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Modulating conductivity type of cuprous oxide（Cu2O） films on copper foil in aqueous solution by comproportionation

Journal of Materials Science & Technology 2019年第8期35卷 1570-1577页

作者： Changwei Tang Xiaohui Ning Jian Li Hui-Lin Guo Ying Yang Shaanxi Provincial Key Laboratory of Electroanalytical Chemistry Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of EducationCollege of Chemistry & Materials ScienceNorthwest UniversityXi'an 710127 China National Demonstration Center for Experimental Chemistry Education Northwest UniversityXi'an 710127 China International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi'an Jiaotong UniversityXi'an 710049 China

Cuprous oxide(Cu2O)is an attractive material for photoelectrochemical(PEC)hydrogen production or photovoltaic application,because of its appropriate band gap,low material cost and *** this paper,Cu2O films were obtained by comproportionation in acid cupric sulfate solutions with varying concentrations of potassium *** and electrochemical experiments,such as zero-bias photocurrent responses,voltammograms,and Mott-Schottky measurements,show that the Cu2O films grown in low(≤0.75 mol dm^–3)and high(≥1.00 mol dm^–3)nitrate ion concentrations presented n-type and p-type conductivity,*** circuit potential and polarization behavior were monitored to investigate the mechanism of modulating conductivity *** ions consume protons in the plating solution during comproportionation with different concentrations of nitrate ions creating different pH at the Cu2O/solution *** gradient leads to the transformation of Cu2Ofilms conductivity changing from n-type to p-type with increasing the concentration of nitrate ions in the plating *** method could be used to fabricate homojunction electrode on metal substrate for PEC hydrogen production or photoelectric application.

关键词： Cuprous oxide(Cu2O) Comproportionation Semiconductor films Tuning conductivity Photoelectrochemical cell

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A state-of-the-art review on the utilization of biochar as renewable energy for the sustainable steel industry

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Applied Energy 2025年 394卷

作者： Shan Ren Siyi Yang Hongsheng Chen Liang Wang Manyi Liu Guangwei Wang Chunbao Xu College of Materials Science and Engineering Chongqing University Chongqing 400044 China State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'an Jiaotong University Xi'an 710049 China State Key Laboratory of Advanced Metallurgy University of Science & Tech. Beijing Beijing 100083 China School of Energy and Environment City University of Hong Kong Kowloon Hong Kong

The steel industry is a major contributor to global anthropogenic CO₂ emissions, accounting for nearly 10 % of the total. Within this sector, ironmaking processes, particularly those using the traditional blast furnace-basic oxygen furnace route, are responsible for almost 90 % of the industry's CO₂ emissions. Biochar, derived from renewable feedstocks, offers a sustainable and eco-friendly alternative to fossil fuels for ironmaking. This review examines the cutting-edge techniques for producing biochar and recent advancements in utilizing biochar across various ironmaking processes, including sintering/pelletizing, coke making, blast furnace injection, and direct reduction iron processes, with a focus on reducing CO₂ emissions. Despite demonstrated benefits such as reduced pollution, improved burden permeability, and enhanced gas utilization efficiency in pilot and industrial trials, large-scale biochar application remains limited by the varying quality requirements of different processes. Innovatively, a green hydrogen-metallurgical route that utilizes hydrogen-rich syngas derived from biomass and biochar is proposed in this work, serving as a comprehensive solution to address the challenges associated with the quality discrepancies of biochar produced by different carbonization methods and the diverse quality requirements for biochar in various ironmaking processes. This solution not only underscores its potential to significantly transform the iron and steel industry towards a more sustainable and low-carbon future, but also highlights the innovative contributions of this research to the fields of renewable energy, solid waste resources, metallurgical industry, and global climate change.

关键词： Iron and steel industry

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Atomically Dispersed Co Sites on BiOCl Nanosheets for Efficient CO 2 Photoreduction

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Green Energy & Environment 2025年

作者： Ting Peng Yiduo Wang Ke Wang Kaini Zhang Yiqing Wang Yufei Xu Qingqing Guan Guofu Wang Wenjie Zhang Binglan Wu Shaohua Shen International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an 710049 China College of Chemical and Biological Engineering Zhejiang University Hangzhou 310058 China Institute of Zhejiang University-Quzhou Quzhou 324000 China

Efficient CO 2 photoreduction to produce fuel remains a great challenge, due to the fast recombination of photogenerated charge carriers and the lack of effective reactive sites in the developed photocatalysts. Herein, single Co atoms (Co SA ) were highly dispersed on hydrothermally synthesized BiOCl nanosheets (BOC) by a facile two-step electrostatic self-assembly and pyrolysis method. The obtained Co SA -BOC could be performed for efficient CO 2 photoreduction to stoichiometrically produce CO and O 2 at the ratio of 2:1, with the CO evolution rate reaching 45.93 μmol g –1 h –1 , ∼4 times that of the pristine BOC. This distinctly improved photocatalytic performance for Co SA -BOC should be benefited from the introduction of atomically dispersed Co-O 4 coordination structures, which could accelerate the migration of photogenerated charge carriers to surface by creating an impurity energy level in the forbidden band, and act as the reactive sites to deliver the photogenerated electrons to activate CO 2 molecules for CO production. This work provides a facile and reliable strategy to highly disperse single atoms on low-dimensional semiconductors for efficient CO 2 photoreduction to selectively produce CO.

关键词： photocatalysis CO 2 reduction BiOCl nanosheets single Co atoms

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Quantifying the interaction between a single kerogen molecule and shale fluids from the perspective of elements and chemical groups

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Separation and Purification Technology 2025年 362卷

作者： Huaisen Song Yongfei Yang Jinlei Wang Lei Zhang Hai Sun Junjie Zhong Kai Zhang Jun Yao State Key Laboratory of Deep Oil and Gas China University of Petroleum (East China) Qingdao 266580 Shandong PR China Center of Multiphase Flow in Porous Media School of Petroleum Engineering China University of Petroleum (East China) Qingdao 266580 Shandong PR China

During the implementation of underground H 2 storage (UHS), geological CO 2 sequestration (GCS), and CO 2 -enhanced oil recovery (CO 2 -EOR) measures in shale reservoirs, kerogen will interact with typical shale fluids (H 2 , CO 2 , shale oil and gas). These interactions will thereby affect the implementation effects of the above industrial measures. Kerogen at various maturity degrees exhibits complex interactions with shale fluids due to its different molecular structures, which are shaped by factors such as reservoir type, maturation time, and geological environment. Despite this complexity, the types of elements (C, H, O, N, and S) and chemical groups that constitute kerogen molecules are limited. In this study, we utilized molecular dynamic (MD) simulations to reveal the interaction mechanism between a single kerogen molecule and typical shale fluid (H 2 , CH 4 , Neopentane, and CO 2 ) from the perspective of component elements and chemical groups. In addition, we developed an interaction energy fitting formula to quantify these interactions without relying on MD simulations, thereby facilitating the rapid assessment of the difficulty in separating shale fluids from shale organic matter. Lastly, we proposed two simplification strategies to reduce the experimental procedures involved in constructing kerogen molecules, while allowing for a certain degree of evaluation of the interaction between kerogen and shale fluids.

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Theoretical and experimental analyses of a novel recirculated regenerative rotary desiccant wheel dehumidification system 32

Theoretical and experimental analyses of a novel recirculate...

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32nd International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems, ECOS 2019

作者： Han, Xiaoqu Wu, Wenxiang Zhou, Zhijie Wang, Yu Chong, Daotong Yan, Junjie State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an China China Ship Development and Design Center Wuhan China

ISBN: (纸本)9788361506515

The high humidity environment in the submarine cabins results in high energy consumption of the air conditioning system. Moreover, the removal of the hydrogen contained in the air, which constitutes a threat to crew’s safety, generates a huge amount of heat. It is of particular significance to reduce the humidity of the air efficiently, through recovery of the waste heat in the dehydrogenation process. Therefore, a novel recirculated regenerative desiccant wheel dehumidification system is proposed in the present work for submarine air-conditioning. The dehumidification rate was optimized through an appropriate proportion between inlet and recirculating air flows. Theoretical modeling and experimental study were carried out to explore the optimal dehumidification performance at different working conditions. The influence of process air parameters (including temperature and humidity), regeneration air parameters (including bypass ratio and regeneration air temperature) and rotary desiccant wheel parameters (including rotation speed and air flow ratio) were analyzed. It was found that the dehumidification rate could be effectively improved compared to sea water direct cooling. It increased with increasing regeneration air temperature and temperature drop. There was an optimal bypass ratio for the system, around 55%-70%, to obtain the highest dehumidification rate. The ratio increased with the regeneration air temperature. There existed an optimal rotary speed (approx. 12 r·h-1) and optimal air flow ratio (approx. 70%). Overall, the feasibility of the proposed system was validated and the dehumidification characteristics at various working conditions were demonstrated to prompt its application. © ECOS 2019 - Proceedings of the 32nd International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems. All rights reserved.

关键词： Air conditioning

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PRELIMINARY NEUTRONIC/THERMAL-HYDRAULIC AND SAFETY ASSESSMENT OF PRESSURIZED WATER REACTOR LOADED WITH FULLY CERAMIC MICROENCAPSULATED FUEL

PRELIMINARY NEUTRONIC/THERMAL-HYDRAULIC AND SAFETY ASSESSMEN...

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2020 International Topical Meeting on Advances in Thermal Hydraulics, ATH 2020

作者： Wu, Di Gui, Minyang Zhang, Dalin Wang, Chenglong Wu, Yingwei Su, G.H. Qiu, Suizheng Tian, Wenxi Yang, Hongfa Peng, Jingyang Shanxi Key Laboratory of Advanced Nuclear Energy and Technology School of Nuclear Science and Technology Xi'an Jiaotong University State Key Laboratory of Multiphase Flow in Power Engineering Xi'an710049 China Science and Technology on Reactor System Design Technology Laboratory Nuclear Power Institute of China Chengdu610213 China Nuclear and Radiation Safety Center Ministry of Ecology and Environment of the People's Republic of China Beijing100082 China

ISBN: (纸本)9780894487774

As one of the accident tolerant fuels (ATFs), fully ceramic microencapsulated (FCM) fuel shows superior safety performance in accidents, which has the characteristics of high melting point, excellent heat transfer ability and strong nuclear proliferation resistance. Based on the neutronic analysis of Chinese advanced three loop pressurized water reactor (PWR), the assemblies and cores of FCM-SiC and UO2-Zr were designed, power distributions and cycle lengths were obtained, and the power was adjusted to ensure the annual refueling requirements. By using system analysis code, station blackout (SBO) accident in FCM-SiC and UO2-Zr was analyzed, where the steam-driven auxiliary feedwater (AFW) in secondary loop failed to be supplied in time. Assuming that the AFW system couldn't be put into operation immediately after accident, the critical time could be calculated, that is to say, fuel centerline temperature (FCT) and peak cladding temperature (PCT) wouldn't exceed corresponding limits during accident once the AFW was provided within the critical time. It is found that the critical time of FCM-SiC is 9000s and higher than that of UO2-Zr (7000s), which shows the advantages of ATFs. This work could provide reference for the optimized design of the reactor safety system in the future. © ATH 2020 - International Topical Meeting on Advances in Thermal *** rights reserved.

关键词： Silicon carbide

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Numerical simulation of high temperature gas cooled reactors on less of coolant accident 18

Numerical simulation of high temperature gas cooled reactors...

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18th International Topical Meeting on Nuclear Reactor Thermal Hydraulics, NURETH 2019

作者： Zhang, Shuangbao Li, Liangxing Xie, Wei Wang, Kailin State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xianning West Road 28# Xi’an city710049 China

The high temperature gas-cooled reactor (HTR) is well known for its prominent inherent safety, high efficiency and low carbon environmental protection, which has been identified as one of the candidates for the Generation IV nuclear energy system technology. Accurate and reliable thermal hydraulic analysis is of great significance to the system design and safe operation of HTR. Based on the coolant flow and heat transfer process in the core of HTR, this study establishes a three-dimensional model by using CFD (Computational Fluid Dynamics) software firstly, and the flow and heat transfer process of helium coolant is simulate in the core. The temperature distribution of HTR is calculated at steady state, and the calculation results were compared with the related published results for validation and verification. After that, the models are employed to study the thermal hydraulic characteristics under the loss of coolant accident of HTR. The results show that as the coolant passes through the core from top to bottom, helium is continuously heated, and the temperature increases from top to bottom. The temperature reached a maximum at the core exit position of 1032.75 K. It stated that the model can be employed to simulate the thermal hydraulic analysis for HTR. The calculation results of the loss-of-coolant, indicates t as the flow rate decreases, the coolant temperature rises gradually. When the coolant is completely lost, the temperature reaches a maximum of 1723.19 K, and it is still lower than the design limit of 1893.15 K. © 2019 American Nuclear Society. All rights reserved.

关键词： Coolants

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The theoretical and numerical analysis on a multi-blade liquid lead pump 27

The theoretical and numerical analysis on a multi-blade liqu...

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27th International Conference on Nuclear Engineering: Nuclear Power Saves the World!, ICONE 2019

作者： Wang, Kailin Li, Liangxing Xie, Wei Zhang, Shuangbao State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xianning West Road 28# Xi'an city710049 China

ISBN: (纸本)9784888983051

Lead or lead-alloy cooled fast reactors (LFRs) have been proved to be the most promising Generation IV reactors with high performance in neutronics, thermal hydraulics and security features. Small forced circulation modular LFRs is one of the potential candidates for LFRs development which has attracted particular attention in recent years. When lead-bismuth eutectic (LBE) is used as coolant, the primary LBE pump is a key conveying equipment, and therefore the hydraulic performance of LBE pump is great important to the safety of LFR. Motivated by improving the hydraulics performance of LBE pump, this paper presents a theoretical and computational analysis on an axial flow pump. The guide blades are set at the outlet of the impeller to eliminate the rotational motion of the liquid LBE and transform the kinetic energy of the rotational motion into pressure energy. The rotation angle of the blade is optimized based on the theoretical analysis to reduce the vortex and raise efficiency. As well, the outlet speed and pressure parameters of each part in the pump are calculated. After that, a three-dimensional model of the modified pump is established by using CFD software and the flow characteristics of LBE in the pump are simulated. Albeit the high velocity liquid LBE alloy still exists in the side of pump shroud, some erosion-related issues remain to be fully addressed. The results of the study show that the axial LBE pump could be used as a viable solution for the design of the new generation of small module reactor primary pump from a thermo-fluid dynamic point of view. © 2018-2019 by JSME

关键词： Pumps

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Rationally Engineered Reox-Cuso4/Tio2 Catalyst with Superior Nh3-Sco Efficiency and Remarkably Boosted So2 Tolerance: Synergy of Acid Sites and Surface Adsorbed Oxygen

SSRN

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SSRN 2022年

作者： Yu, Yanke Wei, Desheng Tong, Zhaojian Wang, Jinxiu Chen, Jinsheng He, Chi Department of Environmental Science and Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an710049 China Center for Excellence in Regional Atmospheric Environment Institute of Urban Environment Chinese Academy of Sciences Xiamen361021 China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Shaanxi Xi'An710049 China National Engineering Laboratory for VOCs Pollution Control Material & Technology University of Chinese Academy of Sciences Beijing101408 China

Ammonia (NH3) is a critical component causing environmental problems like haze and water pollution. Selective catalytic oxidation of ammonia (NH3-SCO) to N2 and H2O is a promising method to abate NH3 emission. However, inferior SO2 tolerance is still a tremendous challenge to be conquered for present NH3-SCO catalysts regarding practical applications. Application of materials which was difficult to be sulfated by SO2 should be an effective pathway to solve this problem. Here, a ReOx-CuSO4/TiO2 catalyst which coupled the advantages of ReOx (Rhenium oxides, supplying highly active adsorbed surface oxygen for enhancing NH3-SCO reaction) and CuSO4 (providing Brønsted acid sites for inhibiting the formation of N2O) was rationally fabricated. Results indicated that ReOx-CuSO4/TiO2 catalyst performed excellent catalytic performance in NH3-SCO with almost 100% of NH3 oxidized at 300 °C (N2 selectivity as high as 96%). Crucially, the composite catalyst exhibited incredible activity and stability under harsh reaction conditions toward SO2 (600 ppm) and H2O (4.0 vol.%) owing to the superior inhibition capability for SO2 adsorption. In situ DRIFTS, in situ Raman and in situ XPS demonstrated that the NH3-SCO reaction over ReOx-CuSO4/TiO2 catalyst mainly obeyed a N2H4 reaction mechanism and oxidation-reduction circle between Re7+ and Re6+ played a vital role. In addition, SO2 would not affect this reaction mechanism on ReOx-CuSO4/TiO2 catalyst. The knowledge and understanding reported could provide critical insights for the design and optimization of efficient materials for industrial NH3 oxidative elimination. © 2022, The Authors. All rights reserved.

关键词： Ammonia

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Three-dimensional modeling and thermal hydraulic analysis of high temperature gas-cooled reactor core 27

Three-dimensional modeling and thermal hydraulic analysis of...

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27th International Conference on Nuclear Engineering: Nuclear Power Saves the World!, ICONE 2019

作者： Zhang, Shuangbao Li, Liangxing Xie, Wei Wang, Kailin State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xianning West Road 28# Xi'an city710049 China

ISBN: (纸本)9784888983051

The high temperature gas-cooled reactor (HTR) is an advanced reactor with the characteristics of Generation IV nuclear energy system which has attracted wide attention due to the excellent performances of inherent safety, economy, high efficiency and low carbon environmental protection. Accurate and reliable thermal hydraulic analysis is of great significance for studying the flow and heat transfer in the core of HTR. Based on the coolant flow and heat transfer process in the core of HTR, this study establishes a three-dimensional coupled model by using CFD (Computational Fluid Dynamics) software firstly, and the flow and heat transfer process of helium coolant is simulate in the core. The temperature variation in the reactor is calculated under the conditions of steady-state operation of the HTR core, and the calculation results by the present models were compared with calculated results from the benchmark software of Thermix and the related published results. The results showed that the average temperature of the outlet section is 759.6 ℃, and the maximum relative error with the published data is 1.25%. The steady-state results under the full power conditions based on the three-dimensional model are in good agreement with the calculation data from those of THERMIX. It stated that the three-dimensional model can be employed to simulate the thermal hydraulic analysis for HTR. On this basis, the heat transfer characteristics of core is simulated under 50% full power, and the are result helpful for the operation and design of HTR. © 2018-2019 by JSME

关键词： Porous materials

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