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Honeycomb-like biochar framework coupled with Fe_(3)O_(4)/FeS nanoparticles as efficient heterogeneous Fenton catalyst for phenol degradation

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Journal of Environmental Sciences 2024年第2期136卷 390-399页

作者： Aihua Cheng Yi He Xiaohe Liu Chi He Department of Environmental Engineering College of Geology and EnvironmentXi’an University of Science and TechnologyXi’an 710054China State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power EngineeringXi’an Jiaotong UniversityXi’an 710049China National Engineering Laboratory for VOCs Pollution Control Material and Technology University of Chinese Academy of SciencesBeijing 101408China

Achieving an efficient and stable heterogeneous Fenton reaction over a wide pH range is of great significance for wastewater ***,a pollen-derived biochar catalyst with a unique honeycomb-like structure,coupled with the dispersion of magnetic Fe_(3)O_(4)/FeS(Fe/S)nanoparticles,was synthesized by simple impregnation precursor,followed by *** prepared Fe/S-biochar catalyst demonstrated outstanding phenol degradation efficiency across a wide pH range,with 98%of which eliminated even under neutral conditions(pH 7.0).The high catalytic activity was due to the multilevel porous structure of pollenderived biochar provided enough active sites and allowed for better electron transfer,then increases oxidation ability to promote the ***,the acid microenvironment formed by SO_(4)^(2-)group from Fe/S composite extended the pH range for Fenton reaction,and S^(2-)facilitated the conversion of≡Fe^(3+)to≡Fe^(2+),resulting in remarkable degradation ***,biochar can effectively promote cycling stability by limiting Fe *** work may provide a general strategy for designing 3D framework biochar-based Fe/S catalysts with excellent performance for heterogeneous Fenton reactions.

关键词： Biomass Biochar Fenton reaction Fe_(3)O_(4)/FeS(Fe/S) Phenol degradation

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Multi-objective optimization of 200 kW air centripetal turbine based on artificial neural networks

International Journal of Advanced Nuclear Reactor Design and...

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International Journal of Advanced Nuclear Reactor Design and Technology 2025年第2期7卷 70-80页

作者： Wang, Zideng Zhang, Yan Leng, Yuyang Lai, Jiabao Wang, Zhenzhen Chen, Weixiong State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China

The air-Brayton cycle has the characteristics of safety and high efficiency, which can be used as an energy conversion system for mobile small reactors. The air turbine is one of the key components in the cycle system, and improving its performance is of great significance. In this paper, an artificial neural network model combined with a genetic algorithm was used to optimize the rotor of an air centrifugal turbine with axial thrust and efficiency as the objective. The results show that the artificial neural network model can fit the CFD numerical simulation results well, with a coefficient of determination larger than 0.97. Then, after optimizing the artificial neural network model with a genetic algorithm, the total -total efficiency of the air centrifugal turbine was improved by 1.479 %, while the axial thrust was reduced by 1.07 %. © 2025 Xi'an Jiaotong University

关键词： Genetic algorithms

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Bubble oscillation and effects of dynamic behaviors on forces and mass transfer in photoelectrochemical water splitting

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Physical Review Fluids 2024年第11期9卷 114305-114305页

作者： Yonglu She Qiang Xu Tengfei Nie Xinyi Luo Mengsha Wang Xingmiao Ye Dengwei Jing State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

The evolution and coverage of bubbles resulting from gas evolution at the reaction interface significantly impact mass transfer and the flow field within the photoelectrochemical water splitting system, posing a significant obstacle to overcoming the efficiency bottleneck of photoelectrochemical water splitting. In situ bubble observation can be realized via a coupled experimental system combining electrochemical measurements and high-speed imaging. The results indicate that bubble growth behavior correlates with system temperature and operating voltage; that is, the bubbles grow in an oscillating state on the electrode surface at the low operating voltage and high system temperature. Besides, the deviation amplitude of oscillating bubbles increases with system temperature yet decreases with operating voltage. The results indicate that the time coefficient of the growing bubble decreases, while the growth rate and gas evolution efficiency of the bubble increase with the increase of oscillating amplitude in the horizontal direction. The study of dynamic behaviors between the oscillating bubble and the contacted electrode reveals that the bubble oscillation is characterized by the periodic contraction and extension of the triple line. The mass transfer model of concentration boundary layer and the force model of oscillating bubble are constructed based on the interaction between the bubbles and the surrounding flow field. The mass transfer model has considered the microconvection caused by single-phase natural convection, gas-liquid interface expansion, and the oscillation of bubbles. Then through the force balance model, the solutal Marangoni force is found to gradually increase as the contact line extends outward.

关键词： Bubble dynamics Contact line dynamics Marangoni convection Microbubbles multiphase flows

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Study on startup characteristic of a supercritical carbon dioxide Brayton cycle coupled with heat pipe cooled reactor 20

Study on startup characteristic of a supercritical carbon di...

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20th International Topical Meeting on Nuclear Reactor Thermal Hydraulics, NURETH 2023

作者： Wang, Zheng Zhang, Minghui Xu, Shihao Gou, Junli Shan, Jianqiang State Key Laboratory of Multiphase Flow in Power Engineering School of Nuclear Science and Technology Xi'an Jiaotong University Shaanxi Xi'an China

ISBN: (纸本)9780894487934

Nuclear energy is a viable choice for Unmanned Undersea Vehicles (UUVs) due to its high density and long operation life. However, traditional PWRs aren't suited to underwater working environments. To provide a safe and reliable power source for UUV, a new nuclear power plant coupled with the supercritical CO2 Brayton cycle and heat pipe cooled reactor is proposed. This provides the advantages of high reliability, high safety and high expansion ability. In this work, a simulation code for the new nuclear power plant is developed, which includes a reactor kinetics model, a core heat conduction model, a two-dimensional heat pipe network model, and a closeCO2 Brayton cycle model. In order to verify the accuracy of the model, the date of the experiment is compared with the model. And the design value of the new nuclear power plant has been modeled by this code. Meanwhile, the control strategies for start-up of the new nuclear power plant are proposed, including core startup, heat pipe startup and supercritical carbon dioxide Brayton loop startup. By utilizing the control strategies, the code has researched the operational characteristics of the start-up of heat pipe-cooled reactors. The development of this code provides a reference for the new nuclear power plant. © 2023 Proceedings of the 20th International Topical Meeting on Nuclear Reactor Thermal Hydraulics, NURETH 2023. All rights reserved.

关键词： Brayton cycle

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Effect of H2/CO ratio on non-isothermal reduction behavior and kinetics of vanadium titanomagnetite

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International Journal of Hydrogen Energy 2025年 139卷 69-79页

作者： Shi, Jian Xu, Qiang Lu, Xuyang Cao, Zeshui Kang, Haopeng Chen, Bin Guo, Liejin State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China

Hydrogen-based direct reduction of vanadium titanomagnetite is crucial for developing clean and efficient hydrogen metallurgy technology, while existing studies lack systematic research on the impact of H2/CO ratios on the reduction of vanadium titanomagnetite under non-isothermal conditions. This study examines the influence of varying H2/CO ratios on the non-isothermal reduction behavior and kinetics of vanadium titanomagnetite through thermogravimetric analysis (TGA). The results of thermogravimetric experiments show that raising the H2 ratio can significantly lower the initial reduction temperature and accelerate the reduction rate. When H2/(H2+CO) rises from 0 to 1, the initial reduction temperature can be lowered by around 150 °C at a heating rate of 10 °C/min. As the heating rate decreases, the reduction curve shifts to the low-temperature region, and the reduction reaction becomes easier to proceed. The vanadium titanomagnetite reduction activation energy was calculated using the Kissinger-Akahira-Sunose (KAS) and Flynn-Wall-Ozawa (FWO) model-free kinetic methods, and the activation energy of vanadium titanomagnetite reduction under pure CO atmosphere (H2/(H2 + CO) = 0) was the highest (120.74 kJ/mol by FWO and 107.82 kJ/mol by KAS). As the H2/(H2+CO) ratio increases, the activation energy continuously decreases, effectively reducing the reduction energy barrier of vanadium titanomagnetite. In contrast to an environment of pure CO, the activation energy for the reduction of vanadium titanomagnetite was reduced by 25.47 % (FWO method) or 28.73 % (KAS method) in a pure H2 atmosphere (H2/(H2 + CO) = 1), indicating that an elevated H2 ratio significantly enhanced the reduction of vanadium titanomagnetite. XRD analysis showed that, after the non-isothermal reduction, unreduced iron oxide was still present within the vanadium titanomagnetite under a pure CO atmosphere, while the final reduction product was mainly metallic iron under different H2/CO ratios. Increas

关键词： Activation energy

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Experimental investigation of nano-particle deposited wick Structure's heat transfer characteristics

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International Journal of Advanced Nuclear Reactor Design and Technology 2022年第4期4卷 196-204页

作者： Han, Ruiyu Wang, Zetao Guo, Kailun Wang, Chenglong Zhang, Dalin Tian, Wenxi Qiu, Suizheng Su, Guanghui School of Nuclear Science and Technology Shaanxi Key Laboratory of Advanced Nuclear Energy and Technology State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China

Recently, nanotechnology attracts more and more attention in heat transfer system. Many studies have shown that using nanofluid as the working fluid can improve the thermal performance of the heat pipe. In this paper, the preliminary effort of applying nano-surface engineering on the heat pipe wick to fabricate the nano-structured wick structure has been carried out. Experimental investigation has been performed to determine the effect of the heat source power, mesh aperture and the wick surface structure on the total thermal resistance of the wick structure. When the heat source power increased from 20 W to 30 W, then to 50 W, the evaporation resistance decreases 25.9% and 13.7% respectively, while the conduction resistance increases 24.8% at first and then decreases 9.5%. The evaporation resistance is less with than without the wick structure, and it increases with the increase of mesh aperture. When the mesh aperture increases from 75 μm to 150 μm, then to 460 μm, the evaporation resistance increases 1.9% and 1.7% respectively. Whereas, the wick structure, as well as the mesh aperture have slight influence on the conduction resistance. The experimental results suggest that the nano structure on the surface can efficiently decrease the evaporation resistance but increase the conduction resistance at the same time. Compared to the wick structure with smooth surface, the evaporation resistance of nano-surface deposited by 0.01% TiO2 and 0.02% TiO2 has decreased 4.3% and 15.5%, respectively. This study provides a reference for the preparation of the heat pipe with greater performance in the future. © 2022 Xi'an Jiaotong University

关键词： Wick structure Nano structure Thermal resistance

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N and O vacancies regulation over semiconductor heterojunction to synergistically boost photocatalytic hydrogen peroxide production

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Journal of Materials Science & Technology 2024年第29期196卷 237-247页

作者： Chaoqian Ai Bing Luo Chunyang Zhang Yadi Wang Baoyuan Wang Lijing Ma Dengwei Jing International Research Center for Renewable Energy&State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China School of Chemical Engineering and Technology Xi’an Jiaotong UniversityXi’an 710049China Department of Chemical Engineering School of Water and Environment&Key Laboratory of Subsurface Hydrology and Ecology in Arid AreasMinistry of Education Chang’an UniversityXi’an 710054China

Defect engineering represents a potent strategy for the modification of electronic properties by introducing atomic vacancies in ***,the synergistic enhancement attributable to different types of atomic vacancies within a heterojunction,as well as their underlying mechanisms,remains sparsely ***,the flexible g-C_(3)N_(4)materials with varying nitrogen vacancies were prepared via a facile calcination method under different atmospheric conditions and then composited with CeO_(2)nanocubes to construct Z-scheme *** was observed that CeO_(2)has abundant O vacancies,and the g-C_(3)N_(4)form tertiary nitrogen defects at the center of the heptazine units under an NH3 atmosphere *** resulting enhancement in the interfacial built-in electric field,coupled with the synergistic effect of O and N vacancies within the Z-scheme heterojunction,has been demonstrated to significantly enhance charge transfer *** results in an optimized photoactivity with a H_(2)O_(2)generation rate of 2.01 mmol g^(-1)h^(-1).This work opens an avenue for constructing and optimizing the heterogeneous photocatalysts by defect engineering technology,and provides deep insight to understand the nature of vacancy engineering in designing effective catalysts for solar energy conversion.

关键词： Photocatalysis H_(2)O_(2) production Z-scheme Defect engineering Synergy effect

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Defect-engineered WO_(x)/ZnIn_(2)S_(4)Z-scheme heterojunction boosting photocatalytic H_(2)production via photothermal coupling

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Journal of Energy Chemistry 2025年第4期103卷 9-18页

作者： Biao Wang Chunyang Zhang Shidong Zhao Shujian Wang Feng Liu Kejian Lu Yitao Si Maochang Liu International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringSchool of Energy and Power EngineeringXi’an Jiaotong UniversityXi’an 710049ShaanxiChina School of Chemistry and Chemical Engineering Southeast UniversityNanjing 211189JiangsuChina Suzhou Academy of Xi’an Jiaotong University Suzhou 215123JiangsuChina

Recent interest in photocatalytic water splitting has intensified the demand in the development of photocatalysts capable of harnessing the full *** study introduces a novel WO_(x)/ZnIn_(2)S_(4)Zscheme heterojunction,prepared by depositing ZnIn_(2)S_(4)(ZIS)nanosheets onto WO_(x)nanorods,enabling efficient photothermal-coupled photocatalytic H_(2)*** success relies on the engineered oxygen vacancies within WO_(x)nanorods,which not only confer excellent photothermal properties lowering the reaction barrier but also create defect levels in WO_(x)facilitating Z-scheme electron transfer from these levels to the valence band of ***,the optimized WO_(x)/ZIS heterojunction exhibits a remarkable H_(2)evolution rate of 33.91 mmol h^(-1)g^(-1)with an apparent quantum efficiency of 23.6%at 400 *** study provides a new strategy for developing efficient Z-scheme heterojunctions with broadspectrum solar hydrogen production capabilities.

关键词： Defect-engineered Z-scheme heterojunction Photocatalytic H2evolution Photothermal coupling

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A direct polymeric carbon nitride/tungsten oxide Z-scheme heterostructure for efficient photocatalytic hydrogen generation via reforming of plastics into value-added chemicals

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Rare Metals 2024年第8期43卷 3771-3783页

作者： Rui-Zhe Wang Zhi Lin Yi-Qing Wang Kai-Ni Zhang Ge-Hong Zhang Jie Zhang Samuel S.Mao Shao-Hua Shen International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi'an Jiaotong UniversityXi'an 710049China School of Civil and Architecture Engineering Xi'an Technological UniversityXi'an 710021China Department of Mechanical Engineering University of California at BerkeleyBerkeleyCA94720USA

To promote charge transfer and separation for efficient photocatalysis,a direct Z-scheme heterostructure was constructed by coupling polymeric carbon nitride(PCN) and WO_(3).Interestingly,the obtained PCN/WO_(3)Z-scheme heterostructure could photocataly tic ally produce hydrogen and value-added chemicals(e.g.,formate and acetate) by reforming of plastic polylactic acid(PLA) in alkaline aqueous *** optimizing WO_(3) contents and reaction conditions,the obtained PCN/WO_(3)heterostructure exhibits much increased photocatalytic activity for PLA photoreforming under visible light,with hydrogen evolution rate reaching 402.90 μmol·g~(-1)·h~(-1),which is 3.5 times that of *** is revealed that the Z-scheme charge transfer between PCN and WO_(3) mainly contributes to the promoted charge separation and thus the improved photocatalytic ***,with h+and·OH experimentally evidenced as the predominant active species,a possible reaction pathway for the reforming of PLA into value-added chemicals(e.g.,formate and acetate)over PCN/WO_(3) Z-scheme heterostructure is cleared by monitoring the reaction intermediates and *** work paves a carbon neutrality and scalable route toward the synergistical production of hydrogen and value-added chemicals by utilizing and recycling plastic waste.

关键词： Carbon nitride Z-scheme heterojunction Plastic waste conversion Photocatalytic H_(2)production Value-added chemicals

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Preliminary study on FROBA-SCO2 with transient models and its application for Reactivity Initiated Accident and loss of flow accident

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International Journal of Advanced Nuclear Reactor Design and Technology 2022年第3期4卷 101-108页

作者： Yang, T.A. Zhang, K. Yang, H.K. Tian, W.X. Qiu, S.Z. School of Nuclear Science and Technology Shaanxi Key Laboratory of Advanced Nuclear Energy and Technology State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China

As a coolant enabling the reactor with a high efficiency and low volume, the supercritical CO2 has becoming a hot topic nowadays. However, the fuel rod behaviors under accidents are not studied thoroughly, especially the interaction between the coolant and the cladding. With the previous study of fuel rod behaviors analysis of supercritical CO2 cooled nuclear reactor under steady state operation, transient state models are implemented and the upgraded code can be used to predict the fuel rod behaviors under RIA and LOFA. After the comparation of the calculation results with SACOS-SCO2, the tendency and numerical value are close, so the accuracy is warranted. The upgraded FROBA-SCO2 is used to predict the fuel rod behaviors under RIA and LOFA conditions and the results indicate that the maximum temperature of cladding and fuel is within safety limits. © 2022

关键词： Coolants

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