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Microalgae bio-oil production by pyrolysis and hydrothermal liquefaction: Mechanism and characteristics

Bioresource Technology 2023年 376卷 128860页

作者： Ağbulut, Ümit Sirohi, Ranjna Lichtfouse, Eric Chen, Wei-Hsin Len, Christophe Show, Pau Loke Le, Anh Tuan Nguyen, Xuan Phuong Hoang, Anh Tuan Department of Mechanical Engineering Duzce University Düzce81620 Turkey School of Health Sciences and Technology University of Petroleum and Energy Studies Uttarakhand Dehradun248 007 India State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Shaanxi Xi'an710049 China Department of Aeronautics and Astronautics National Cheng Kung University Tainan701 Taiwan Research Center for Smart Sustainable Circular Economy Tunghai University Taichung407 Taiwan Department of Mechanical Engineering National Chin-Yi University of Technology Taichung411 Taiwan Institute of Chemistry for Life and Health Sciences PSL University France Department of Chemical Engineering Khalifa University P.O. Box 127788 Abu Dhabi United Arab Emirates Zhejiang Provincial Key Laboratory for Subtropical Water Environment and Marine Biological Resources Protection Wenzhou University Wenzhou325035 China Department of Chemical and Environmental Engineering Faculty of Science and Engineering University of Nottingham Malaysia Jalan Broga Selangor Darul Ehsan Semenyih43500 Malaysia Department of Sustainable Engineering Saveetha School of Engineering SIMATS Chennai602105 India School of Mechanical Engineering Hanoi University of Science and Technology Hanoi Viet Nam PATET Research Group Ho Chi Minh City University of Transport Ho Chi Minh City Viet Nam Institute of Engineering HUTECH University Ho Chi Minh City Viet Nam

Microalgae have great potential in producing energy-dense and valuable products via thermochemical processes. Therefore, producing alternative bio-oil to fossil fuel from microalgae has rapidly gained popularity due to its environmentally friendly process and elevated productivity. This current work aims to review comprehensively the microalgae bio-oil production using pyrolysis and hydrothermal liquefaction. In addition, core mechanisms of pyrolysis and hydrothermal liquefaction process for microalgae were scrutinized, showing that the presence of lipids and proteins could contribute to forming a large amount of compounds containing O and N elements in bio-oil. However, applying proper catalysts and advanced technologies for the two aforementioned approaches could improve the quality, heating value, and yield of microalgae bio-oil. In general, microalgae bio-oil produced under optimal conditions could have 46 MJ/kg heating value and 60% yield, indicating that microalgae bio-oil could become a promising alternative fuel for transportation and power generation. © 2023 Elsevier Ltd

关键词： Microalgae

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Study on ash fusion behaviors and physico-chemical characteristics of semi-coke and its blended fuel with coal 35

Study on ash fusion behaviors and physico-chemical character...

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35th Annual International Pittsburgh Coal Conference, PCC 2018

作者： Yuan, Maobo Wang, Chang'an Wang, Pengqian Tao, Zichen Du, Yongbo Zhao, Lei Che, Defu State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an710049 China

ISBN: (纸本)1890977357

With the rapid development of coal chemical industry in China, a large number of low-volatile carbon-based fuels such as semi-coke are in urgent need of combustion and utilization, and the co-combustion with high-volatile coal shows the potential to realize the large-scale utilization of semi-coke in coal-fired power plant. Because the blending coal can hardly match the design coal, it is easy to aggravate the degree of deposition and slagging on the heating surface and affect the operation of the boiler. However, the melting behavior of ash produced by blended coal with semi-coke combustion needs further study. In this paper, the ash melting behavior and physico-chemical characteristics of semi-coke and its blended fuel with coal were experimentally studied. Firstly, the relation of ash composition and ash melting behavior was observed by comparing the ash composition and ash fusion point of semi-coke and raw coal. Secondly, the influence of blending ratio and blending mode on the ash melting behavior of semi-coke blended fuel was studied by micro-computer ash melting point meter. Finally, the microstructure and physico-chemical properties of the melted ash at the softening temperature were evaluated by scanning electron microscope (SEM) technique with X-ray spectrometer (EDS) and X-ray diffractometer (XRD) technique. The experimental results showed that the mineral composition and oxide content in the semi-coke were different from the raw coal, which led to the change of coal ash fusibility. Meanwhile, the ash fusion point of semi-coke blended fuel could not be expressed linearly by the ash fusion point of its raw coal, and the influence of blending mode including in-furnace blending and out-furnace blending on the ash fusion point could be neglected. While the microstructure and physico-chemical properties were affected by the blending mode. Compared to the in-furnace blending, the carbon content was lower in out-furnace blending. Furthermore, the blending mode h

关键词： Coal

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Modeling and optimizing of anode-supported solid oxide fuel cells with gradient anode: Part I. Model description and validation by experiments

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Numerical Heat Transfer, Part A: Applications 2019年第12期76卷 925-948页

作者： Pei Fu Xionghui Li Jian Chen Jian Yang Jianbing Huang Qiuwang Wang Key Laboratory of Thermo-Fluid Science and Engineering MOE School of Energy and Power Engineering Xi’an Jiaotong University Shaanxi P.R. China State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Shaanxi P.R. China

Grading the porous anode microstructure, i.e., gradient anode is an effective way to enhance the electrical performance of anode-supported solid oxide fuel cells (SOFCs). This article is the first part of a two-part article which presents a 3D numerical model of a gradient anode SOFC and conducts a model validation in comparison with the experiments for the gradient anode SOFC modeling and optimizing. An experimental test setup was constructed first to evaluate the electrical performance of a SOFC button cell with a gradient anode. Then the microstructure characterization of each cell component was obtained by combining the mercury porosimetry with image analysis. Parameters relating to the microstructure mainly included the layer thickness, porosity, pore size, and particle size. Based on the microstructure parameters and measured electrical performances, the numerical model of the gradient anode SOFC button cell was established, which related the cell microstructure to the electrochemical characteristics. The results show that the microstructure parameters of each cell component can be quantificationally obtained by the backscatter electron image analysis. The modeledi-Vandi-Pcurves at three flow rates of fuel gas (75/100/125 mL·min−1) agree well with the experimental data. This validation process indicates that the numerical model is able to accurately describe the electrical performance of the gradient anode SOFC and it can be further extended to optimize the anode microstructure distribution.

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Experimental study on nanosecond pulsed pin-to-plate discharge in supersonic air flow

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Plasma Science and Technology 2019年第9期21卷 122-131页

作者： Yiwen LI zhong ZHUANG Lei PANG Pengzhen DUAN Zhiwen DING Bailing ZHANG Science and Technology on Plasma Dynamics Laboratory Air Force Engineering University Xi'an 710038 People's Republic of China Science and Technology on Combustion Internal Flow and Thermo-Structure Laboratory Astronautics School Northwestern Polytechnical University Xi'an 710072 People's Republic of China State Key Laboratory of Electrical Insulation and Power Equipment Xi'an Jiaotong University Xi'an 710049 People's Republic of China

Development of magnetohydrodynamic acceleration technology is expected to improve wind tunnel simulation capability and testing *** underlying premise is to produce uniform and stable plasma in supersonic air flow,and gas discharge is an effective way to achieve this.A nanosecond pulsed discharge experimental system under supersonic conditions was established,and a pin-to-plate nanosecond pulsed discharge experiment in Mach 2 air flow was performed to verify that the proposed method produced uniform and stable plasma under supersonic *** results show that the discharge under supersonic conditions was stable overall,but uniformity was not as good as that under static *** the number of pins improved discharge uniformity,but reduced discharge intensity and hence plasma *** multi-pin conditions at 1000Hz,the discharge was almost completely corona discharge,with the main current component being the displacement current,which was smaller than that under static conditions.

关键词： nanosecond pulse discharge supersonic air flow pin-to-plate discharge plasma uniform and stable

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Numerical simulation on filling process of drag reduction agent in natural gas pipeline

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Journal of Physics: Conference Series 2021年第1期1985卷

作者： Xiaoyun Yin Jiaqiang Jing Peiyu Jing Jie Sun Ying Yuan School of Oil & Natural Gas Engineering Southwest Petroleum University Chengdu China Oil & Gas Fire Protection Key Laboratory of Sichuan Province Chengdu China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an China

In this paper, a numerical simulation is established to model the filling process of atomized natural gas drag reduction agent (DRA) at the pipeline inlet section. The computations are on the basis of the Euler-Lagrange method with the standard k-ε turbulence model. The effects of atomizing parameters on the droplets Sauter Mean Diameter (SMD) and the adsorption performance on the wall of pipe are investigated using the validated model. The results show that nozzle diameter and nozzle angle have little effect on the SMD of DRA droplets, whereas the size of the droplets SMD reduces with the increase of atomizing pressure, and the influence of atomizing flow rate is just the opposite.

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Back Cover Image, Volume 7, Number 3, March 2025

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Carbon Energy 2025年第3期7卷

作者： Binglan Wu Karim Harrath Marshet Getaye Sendeku Tofik Ahmed Shifa Yuxin Huang Jing Tai Fekadu Tsegaye Dajan Kassa Belay Ibrahim Xueying Zhan Zhenxing Wang Elisa Moretti Ying Yang Fengmei Wang Alberto Vomiero State Key Laboratory of Chemical Resource Engineering College of Chemistry Beijing University of Chemical Technology Beijing China CAS Key Laboratory of Nanosystem and Hierarchical Fabrication National Center for Nanoscience and Technology (NCNST) Beijing China Shaanxi Provincial Key Laboratory of Electroanalytical Chemistry Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education College of Chemistry & Materials Science Northwest University Xi'an China State Key Laboratory of Multiphase Flow in Power Engineering International Research Center for Renewable Energy Xi'an Jiaotong University Shaanxi China Fundamental Science Center of Rare Earths Ganjiang Innovation Academy Chinese Academy of Science Ganzhou China Ocean Hydrogen Energy R&D Center Research Institute of Tsinghua University in Shenzhen Shenzhen China Department of Molecular Sciences and Nanosystems Ca' Foscari University of Venice Venezia Mestre Italy Testing and Analysis Center Institute of Chemistry Chinese Academy of Sciences Beijing China Department of Engineering Sciences and Mathematics Division of Materials Science Luleå University of Technology Luleå Sweden

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Heat transfer characteristics in super-low finned-tube bundles of moisture separator reheaters

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Nuclear engineering and Design 2019年 341卷 368-376页

作者： Dalin Zhang Jiangtao Yu Wenxi Tian G.H. Su Suizheng Qiu State Key Laboratory of Multiphase Flow in Power Engineering Shaanxi Key Laboratory of Advanced Nuclear Energy and Technology School of Nuclear Science and Technology Xi’an Jiaotong University No. 28 Xianning West Road Xi’an 710049 China

Experimental investigation on the heat transfer characteristics of superheat vapor through a new designed moisture separator reheater with “super-low” finned-tube bundles for Generation III+ nuclear power plant, was carried out based on a 5*30 tube bundle test section. Impacts of the vapor mass flow rates are analyzed on the heat transfer characteristics of superheat vapor through the finned-tube bundle. A group of experiments are reviewed on single-phase fluid flowing across the triangular super-low finned-tube bundles whose fin heights are less than 2.75 mm and ratios of fin height to fin diameter are from 0.05 to 0.15. Combining the presented experimental data with the other open published data for single-phase turbulent gases flowing across triangular super-low finned-tube, a new heat transfer correlation is proposed for the MSRs super-low finned-tube bundles, which shows better accuracy and has wider Reynolds number range in application.

关键词： Super-low finned-tube bundle Moisture separator reheater Superheated vapor Heat transfer

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3 μm Hydrocarbon Gas Absorption Detection Based on DFG-TDLAS

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Guangxue Xuebao/Acta Optica Sinica 2025年第8期45卷

作者： Zhou, Wangzheng Qi, Chao Qin, Xiaowei Wang, Zhenzhen Yoshihiro, Deguchi Chong, Daotong Yan, Junjie State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Shaanxi Xi’an710049 China Graduate School of Technology Industrial and Social Sciences Tokushima University Tokushima770-8506 Japan Xi’an Aerospace Propulsion Institute Shaanxi Xi’an710100 China

Objective To achieve in-situ online detection of hydrocarbon gases at various temperatures, we explore the use of tunable diode laser absorption spectroscopy (TDLAS) for measuring hydrocarbon gas content. A difference frequency generation (DFG) laser, with a scanning range of 3250-3400 nm, is used to construct a hydrocarbon gas detection system. The 3 μm wide-band scanning provides a significant number of characteristic absorption peaks and reveals the absorbance line shapes of the absorption band. This makes hyperspectral fitting feasible and enhances the system’s versatility. Methods First, the DFG-TDLAS system and hydrocarbon gas detection experimental setup are established. The DFG-TDLAS system includes a 1060 nm ECDL, a 1582 nm DFB laser, a WDM fiber coupler, and a PPLN module. This system can achieve 3250-3400 nm laser output with a resolution of 0.01 cm-1. The hydrocarbon gas detection experimental system includes a high-temperature absorption chamber and a heating chamber. The absorbed laser signal is collected from the high-temperature chamber. Samples are heated in the chamber, and the gas produced during the decomposition process is collected. Second, the DFG-TDLAS output laser is employed to measure the absorption spectra of seven hydrocarbon molecules, including C1-C4 hydrocarbons and benzene. Standard hydrocarbon gases are measured at different temperatures and volume fractions to establish the absorption spectra database. The coal is heated to 623 K in the heating chamber, and the resulting gases from thermal decomposition are measured in the high-temperature chamber. The DFG-TDLAS system and hydrocarbon absorption spectra databases are used for qualitative analysis. Results and Discussions During the detection of standard hydrocarbon gases, the pressure in the high-temperature absorption chamber is maintained at 0.1 MPa, and the detection temperatures are 298, 423, 523, 623, and 723 K (Fig. 3). Hydrocarbon gas absorption is also measured at different

关键词： Absorption spectroscopy

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Influence of dolomite additive on the ash fusion and potassium fixation characteristics of rice straw

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Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology 2020年第7期48卷 795-803页

作者： Yu, Zhi-Hao Jin, Jing Zhang, Rui-Pu Zhao, Bing Zhu, Yi-Zhou Wang, Guang-Xu School of Energy and Power Engineering University of Shanghai for Science and Technology Shanghai200093 China Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering Shanghai200093 China

The influence of dolomite as an additive on the slagging and potassium fixation characteristics of rice straw upon burning was investigated in a tube furnace;the slagging mechanism as well as the interaction between the rice straw ash and dolomite were explored by using the inductively coupled plasma optical emission spectrometry (ICP-OES) and X-ray diffraction (XRD). The results show that the slagging characteristics of rice straw are significantly influenced by adding 5% dolomite. Dolomite can greatly improve the potassium fixation ability, especially at 900-1000℃;moreover, the Mg and Ca elements rich in dolomite can react with SiO2 in the rice straw ash, forming high-melting silicate minerals including diopside, monticellite and merwinite. © 2020, Science Press. All right reserved.

关键词： Dolomite

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Shale oil redistribution-induced flow regime transition in nanopores

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Energy 2023年 282卷

作者： Hai Sun Tianhao Li Zheng Li Dongyan Fan Lei Zhang Yongfei Yang Kai Zhang Junjie Zhong Jun Yao Key Laboratory of Unconventional Oil & Gas Development (China University of Petroleum (East China)) Ministry of Education Qingdao 266580 PR China Research Center of Multiphase Flow in Porous Media School of Petroleum Engineering China University of Petroleum (East China) Qingdao 266580 PR China State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Chengdu University of Technology Chengdu 610059 PR China

The previous neglect of shale oil multi-component characteristics and the nanpore wall properties of real shale result in an insufficient understanding of shale oil flow mechanisms in nanopores . Meanwhile, research on the flow regimes of shale oil remains lacking. In this study, molecular dynamics simulations are employed to investigate the flow of shale oil in hydroxylated quartz nanopores and rough kerogen nanopores. Simulation results show that the flow regime changed as the pressure gradient (∇ p ) increased to a critical value (∇ p c ). The velocity profile was parabolic when ∇ p < ∇ p c , but gradually became piston-like when ∇ p ≥ ∇ p c . Because increasing ∇ p leads the adsorbed molecules desorbing, aggregating in the pore center, and forming clusters that are not easy to shear. Increasing vertical force from pore wall causes fluid aggregation in the pore center as ∇ p increases. The ∇ p c in kerogen nanopores is larger than that in quartz nanopores due to the rough kerogen surface and sticky layers. Multi-component fluids have higher ∇ p c than single-component fluids in quartz nanopores. However, they have the same ∇ p c in kerogen nanopores due to the rough kerogen surface. This investigation can provide theoretical basis for high-efficient production of shale oil.

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