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SSRN 2023年

作者： Yao, Chen Liu, Jiping Yan, Junjie State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi’an710049 China

Understanding the nonlinear effects in thermoacoustic heat engines operating under high-pressure amplitude conditions plays a crucial role in improving their operational performance and efficiency. The discontinuous Galerkin (DG) method has several advantages, including high accuracy, adaptability, efficiency, and the ability to handle the coupling of multiple physical fields, making it suitable for accurately simulating the flow and heat transfer characteristics in thermoacoustic engines. The simulation code was developed based on MFEM, an open-source C++ library for modular finite element methods. The fully compressible Navier-Stokes equations and Fourier heat conduction equation were solved to investigate the nonlinear effects, which cannot be captured by the linear theory. To verify the accuracy of the simulation code, the numerical investigation of the thermoacoustic wave propagations induced by thermal effects in a square enclosure was first conducted. The simulation results presented the details of the generation and propagation of thermoacoustic waves, which were largely consistent with the results obtained using the flux-corrected transport (FCT) algorithm. Second, a quarter-wavelength standing wave thermoacoustic engine was simulated. The simulation results captured the process of pressure wave generation in the thermoacoustic engine, which was consistent with the pressure wave generation process in the enclosure. The results revealed the flow and heat transfer characteristics and nonlinear effects in the thermoacoustic engine under high-pressure amplitudes, which were consistent with the results obtained using finite volume method. The simulation results showed that the DG method is an effective numerical method for simulating thermoacoustic engines. © 2023, The Authors. All rights reserved.

关键词： Navier Stokes equations

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Spherical Particle Assumption Underestimates Fluid-Solid Reaction Rate

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SSRN 2023年

作者： Zhao, Shuaiqi Zhang, Rui Huang, Han Zhao, Kunpeng Bai, Bofeng State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

Fluid-solid reaction of porous particles is pivotal to many modern chemical industries from heterogeneous catalysis to solid gasification. Most studies usually assume the particles are spherical, and the morphology of the shrinking reaction fronts inside particles are invariant. However, the developed models cannot explain the recent experimental observations of the non-spherical particles reaction, and lead to significant estimation errors of reaction rate. Here, we propose a three-dimensional (3D) reaction-diffusion model inside the irregular-shaped particles, and investigate the universal fluid-solid reaction kinetics. Intrapore homogenous reactions, multi-species diffusion, the sphericity (φ) and 3D roundness (R3d) evolution of the reaction front morphology are fully accounted for. The numerical method has been experimentally validated. When compared with spherical particles, we found that particles have higher heat and species transfer efficiency with fluids through the irregular-shaped particle surfaces, and higher reaction rate through the irregular-shaped reaction fronts. Thus, the invariant reaction front morphology assumption overestimates the fluid-solid reaction rate by up to 52%, while the spherical particle assumption underestimates the reaction rate by up to 42%. A corrected correlation is thereby proposed to better estimate the average reaction rate and complete reaction time of the irregular-shaped particles. The underestimation of reaction rate by the spherical particle assumption is inversely proportional to φ1.7 of the initial particle morphology, and directly proportional to [[EQUATION]]. The present work provides an accurate theoretical method for the fluid-solid reaction kinetics, and a detailed description of the reaction front inside particles. © 2023, The Authors. All rights reserved.

关键词： Reaction rates

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Numerical investigation on the drag characteristics of supercritical water flow past a sphere

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Science China(Technological Sciences) 2020年第8期63卷 1509-1519页

作者： WU ZhenQun OU GuoBiao REN YiFei JIN Hui State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi'an 710049China

Numerical simulation has become a useful approach to explore the complex physical and chemical process inside the supercritical water(SCW)fluidized bed *** to the drastic and non-linear variation of water properties near pseudocritical point,the flow field and drag coefficient of SCW flow past a cold particle are considerably different from that of conventional ***,in this work,particle-resolved numerical investigation is conducted to study the flow field and drag characteristics under the influence of the special water properties *** varying the enthalpy corresponding to the particle surface temperature,which will be called the particle surface enthalpy for short,in a wide range,it realizes the study under different properties variation *** simulated results demonstrate that the variations of drag coefficient versus Reynolds number(Re)and particle surface enthalpy are in good regularity when taking the freestream temperature as reference *** drag coefficient is enhanced greatly at high enthalpy difference between particle surface and inflow,and the enhancement is mainly contributed by that of the frictional drag ***,the drag coefficient variations under different pressures are in good agreement when cases are set with the same inflow and particle surface enthalpies,*** fitting the simulated results,a new drag coefficient correlation is developed for Re range of 10–200 with consideration of the influence of the special properties *** fitting quality is good that the maximum deviation between the new correlation and simulated data is 13.92%,and the mean deviation is 3.67%.

关键词： supercritical water numerical simulation sphere drag coefficient

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Heat transfer behaviors of some supercritical fluids: A review

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Chinese Journal of Aeronautics 2022年第1期35卷 290-306页

作者： Gongnan XIE Xiaoxiao XU Xianliang LEI Zhouhang LI Yong LI Bengt SUNDEN School of Marine Science and Technology Northwestern Poly technical UniversityXi'an 710072China Key Laboratory of Low-grade Energy Utilization Technologies and Systems Chongqing UniversityChongqing 400044China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an 710049China State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization Kunming University of Science and TechnologyKunming 650093China School of Mechanical Engineering Northwestern Polyteclwical UniversityXi'an 710072China Department of Energy Sciences Lund UniversitySE-22100 LundSweden

Supercritical fluids(e.g.,hydrocarbon fuels,water,carbon dioxide,and organic working medium,etc)have been recognized as working media to improve thermal efficiencies in power cycles and energy conversion,and have been used or selected as the working fluids in engineering fields such as aerospace,nuclear power,solar energy,refrigeration,geothermal energy,chemical technology,and so *** better understand the interesting characteristic or abnormal behaviors of supercritical fluids,most valuable research works(including experimental results and numerical studies)from domestic and abroad have been *** such,this paper presents a comprehensive review on heat transfer behaviors of some supercritical fluids in engineering *** review focuses on recently available articles published mainly from 2016 up to the present *** common problems(i.e.,heat transfer enhancement and heat transfer deterioration particularly for the supercritical hydrocarbon fuels)in the supercritical field are summarized and some perspectives on future prospects are also included.

关键词： Heat transfer behavior Supercritical fluids Thermo-physical property Turbulence model Working condition

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Simultaneous Analysis of Swirl Spray Dynamics Using a Telecentric System

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SSRN 2023年

作者： Machado, Danilo Almeida de Souza Costa, Fernando Dias, Gabriel Silva Mota, Fábio A.S. Combustion and Propulsion Laboratory National Institute for Space Research SP Cachoeira Paulista12630-000 Brazil State Key Laboratory of Multiphase Flows in Power Engineering Xi’an Jiaotong University Shanxi Xi’an710049 China

A telecentric shadowgraphy optical system was utilized to determine macroscopic and microscopic parameters of sprays and the measurement of conical liquid films formed by dual pressure swirl injectors. Spray cone angles, breakup lengths, mean droplet velocities, momentum flows, wave amplitude ratios and maximum wave growth rates were simultaneously measured using high-speed images with kHz frequencies. Two injectors were tested with inner nozzles having Abramovich geometric constants Kint = 2 and 2.125 and external nozzles with geometric constants Kext = 2.9 and 1.9792, respectively. Injection pressures were varied from 0.05 to 0.5 MPa and water was used as test fluid. The experimental data indicate that the breakup length, droplet velocity, flow momentum and disturbance amplitude ratio are higher for injectors with larger mass flow rates, for a given injection pressure. The maximum amplitude ratios of the conical liquid film disturbances varied in the range 2.32 © 2023, The Authors. All rights reserved.

关键词： Liquid films

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Experimental Investigation on Heat Transfer of Supercritical Water Flowing in a Horizontal Tube with Axially Non-Uniform Heating

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SSRN 2023年

作者： Hou, Zhenghui Huang, Xin Gao, Yu Zhang, Shengjie Wang, Haijun State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

For a heat exchanger, the heat flux is usually non-uniform in the axial direction, and the knowledge about heat transfer of supercritical water with axially non-uniform heating is scarce. To fill the gap, experiments were conducted in a horizontal tube to study the heat transfer characteristics of supercritical water with axially sinusoidal heating. The pressures varied from 23.5 to 26.5 MPa, mass fluxes 200 to 400 kg·m-2·s-1 and average heat fluxes 50 to 150 kW·m-2. Compared with uniform heat flux, the temperature difference between the top and bottom wall is larger than that of the axially sinusoidal heat flux. The inner-wall heat flux is non-uniform along the circumference due to the temperature difference, being higher at the side wall and lower at the top wall. A relative heat flux parameter is defined to describe the relative magnitude of the local heat flux. The relative heat flux parameter of the top generatrix, which is inversely proportional to the average heat flux, decreases linearly with the increase of the temperature difference between the top and side generatrix. The non-uniform degree of heat flux along the circumference is positively correlated with the average heat flux. Additionally, the local heat transfer characteristics should be considered in horizontal tubes. On the one hand, the heat transfer deterioration may occur when the fluid temperature near the top wall is higher than the pseudo-critical temperature and it can be suppressed with increasing Reynolds number. On the other hand, the local heat transfer can be enhanced if the side and bottom wall temperatures exceed the pseudo-critical temperature. © 2023, The Authors. All rights reserved.

关键词： Heat flux

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An Investigation on Characteristics of Severe Slugging in an Offshore S-Shaped Riser with a Long Pipeline

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SSRN 2023年

作者： Yu, Haiyang Xu, Qiang Huang, Bo Cao, Yeqi Guo, Liejin State Key Laboratory of Multiphase Flow in Power Engineering Xi 'an Jiaotong University Xi’an710049 China

Long pipelines and risers are essential for transporting oil and gas from the seabed to offshore processing facilities. However, most research focuses on riser systems with short pipelines (≤ 400 m). A 29.1 m high S-shaped riser connecting a 1657 m horizontal pipe, which is comparable to the scale of industrial fields, is utilized for investigating the characteristics of severe slugging. Based on the visual data of gas-liquid interface evolution and the fluctuation of the riser's pressure, the flow pattern map is drawn. Long pipelines delay the liquid accumulation and prolong the severe slugging period. A new correlation for predicting the slugging period is proposed with a deviation of ±15%. The long pipeline provides sufficient compression space and aggravates the blowouts of liquid slugs. The maximum blowout velocity reaches 23 times the mixing velocity. The gas accumulated in the pipeline expands sharply, which causes the instability of the gas-liquid interface in the horizontal pipe and induces a large number of liquid slugs to flow into the riser, where the continuity blowdown of slugs appears. A slug-tracking model considering pressure and liquid holdup is established to precisely forecast the fluctuation of riser pressure during the slug continuity blowdown. © 2023, The Authors. All rights reserved.

关键词： Flow patterns

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Experimental and Kinetic Study of Methanol Reforming and Methanol-Syngas Co-Oxidation at High Pressure

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SSRN 2023年

作者： Zhan, Haochen Li, Shuming Yin, Geyuan Gao, Yibo Hu, Erjiang Huang, Zuohua State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

Using engine exhaust heat to improve efficiency by performing co-combustion after partial reforming of methanol to syngas is a favored strategy to address the challenges associated with methanol engine applications. In the present work, experiments of methanol pyrolysis and methanol-syngas oxidation were conducted using high-pressure flow reactors at 1.0-5.0 MPa. The ratio of syngas to methanol varied from 0–50%. Mech15.34 was selected as the most reliable kinetic model to further kinetic analysis, which revealed that pressure decreases the decomposition of CH3OH to CH3, enhances the H-abstraction of CH3OH to CH2OH and CH3O, and increases the yield of H2 and CO. Furthermore, high pressure inhibits CH2OH = CH2O + H, thus reducing CH2O. The effects of blending syngas can be divided into dilution and chemical effects. The dilution effect refers to the reduction of CH3OH, which directly decreases the CH2O formation. The chemical effect refers to the competition of H2 and CO for OH radicals, which decelerates the CH3OH oxidation, decreasing the CH2O generation. Meanwhile, the reaction H2O2 + H = H2 + HO2 proceeds in reverse direction with H2 blending, generating more H radicals, which enhances the CH2O consumption through the reaction CH2O + H = HCO + H2. © 2023, The Authors. All rights reserved.

关键词： Oxidation

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Hydrodynamic Interaction of Two Droplets Covered with Insoluble Surfactant in Shear Flow

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SSRN 2023年

作者： Wei, Wei Luo, Zhengyuan Bai, Bofeng State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

Despite its significance in various applications, e.g., droplet microfluidics and enhancing oil recovery, the effects of surfactants on the hydrodynamic interactions of droplets in shear flow still need to be clarified. This paper presents a systematic investigation on the hydrodynamic interaction of two droplets covered with the insoluble surfactant in a simple shear flow, which is realized by using our own three-dimensional front-tracking code. Our results indicate that surfactants significantly affect the hydrodynamic interactions of droplets, characterized by the maximum deviation in the z-direction and the shear-induced self-diffusion. Then we examine the effects of surfactant-relevant parameters, i.e., the surface Peclet number and the elasticity number. Both the maximum deviation in the z-direction and the shear-induced self-diffusion increase with the elasticity number and the surface Peclet number. Specifically, we find two mechanisms underlying the effects of surfactant on the hydrodynamic interaction of two droplets. First, Marangoni stress induced by surfactant sharply increases the maximum deviation in the z-direction when the surface Peclet number is large. It is because that Marangoni stress hinders liquid drainage from the near-contact region and thickens the liquid film between the droplets. Second, hydrodynamic interactions during crossing lead to considerable alterations of the shape and local surfactant concentration, resulting in an irreversible trajectory shift of the droplets. So, the shear-induced self-diffusion sharply rises at the high surface Peclet number. © 2023, The Authors. All rights reserved.

关键词： Surface active agents

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Simulation Study on Hydrogen-Heating-power Poly-Generation System based on Solar Driven Supercritical Water Biomass Gasification with Compressed Gas Products as an Energy Storage System

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Journal of Thermal Science 2020年第2期29卷 365-377页

作者： JIN Hui WANG Cui FAN Chao State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an 710049China

Supercritical water gasification driven by solar energy is a promising way for clean utilization of biomass with high moisture content, but direct discharge of liquid residual causes energy waste and decreases energy efficiency. To reduce energy waste, a poly-generation system for hydrogen-rich gas production coupling heat supply and power generation based on supercritical water gasification of biomass driven by concentrated solar energy was established in this paper, which also provided a novel energy storage method to overcome the shortcomings of solar discontinuity. Thermodynamic model of the system was proposed and life cycle assessment(LCA) of the system was conducted. Influence of different parameters(temperature of 600℃ to 800℃, outlet temperature of heat exchanger of 42℃ to 56℃, biomass slurry concentration of 5% to 6.5%) on the gasification performance, energy and exergy efficiency, energy distribution and global warming potential(GWP) was discussed. The results indicated that hydrogen yield increased as gasification temperature increased since free radical reaction was enhanced which gas production reaction was classified into. Molar fraction of hydrogen increased as gasification temperature increased and reached 65.6% at 750℃. Energy and exergy efficiency of the system reached 74.84% and 34.87% at 700℃ and 600℃ respectively and that of gas production was 18.15% at 650℃, which was the highest. Increasing reaction temperature and decreasing biomass slurry concentration were effective ways to decrease GWP. Optimal operating parameter was reaction temperature of 650℃, outlet temperature of heat exchanger of 50℃ and biomass concentration of 5%.

关键词： biomass supercritical water gasification poly-generation system thermodynamics analysis energy storage life cycle assessment

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