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Effect of ammonium ion on the corrosion behavior of Ni 2 FeCrMo 0.2 high-entropy alloy in simulated haze solution

Journal of Materials Research and Technology 2025年 37卷 146-156页

作者： Kai Wang Qilong Zhao Yanhui Li Ruidong Li Qipeng Xu State Key Laboratory of Eco-hydraulics in Northwest Arid Region Xi'an University of Technology No.5 Jinhua South Road Xi'an 710048 China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University No.28 Xianning West Road Xi'an 710049 China School of Chemical Engineering Northwest University No.229 Taibai North Road Xi'an 710069 China

Various constituents of PM 2.5 in haze can accelerate metal corrosion, but traditional carbon steel and stainless steel perform poorly in such complex corrosive environments, and thus developing new corrosion-resistant materials are of great importance for mitigating haze-induced corrosion. The corrosion behavior of Ni 2 FeCrMo 0.2 alloy in haze-simulating aqueous solutions containing various constituents of PM 2.5 in haze is investigated. By the coupling analysis of electrochemical experiments, corrosion morphology, and corrosion product film, the influence of NH 4 + concentration on the corrosion mechanism related to multi-principal metal elements is revealed. The results show that the Ni 2 FeCrMo 0.2 alloy exhibits superior corrosion resistance compared with 2205 duplex stainless steel. As the NH 4 + concentration increases, the corrosion rate increases initially but then decreases at higher NH 4 + concentrations, and the corrosion morphology also confirms this changing trend. The corrosion prompt is primarily due to the lower solution pH caused by the hydrolysis reaction of NH 4 + . In contrast, the corrosion inhibition at higher NH 4 + concentration is attributed to the passive film on the alloy surface, which is composed of Cr, Fe, Mo, Ni, and their oxides, with the presence of Mo elements forming a unique structure that improved the density and stability of the film, thereby inhibiting the growth of corrosion pits. The changing trend of corrosion film resistance and corrosion product film thickness agrees well with this change in corrosion rate. This study provides an insightful understanding of the corrosion behavior of multi-principal alloy materials in haze environments, which is crucial for the corrosion protection design of metal equipment materials.

关键词： Haze constituents Corrosion High entropy alloy Passive film

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The blow-off and transient characteristics of co-firing ammonia/methane fuels in a swirl combustor 38th

The blow-off and transient characteristics of co-firing ammo...

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38th International Symposium on Combustion, 2021

作者： Zhang, Meng Wei, Xutao Wang, Jinhua Huang, Zuohua Tan, Houzhang State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China MOE Key Laboratory of Thermo-Fluid Science and Engineering Xi'an Jiaotong University Xi'an 710049 China

Recent studies have demonstrated that ammonia could be one of the most promising hydrogen carrier candidates which can be used in large-scale power plants. However, it is challenging to burn ammonia in gas turbines due to its narrow flame stabilization limits. In this study, the blow-off characteristics and flame macrostructure transition behavior of ammonia/air flame (NH₃ flame) and ammonia/methane/air flame (50%NH₃ flame) in a swirl combustor were investigated. Flame structures and flow fields near the blow-off limit were analyzed. Methane/air flame (CH₄ flame) was also examined for comparative purposes. The flow field and instantaneous OH profile were measured with PIV and OH-PLIF technique, respectively. Large eddy simulation (LES) was conducted to extend the understanding of the experimental findings. Results revealed that the NH₃ flame possesses a poor lean flame stability limit which can be largely extended by adding CH₄ in the fuel. Changing swirl number (S) had no apparent effect on the lean blow-off limit (Φ_b) for the NH₃ flame. On the contrary, a clear extension on Φ_b was found for the 50%NH₃ flame when increasing S. Four flame macrostructure modes were identified when decreasing equivalence ratio (Φ). The transition from flame II to flame III ((Φ_tdescribes the transition equivalence ratio) can be considered as the early warning of blow-off for a swirl stabilized flame. For the NH₃ flame, there was no clear flame macrostructure transition at small inlet velocities (U < 3.8 m/sec), i.e., Φ_b ≈ Φt. The difference between Φ_b and (Φ_twas observed as the inlet velocity increased. However, for the 50%NH₃ and CH₄ flames, a clear flame macrostructure transition from flame II to flame III was observed even for a lower inlet velocity. The LES results demonstrated that the NH₃ flame h

关键词： Ammonia

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Operational Flexibility Analysis of 1100 MW Supercritical Coal-Fired Power Plants during Load Cycling Transient Processes

Operational Flexibility Analysis of 1100 MW Supercritical Co...

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IEEE Asia Power and Energy Engineering Conference (APEEC)

作者： Lu Chen Dengliang Wang Jie Ma Yongliang Zhao Weixiong Chen State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University China Energy Engineering Group Northwest China Electric Power Test Research Institute Co. LTD Xi’an China State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an China Ulatt Power Plant of Northern United Power Co. Ltd Bayannur

Operational flexibility of the coal-fired power plants must be improved so as to deal with the unpredictability of renewable energy in the future. In this study, a 1100 MW supercritical coal-fired power plant was selected, and dynamic simulation model of the unit was established via GSE software. Moreover, control model was added. Dynamic response characteristics of key thermal parameters under different power ramp rates in the region of 30%-100% THA was obtained. The cumulative standard coal consumption rate and integral absolute error were selected as the economic evaluation index of the thermal system. The results show that the maximum power ramp rate of the unit in each region during loading up is smaller than that during loading down. In the loading down process, the standard coal consumption rate of the unit firstly decreases with the reduction of output power. When the load of the unit drops to the target load, the standard coal consumption rate rises to a stabler stage. The process of loading up is the contrary. The cumulative standard coal consumption rate of coal-fired power plant is the lowest, only 275 g•(kW•h) -1 during the loading down process of 100%-75% THA. However, the cumulative standard coal consumption rate is the highest, reaching 311 g(•kW•h) -1 during the loading up process of 30%-50% THA. Due to the output power of the unit fluctuating greatly, the integral absolute error of the unit is much higher than that of other load cycling transient processes during the loading up process of 50%-75% THA and 30%-50% THA. It can be concluded that the loading up process of the unit is more difficult to control stably. This study can provide sufficient theoretical and data guidance for improving the operational flexibility of the coal-fired power plants.

关键词： Economics Fluctuations Loading Process control Coal Software Transient analysis

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Influence of Bentonite on Copper Corrosion in Simulated Repository Electrolyte

SSRN

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SSRN 2024年

作者： Ning, Zhiyuan Zhou, Qulan Li, Na Macdonald, Digby D. State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China Departments of Nuclear Engineering and Materials Science and Engineering University of California at Berkeley BerkeleyCA94720 United States

The impact of bentonite on the corrosion of oxygen-free copper (OF-Cu) and oxygen-free phosphorous copper (OFP-Cu) in prototypical groundwater environments (standard reference electrolyte, SRE) simulating the storage of copper High-Level Nuclear Waste (HLNW) cannisters in granitic rock repositories is explored. At low corrosion potentials (-0.1VSCE), bentonite suppresses copper corrosion in SRE through the anion-exclusion effect, with its inhibitory impact intensifying at higher bentonite concentrations. As the corrosion potential rises, bentonite’s enhanced adsorption of metal cations increases the corrosion current. Additionally, bentonite hydrolysis producing silicate ions that accelerates pitting corrosion, culminating in passive film breakdown. This dual mechanism may amplify intergranular corrosion. In environments where bentonite exacerbates corrosion, OFP-Cu demonstrates superior corrosion resistance, though the introduction of phosphorus may influence the acceleration of intergranular corrosion following passivity breakdown. © 2024, The Authors. All rights reserved.

关键词： Bentonite

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Influence of Bentonite on Copper Corrosion in Simulated Repository Electrolyte

SSRN

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SSRN 2024年

The impact of bentonite on the corrosion of oxygen-free copper (OF-Cu) and oxygen-free phosphorous copper (OFP-Cu) in prototypical groundwater environments (standard reference electrolyte, SRE) simulating the storage of copper High-Level Nuclear Waste (HLNW) cannisters in granitic rock repositories is explored. At low corrosion potentials (-0.1V), bentonite suppresses copper corrosion in SRE through the anion-exclusion effect, with its inhibitory impact intensifying at higher bentonite concentrations. As the corrosion potential rises, particularly beyond the "bell-shaped" region in the polarization curve, bentonite's enhanced adsorption of metal cations increases the corrosion current. Additionally, bentonite hydrolysis producing silicate ions that accelerates pitting corrosion, culminating in passive film breakdown. This dual mechanism may amplify intergranular corrosion. In environments where bentonite exacerbates corrosion, OFP-Cu demonstrates superior corrosion resistance, though the introduction of phosphorus may influence the acceleration of intergranular corrosion following passivity breakdown. © 2024, The Authors. All rights reserved.

关键词： Copper corrosion

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Effect of Fuel System on the Heat Releasing Method and flow-Path Design of Rocket-Based Combined Cycle Engine

Effect of Fuel System on the Heat Releasing Method and Flow-...

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International Conference on Mechanical and Aerospace Engineering (ICMAE)

作者： Xiao Liu Yinhu Wang Yiyan Yang Lei Shi Dekun Yan State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an China Beijing Institute of Long March Vehicle Beijing China Science and Technology on Combustion Internal Flow and Thermal-structure Laboratory Northwestern Polytechnical University Xi’an China

Multi-components rocket-based combined cycle (RBCC) engine is widely applied in most two-stage-to-orbit program due to stable operation performance under variable flight conditions. Present researches numerically compared RBCC’s performance under ramjet mode and scramjet mode, respectively, by using two fuel system, hydrogen and kerosene together with a $\mathrm{k}-\omega$ SST turbulence model. Researches showed that the combustor area ratio should be increased to keep stable pressure difference balance between inflow and flame because of higher caloric value using hydrogen. Distributed heat addition method is benifit for overall performance improvement when using hydrogen. Different from using kerosene, head should be delayedly added in combustor downtream under scramjet mode. Moreover, the advanced heat addition amount should be decreased under ramjet mode to ensure effective isolator operation.

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Analysis of Gas-Cooled Micro Modular Reactor (MMR) Fuel

SSRN

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SSRN 2024年

作者： Deng, Chaoqun Zhu, Siyang He, Yanan Wu, Yingwei He, Kai Zhang, Jing Su, Guanghui School of Nuclear Science and Technology Shaanxi Key Laboratory of Advanced Nuclear Energy and Technology State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi’an710049 China China Nuclear Power Engineering Co. Ltd. Beijing100840 China

The gas-cooled micro modular reactor (MMR) is a novel concept with compact fuel form consists of thousands of tri-isotropic fuel (TRISO) particles dispersed in silicon carbide matrix. The MMR fuel is high volume packing fraction and horizontally placed within graphite channels. Due to the complexity of the fuel structure and the challenges involved in simulation, a multi-scale and multi-physics coupled analyses method of MMR fuel was realized in this work by implementing physical models into the open-source finite element platform MOOSE. Though the simulation of the typical design MMR fuel during normal operation, the thermal-mechanical analysis and the failure analysis were conducted. The results show that the arrangement of MMR fuel horizontally within graphite channels resulted in non-uniform gap between the fuel and graphite brick, leading to an "off-center" temperature distribution within the fuel, the peak temperature is about 1314 K. Higher-temperature sub-zones exhibit greater internal pressure within TRISO and show greater tensile stress in the Chemical Vapor Deposited Silicon Carbide (CVD-SiC) layer. Regarding fuel failure analysis, this work found limited impact from Pd penetration and kernel migration. Pressure-induced particle failure, closely linked with stress in CVD-SiC, emerges as the primary failure criterion. The overall probability of fuel failure remains relatively low, with a maximum probability of 4.1×10-5. Statistical data reveals that a significant majority (71%) of TRISO particles exhibit a failure probability below 2×10-5, while only 8.8% reach 4×10-5 © 2024, The Authors. All rights reserved.

关键词： Graphite

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Preliminary Conceptual Design with Neutronics and Thermal-Hydraulics Assessments of Fustar

SSRN

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SSRN 2023年

作者： Zhou, Xingguang Zhang, Dalin Li, Xinyu Lv, Xindi Jiang, Dianqiang Tian, Wenxi Qiu, Suizheng State Key Laboratory of Multiphase Flow in Power Engineering Shaanxi Key Lab. of Advanced Nuclear Energy and Technology School of Nuclear Science and Technology Xi'an Jiaotong University Xi'An710049 China

The fluoride-salt-cooled high-temperature advanced reactor (FuSTAR) is an advanced small modular reactor, which aims to the electric supplement and clean heat production to western China. In this study, neutronics and thermal-hydraulics analysis are also carried out, and established the core layout and material ratio under the near-critical condition. The parameters of the designed core are evaluated quantitatively from various aspects. The results show that FuSTAR has sufficient shutdown depth, the equilibrium cycle is 3.24 years, and the discharge burnup depth is 106 GWd/MtU. The analysis of 1/6 core porous media shows that the peak fuel temperature under normal operating condition is 1009.3 K, which is far below the limit of 1573 K. Relevant design and analysis results can provide the reference for the subsequent small modular FHR design and construction. © 2023, The Authors. All rights reserved.

关键词： Computational fluid dynamics

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Development of a Two-Phase flow Solver with Drift-Flux Model Based on Openfoam: Validation Against Single/Two-Phase and Boiling flow

SSRN

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SSRN 2024年

作者： Wu, Wenqiang Zhang, Dalin Huang, Tao Du, Peng Zhou, Lei Wang, Bo Deng, Jian Qiu, Zhifang Tian, Wenxi Qiu, Suizheng Su, Guanghui State Key Laboratory of Multiphase Flow in Power Engineering Shaanxi Key Laboratory of Advanced Nuclear Energy and Technology School of Nuclear Science and Technology Xi’an Jiaotong University Shaanxi Xi’an710049 China Nuclear Power Institute of China 328 Changshun Avenue Chengdu610213 China

Based on the open-source platform OpenFOAM, this paper implements a two-phase flow solver for drift flux models with realistic closure relations. The solver inherits the numerical method from the OpenFOAM framework, adopts the PIMPLE algorithm, and follows its discrete and matrix-solving criteria, focusing on developing a two-phase flow model and constitutive models. The drift velocity model is based on Ishii and his collaborators’ work. The remaining models, such as wall friction, wall heat transfer, interfacial heat and mass transfer, are taken from TRACE Theory Manual. To fulfill the condition of conjugate heat transfer between fluid and solid, a virtual solid heat transfer function is developed under the premise of a single-domain solver. Extensive and successful validation has been conducted involving single-phase, two-phase, and boiling flow heat transfer phenomena by comparing with experimental data or typical system codes, and the two-phase flow solver's success has been demonstrated in several aspects. © 2024, The Authors. All rights reserved.

关键词： Two phase flow

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Integrated Co2 Capture and Conversion by Three-Step Chemical Looping Dry Reforming of Methane

SSRN

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SSRN 2025年

作者： Liu, Yunlian Liu, Mingkai Shen, Yuanhui Li, Yang Gai, Zhongrui Zhang, Ruqi Pan, Ying Jin, Hongguang Institute of Engineering Thermophysics Chinese Academy of Sciences Beijing100190 China University of Chinese Academy of Sciences Beijing100049 China State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

The integrated CO2 capture and conversion (ICCC) has emerged as a promising and cost-effective pathway for achieving carbon neutrality. However, limited energy-efficient pathways and durable materials for ICCC systems remains challenging. This study proposes a novel approach that synergistically integrates CO2 capture and conversion through a unified chemical framework. The method employs Li-based sorbents for CO2 capture, coupled with CH4-driven sorbent regeneration that is seamlessly integrated with chemical looping dry reforming of methane (CLDRM), enabling in-situ CO2 conversion. By coupling sorbent regeneration with CLDRM, this system enhances decarbonation kinetics through Le Chatelier's principle via continuous CO2 conversion. One-step calcination synthesized Li-based sorbents particles exhibit stable CO2 capture capacity of 5.25 mmol·g-1 within 15 min per cycle, maintaining 7.5-15% operational efficiency over 40 cycles at 600 ℃. In CLDRM, hydrogen radicals from CH4 dissociation promote the conversion of CO2 to intermediates, lowering the apparent activation energy of sorbents regeneration by 29.2%. Through systematic optimization in a fixed-bed reactor, we achieved 90% CO2 uptake and 85% CH4 conversion, with syngas production rates reaching 13.71 mL·min-1·g-1. Notably, the H2/CO molar ratio in syngas stabilizes ~1.6, aligns with iron-based Fischer-Tropsch and methanol synthesis to produce valuable fuels. This integrated system maintains >80% syngas purity with © 2025, The Authors. All rights reserved.

关键词： Activation energy

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