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DISTRIBUTED MULTI-ENERGY SYSTEMS CONSIDERING power-TO-X TECHNOLOGY: PLANNING, SCHEDULING, AND PERFORMANCE ASSESSMENT 37

DISTRIBUTED MULTI-ENERGY SYSTEMS CONSIDERING POWER-TO-X TECH...

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37th International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems, ECOS 2024

作者： Xue, Kai Wang, Jinshi Han, Xiaoqu Zhao, Quanbin Chong, Daotong Chen, Weixiong Yan, Junjie State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Shannxi Xi'an China

ISBN: (纸本)9798331307660

The distributed multi-energy systems place emphasis on the complementary and local application of heterogeneous energy sources, and power to methanol process can be coupled, reducing carbon emissions while increasing the *** providing an economical and low-carbon solution, a real community energy system integrated with solar energy and natural gas has been investigated in this *** at the minimization of the daily cost referring to the net expenditure after considering the offsetting benefits, the carbon capture, water electrolysis, and methanol synthesis are combined, with the methanol and oxygen exported as *** capacity planning and operation scheduling have been performed, and the results indicated that the daily cost can be reduced by 69.67% compared to the conventional energy supply after the scheduling *** the case scenario and typical day, the production of methanol and oxygen is 6.30 t and 13.49 t based on an electricity demand of 28.78 MWh and a heat demand of 11.85 *** to the contribution of carbon capture, the purchase of 5.90 t of carbon allowances is avoided and instead there are 3.86 t of allowances available for ***, the effect of device capacity and operating parameters on economics has been *** study could help to promote the application of power to methanol in distributed energy systems. © 2024 37th International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems, ECOS 2024. All rights reserved.

关键词： Carbon capture and utilization

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High tension cyclic hydrocarbons synthesized from biomass-derived platform molecules for aviation fuels in two steps

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Green Energy & Environment 2023年第1期8卷 331-337页

作者： Zhanchao Li Yizhuo Wang Qing Li Liqing Xu Hong Wang Frontier Institute of Science and Technology Xi'an Jiaotong UniversityXi'an710054China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an710054China

Synthesizing ring structure aviation fuels from biomass-derived platform molecules is challenging,especially for bridged ring structure aviation fuels which are typically achieved from fossil-derived ***,we report the synthesis of a series of ring structure biofuels in two steps by a combination of a solvent-free Michael-cyclization reaction and a hydrodeoxygenation(HDO)reaction from lignocellulosederived 5,5-dimethyl-1,*** biofuels are obtained with high overall yields up to 90%,which exhibit high densities of 0.81 g cm^(-3)-0.88 g cm^(-3)and high volumetric neat heat of combustion(VNHOC)values of 36.0 MJ L^(-1)-38.6 MJ L^(-1).More importantly,bridged-ring structure hydrocarbons can also be achieved in two steps by a combination of a Robinson annulation reaction and an HDO reaction to afford the final products at high overall yields up to 90%.The bridged-ring structure products have comparable high densities and high VNHOC values to the best artificial fuel JP-10(0.94 g cm^(-3)and 39.6 MJ L^(-1)).The results demonstrate a promising way for the synthesis of high-density aviation fuels with different fuel properties at high yields.

关键词： Biofuels 5,5-Dimethyl-1,3-cyclohexanedione Solvent-free Michael-cyclization Robinson annulation Green reaction

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Fast design of catalyst layer with optimal electrical-thermal-water performance for proton exchange membrane fuel cells

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Journal of Energy Chemistry 2023年第6期81卷 642-655,I0014页

作者： Jing Yao Yuchen Yang Xiongpo Hou Yikun Yang Fusheng Yang Zhen Wu Zaoxiao Zhang School of Chemical Engineering and Technology Xi’an Jiaotong UniversityXi’an 710049ShaanxiChina State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049ShaanxiChina

The catalyst layer(CL)is the core component in determining the electrical-thermal-water performance and cost of proton exchange membrane fuel cell(PEMFC).Systemic analysis and rapid prediction tools are required to improve the design efficiency of *** this study,a 3D multi-phase model integrated with the multi-level agglomerate model for CL is developed to describe the heat and mass transfer processes inside ***,a research framework combining the response surface method(RSM)and artificial neural network(ANN)model is proposed to conduct a quantitative analysis,and further a rapid and accurate *** the help of this research framework,the effects of CL composition on the electrical-thermal-water performance of PEMFC are *** results show that the mass of platinum,the mass of carbon,and the volume fraction of dry ionomer has a significant impact on the electrical-thermal-water *** the selected points,the sensitivity of the decision variables is ranked:volume fraction of dry ionomer>mass of platinum>mass of carbon>agglomerate *** particular,the sensitivity of the volume fraction of dry ionomer is over 50%at these ***,the comparison results show that the ANN model could implement a more rapid and accurate prediction than the RSM model based on the same sample *** in-depth study is beneficial to provide feasible guidance for high-performance CL design.

关键词： Catalyst layer Agglomerate model Sensitivity analysis Response surface Artificial neural network

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EXPERIMENTAL INVESTIGATION ON THE TRANSCRITICAL DYNAMIC CHARACTERISTICS OF WATER WALL FOR A SUPERCRITICAL CFB BOILER

EXPERIMENTAL INVESTIGATION ON THE TRANSCRITICAL DYNAMIC CHAR...

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ASME 2024 International Mechanical engineering Congress and Exposition, IMECE 2024

作者： Yang, Dong An, Ning Du, Xiaocheng Han, Lei Guo, Zerui Wei, Ziyu State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Shaanxi Xi'an China

ISBN: (纸本)9780791888667

When the boiler load varies, the operational parameters in the water wall will change, this process is called as dynamic process. Dynamic process presents unique flow and heat transfer phenomena within the water wall. To investigate the process, the research was conducted in a vertical upward smooth tube for a supercritical circulating fluidized bed (CFB) boiler. Experiments were conducted to explore the dynamic characteristics during transcritical pressure process. The results indicate that as system pressure decreases from 23 MPa to 21 MPa, the mass flux within the tube increases sharply, and the outlet fluid temperature decreases. Concurrently, a rapid rise in wall temperature was observed. As the inlet mass flux increases, the wall temperature eventually returns to the normal value. The dynamic heat transfer coefficients were calculated throughout the transcritical pressure process, revealing stages of heat transfer deterioration, subcooled boiling, and single-phase water heat transfer. In addition, experiments and numerical simulations were carried out to explore the dynamic characteristics at supercritical pressure. The dynamic response curves during the step process of heat flux and inlet enthalpy under supercritical pressure conditions were obtained. As the inlet enthalpy decreases, the system mass flux increases, and as the heat flux increases, the system mass flux decreases. And there is no rise in wall temperature during the dynamic response at supercritical pressure. Copyright © 2024 by ASME.

关键词： Water tube boilers

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On the Intelligent Optimization of the Crevice Structure in a Rapid Compression Machine

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Journal of Thermal Science 2024年第3期33卷 1200-1215页

作者： GUO Qiang LIU Jie WU Yingtao WANG Hewu TANG Chenglong YU Ruiguang Department of Power Mechanical Engineering Beijing Jiaotong UniversityBeijing100044China State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an710049China State Key Laboratory of Automotive Safety and Energy Tsinghua UniversityBeijing100084China Beijing Key Laboratory of New Energy Vehicle Powertrain Technology Beijing100044China National International Science and Technology Cooperation Base Beijing Jiaotong UniversityBeijing100044China

In this study,the multi-objective intelligent optimization of the crevice structure in a rapid compression machine(RCM)is carried out based on the RCM simulation model modified with the KIVA-3V program.A multi-objective optimization simulation model of the crevice structure based on the large eddy simulation model coupled with the genetic algorithm NSGA-Ⅲis *** optimization parameters and seven optimization objectives are selected in the optimization *** results show that the genetic algorithm can quickly find the values of the optimized *** crevice volume ratio shows a trade-off relationship with the dimensionless temperature ratio T_(max)/T_(aver)and the tumble ratio.A larger crevice volume can reduce the flow of boundary layer cryogenic gas into the combustion chamber,thus improving the temperature *** addition,the crevice entrance width and the connecting channel length should be smaller,while the volume of the crevice main chamber should be larger,so as to sufficiently introduce the low-temperature gas of the boundary layer into the crevice and reduce their influence on the temperature field of the combustion *** the crevice volume accounts for10%of the total volume,the temperature uniformity of the combustor is significantly enhanced,and when the crevice volume accounts for 30.4%,there is almost no low-temperature vortex in the combustion chamber.

关键词： rapid compression machine adiabatic core area ignition delay period crevice structure

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Morphology Structure Evolution and Combustion Reactivity of Bituminous Char at Around Ash Melting Temperature

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Journal of Thermal Science 2022年第6期31卷 2189-2202页

作者： ZHANG Yandi YANG Huan WANG Bo HMShahzaib KHAN DUAN Xiaoli LIU Yinhe State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi'an Jiaotong UniversityXi'an 710049China

In slag tapping furnaces, char particles undergo a series of complex structural evolution before and after being captured by the liquid slag layer. The evolution results affect the carbon conversion rate and are affected by temperature fluctuations, especially in the ash melting temperature zone. Experimental study on structure evolution of bituminous char prepared at around ash melting temperature was carried out on a fixed bed. The morphology, specific surface area and mineral chemical composition were measured at different temperatures. Experimental results show that the number density and the size of ash droplets exuded on the char surface increased significantly with the increasing temperature. The ash specific surface area from gasification was slightly greater than that from combustion. The residual content of chloride in the char become 1% and the contents of Fe, K, Mg and Na decrease significantly during the pyrolysis process across the ash melting temperature zone. The diffraction intensity of oldhamite increase which indicates the reaction of carbon substrate with minerals during the evolution;the diffraction intensity of quartz dramatically decreases for the reason of anorthite generation. The ignition and burnout temperatures of char were found to increase and the combustion stability decreased with the increasing pyrolysis temperature.

关键词： coal char structure evolution carbothermal reaction combustion

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Experimental and Theoretical Study on CHF of a Ultra-Supercritical Circulating Fluidized Bed Boiler Water-Wall Tube at near-Critical Pressures

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Journal of Thermal Science 2023年第1期32卷 166-182页

作者： WANG Wenyu MA Zhan QING Hao NIE Chao YANG Haoyu BI Lingfeng YANG Dong PAN Wenxiao State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an 710049China Department of Mechanical Engineering University of Wisconsin-Madison1513 University AveMadisonWI 53706USA

The experimental and theoretical research on the critical heat flux(CHF)in a uniformly heated water-wall tube of the efficient ultra-supercritical circulating fluidized bed(USCFB)boiler has been *** particular,the experimental pressure varies from 18 MPa to 21 MPa,which is from 0.814Pcr–0.95Pcr(Pcr:critical pressure).The mass flux varies from 310 kg·m^(–2)·s^(–1)to 550 kg·m^(–2)·s^(–1).The inlet sub-cooling temperatures vary from 5°C to 10°*** material of the tube is *** experimental investigation,the near critical pressure CHF test data of water are *** find that the CHF mainly occurs when the vapor qualities are less than 0.4,and it occurs earlier(at lower vapor quality)when the pressure is closer to 22.115 MPa or the mass flux is *** the experimental data,a correlation function for the CHF is established via regression and machine *** established via machine learning greatly improved the regression *** study the CHF phenomenon mechanically,a theoretical model is established based on the near-surface bubble crowding model describing the DNB-type *** the development of the CHF model,the friction resistance coefficient is determined according to our test *** comparison with different experimental results,the near-surface bubble crowding model is well suited to describe DNB-type *** calculation results of the model can provide reference for the optimal design of the USCFB boiler.

关键词： circulating fluidized bed critical heat flux near-critical pressure bubble crowding machine learning

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Function-reversible facets enabling SrTiO_(3)nanocrystals for improved photocatalytic hydrogen evolution

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Frontiers in Energy 2024年第1期18卷 101-109页

作者： Bin WANG Bei AN Xiaoqian LI Shaohua SHEN School of Physics Key Laboratory for Non-equilibrium Synthesis and Modulation of Condensed Matter(Ministry of Education)Key Laboratory of Shaanxi for Advanced Materials and Mesoscopic PhysicsXi’an Jiaotong UniversityXi’an 710049China International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an 710049China

It has been widely reported that,for faceted nanocrystals,the two adjacent facets with different band levels contribute to promoted charge separation,and provide active sites for photocatalytic reduction and oxidation reaction,*** such cases,only one family of facets can be used for photocatalytic hydrogen ***,by using SrTiO_(3)nanocrystals enclosed by{023}and{001}facets as a model photocatalyst,this paper proposed a strategy to achieve the full-facets-utilization of the nanocrystals for photocatalytic hydrogen via chemically depositing Pt nanoparticles on all *** photo-deposition experiment of CdS provided direct evidence to demonstrate that the{023}facets which were responsible for photooxidation reaction can be function-reversed for photocatalytic hydrogen evolution after depositing Pt nanoparticles,together with the{001}***,the full-facets-utilization led to a much-improved activity for photocatalytic hydrogen,in contrast to those SrTiO_(3)nanocrystals with only{001}facets deposited by Pt nanoparticles via a photo-deposition method.

关键词： SrTiO_(3)nanocrystals crystal facets photocatalysis hydrogen evolution

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Experimental and kinetic study on laminar flame speeds of ammonia/syngas/air at a high temperature and elevated pressure

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Frontiers in Energy 2022年第2期16卷 263-276页

作者： Geyuan YIN Chaojun WANG Meng ZHOU Yajie ZHOU Erjiang HU Zuohua HUANG State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China Key Laboratory for Thermal Science and Power Engineering of the Ministry of Education Department of Thermal EngineeringTsinghua UniversityBeijing 100084China

The laminar flame speeds of ammonia mixed with syngas at a high pressure, temperature, and different syngas ratios were measured. The data obtained were fitted at different pressures, temperatures, syngas ratios, and equivalence ratios. Four kinetic models (the Glarborg model, Shrestha model, Mei model, and Han model) were compared and validated with experimental data. Pathway, sensitivity and radical pool analysis are conducted to find out the deep kinetic insight on ammonia oxidation and NO formation. The pathway analysis shows that H abstraction reactions and NHi combination reactions play important roles in ammonia oxidation. NO formation is closely related to H, OH, the O radical produced, and formation reactions. NO is mainly formed from reaction, HNO+ H= NO+ H2. Furthermore, both ammonia oxidation and NO formation are sensitive to small radical reactions and ammonia related reactions.

关键词： ammonia mixed with syngas laminar flame speed kinetic model sensitivity analysis pathway analysis

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Alloy nanocrystals:Synthesis paradigms and implications

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Chinese Journal of Structural Chemistry 2023年第11期42卷 1-5页

作者： Zhaojun Liu Zerui Mu Chuanbo Gao State Key Laboratory of Multiphase Flow in Power Engineering Frontier Institute of Science and TechnologyXi'an Jiaotong UniversityXi'an710054China

*** Noble metal nanocrystals serve as exceptional catalysts across a wide spectrum of industrial processes[1].Moreover,there exists a substantial demand for noble metal catalysts in emerging clean-energy applications,such as water-splitting hydrogen production and fuel *** non-noble transition metals or main-group metals into noble metal nanocrystals can reduce the weight of noble metals in the catalysts,thus remarkably lowering the ***,alloy nanocrystals offer intriguing catalytic properties that surpass those of their monometallic counterparts,thanks to the charge transfer between the constituent components and the expansion or shrinkage of the lattice size[2].

关键词： alloy metals noble

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