检索结果-内蒙古大学图书馆

Boosting photocatalytic hydrogen production via interfacial engineering over a Z-scheme core/shell heterojunction

Nano Research 2023年第1期16卷 352-359页

作者： Bing Luo Jinghua Li Wei Wang Chaoqian Ai Haihan Zhang Yuxin Zhao Dengwei Jing School of Chemical Engineering and Technology Xi'an Jiaotong UniversityXi'an 710049China International Research Center for Renewable Energy&State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China

Designing high efficacy photocatalysts is a promising way to improve solar fuel production *** this work,we prepared a core/shell composite of loose ZnCr layered double hydroxide nanosheets modified CdS nanorods for efficient visible light driven photocatalytic hydrogen *** highest hydrogen production rate achieved 425.8μmol·h^(−1) without adding any noble metal cocatalyst under the visible light stimulus,which is 22.4 times that of 1 wt.%Pt-modified *** corresponding apparent quantum yield is 13.9%at 420 *** is revealed that the synergistic actions of the interfacial redox shuttle of Cr^(3+)/Cr^(δ+)and the interfacial electric field enable the efficient separation of photoinduced charge carriers between two components via a Z-scheme energy band ***,with the hydrogen evolution contribution of Zn^(2+),a remarkable improvement in photocatalytic performance was achieved in contrast to bare *** work provides an effective methodology to construct highly efficient and economically viable photocatalysts for solar H_(2)production and mechanistic study.

关键词： photocatalysis heterojunction interfacial engineering noble metal free hydrogen production

来源：评论

学校读者我要写书评

暂无评论

Photochemical Systems for Solar‑to‑Fuel Production

引用

Electrochemical Energy Reviews 2022年第3期5卷 137-177页

作者： Ya Liu Feng Wang Zihao Jiao Shengjie Bai Haoran Qiu Liejin Guo International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an 710049ShaanxiChina

The photochemical system,which utilizes only solar energy and H_(2)O/CO_(2) to produce hydrogen/carbon-based fuels,is considered a promising approach to reduce CO_(2) emissions and achieve the goal of carbon *** date,numerous photochemical systems have been developed to obtain a viable solar-to-fuel production system with sufficient energy ***,more effort is still needed to meet the requirements of industrial *** this review,we systematically discuss a typical photochemical system for solar-to-fuel production,from classical theories and fundamental mechanisms to raw material selection,reaction condition optimization,and unit device/system advancement,from the viewpoint of ordered energy ***-of-the-art photochemical systems,including photocatalytic,photovoltaic-electrochemical,photoelectrochemical,solar thermochemical,and other emerging systems,are *** highlight the existing bottlenecks and discuss the developing trend of this ***,optimization strategies and new opportunities are proposed to enhance photochemical systems with higher energy efficiency.

关键词： Solar energy Photochemical Hydrogen Carbon-based fuels

来源：评论

学校读者我要写书评

暂无评论

Numerical investigation on the scale-up and optimization of coal-supercritical water fluidized bed gasification reactors for hydrogen production

引用

International Journal of Hydrogen Energy 2025年 144卷 112-123页

作者： Zhenqun Wu Guobiao Ou Hui Jin State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University China

The supercritical water fluidized bed (SCWFB) is an ideal reactor for the industrial application of the technology of coal gasification in supercritical water (SCW) for hydrogen production. To address the lack of scale-up theory for SCWFB reactors, this study develops a new coal-SCW particulate flow reaction model and performs systematic numerical investigations on the effects of reactor size scale-up (2-, 5-, and 10-fold) and operating parameters scale-up. Results demonstrate that as the reactor size increases, the high-quality fluidization characteristic of SCWFB get maintained, while coal gasification efficiency (CE) gets enhanced. At the 10-fold scale-up level, CE increases by more than 4 % compared to the original reactor, and efficient gasification can be achieved for high-concentration coal slurries (60 wt %) with the CE of 93.98 %. Moreover, through optimization of feedstock injection velocity and multi-nozzle configurations, the temperature distribution homogeneity and CE get further enhancement in scaled-up SCWFB reactors.

关键词：

来源：评论

学校读者我要写书评

暂无评论

Experimental study on flow excursion instability of supercritical hydrocarbon fuel in scramjet regenerative cooling parallel channels

引用

Chinese Journal of Aeronautics 2023年第1期36卷 201-215页

作者： Xiaoyong LIU Zhuqiang YANG Ruipu MIAO Feng LIU Shujun ZHAO Qincheng BI Beijing Power Machinery Research Institute Beijing 100074China Liaoning Key Laboratory of Complex Energy Conversion and Utilization School of Energy and Power EngineeringDalian University of TechnologyDalian 116024China State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China

flow instability of supercritical hydrocarbon fuel is a crucial issue in scramjet regenerative cooling structure. In this study, flow excursion instability and flow distribution in parallel tubes were experimentally studied for supercritical fluids. Two types of flow excursion occur in a single tube. Type Ⅰ and Type Ⅱ excursions, and they are corresponding to decreasing and increasing flow rate respectively. They can trigger flow maldistribution between parallel tubes and the hysteresis phenomenon of flow distribution. The effects of system parameters, including inlet temperature,system pressure, and heat flux, on flow distribution were analyzed. In addition, the relationship between flow excursion and the pseudo-critical interval proposed in the literature was established according to the heated tube outlet temperature at the onset of flow instability. Finally, the flow excursion instability boundary was obtained using two dimensionless parameters. These experimental results can provide helpful insight on the mechanism of Scramjet regenerative cooling.

关键词： flow distribution Ledinegg instability Onset of flow excursion Parallel channels Regenerative cooling Scramjet Supercritical flow

来源：评论

学校读者我要写书评

暂无评论

Photocatalytic water splitting on BiVO_(4):Balanced charge-carrier consumption and selective redox reaction

引用

Nano Research 2023年第4期16卷 4568-4573页

作者： Xiangjiu Guan Li Tian Yazhou Zhang Jinwen Shi Shaohua Shen International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an 710049China Suzhou Academy of Xi’an Jiaotong University Suzhou 215123China State Key Laboratory for Physical Chemistry of Solid Surfaces College of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China

Surficial redox reactions play an essential role in photocatalytic water splitting,and are closely related to the surface properties of a specific *** this work,using monoclinic BiVO_(4)decahedral single crystals as a model photocatalyst,we report on the interrelationship between the photocatalytic activity and the surficial reaction sites for charge-carrier *** controlled hydrothermal synthesis,the ratio of{010}to{110}facets on BiVO_(4),which respectively serve as reductive and oxidative sites,is carefully *** results show that superior photocatalytic water oxidation could be obtained on BiVO_(4)decahedrons with a medium ratio of reductive/oxidative sites and that efficient overall water splitting could be achieved via further modification of appropriate cocatalysts in Z-scheme *** excellent photocatalytic performance is attributed to the accelerated selective redox reactions by realizing balanced charge-carrier consumption,which provides insightful guidance for prospering photocatalytic reactions in energy conversion.

关键词： BiVO_(4) photocatalytic water splitting reactive site

来源：评论

学校读者我要写书评

暂无评论

EFFECT OF BLENDING STRAW POWDER INTO COAL GANGUE ON LOADING-UP CHARACTERISTICS OF THE CIRCULATING FLUIDIZED BED GENERATOR UNIT

EFFECT OF BLENDING STRAW POWDER INTO COAL GANGUE ON LOADING-...

引用

ASME 2024 Power Conference, POWER 2024

作者： Zhao, Chenyu Wang, Chaoyang Liu, Ming Liu, Jiping Yan, Junjie MOE Key Laboratory of Thermal Fluid Science Engineering Xi'an Jiaotong University Xi'an China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an China

ISBN: (纸本)9780791888186

To increase the contribution to the regional environment, the feasibility of blending agricultural residues was explored by a circulating fluidized bed (CFB) generator unit using coal gangue as the single fuel. In this study, straw powder was chosen to blend into the coal gangue, and the whole thermal system was built as a dynamic model based on self-programming and GSE software. Blending affects the load-increasing process from 75 % to 100 % rated power (Pe) with a load variation rate of 1 % Pe/min. With the blended fuel, the deviation of the output power was almost unchanged, and the maximum deviation of the live steam pressure was reduced by 0.04 MPa. With the blending ratios of 10 % and 20 %, the energy efficiencies of the whole unit were improved by 0.48% and 0.81%, respectively, the accumulative deviations of live steam temperature were reduced by 10.4% and 16.5%, respectively, the accumulative deviations of reheat steam temperature were reduced by 13.3% and 18.2% respectively, and the maximum deviations of bed temperature were increased to 8.9 ℃ and 9.5 ℃ respectively. The increased fluctuations in bed temperature are still far from the safe boundary, so the CFB generator unit can safely load up with the blending ratios of 10 % and 20 %. Copyright © 2024 by ASME.

关键词： Coal

来源：评论

学校读者我要写书评

暂无评论

Uncertainty analysis of molten corium In-Vessel Retention under External Reactor Vessel Cooling

引用

International Journal of Advanced Nuclear Reactor Design and Technology 2023年第4期5卷 159-167页

作者： Wu, Shihao Wang, Dong Zhang, Yapei Zhou, Yukun Tian, Wenxi Qiu, Suizheng Su, G.H. School of Nuclear Science and Technology Shaanxi Engineering Research Center of Advanced Nuclear Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China

External Reactor Vessel Cooling (ERVC) is a key measure to realize molten corium In-Vessel Retention (IVR). The uncertainty of severe accident in core leads to the uncertainty of molten pool parameters in lower head, which may threat the reliability of successful implementation of IVR. In this study, an uncertainty analysis is employed to ensure the reliability of ERVC technology to IVR with the final two-layer molten pool configuration of AP1000.600 simulations are performed to determine the effect of five key parameters. As long as parameters are within high probability density range, lower head can remain intact, and safety margin is greater than 15 %. For influence level and correlation of parameters, the order on metal layer is: Decay heat > Fe mass > UO2 mass > Zr oxidation fraction > Emissivity of metal layer. The results can provide guidance for subsequent research direction and optimal design of mitigation measures. © 2024 Xi'an Jiaotong University

关键词： Uncertainty analysis

来源：评论

学校读者我要写书评

暂无评论

Thermal-Hydraulic Calculation and Analysis on Evaporator System of a 1000 MW Ultra-Supercritical Pulverized Combustion Boiler with Double Reheat

引用

Journal of Thermal Science 2021年第3期30卷 807-816页

作者： WAN Li YANG Dong ZHOU Xihong DONG Le LI Juan State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China

A double reheat ultra-supercritical boiler is an important development direction for high-parameter and large-capacity coal-fired power plants due to its high thermal efficiency and environmental *** has developed a 1000 MW double reheat ultra-supercritical boiler with steam parameters of 35 MPa at 605℃/613℃/613℃.Reasonable water wall design is one of the keys to safe and reliable operation of the *** order to examine the thermal-hydraulic characteristics of the double reheat ultra-supercritical boiler,the water wall system was equivalent to a flow network comprising series-parallel circuits,linking circuits and pressure nodes,and a calculation model was built on account of the conservation equations of energy,momentum and *** the iterative solving of nonlinear equations,the prediction parameters of the water wall at boiler maximum continue rate(BMCR),75%turbine heat-acceptance rate(THA)and 30%THA loads,including total pressure drops,flow distribution,outlet steam temperatures,fluid and metal temperatures were *** results of calculation exhibit excellent thermal-hydraulic characteristics and substantiate the feasibility of the water wall design of the double reheat ultra-supercritical boiler.

关键词： double reheat ultra-supercritical boiler water wall flow network method thermal-hydraulic characteristic

来源：评论

学校读者我要写书评

暂无评论

TiO_(2) nanorods based self-supported electrode of 1T/2H MoS_(2) nanosheets decorated by Ag nano-particles for efficient hydrogen evolution reaction

引用

Chinese Chemical Letters 2023年第11期34卷 355-359页

作者： Changzheng Lin Yunpeng Liu Yaxing Sun Zhenyu Wang Hao Xu Mingtao Li Jiangtao Feng Bo Hou Wei Yan Department of Environmental Science&Engineering Xi’an Jiaotong UniversityXi’an 710049China School of Physics and Astronomy Cardiff UniversityThe ParadeCardiffCF243AAWalesUnited Kingdom State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China International Research Center for Renewable Energy(IRCRE) State Key Laboratory of Multiphase Flow in Power Engineering(MFPE)Xi’an Jiaotong UniversityXi’an 710049China

Molybdenum disulfide(MoS_(2))has shown significant promise as an economic hydrogen evolution reaction(HER)catalyst for hydrogen generation,but its catalytic performance is still lower than noble metalbased ***,a silver nanoparticles(Ag NPs)-decorated 1T/2H phase layered MoS_(2) electrocatalyst grown on titanium dioxide nanorod arrays(Ag NPs/1T(2H)MoS_(2)/TNRs)was prepared through acid-tunable ammonium ion *** advantage of MoS_(2) layered structure and crystal phase controllability,as-prepared Ag NPs/1T(2H)MoS_(2)/TNRs exhibited ultrahigh HER ***-proposed strategy combines facile hydrogen desorption(Ag NPs)with efficient hydrogen adsorption(1T/2H MoS_(2))effectively circumventes the kinetic limitation of hydrogen desorption by 1T/2H MoS_(2).The as-prepared Ag NPs/1T(2H)MoS_(2)/TNRs electrocatalyst exhibited excellent HER activity in 0.5 mol/L H2SO4 with low overpotential(118 mV *** hydrogen electrode(RHE))and small Tafel slope(38.61 mV/dec).The overpotential exhibts no obvious attenuation after 10 h of constant current ***-principles calculation demonstrates that as-prepared 1T/2H MoS_(2) exhibit a large capacity to store *** protons can be subsequently transferred to Ag NPs,which significantly increases the hydrogen coverage on the surface of Ag NPs in HER process and thus change the rate-determining step of HER on Ag NPs from water dissociation to hydrogen *** study provides a unique strategy to improve the catalytic activity and stability for MoS_(2)-based electrocatalyst.

关键词： Molybdenum disulfide Silver nanoparticles Hydrogen evolution reaction Density functional theory Hydrogen spillover

来源：评论

学校读者我要写书评

暂无评论

Experimental and kinetic study on laminar flame speeds of ammonia/syngas/air at a high temperature and elevated pressure

引用

Frontiers in Energy 2022年第2期16卷 263-276页

作者： Geyuan YIN Chaojun WANG Meng ZHOU Yajie ZHOU Erjiang HU Zuohua HUANG State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China Key Laboratory for Thermal Science and Power Engineering of the Ministry of Education Department of Thermal EngineeringTsinghua UniversityBeijing 100084China

The laminar flame speeds of ammonia mixed with syngas at a high pressure, temperature, and different syngas ratios were measured. The data obtained were fitted at different pressures, temperatures, syngas ratios, and equivalence ratios. Four kinetic models (the Glarborg model, Shrestha model, Mei model, and Han model) were compared and validated with experimental data. Pathway, sensitivity and radical pool analysis are conducted to find out the deep kinetic insight on ammonia oxidation and NO formation. The pathway analysis shows that H abstraction reactions and NHi combination reactions play important roles in ammonia oxidation. NO formation is closely related to H, OH, the O radical produced, and formation reactions. NO is mainly formed from reaction, HNO+ H= NO+ H2. Furthermore, both ammonia oxidation and NO formation are sensitive to small radical reactions and ammonia related reactions.

关键词： ammonia mixed with syngas laminar flame speed kinetic model sensitivity analysis pathway analysis

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：