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Construction of Pd-M （M = Ni, Ag, Cu） alloy surfaces for catalytic applications

Nano Research 2018年第2期11卷 780-790页

作者： Xiang Li Xixi Wang Maochang Liu Hongyang Liu Qiang Chen Yadong Yin Mingshang Jin Frontier Institute of Science and Technology (FIST) School of Chemical Engineering and Technology and State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an China Shenyang National Laboratory for Materials Science Institute of Metal Research Chinese Academy of Sciences Shenyang China State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology Beijing China Department of Chemistry University of California Riverside USA

The fabrication of ultrathin alloy shells as heterogeneous catalysts to increase the utilization efficiency and enhance the catalytic activity of metal atoms has been recognized as an effective method for the construction of efficient metal nanocatalysts, particularly noble-metal nanocatalysts. In this study, we demonstrate the successful formation of Pd-M （M = Ni, Ag, Cu） alloy shells with a tunable thickness on preformed nanoscale Pd seeds. The success of this synthesis mainly relies on the combination of the slow reduction of ＂M＂ ions and the subsequent diffusion of M ad-atoms into the surface lattice of Pd seeds. The composition of the Pd-M alloy shell is easily tuned by changing the type and amount of the added precursor, and the shell thickness is manipulated according to the reaction time. More significantl the surface structure of these alloy shells is maintained after the reaction, implying that any desired surface structure of Pd-M alloy shells can be prepared by using the appropriate starting materials. Further catalytic evaluation of the hydrogenation of chloronitrobenzenes shows that these alloy surfaces exhibit significantly improved selectivity compared to the Pd seeds. The Pd-Ni alloy surfaces exhibit much better catalytic selectivity （as high as 〉 99%） than Pd catalysts.

关键词： Pd allo3 catalyst shape control hydrogenation

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Radiation Effects of 500 MeV Kr+ ions on NiO/β-Ga2O3 heterojunction diodes

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IEEE Transactions on Nuclear Science 2025年

作者： Zhao, Penghui Chen, Hao Zhou, Leidang Ma, Teng Chen, Liang Yang, Tao Lei, Zhifeng Lu, Xing Zhou, Genshu Guo, Hui Ouyang, Xiaoping School of Materials Science and Engineering Xi’an Jiaotong University Xi’an710049 China Xi’an Jiaotong University School of Microelectronics Xi’an710049 China State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China Xi’an Engineering Research Center of Advanced3D Vision Shaanxi Xi’an710000 China China Electronic Product Reliability and Environmental Testing Research Institute Science and Technology on Reliability Physics and Application of Electronic Component Laboratory Guangzhou510610 China Northwest Institute of Nuclear Technology Radiation Detection Research Center Xi’an710024 China Xi’an Jiaotong University School of Instrument Science and Technology Xi’an710049 China Sun Yat-sen University State Key Laboratory of Optoelectronic Materials and Technologies School of Electronics and Information Technology Guangzhou510275 China Xidian University School of Microelectronics Shaanxi Xi’an710016 China

This study investigates the in-situ radiation effects on NiO/β-Ga2O3 heterojunction diodes (HJDs) under 500 MeV Kr+ ions irradiation, with a fluence of 1×108 cm-2 at -200 V. The statistical results show that both the forward conductive and reverse blocking characteristics of the HJDs were degraded after the irradiation of Kr+ ions. Associated with the analysis of current-voltage characteristics and the SRIM simulation results, the performance degradations were attributed to the vacancies induced by Kr+ ions radiation in the β-Ga2O3 material. On the one hand, the Kr+ radiation-induced vacancies reduced the net carrier concentration of the β-Ga2O3 and increased the generation-recombination current, leading to increased specific on-resistance and ideality factor of the irradiated HJDs. On the other hand, an oxygen di-vacancies-related trap, set at 1.07±0.01 eV below the conduction band, was involved after Kr+ ions radiation, which enhanced the Poole-Frenkel emission process, dominating the higher leakage current of the irradiated HJDs beyond -300 V. These results provide valuable insights into the radiation damage and performance degradation mechanisms in β-Ga2O3-based devices for space applications. © 1963-2012 IEEE.

关键词： Radiation damage

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Retraction notice to “Exploration over combined impacts of modified piston bowl geometry and tert-butyl hydroquinone additive-included biodiesel/diesel blend on” [FUEL 322C (2002) 124206]

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Fuel 2025年 384卷

作者： Krupakaran Radhakrishnan Lawrence Zuohua Huang Xuan Phuong Nguyen Dhinesh Balasubramanian Vidyasagar Reddy Gangula Raghurami Reddy Doddipalli Van Vang Le Sachuthananthan Bharathy Anh Tuan Hoang Department of Mechanical Engineering Sree Vidyanikethan Engineering College Tirupati Andhra Pradesh India State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an 710049 China PATET Research Group Ho Chi Minh City University of Transport Ho Chi Minh City Viet Nam Department of Mechanical Engineering Mepco Schlenk Engineering College Sivakasi India Mechanical Engineering Faculty of Engineering Khon Kaen University Khon Kaen Thailand Center for Alternative Energy Research and Development Khon Kaen University Khon Kaen Thailand Institute of Maritime Ho Chi Minh City University of Transport Ho Chi Minh City Viet Nam Institute of Engineering HUTECH University Ho Chi Minh City Viet Nam

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Elucidating Confinement and Microenvironment of Ru Clusters Stably Confined in MFI Zeolite for Efficient Propane Oxidation

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Angewandte Chemie 2024年第5期137卷

作者： Jingjing Wang Dr. Zeyu Jiang Hengyue Xu Prof. Xinzhe Li Dr. Yanfei Jian Dr. Lianghui Xia Dr. Pei Su Qiyuan Liu Prof. Shouning Chai Dr. Mudi Ma Dr. Abdallah Amedlous Dr. Mathias Barreau Prof. Zhengping Hao Prof. Jiaguo Yu Prof. Chi He State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 Shaanxi P.R. China Laboratoire Catalyse & Spectrochimie Normandie Univ ENSICAEN UNICAEN CNRS Caen 14000 France Department of Chemistry Tsinghua University Beijing 100084 P.R. China College of Environmental and Chemical Engineering Yanshan University Qinhuangdao 066004 P.R. China National Engineering Laboratory for VOCs Pollution Control Material & Technology University of Chinese Academy of Sciences Beijing 101408 P.R. China Laboratory of Solar Fuel Faculty of Materials Science and Chemistry China University of Geosciences Wuhan 430078 P.R. China

Achieving active and stable heterogeneous catalysts by encapsulating noble metal species within zeolites is highly promising for high utilization and cost efficiency in thermal and environmental catalytic reactions. Ru, considered an economical noble metal alternative with comparable performance, faces great challenges within MFI-type microporous zeolites due to its high cohesive energy and mobility. Herein, an innovative strategy was explored that couples hydrothermal in situ ligand protection with stepwise calcination in a flowing atmosphere to embed ultrasmall Ru clusters anchored at K + -healed silanol sites (≡Si−Ru δ+ −O−K complexes) within 10-membered ring sinusoidal channels of MFI. Comprehensive experiments and theoretical calculations unveiled that the interplay between confined Ru clusters and MFI induces local strain in MFI, creating a unique catalytic microenvironment around the Ru clusters. This synergy interaction enhances alkane deep oxidation as the confined Ru clusters and the MFI microenvironment collectively pre-activate C 3 H 8 and O 2 , facilitate the cleavage of C−H and C−C bonds at low temperatures. Notably, the stable geometric and electronic properties of the confined Ru show exceptional thermal stability up to 1000 °C, rivaling fresh catalysts. These findings shed vital methodological and mechanistic insights for developing efficacious heterogeneous catalysts for thermal catalysis.

关键词： heterogeneous catalysis microenvironment Ruthenium strain zeolite

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Vibrational relaxation in compressible isotropic turbulence with thermal nonequilibrium

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Physical Review Fluids 2020年第4期5卷 044602-044602页

作者： Qinmin Zheng Jianchun Wang Bernd R. Noack Hui Li Minping Wan Shiyi Chen Shenzhen Key Laboratory of Complex Aerospace Flows Center for Complex Flows and Soft Matter Research Department of Mechanics and Aerospace Engineering Southern University of Science and Technology Shenzhen 518055 China School of Power and Mechanical Engineering Wuhan University Wuhan 430072 China Institute for Turbulence-Noise-Vibration Interaction and Control Harbin Institute of Technology (Shenzhen) Shenzhen 518055 China LIMSI CNRS Université Paris-Saclay Bât 507 rue du Belvédère Campus Universitaire F-91405 Orsay France Institut für Strömungsmechanik und Technische Akustik Technische Universität Berlin Müller-Breslau-Straße 8 D-10623 Berlin Germany State Key Laboratory of Turbulence and Complex Systems Peking University Beijing 100871 China

As pioneered by Donzis and Maqui [J. Fluid Mech. 797, 181 (2016)] and Khurshid and Donzis [Phys. Fluids 31, 015103 (2019)], the compressible isotropic turbulence in thermal nonequilibrium is drawing attention in the fluid dynamics community. In the present study, the vibrational rate and the dissipation or production of vibrational energy fluctuation of compressible isotropic turbulence with solenoidal forcing in vibrational nonequilibrium are investigated using numerical simulations. The turbulent Mach number (Mt) is set to be 0.44 and 1.09, and the Taylor Reynolds number (Reλ) equals 98.58 approximately. The focus is on the effect of the normalized vibrational relaxation time (Kτ) and characteristic temperature (θv) on statistical features of the vibrational rate and the dissipation or production components of vibrational energy fluctuation. When Kτ is small (≲1.0), the average of normalized vibrational rate conditioned on the normalized dilatation is positive in the compression region and negative in the expansion region, enhanced with increase of compression and expansion level, respectively. It indicates that, on average, the energy transfers from translational-rotational to vibrational modes in the compression region and in the inverse direction in the expansion region. The conditional average of the normalized vibrational rate reduces with increase of Kτ, and is insensitive to θv. The joint probability density functions (PDFs) and conditional PDFs of the normalized vibrational rate are also analyzed, to reveal the effect of compression and expansion motions on the internal energy exchange between the translational-rotational and vibrational modes. The dissipation or production of vibrational energy fluctuation can result from effects of dilatation, thermal diffusion, and vibrational relaxation. The dissipation component due to thermal diffusion always weakens the vibrational energy fluctuation in both compression and expansion regions for the weakly and highl

关键词： Compressible flows Nonequilibrium & irreversible thermodynamics Turbulence

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Revealing the unexpected promotion effect of EuO_x on Pt/CeO_2 catalysts for catalytic combustion of toluene

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Chinese Journal of Catalysis 2019年第4期40卷 543-552,M0003页

作者： Baoming Zhao Yanfei Jian Zeyu Jiang Chi He Xi’an Modern Chemistry Research Institute Xi’an 710065ShaanxiChina State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power EngineeringXi'an Jiaotong UniversityXi'an 710049ShaanxiChina Department of Chemistry College of ScienceImam Abdulrahman Bin Faisal UniversityP.O.Box 1982Dammam 31441Saudi Arabia National Engineering Laboratory for VOCs Pollution Control Material & Technology University of Chinese Academy of SciencesBeijing 101408China

Pt/Eu2O3-CeO2 materials with different Eu concentrations were prepared and applied to toluene destruction,and the remarkable promotion impact of EuOx on Pt/CeO2 can be *** characterization results reveal that the presence of EuOx significantly enhances the redox property,lattice O concentration,and Ce3+ ratio of the Pt/CeO2 material,which facilitates the dispersion and activity of Pt active sites and thus accelerates the decomposition process of *** all catalysts,a sample with an Eu content of 2.5 at.%(Pt/EC-2.5)possesses the best catalytic activity with 0.09 vol% of toluene completely destructed at 200 ℃ under a relatively high GHSV of 50000 h^-*** possible reaction pathway and mechanism of toluene combustion over Pt/Eu2O3-CeO2 samples are presented according to in-situ DRIFTS,which confirms that the toluene oxidation process obeys the Mars-van Krevelen mechanism with aldehydes and ketones as primary organic intermediates.

关键词： Pt/Eu2O3-CeO2 material Promotion effect Toluene Catalytic oxidation In-situ DRIFTS Reaction mechanism

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Front Cover: Decoupled Water Electrolysis Driven by 1 cm2Single Perovskite Solar Cell Yielding a Solar-to-Hydrogen Efficiency of 14.4 % (ChemSusChem 1/2023)

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ChemSusChem 2022年第1期16卷

作者： Fei Lv Dr. Zhixiao Qin Jiazhe Wu Lixia Pan Longjie Liu Prof. Yubin Chen Prof. Yixin Zhao International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Shaanxi 710049 P. R. China School of Environmental Science and Engineering Frontiers Science Center for Transformative Molecules Shanghai Jiao Tong University Shanghai 200240 P. R. China

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A study of a computational BVP for heat transfer and friction drag in magnetohydrodynamics viscous flow of a nanofluid subject to the curved surface

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Proceedings of the Institution of Mechanical Engineers, Part E: Journal of Process Mechanical engineering 2021年

作者： Khan, M Riaz Saleel, C Ahamed Saeed, Tareq Allehiany, F.M. El-Refaey, Adel M Jing, Dengwei Mahmoud, Emad E LSEC and ICMSEC Academy of Mathematics and Systems Science Chinese Academy of Sciences China School of Mathematical Science University of Chinese Academy of Sciences China Department of Mechanical Engineering College of Engineering King Khalid University Saudi Arabia -Research Group Department of Mathematics Faculty of Science King Abdulaziz University Saudi Arabia Department of Mathematical Sciences College of Applied Sciences Umm Al-Qura University Saudi Arabia Department of Basic and Applied Science College of Engineering and Technology Arab Academy for Science Technology Maritime Transport Smart Village Campus Egypt State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University China Department of Mathematics and Statistics College of Science Taif University Taif Saudi Arabia

The ongoing work investigates the features of Joule heating and convective condition over a magnetohydrodynamic stagnation point flow of (Formula presented.) nanofluid moving across a curved surface. Moreover, mass suction is supposed through the stretching/shrinking surface. The initially developed model of partial differential equations is transformed into the ordinary ones assisted by suitable similarity variables. Subsequently, the ultimate nonlinear model of ordinary differential equations is solved with the help of a built-in function bvp4c package in MATLAB. Several graphical results are plotted to see the influence of various dimensionless parameters over the velocity, temperature, heat transfer, and friction drag. We found that there exists an escalation in temperature with increasing values of curvature, Eckert number, Hartmann number, and Biot number;however, the velocity profile declines with large curvature, ratio parameter, and high concentration of nanoparticles. It is also important to note that the friction drag rises with the mass suction, and reduces with vast curvature, whereas the rate of heat transfer improves with suction and Biot number but lowers with Eckert number and Hartmann number. © IMechE 2021.

关键词： Magnetohydrodynamics

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Novel Cu_3P/g-C_3N_4 p-n heterojunction photocatalysts for solar hydrogen generation

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Science China Materials 2018年第6期61卷 861-868页

作者： Zhixiao Qin Menglong Wang Rui Li Yubin Chen International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University

Developing efficient heterostructured photocatalysts to accelerate charge separation and transfer is crucial to improving photocatalytic hydrogen generation using solar energy. Herein, we report for the first time that p-type copper phosphide（Cu3P） coupled with n-type graphitic carbon nitride（g-C3N4） forms a p-n junction to accelerate charge separation and transfer for enhanced photocatalytic *** optimized Cu3P/g-C3N4 p-n heterojunction photocatalyst exhibits 95 times higher activity than bare g-C3N4, with an apparent quantum efficiency of 2.6% at 420 nm. A detail analysis of the reaction mechanism by photoluminescence,surface photovoltaics and electrochemical measurements revealed that the improved photocatalytic activity can be ascribed to efficient separation of photo-induced charge carriers. This work demonstrates that p-n junction structure is a useful strategy for developing efficient heterostructured photocatalysts.

关键词： photocatalysis copper phosphide p-n junction heterostructure hydrogen production

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Vapor condensation with low air mass fraction inside water seal branch tube under free convection

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Nuclear engineering and Design 2021年 379卷

作者： Bing Tan Xi Wang Y.W. Wu W.X. Tian S.Z. Qiu G.H. Su School of Nuclear Science and Technology State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University 28 Xianning West Road Xi an 710049 China School of Electric Power South China University of Technology Guangzhou 510640 China

The pressure vessel has used a newly designed water seal structure, and the sealed water is from condensation at low hydrogen concentration. To get the condensation capacity of the water seal branch tube under the pressure vessel normal operation, the experimental loop named WASETEL was constructed, which is aimed at studying the heat transfer during the process of air-steam mixture condensation inside the inclined branch tube at the condition of low air mass fraction. The inner tube is diameter 0.134 m with length 0.68 m which is connected with diameter 1.4 m, high 2.5 m pressure vessel. A canon camera was set to record the images and videos of the condensate height through glass tube in communicating vessel liquidometer. The experiment was conducted under the pressure ranged from 0.2 to 0.6 MPa, air mass concentration ranged from 0.49 to 6.42% and wall subcooling ranged from 11 to 40 K. The test showed HTC (heat transfer coefficient) would sharply deteriorate with the small air fraction, compared with pure steam condensation, about 0.49% mass fraction of the air will reduce heat transfer coefficient by 70–80%. When air concentration is relatively small, those widely used relations can not predict the condensation well, therefore, a new heat transfer empirical correlation with air mass fraction, pressure and subcooling is proposed, covered all the experimental data within the error band ±13%.

关键词： Natural condensation New empirical correlation Water seal

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