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Insights into Charge Transfer at an Atomically Precise Nanocluster/Semiconductor Interface

Angewandte Chemie 2020年第20期132卷

作者： Yu Wang Xiao‐He Liu Qiankun Wang Martin Quick Sergey A. Kovalenko Qing‐Yun Chen Norbert Koch Nicola Pinna Institut für Chemie and IRIS Adlershof Humboldt-Universität zu Berlin Brook-Taylor-Strasse 2 12489 Berlin Germany International Research Center for Renewable Energy (IRCRE) and State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'an Jiaotong University Xi'an 710049 P. R. China Institut für Physik and IRIS Adlershof Humboldt-Universität zu Berlin Brook-Taylor-Strasse 6 12489 Berlin Germany

The deposition of an atomically precise nanocluster, for example, Ag 44 (SR) 30 , onto a large‐band‐gap semiconductor such as TiO 2 allows a clear interface to be obtained to study charge transfer at the interface. Changing the light source from visible light to simulated sunlight led to a three orders of magnitude enhancement in the photocatalytic H 2 generation, with the H 2 production rate reaching 7.4 mmol h −1 g catalyst −1 . This is five times higher than that of TiO 2 modified with Ag nanoparticles and even comparable to that of TiO 2 modified with Pt nanoparticles under similar conditions. Energy band alignment and transient absorption spectroscopy reveal that the role of the metal clusters is different from that of both organometallic complexes and plasmonic nanoparticles: A type II heterojunction charge‐transfer route is achieved under UV/Vis irradiation, with the cluster serving as a small‐band‐gap semiconductor. This results in the clusters acting as co‐catalysts rather than merely photosensitizers.

关键词： Ladungstransfer Cokatalysatoren Photosensibilisator Silber-Nanocluster

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Ash Deposition and Alkali Metal Migration during Zhundong High-alkali Coal Gasification

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Energy Procedia 2017年 105卷 1350-1355页

作者： Guangyu Li Chang’an Wang Pengqian Wang Yongbo Du Xuan Liu Wufeng Chen Defu Che State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an 710049 China

Ash deposition is particularly serious during Zhundong coal combustion/gasification due to its high alkali metal content, which causes great troubles and limits its utilization. This paper focuses on the ash deposition characteristics and migration disciplinarian of akali metal during Zhundong coal gasification varing with different conditions, such as ash deposition temperature, gasification temperature, O 2 /coal, steam/coal, and deposition time. Experimental result indicates that gasification conditions play a significant role on ash deposition. The root cause of severe fouling is the high content of Na in Zhundong coal, most of which is water-soluble. Besides, the contents of Na, Fe, S, Cl in ash are obviously changed with flue gas temperature increasing, indicating these elements have great influence on ash deposition, and the migration of Na, Fe and Cl presents similar variation during deposition. In addition, Na deposits mainly above 873 K, and Fe gains enrichment in ash at various temperatures. With the increase of gasification temperature, the content of Na in the ash is increased, which could exacerbate ash deposition. Both O 2 /coal and steam/coal have a certain influence on migration of elements, and the increases of O 2 /coal and steam/coal can relieve the ash fouling phenomena. Deposited ash on heating surface will react with Na in flue gas at high temperature, leading to the increase of content of Na in the ash with deposition time increasing.

关键词： Coal gasification Zhundong coal alkali metal ash Deposition

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Chaotic Characteristics Analysis on Recognition of Steam Plume Flow Pattern of Direct Contact Condensation in a Rectangular Channel

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Energy Procedia 2017年 142卷 3827-3832页

作者： Binbin Qiu Jia Liu Jiping Liu Junjie Yan Xiaoping Yang State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an 710049 China

Chaotic characteristics of direct contact condensation(DCC) for steam jet in subcooled water in a rectangular channel were analyzed at subcooled water temperature of 30 ℃. The steam mass flux and Reynolds number of subcooled water were in the range of 250-600kg/(m 2 s) and 78,000-172,000 respectively. Three different flow patterns, bubble flow, oscillation jet and stable jet, were observed. Correlation dimension( D 2 ) changes with flow patterns. For bubble flow, oscillation jet and stable jet, the corresponding correlation dimension values increase and are in the ranges of 9.68~10.30, 10.03~11.17 and 11.10~12.62, respectively. Different flow patterns have different Hurst exponent( H ). From the range of correlation dimensions and Hurst exponents, the flow pattern of steam jet can be recognized without looking the picture of steam plume. This result is very important for flow pattern recognition without the observation windows.

关键词： flow pattern recognition chaotic characteristics correlation dimension Hurst exponent

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Experimental study on pressure drop characteristic of wet air with ash particles in a horizontal tube bundle heat exchanger

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Energy Procedia 2017年 142卷 4010-4015页

作者： Yuanzhi Qin Jingying Yang Haibo Dai Jinshi Wang Ming Liu Junjie Yan State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an 710049 China

The pressure drop characteristic of wet air with ash particles in a horizontal tube bundle heat exchanger was studied experimentally. The variations with time, effects of water vapor mass fractions and mainstream velocities on pressure drop characteristic were presented. Experimentally results showed that with the increase in the time, the pressure drop coefficient firstly increased then became stable. In the case of wet air with ash particles, the pressure drop coefficient increased with the increase of the water mass fraction and decreased with the increase of the mainstream velocity. Compared with wet air without ash particles, the pressure drop coefficients were higher in the presence of ash particles, due to ash deposition.

关键词： Pressure drop coefficient Heat exchanger wet air Ash particles

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Release and Transformation of Potassium during Combustion of Biomass

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Energy Procedia 2017年 142卷 401-406页

作者： Lei Deng Jiaming Ye Xi Jin Tao Zhu Defu Che State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an 710049 China

To investigate the release and transformation of fuel K during combustion of biomass, wheat straw and corn stalk are burnt in a fixed-bed reactor system during 400−1000 °C, and weight measurement, elemental composition analysis, and chemical fractionation analysis are performed. The influences of fuel type, combustion temperature, and water washing pretreatment are discussed. The results show that wheat straw has a higher K release ratio than corn stalk, especially when combustion temperature is above 500 °C. For both biomass fuels, the released K is far less than the water-soluble K. For wheat straw, some of the other occurrence modes of K turn into the insoluble K gradually. For corn stalk, the water-soluble and ion-exchangeable K turn into HCl-soluble and insoluble K. Water washing removes all the water-soluble K of corn stalk and reduces the K release from 3.26 to 0.27 mg g -1 at 1000 °C.

关键词： Potassium release Transformation Biomass combustion Water washing

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Experimental study on heat transfer to supercritical CO2 flowing in vertical upward tube at medium mass flux

Experimental study on heat transfer to supercritical CO2 flo...

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ASME 2017 Nuclear Forum, NUCLRF 2017, collocated with the ASME 2017 power Conference Joint with ICOPE 2017, the ASME 2017 11th International Conference on Energy Sustainability, and the ASME 2017 15th International Conference on Fuel Cell Science, engineering and Technology

作者： Zhang, Qian Li, Huixiong Kong, Xiangfei Zhang, Jun Lei, Xianliang Zhang, Weiqiang State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi'anShaanxi China North Carolina State University United States Burlington Laboratory 3144 North Carolina State University RaleighNC27607 United States

ISBN: (纸本)9780791840597

An experimental study was performed on heat transfer characteristics of supercritical pressure CO2 (SC-CO2) flowing at medium mass flux conditions in a vertically-upward tube of 16 mm inner diameter at the Heat Transfer and Flow test loop of Supercritical CO2 (HTF-SCO2) in Xi’an Jiaotong University. Experimental parameters included the pressure ranging from 7.5 to10.5 MPa, the mass flux of 400-600 kg/m2s, and the heat flux of 20-100 kW/m2. Based on the experimental data, effects of mass flux, heat flux and operation pressure on heat transfer characteristics of SC-CO2 were thoroughly discussed. With the decrease of mass flux and increase of heat flux, heat transfer characteristics of SC-CO2 becomes worse and worse. The wall temperature rises to high levels with the occurrence of a wall temperature peak and the wall temperature peak also rises remarkably with the decrease in mass flux and increase in heat flux. Especially, effect of pressures on the heat transfer of SC-CO2 was found to be quite different from that previously reported in literature. When the heat flux is low (such as 30 kW/m2), the HTD was diminished with the increase in pressures, but when the heat flux is up to 50 kW/m2, the HTD is surprisingly intensified by the increase of pressure. The buoyancy effect was considered to explain this distinct influence of pressure on the heat transfer of SC-CO2 by employed a non-dimensional parameter Bu. With the increase of pressure, buoyancy effect was diminished owing to the decrease of density difference between fluids near the wall and the center. When heat flux was lower, the Bu was located between 5×10-6 and 10-4, where buoyancy effect impaired heat transfer, so the heat transfer coefficient increased by rising pressure. But when heat flux was larger, the Bu was above 10-4, where buoyancy effect began to enhance heat transfer, as a result, the heat transfer coefficient was reduced by weakened buoyancy effect because of the increase of pressure (CSPE). Copyrig

关键词： Heat flux

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Flame brush thickness of premixed turbulent flames: Hydrodynamic theory versus experiments 9

Flame brush thickness of premixed turbulent flames: Hydrodyn...

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9th International Conference on Modeling and Diagnostics for Advanved Engine Systems, COMODIA 2017

作者： Zhang, M. Patyal, A. Fogla, N. Wang, J.H. Huang, Z.H. Matalon, M. State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China Department of Mechanical Science and Engineering University of Illinois at Urbana-Champaign UrbanaIL61801 United States

The effect of varying turbulence intensities on the flame brush thickness is investigated numerically using a hybrid Navier-Stokes/front-tracking methodology in the context of the hydrodynamic theory. Two configurations, namely planar and Bunsen, are chosen with the latter used for direct comparison with experimental OH-PLIF Bunsen flame images. The Darrieus-Landau influences are controlled through the mixture Markstein length and the flame brush is analyzed under two regimes, sub- and supercritical based on the absence/presence of the hydrodynamic instability. In the planar configuration at low intensities, the sub-critical flame brush retains its near flat shape, while the super-critical flame brush forms a highly corrugated structure reminiscent of the cusped-like flames that result in the laminar setting. With increasing turbulence levels, these effects start to gradually diminish as the flame becomes dominated by velocity fluctuations arising from the turbulent field, finally leading to nearly identical behavior in both regimes for very high intensities. Unlike the planar flame, the sub-critical Bunsen flame surface is dominated by large wrinkles with a more rounded shape while the super-critical flame highlights the formation of cusp-like structures on its surface. Numerical verification of the Bunsen flame brush thickness shows a good qualitative match with experimental tests for turbulent CH4/air flames. The good agreement indicates the qualitative prediction capabilities of the hydrodynamic model. Copyright © 2017 by the Japan Society of Mechanical Engineers.

关键词： Navier Stokes equations

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A comprehensive model for uniform heat flux inside cavity receiver with air-carbon mixture

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Energy Procedia 2017年 142卷 177-183页

作者： Yabin Jin Jiabin Fang Jinjia Wei Xinhe Wang State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an Shaanxi 710049 China

Cavity receiver is one of the main components of efficient concentrating solar collector systems. It has the ability to operate at relatively higher temperature and efficiency. The safety and thermal efficiency of solar cavity receiver can affect the efficiency of the whole power system. However, the non-uniform distribution of heat flux and temperature inside the cavity tends to cause the operation instability and bring damage to the tube as well. In the present work, a comprehensive numerical model was developed by coupling Monte Carlo Ray Tracing (MCRT) and Finite Volume Method (FVM) to simulate the thermal performance of a 2D square solar cavity filled with air-carbon particle mixture. Firstly, the complicated photon transmission in the air-carbon particle mixture absorber is simplified as the transmission process in the statistically homogenous and isotropic turbid media. The solar heat flux distribution from the aperture to the wall is simulated by MCRT, and the photo-thermal convection process in the cavity receiver is modeled by FVM. Then the two parts are coupled in the cavity receiver by transferring the absorbed energy computed by MCRT to FVM, and this energy is applied as a source term of the energy equation in the FVM part. Based on this model, the temperature and heat flux characteristics of the cavity receiver were studied at various carbon densities. The result indicated that the air-carbon particle mixture can actively take part in the radiation and it appears that it has a remarkable effect on the temperature homogenization. It decreases the temperature of wall 3 dramatically and increases the temperature of wall 2 and wall 4. The relationships between the temperature unevenness and the number particle density were also analyzed. The temperature unevenness on the wall 3 drops most with the increase of number density of carbon particle, from 25.0K to 2.4K. The unevenness of temperature on the top and bottom walls also decreases slightly by 3K. In ad

关键词： solar cavity receiver non-uniform air-carbon particle mixture homogenization Monte Carlo ray tracing Finite volume method

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Influence of Oxy-fuel Atmosphere on Microscopic Physical-Chemical Properties of High-alkali Ash at Softening Temperature

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Energy Procedia 2017年 142卷 3240-3243页

作者： Chang’an Wang Hanqing Li Chenzhao Zhu Tao Han Yinhe Liu Lei Deng Defu Che State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an 710049 China

The utilization of high-alkali coals in Zhundong coalfield with oxy-fuel combustion technology has a great potential, however, the ash fusion properties of high-alkali coals are still unclear. Here, we studied the influence of oxy-fuel atmosphere on the microscopic properties of high-sodium ash. The change from air to oxy-fuel condition has a negligible influence on ash fusion temperatures, but exhibits certain impact on physical-chemical properties of high-alkali ash. Oxygen content presents a primary effect on the microscopic morphology of ash at softening temperature.

关键词： high-alkali coal oxy-fuel combustion CO 2 capture microscopic properties SEM

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Investigation on Heat Transfer Characteristics of the H-type Finned Tube in Flue Gas with High Content of Ash

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Energy Procedia 2017年 105卷 4680-4684页

作者： Tao Han Chang’an Wang Qi Cao Wufeng Chen Defu Che State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an 710049 China

H-type finned tube is rarely used in waste heat recovery power generation stations, though it has an efficient heat transfer performance in large thermal power stations (WHRPGs, hereafter). To date, understanding of heat performance of H-type finned tube in WHRPGs is still lacked. The heat transfer characteristics of H-type finned tube in gas with high content of ash in WHRPGs was investigated in practical cement plant in present work. The actual ash deposition pattern was observed meanwhile. The characteristics of heat transfer process including heat transfer coefficient, heat effective coefficient, and flue resistance at gas velocity between 4.5 - 6.5 m·s –1 are obtained. Experimental results show that the heat transfer coefficient increases with gas velocity linearly, the heat effective coefficient nearly keep stable on the other hand, and serious ash-block problem occurs in flow area in the heat exchanger at the gas velocity of 4.5 - 6.5 m·s –1 . The max heat transfer coefficient remain below 10 w·m –2 ·k –1 , implying heat performance of H-type finned tube in WHRPGs is possibly inefficient.

关键词： H-type finned tube heat performance heat transfer

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