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Boosting photocatalytic hydrogen production via interfacial engineering over a Z-scheme core/shell heterojunction

Nano Research 2023年第1期16卷 352-359页

作者： Bing Luo Jinghua Li Wei Wang Chaoqian Ai Haihan Zhang Yuxin Zhao Dengwei Jing School of Chemical Engineering and Technology Xi'an Jiaotong UniversityXi'an 710049China International Research Center for Renewable Energy&State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China

Designing high efficacy photocatalysts is a promising way to improve solar fuel production *** this work,we prepared a core/shell composite of loose ZnCr layered double hydroxide nanosheets modified CdS nanorods for efficient visible light driven photocatalytic hydrogen *** highest hydrogen production rate achieved 425.8μmol·h^(−1) without adding any noble metal cocatalyst under the visible light stimulus,which is 22.4 times that of 1 wt.%Pt-modified *** corresponding apparent quantum yield is 13.9%at 420 *** is revealed that the synergistic actions of the interfacial redox shuttle of Cr^(3+)/Cr^(δ+)and the interfacial electric field enable the efficient separation of photoinduced charge carriers between two components via a Z-scheme energy band ***,with the hydrogen evolution contribution of Zn^(2+),a remarkable improvement in photocatalytic performance was achieved in contrast to bare *** work provides an effective methodology to construct highly efficient and economically viable photocatalysts for solar H_(2)production and mechanistic study.

关键词： photocatalysis heterojunction interfacial engineering noble metal free hydrogen production

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Fabricating PdCe/OMS-2 catalysts with boosted low-temperature activity for toluene deep degradation

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Journal of Rare Earths 2023年第6期41卷 839-849,I0002页

作者： Lin Yue Zhihua Xu Minghua Hu Mingjiao Tian Mudi Ma Bijie Huang Chi He State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power EngineeringXi'an Jiaotong UniversityXi'an 710049China State Key Laboratory of Precision Blasting and Hubei Key Laboratory of Industrial Fume and Dust Pollution Control Jianghan UniversityWuhan 430056China National Engineering Laboratory for VOCs Pollution Control Material&Technology University of Chinese Academy of SciencesBeijing 101408China

Porous cryptomelane-type octahedral molecular sieve(OMS-2)with mixed Mn valence and abundant lattice oxygen species has attracted much attention in volatile organic compounds(VOC)catalytic ***,complete conversion of arene over OMS-2 catalysts at relatively low temperature is still a challenge due to its limited crystal structure and inferior ***,a series of PdCe/OMS-2 catalysts with different Pd/Ce molar ratios was fabricated by a facile impregnation method and the physicochemical properties of which were extensively characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),high-resolution transmission electron microscopy(HR-TEM),B runauer-Emmett-Teller(BET)method,X-ray fluorescence(XRF),X-ray photoelectron spectroscopy(XPS),temperature programmed reduction of H2(H2-TPR),Raman,In situ diffused reflectance infrared Fourier transform spectra(DRIFTS),and density functional theory(DFT)*** show that the total conversion of toluene can be achieved at 207℃ over PdCe2 with apparent activation energy as low as 62.6 kJ/*** strong synergistic effect between Pd and Ce remarkably boosts the catalytic activity of OMS-2,attributed to the abundant Mn^(3+)-O bands and active surface oxygen *** results reveal that oxygen vacancy can be formed over PdCe2 much easily than that of Pd/OMS-2 and Ce/OMS-2 with the oxygen vacancy formation energy of2.42,2.83 and 2.68 eV,*** increasing the Pd content cannot promote the catalytic activity although PdO is a critical active center in toluene *** vacancy attributed to the integrative effect of Pd,Ce and Mn species plays a promine nt role over prepared catalysts in toluene activation *** findings reported in this work showed new insights into the designing of highly efficient OMS-2catalysts for VOC deep oxidation by tuning oxygen vacancy concentration.

关键词： PdCe/OMS-2 Toluene Catalytic oxidation Oxygen vacancy Rare earths

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Honeycomb-like biochar framework coupled with Fe_(3)O_(4)/FeS nanoparticles as efficient heterogeneous Fenton catalyst for phenol degradation

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Journal of Environmental Sciences 2024年第2期136卷 390-399页

作者： Aihua Cheng Yi He Xiaohe Liu Chi He Department of Environmental Engineering College of Geology and EnvironmentXi’an University of Science and TechnologyXi’an 710054China State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power EngineeringXi’an Jiaotong UniversityXi’an 710049China National Engineering Laboratory for VOCs Pollution Control Material and Technology University of Chinese Academy of SciencesBeijing 101408China

Achieving an efficient and stable heterogeneous Fenton reaction over a wide pH range is of great significance for wastewater ***,a pollen-derived biochar catalyst with a unique honeycomb-like structure,coupled with the dispersion of magnetic Fe_(3)O_(4)/FeS(Fe/S)nanoparticles,was synthesized by simple impregnation precursor,followed by *** prepared Fe/S-biochar catalyst demonstrated outstanding phenol degradation efficiency across a wide pH range,with 98%of which eliminated even under neutral conditions(pH 7.0).The high catalytic activity was due to the multilevel porous structure of pollenderived biochar provided enough active sites and allowed for better electron transfer,then increases oxidation ability to promote the ***,the acid microenvironment formed by SO_(4)^(2-)group from Fe/S composite extended the pH range for Fenton reaction,and S^(2-)facilitated the conversion of≡Fe^(3+)to≡Fe^(2+),resulting in remarkable degradation ***,biochar can effectively promote cycling stability by limiting Fe *** work may provide a general strategy for designing 3D framework biochar-based Fe/S catalysts with excellent performance for heterogeneous Fenton reactions.

关键词： Biomass Biochar Fenton reaction Fe_(3)O_(4)/FeS(Fe/S) Phenol degradation

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Development of low-cost, large-scale green H2 production/power generation and large capacity long-term energy storage

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Science China Technological Sciences 2025年

作者： Liejin GUO Yonggang GUAN Hui JIN State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Engineering Thermophysics and Energy Utilization Discipline of National Natural Science Foundation of China

Abstract Renewable energy,such as solar energy,wind energy,and hydraulic energy,mostly belongs to process energy,which is hard to store,while fossil energy belongs to energy-carrier energy,which can achieve long-term *** conversion and utilization technologies for all types of energy mainly focus on power *** energy is convenient to store,but its conversion and utilization technologies mainly rely on the combustion of fossil fuels for power and thermal energy generation,emitting huge amounts of pollutants and *** and thermal energy are still process energy which is hard to be stored,and the problem of the low-cost,efficient and long-term storage of energy is difficult to solve,which is the fundamental deficiencies of the current energy production and supply system.H2as an energy-carrier energy enables both clean and efficient use and ***,the development of efficient,low-cost,large-scale green H2/power generation is *** is recommended that:（1） new renewable energy units be developed based on integrating H2,thermal energy and power energy poly-generation technology on *** already built“sole power generation”renewable energy units should be transformed into H2,thermal energy and power energy poly-generation model,to build a comprehensive energy multi-link supply system that achieves energy storage,transportation and utilization,as well as the full-time,high-efficiency,low-cost conversion and utilization of renewable energy.（2） Developing low-carbon and clean technologies for green H2and power from carbonbased energy sources,achieving efficient energy conversion and full utilization of resources.（3） Building a new industry for high-value conversion and high-quality utilization of fossil fuels to produce the high-value chemical products instead of pollutants which also provides the best solution for large-capacity and long-term energy storage.

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Experimental investigation of inflow-outflow asymmetry in induced-charge electro-osmosis

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Energy Storage and Saving 2024年第1期3卷 16-22页

作者： Lingqi Zhao Tianwei Lai Yingke Gao Shaohang Yan Mingzhe Liu Yu Hou State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an710049China MOE Key Laboratory of Cryogenic Technology and Equipment Xi’an Jiaotong UniversityXi’an710049China

Induced-charge electro-osmosis(ICEO)is a research hotspot in bioengineering and analytical ***-outflow asymmetry of ICEO was reported in the existing literatures,but systematic study on this phenomenon is *** this experimental study,we found that in strong electric fields,not only the velocity magnitude but also the vortex positions of ICEO are asymmetrical along the inflow and outflow directions because of the pronounced non-uniform surface electrokinetic *** the inflow and outflow directions,the amplitudes of velocities are unequal,ICEO maximum velocity positions change depending on the electric field intensity and sodium chloride(NaCl)***,the distances between vortex centers are *** NaCl solution concentration of 0.001 mol⋅L^(-1),the outflow velocity almost *** asymmetry rises with the increasing electric field *** new discoveries can direct the application of microscale devices.

关键词： Induced-charge electro-osmosis Micro-particle image velocimetry Inflow-outflow asymmetry

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Laminar Flame Instability of n-Hexane,n-Octane,and n-Decane in Spherical Expanding Flames

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Journal of Thermal Science 2024年第3期33卷 1189-1199页

作者： YIN Geyuan HU Erjiang LI Xiaotian LV Xin HUANG Zuohua State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an710049China United Automotive Electronic Systems Co. LtdShanghai201206China Chongqing Changan Automobile Co. Ltd.Chongqing401120China

This paper focuses on the laminar flame instability of three high molecular weight n-alkanes,namely n-hexane,n-octane,and *** experiment was carried out in a constant volume combustion bomb to get the flame *** critical radius under different conditions was extracted using the image processing *** with the existing critical Peclet number theory,the dominant factors of flame instability under current conditions for three n-alkanes can be figured ***,the average cell size(equivalent cell radius,R_(cell))was extracted to provide quantitative analysis of the flame cellular structure,based on the method developed in this *** theoretical R_(cell)were also calculated and compared with the experimental results to validate the proposed method.

关键词： cellular instability equivalent cell radius critical Peclet number spherical flame

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On the Intelligent Optimization of the Crevice Structure in a Rapid Compression Machine

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Journal of Thermal Science 2024年第3期33卷 1200-1215页

作者： GUO Qiang LIU Jie WU Yingtao WANG Hewu TANG Chenglong YU Ruiguang Department of Power Mechanical Engineering Beijing Jiaotong UniversityBeijing100044China State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an710049China State Key Laboratory of Automotive Safety and Energy Tsinghua UniversityBeijing100084China Beijing Key Laboratory of New Energy Vehicle Powertrain Technology Beijing100044China National International Science and Technology Cooperation Base Beijing Jiaotong UniversityBeijing100044China

In this study,the multi-objective intelligent optimization of the crevice structure in a rapid compression machine(RCM)is carried out based on the RCM simulation model modified with the KIVA-3V program.A multi-objective optimization simulation model of the crevice structure based on the large eddy simulation model coupled with the genetic algorithm NSGA-Ⅲis *** optimization parameters and seven optimization objectives are selected in the optimization *** results show that the genetic algorithm can quickly find the values of the optimized *** crevice volume ratio shows a trade-off relationship with the dimensionless temperature ratio T_(max)/T_(aver)and the tumble ratio.A larger crevice volume can reduce the flow of boundary layer cryogenic gas into the combustion chamber,thus improving the temperature *** addition,the crevice entrance width and the connecting channel length should be smaller,while the volume of the crevice main chamber should be larger,so as to sufficiently introduce the low-temperature gas of the boundary layer into the crevice and reduce their influence on the temperature field of the combustion *** the crevice volume accounts for10%of the total volume,the temperature uniformity of the combustor is significantly enhanced,and when the crevice volume accounts for 30.4%,there is almost no low-temperature vortex in the combustion chamber.

关键词： rapid compression machine adiabatic core area ignition delay period crevice structure

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Uncertainty analysis of molten corium In-Vessel Retention under External Reactor Vessel Cooling

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International Journal of Advanced Nuclear Reactor Design and Technology 2023年第4期5卷 159-167页

作者： Wu, Shihao Wang, Dong Zhang, Yapei Zhou, Yukun Tian, Wenxi Qiu, Suizheng Su, G.H. School of Nuclear Science and Technology Shaanxi Engineering Research Center of Advanced Nuclear Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China

External Reactor Vessel Cooling (ERVC) is a key measure to realize molten corium In-Vessel Retention (IVR). The uncertainty of severe accident in core leads to the uncertainty of molten pool parameters in lower head, which may threat the reliability of successful implementation of IVR. In this study, an uncertainty analysis is employed to ensure the reliability of ERVC technology to IVR with the final two-layer molten pool configuration of AP1000.600 simulations are performed to determine the effect of five key parameters. As long as parameters are within high probability density range, lower head can remain intact, and safety margin is greater than 15 %. For influence level and correlation of parameters, the order on metal layer is: Decay heat > Fe mass > UO2 mass > Zr oxidation fraction > Emissivity of metal layer. The results can provide guidance for subsequent research direction and optimal design of mitigation measures. © 2024 Xi'an Jiaotong University

关键词： Uncertainty analysis

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Experimental and kinetic study on laminar flame speeds of ammonia/syngas/air at a high temperature and elevated pressure

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Frontiers in Energy 2022年第2期16卷 263-276页

作者： Geyuan YIN Chaojun WANG Meng ZHOU Yajie ZHOU Erjiang HU Zuohua HUANG State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China Key Laboratory for Thermal Science and Power Engineering of the Ministry of Education Department of Thermal EngineeringTsinghua UniversityBeijing 100084China

The laminar flame speeds of ammonia mixed with syngas at a high pressure, temperature, and different syngas ratios were measured. The data obtained were fitted at different pressures, temperatures, syngas ratios, and equivalence ratios. Four kinetic models (the Glarborg model, Shrestha model, Mei model, and Han model) were compared and validated with experimental data. Pathway, sensitivity and radical pool analysis are conducted to find out the deep kinetic insight on ammonia oxidation and NO formation. The pathway analysis shows that H abstraction reactions and NHi combination reactions play important roles in ammonia oxidation. NO formation is closely related to H, OH, the O radical produced, and formation reactions. NO is mainly formed from reaction, HNO+ H= NO+ H2. Furthermore, both ammonia oxidation and NO formation are sensitive to small radical reactions and ammonia related reactions.

关键词： ammonia mixed with syngas laminar flame speed kinetic model sensitivity analysis pathway analysis

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The evaporation of nanoscale sodium liquid film on the non-ideal nanostructure surface: A molecular dynamics study

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International Journal of Advanced Nuclear Reactor Design and Technology 2023年第1期5卷 1-8页

作者： Wang, Zetao Ye, Tianzhou Guo, Kailun Tian, Wenxi Qiu, Suizheng Su, Guanghui State Key Laboratory of Multiphase Flow in Power Engineering Shaanxi Key Lab of Advanced Nuclear Energy and Technology School of Nuclear Science and Technology Xi'an Jiaotong University Xi'an710049 China

The nanoscale liquid sodium film inside the microporous wick structure is of great importance to understanding the evaporation mechanism of the sodium heat pipe. The novel optimized wick structure is made of several layers of special screen. The surface of each screen exhibits a nanostructure type. Some non-ideal nanostructures may result from experimental faults or limits. And they will have an effect on the evaporation of film. In the present study, molecular dynamics is adopted to investigate this effect. The simulation system consists of the liquid sodium film and the solid surface. The flat surface is set as the reference. Based on the three non-ideal shapes of deposition, the sinusoidal nanostructures, conical nanostructures, and spherical nanostructures are built. The results indicate that the evaporation is suppressed by the above nanostructure surfaces. The weakening effect is through three forms: the potential gradient of the liquid film is intensified and the evaporation difficulty is increased;the heat transfer in the solid-liquid contact region is impeded;the collision heat transfer inside the liquid film is affected due to the delay of the aggregation variation between liquid atoms. © 2023 Xi'an Jiaotong University

关键词： Heat pipes

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