Science and Nanotechnology Engineering TOBB University of Economics and Technology Sogutozu Caddesi No 43 Sogutozu 06560 Ankara Turkey

ZnO thin films in nanorod (NR) and nanoflower (NF) morphologies were used as photoelectrode scaffolds for efficient visible-light-driven photoelectrochemical (PEC) water splitting process, where their decoration with copper indium gallium sulfide (CIGS) and indium sulfide (In2S3) layers resulted in significant PEC performance enhancement. ZnO NF/CIGS/In2S3 photoelectrodes exhibited a remarkably high PEC efficiency (∼6.0% applied bias photon-to-current efficiency, 83% incident photon-to-current efficiency) due to the negligible dark current, while ZnO NR/CIGS/In2S3 generated a photocurrent density of ***–2 at 0.4 V (vs Ag/AgCl), being one of the highest performances reported in the literature for copper-based chalcopyrite photoelectrodes so far. The interfacial photoelectrode-electrolyte charge transport dynamics, investigated via intensity-modulated photocurrent spectroscopy, exhibited a sevenfold increase in charge transfer efficiencies with a significant drop in surface recombination kinetics for ZnO NF after CIGS/In2S3 decoration. The obtained results show consistency with numerically modeled electric field distribution profiles and electron paramagnetic resonance results of ZnO NF, rationalizing the enhanced charge transfer rates for decorated samples and confirming the defect passivating nature of CIGS/In2S3.

关键词： Electrochemical properties Photoconductivity

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Customizable Ligand Exchange for Tailored Surface Property of Noble Metal Nanocrystals

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研究（英文） 2020年第3期 192-203页

作者： Qikui Fan Hao Yang Juan Ge Shumeng Zhang Zhaojun Liu Bo Lei Tao Cheng Youyong Li Yadong Yin Chuanbo Gao Frontier Institute of Science and Technology State Key Laboratory of Multiphase Flow in Power EngineeringXi'an Jiaotong University Xi'an Shaanxi 710054 China Institute of Functional Nano & Soft Materials (FUNSOM) Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices Joint International Research Laboratory of Carbon-Based Functional Materials and Devices Soochow UniversitySuzhou Jiangsu 215123 China Department of Chemistry University of California Riverside California 92521 USA

It is highly desirable,while still challenging,to obtain noble metal nanocrystals with custom capping ligands,because their colloidal synthesis relies on specific capping ligands for the shape control while conventional ligand exchange processes suffer from 'the strong replaces the weak' limitation,which greatly hinders their ***,we report a general and effective ligand exchange approach that can replace the native capping ligands of noble metal nanocrystals with virtually any type of ligands,producing flexibly tailored surface *** key is to use diethylamine with conveniently switchable binding affinity to the metal surface as an intermediate *** a strong ligand,it in its original form can effectively remove the native ligands;while protonated,it loses its binding affinity and facilitates the adsorption of new ligands,especially weak ones,onto the metal *** this means,the irreversible order in the conventional ligand exchange processes could be *** efficacy of the strategy is demonstrated by mutual exchange of the capping ligands among cetyltrimethylammonium,citrate,polyvinylpyrrolidone,and *** novel strategy significantly expands our ability to manipulate the surface property of noble metal nanocrystals and extends their applicability to a wide range of fields,particularly biomedical applications.

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Microalgae bio-oil production by pyrolysis and hydrothermal liquefaction: Mechanism and characteristics

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Bioresource Technology 2023年 376卷 128860页

作者： Ağbulut, Ümit Sirohi, Ranjna Lichtfouse, Eric Chen, Wei-Hsin Len, Christophe Show, Pau Loke Le, Anh Tuan Nguyen, Xuan Phuong Hoang, Anh Tuan Department of Mechanical Engineering Duzce University Düzce81620 Turkey School of Health Sciences and Technology University of Petroleum and Energy Studies Uttarakhand Dehradun248 007 India State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Shaanxi Xi'an710049 China Department of Aeronautics and Astronautics National Cheng Kung University Tainan701 Taiwan Research Center for Smart Sustainable Circular Economy Tunghai University Taichung407 Taiwan Department of Mechanical Engineering National Chin-Yi University of Technology Taichung411 Taiwan Institute of Chemistry for Life and Health Sciences PSL University France Department of Chemical Engineering Khalifa University P.O. Box 127788 Abu Dhabi United Arab Emirates Zhejiang Provincial Key Laboratory for Subtropical Water Environment and Marine Biological Resources Protection Wenzhou University Wenzhou325035 China Department of Chemical and Environmental Engineering Faculty of Science and Engineering University of Nottingham Malaysia Jalan Broga Selangor Darul Ehsan Semenyih43500 Malaysia Department of Sustainable Engineering Saveetha School of Engineering SIMATS Chennai602105 India School of Mechanical Engineering Hanoi University of Science and Technology Hanoi Viet Nam PATET Research Group Ho Chi Minh City University of Transport Ho Chi Minh City Viet Nam Institute of Engineering HUTECH University Ho Chi Minh City Viet Nam

Microalgae have great potential in producing energy-dense and valuable products via thermochemical processes. Therefore, producing alternative bio-oil to fossil fuel from microalgae has rapidly gained popularity due to its environmentally friendly process and elevated productivity. This current work aims to review comprehensively the microalgae bio-oil production using pyrolysis and hydrothermal liquefaction. In addition, core mechanisms of pyrolysis and hydrothermal liquefaction process for microalgae were scrutinized, showing that the presence of lipids and proteins could contribute to forming a large amount of compounds containing O and N elements in bio-oil. However, applying proper catalysts and advanced technologies for the two aforementioned approaches could improve the quality, heating value, and yield of microalgae bio-oil. In general, microalgae bio-oil produced under optimal conditions could have 46 MJ/kg heating value and 60% yield, indicating that microalgae bio-oil could become a promising alternative fuel for transportation and power generation. © 2023 Elsevier Ltd

关键词： Microalgae

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Study on ash fusion behaviors and physico-chemical characteristics of semi-coke and its blended fuel with coal 35

Study on ash fusion behaviors and physico-chemical character...

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35th Annual International Pittsburgh Coal Conference, PCC 2018

作者： Yuan, Maobo Wang, Chang'an Wang, Pengqian Tao, Zichen Du, Yongbo Zhao, Lei Che, Defu State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an710049 China

ISBN: (纸本)1890977357

With the rapid development of coal chemical industry in China, a large number of low-volatile carbon-based fuels such as semi-coke are in urgent need of combustion and utilization, and the co-combustion with high-volatile coal shows the potential to realize the large-scale utilization of semi-coke in coal-fired power plant. Because the blending coal can hardly match the design coal, it is easy to aggravate the degree of deposition and slagging on the heating surface and affect the operation of the boiler. However, the melting behavior of ash produced by blended coal with semi-coke combustion needs further study. In this paper, the ash melting behavior and physico-chemical characteristics of semi-coke and its blended fuel with coal were experimentally studied. Firstly, the relation of ash composition and ash melting behavior was observed by comparing the ash composition and ash fusion point of semi-coke and raw coal. Secondly, the influence of blending ratio and blending mode on the ash melting behavior of semi-coke blended fuel was studied by micro-computer ash melting point meter. Finally, the microstructure and physico-chemical properties of the melted ash at the softening temperature were evaluated by scanning electron microscope (SEM) technique with X-ray spectrometer (EDS) and X-ray diffractometer (XRD) technique. The experimental results showed that the mineral composition and oxide content in the semi-coke were different from the raw coal, which led to the change of coal ash fusibility. Meanwhile, the ash fusion point of semi-coke blended fuel could not be expressed linearly by the ash fusion point of its raw coal, and the influence of blending mode including in-furnace blending and out-furnace blending on the ash fusion point could be neglected. While the microstructure and physico-chemical properties were affected by the blending mode. Compared to the in-furnace blending, the carbon content was lower in out-furnace blending. Furthermore, the blending mode h

关键词： Coal

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Modeling and optimizing of anode-supported solid oxide fuel cells with gradient anode: Part I. Model description and validation by experiments

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Numerical Heat Transfer, Part A: Applications 2019年第12期76卷 925-948页

作者： Pei Fu Xionghui Li Jian Chen Jian Yang Jianbing Huang Qiuwang Wang Key Laboratory of Thermo-Fluid Science and Engineering MOE School of Energy and Power Engineering Xi’an Jiaotong University Shaanxi P.R. China State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Shaanxi P.R. China

Grading the porous anode microstructure, i.e., gradient anode is an effective way to enhance the electrical performance of anode-supported solid oxide fuel cells (SOFCs). This article is the first part of a two-part article which presents a 3D numerical model of a gradient anode SOFC and conducts a model validation in comparison with the experiments for the gradient anode SOFC modeling and optimizing. An experimental test setup was constructed first to evaluate the electrical performance of a SOFC button cell with a gradient anode. Then the microstructure characterization of each cell component was obtained by combining the mercury porosimetry with image analysis. Parameters relating to the microstructure mainly included the layer thickness, porosity, pore size, and particle size. Based on the microstructure parameters and measured electrical performances, the numerical model of the gradient anode SOFC button cell was established, which related the cell microstructure to the electrochemical characteristics. The results show that the microstructure parameters of each cell component can be quantificationally obtained by the backscatter electron image analysis. The modeledi-Vandi-Pcurves at three flow rates of fuel gas (75/100/125 mL·min−1) agree well with the experimental data. This validation process indicates that the numerical model is able to accurately describe the electrical performance of the gradient anode SOFC and it can be further extended to optimize the anode microstructure distribution.

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Experimental study on nanosecond pulsed pin-to-plate discharge in supersonic air flow

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Plasma Science and Technology 2019年第9期21卷 122-131页

作者： Yiwen LI zhong ZHUANG Lei PANG Pengzhen DUAN Zhiwen DING Bailing ZHANG Science and Technology on Plasma Dynamics Laboratory Air Force Engineering University Xi'an 710038 People's Republic of China Science and Technology on Combustion Internal Flow and Thermo-Structure Laboratory Astronautics School Northwestern Polytechnical University Xi'an 710072 People's Republic of China State Key Laboratory of Electrical Insulation and Power Equipment Xi'an Jiaotong University Xi'an 710049 People's Republic of China

Development of magnetohydrodynamic acceleration technology is expected to improve wind tunnel simulation capability and testing *** underlying premise is to produce uniform and stable plasma in supersonic air flow,and gas discharge is an effective way to achieve this.A nanosecond pulsed discharge experimental system under supersonic conditions was established,and a pin-to-plate nanosecond pulsed discharge experiment in Mach 2 air flow was performed to verify that the proposed method produced uniform and stable plasma under supersonic *** results show that the discharge under supersonic conditions was stable overall,but uniformity was not as good as that under static *** the number of pins improved discharge uniformity,but reduced discharge intensity and hence plasma *** multi-pin conditions at 1000Hz,the discharge was almost completely corona discharge,with the main current component being the displacement current,which was smaller than that under static conditions.

关键词： nanosecond pulse discharge supersonic air flow pin-to-plate discharge plasma uniform and stable

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Numerical simulation on filling process of drag reduction agent in natural gas pipeline

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Journal of Physics: Conference Series 2021年第1期1985卷

作者： Xiaoyun Yin Jiaqiang Jing Peiyu Jing Jie Sun Ying Yuan School of Oil & Natural Gas Engineering Southwest Petroleum University Chengdu China Oil & Gas Fire Protection Key Laboratory of Sichuan Province Chengdu China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an China

In this paper, a numerical simulation is established to model the filling process of atomized natural gas drag reduction agent (DRA) at the pipeline inlet section. The computations are on the basis of the Euler-Lagrange method with the standard k-ε turbulence model. The effects of atomizing parameters on the droplets Sauter Mean Diameter (SMD) and the adsorption performance on the wall of pipe are investigated using the validated model. The results show that nozzle diameter and nozzle angle have little effect on the SMD of DRA droplets, whereas the size of the droplets SMD reduces with the increase of atomizing pressure, and the influence of atomizing flow rate is just the opposite.

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Back Cover Image, Volume 7, Number 3, March 2025

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Carbon Energy 2025年第3期7卷

作者： Binglan Wu Karim Harrath Marshet Getaye Sendeku Tofik Ahmed Shifa Yuxin Huang Jing Tai Fekadu Tsegaye Dajan Kassa Belay Ibrahim Xueying Zhan Zhenxing Wang Elisa Moretti Ying Yang Fengmei Wang Alberto Vomiero State Key Laboratory of Chemical Resource Engineering College of Chemistry Beijing University of Chemical Technology Beijing China CAS Key Laboratory of Nanosystem and Hierarchical Fabrication National Center for Nanoscience and Technology (NCNST) Beijing China Shaanxi Provincial Key Laboratory of Electroanalytical Chemistry Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education College of Chemistry & Materials Science Northwest University Xi'an China State Key Laboratory of Multiphase Flow in Power Engineering International Research Center for Renewable Energy Xi'an Jiaotong University Shaanxi China Fundamental Science Center of Rare Earths Ganjiang Innovation Academy Chinese Academy of Science Ganzhou China Ocean Hydrogen Energy R&D Center Research Institute of Tsinghua University in Shenzhen Shenzhen China Department of Molecular Sciences and Nanosystems Ca' Foscari University of Venice Venezia Mestre Italy Testing and Analysis Center Institute of Chemistry Chinese Academy of Sciences Beijing China Department of Engineering Sciences and Mathematics Division of Materials Science Luleå University of Technology Luleå Sweden

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