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Research on Artificial Neural Network for Geometric Design and Optimization of Three-Stage Segmented Thermoelectric Generators

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SSRN 2024年

作者： Zhang, Yin Guo, Kailun Wang, Chenglong Zhang, Jing Wang, Yulu Tian, Wenxi Su, Guanghui Qiu, Suizheng School of Nuclear Science and Technology Shanxi Key Laboratory of Advanced Nuclear Energy and Technology State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi’an710049 China School of Mechatronic Engineering Xianyang Vocational Technical College Xi’an712000 China

More green and environmentally friendly electricity production is the driving force for the development of thermoelectric generators. In addition to high-performance thermoelectric materials, optimizing the geometric shape of thermoelectric generators can also maximize thermoelectric efficiency. This work applies artificial neural networks to the design and optimization of a three-stage segmented thermoelectric generator. After verifying the thermoelectric numerical model of COMSOL, this work generated 3000 sets of simulation data for neural network training. After hyperparameter and particle swarm optimization, the trained neural network can exhibit extremely high prediction accuracy. By coupling the genetic algorithm and artificial fish swarm algorithm, the trained artificial neural network can optimize eight geometric parameters of a three-stage segmented thermoelectric generator under different temperature differences. Compared with COMSOL optimization results, the conversion efficiency optimized by GA has increased by 1.42% and 2.48% in cases 1 and 2, respectively;The conversion efficiency optimized by AFSA has increased by 3.61% and 2.86% in cases 1 and 2, respectively. By obtaining almost identical optimization values, the neural network can achieve geometric design optimization within 5 minutes under different temperature differences. This method provides a new and economical avenue for rapid prediction and design of thermoelectric generators. © 2024, The Authors. All rights reserved.

关键词： Genetic algorithms

Experimental Study on Frost Crystal Morphologies and Frosting Characteristics Under Different Working Pressures

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SSRN 2022年

作者： Lai, Tianwei Liu, Xue Dong, Xiaojun Qiang, Mingchen Yan, Shaohang Hou, Yu State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

Frost usually grows on the cooling surface of heat transfer equipment which often operates under different working pressures. In such conditions, one of the fundamental influencing factors of frosting, the diffusion coefficient of water vapor around the cooling surface is different from that in the normal atmosphere pressure. In order to investigate the pressure effect on frosting, a test rig for frosting visualization is designed. The role of working pressure around the cooling surface on the frost crystal morphologies and frost layer characteristics are evaluated under different air parameters and temperatures of cooling surface. The vertical growth and lateral distribution of frost crystals are related strongly to working pressure around the cooling surface. More frost crystal morphologies and faster growth rate of frost layer are presented at a lower pressure. The frost thickness, frost accumulation and density reduce with higher pressure. The dimensionless correlation of frost thickness is proposed considering working pressure around the cooling surface, humid air parameters, and temperature of cooling surface. © 2022, The Authors. All rights reserved.

关键词： Working pressure

Co_(2)N Nanoparticles Anchored on N-Doped Active Carbon as Catalyst for Oxygen Reduction Reaction in Zinc–Air Battery

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Energy & Environmental Materials 2022年第3期5卷 935-943页

作者： Xianli Wu Guosheng Han Hao Wen Yanyan Liu Lei Han Xingyu Cui Jiajing Kou Baojun Li Jianchun Jiang Research Center of Green Catalysis College of ChemistryZhengzhou University100 Science RoadZhengzhou 450001China National Engineering Laboratory for Biomass Chemical Utilization Institute of Chemical Industry of Forest ProductsChinese Academy of ForestryNanjing 210042China College of Science Henan Agricultural UniversityZhengzhou 450002China Davidson School of Chemical Engineering Purdue University480 Stadium Mall DriveIN 47906United States State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University28 Xianning West RoadXi'an 710049China

The development of efficient catalytic electrode toward oxygen reduction reaction(ORR)is still a great challenge for the wide use of zinc–air ***,Co_(2)N nanoparticles(NPs)anchored on N-doped carbon from cattail were verified with excellent catalytic performances for *** onset and half-wave potentials over the optimal catalyst reach to 0.96 V and 0.84 V,*** retention rates of 96.8%after 22-h test and 98.8%after running 1600 s were obtained in 1 M methanol *** functional theory simulation proposes an apparently increased electronic states of Co_(2)N in N-doped carbon layer close to the Fermi *** charge density,favorable adsorption,and charge transfer of intermediates originate from the coexistence of Co_(2)N NPs and N atoms in carbon *** superior catalytic activity of composites also was confirmed in zinc–air *** novel catalytic property and controllable preparation approach of Co_(2)Ncarbon composites provide a promising avenue to fabricate metal-containing catalytically active carbon from biomass.

关键词： catalytically active carbon Co2N nanoparticles N-doping oxygen reduction reaction zinc–air battery

Effect of Mixer Structure on Liquid Film Formation and Nox Conversion Efficiency in Selective Catalytic Reduction System

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SSRN 2022年

作者： Fu, Hang Huang, Zuohua Tang, Chenglong State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

Selective Catalytic Reduction as an efficient technology to reduce NOx emission has been widely applied in exhaust aftertreatment system. However, the reductant injection causes inevitable impingement on the exhaust pipe and mixer surface and the liquid film will be generated. In this paper, the simulation of a double-blade mixer (Mixer 1) is verified by a bench test and other three kinds of mixer structures (baffle mixer: Mixer 2, blade-baffle mixer: Mixer 3, and blade mixer: Mixer 4) are simulated. The effect of the mixer structures on the liquid film formation, the pressure drop, the flow and temperature distribution after the mixers and ultimately the NOx conversion efficiency are investigated. Results show that the liquid film is prone to form and accumulate at the connection region between the mixer and exhaust pipe, and liquid film tends to develop with the flow direction. Mixer 2 and Mixer 4 shows smaller liquid film area about 15 cm2. The temperature distribution in four types of mixers shows negligible difference (within 4 °C). NH3 mass fraction distribution uniformity and pressure drop shows a trade-off relationship. For the vertical injection system, it is found Mixer 3 gets the worst NOx conversion efficiency, 57%, and Mixer 2 shows better NOx conversion efficiency, 78%. The paper are supportive to the SCR mixer selection and design. © 2022, The Authors. All rights reserved.

关键词： Computational fluid dynamics

The blow-off and transient characteristics of co-firing ammonia/methane fuels in a swirl combustor 38th

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The blow-off and transient characteristics of co-firing ammo...

38th International Symposium on Combustion, 2021

作者： Zhang, Meng Wei, Xutao Wang, Jinhua Huang, Zuohua Tan, Houzhang State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China MOE Key Laboratory of Thermo-Fluid Science and Engineering Xi'an Jiaotong University Xi'an 710049 China

Recent studies have demonstrated that ammonia could be one of the most promising hydrogen carrier candidates which can be used in large-scale power plants. However, it is challenging to burn ammonia in gas turbines due to its narrow flame stabilization limits. In this study, the blow-off characteristics and flame macrostructure transition behavior of ammonia/air flame (NH₃ flame) and ammonia/methane/air flame (50%NH₃ flame) in a swirl combustor were investigated. Flame structures and flow fields near the blow-off limit were analyzed. Methane/air flame (CH₄ flame) was also examined for comparative purposes. The flow field and instantaneous OH profile were measured with PIV and OH-PLIF technique, respectively. Large eddy simulation (LES) was conducted to extend the understanding of the experimental findings. Results revealed that the NH₃ flame possesses a poor lean flame stability limit which can be largely extended by adding CH₄ in the fuel. Changing swirl number (S) had no apparent effect on the lean blow-off limit (Φ_b) for the NH₃ flame. On the contrary, a clear extension on Φ_b was found for the 50%NH₃ flame when increasing S. Four flame macrostructure modes were identified when decreasing equivalence ratio (Φ). The transition from flame II to flame III ((Φ_tdescribes the transition equivalence ratio) can be considered as the early warning of blow-off for a swirl stabilized flame. For the NH₃ flame, there was no clear flame macrostructure transition at small inlet velocities (U < 3.8 m/sec), i.e., Φ_b ≈ Φt. The difference between Φ_b and (Φ_twas observed as the inlet velocity increased. However, for the 50%NH₃ and CH₄ flames, a clear flame macrostructure transition from flame II to flame III was observed even for a lower inlet velocity. The LES results demonstrated that the NH₃ flame h

关键词： Ammonia

Preparation, improvement, and application of metal–organic framework-based sensing materials for gas leakage and emission: A review

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Nano Materials Science 2025年

作者： Liu, Manyi Wang, Liang Ren, Shan Bai, Bofeng Chai, Shouning He, Chi Zheng, Chunli Yin, Xitao Li, Fengguang College of Materials Science and Engineering Chongqing University Chongqing400044 China State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'an Jiaotong University Xi'an710049 China School of Physics and Optoelectronic Engineering Ludong University Yantai264000 China School of Materials Science and Engineering Hubei University of Automotive Technology Shiyan442002 China

Industrial gas leaks and flue gas emissions pose significant threats to the safety of industrial operations and the atmospheric ecological environment. Traditional gas sensing materials often struggle to meet the challenges posed by complex industrial environments. Recently, metal-organic framework (MOF)-based gas sensing materials have garnered significant attention in industrial gas detection due to their high sensitivity, selectivity, and tunable properties. The exponential increase in related publications highlights the growing research interest in this field. This paper presents a comprehensive review of the advantages of various types of metal-organic frameworks and their derivatives for detecting industrial gas leaks and flue gas emissions, alongside an introduction of representative MOF synthesis methods. Furthermore, the primary sensing mechanisms of MOF-based gas sensing materials and strategies for enhancing the sensing performance are summarized. The current state of MOF-based gas sensing materials in industrial gas detection is also discussed. Finally, the potential limitations, existing challenges, and future directions of MOF-based industrial gas sensing materials are systematically analyzed, with suggestions for addressing these challenges to advance industrial gas detection technologies. © 2025 Chongqing University

关键词： Application Improvement Industrial gas detection MOF-Based sensing materials Preparation

Numerical Investigation on the Radiation Performance of a Crisscross Liquid Droplet Radiator in Space Under Different Operating Conditions

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SSRN 2022年

作者： Zhu, Maoguo Sha, Zhaoyang Zhao, Quanbin Chong, Daotong Chen, Weixiong Yan, Junjie State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'An710049 China

Crisscross liquid droplet radiator (LDR) is a promising solution for the heat dissipation of large-power space structures. In this study, a three-dimensional steady numerical simulation of the radiation performance of crisscross LDR in space under different operating conditions was conducted. Significantly, the radiation interaction between adjacent droplet planes was introduced into the radiation model to accurately compute the energy radiated by the crisscross droplet sheet. Simulation results indicated the radiation performance of crisscross droplet sheet deteriorated with an increase in the nonuniformity of droplet planes arrangement and hence droplet planes uniformly arranged were required for a good crisscross LDR. Moreover, there existed a critical droplet sheet angle of 72° where the pressure disturbance frequency almost had no influence on the radiation performance of crisscross LDR. For certain pressure disturbance frequency, decreasing the droplet sheet angle can expand the available operational pressure difference range. The radiation performance of crisscross LDR with high initial droplet temperature was more sensitive to the changes in droplet sheet angle than that with low initial droplet temperature. Finally, the optimal working medium collocation scheme and droplet sheet configuration for crisscross liquid metal LDR were proposed. Given the lightweight and efficiency of crisscross liquid metal LDR, the collocation scheme of working medium including tin and lithium can be adopted and the droplet sheet angle should be designed as 15°. The present work can provide significant guidance for selecting suitable operating conditions for droplet generators to optimize the thermal design of a crisscross LDR. © 2022, The Authors. All rights reserved.

关键词： Drops

Integrated Co2 Capture and Conversion by Three-Step Chemical Looping Dry Reforming of Methane

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SSRN 2025年

作者： Liu, Yunlian Liu, Mingkai Shen, Yuanhui Li, Yang Gai, Zhongrui Zhang, Ruqi Pan, Ying Jin, Hongguang Institute of Engineering Thermophysics Chinese Academy of Sciences Beijing100190 China University of Chinese Academy of Sciences Beijing100049 China State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

The integrated CO2 capture and conversion (ICCC) has emerged as a promising and cost-effective pathway for achieving carbon neutrality. However, limited energy-efficient pathways and durable materials for ICCC systems remains challenging. This study proposes a novel approach that synergistically integrates CO2 capture and conversion through a unified chemical framework. The method employs Li-based sorbents for CO2 capture, coupled with CH4-driven sorbent regeneration that is seamlessly integrated with chemical looping dry reforming of methane (CLDRM), enabling in-situ CO2 conversion. By coupling sorbent regeneration with CLDRM, this system enhances decarbonation kinetics through Le Chatelier's principle via continuous CO2 conversion. One-step calcination synthesized Li-based sorbents particles exhibit stable CO2 capture capacity of 5.25 mmol·g-1 within 15 min per cycle, maintaining 7.5-15% operational efficiency over 40 cycles at 600 ℃. In CLDRM, hydrogen radicals from CH4 dissociation promote the conversion of CO2 to intermediates, lowering the apparent activation energy of sorbents regeneration by 29.2%. Through systematic optimization in a fixed-bed reactor, we achieved 90% CO2 uptake and 85% CH4 conversion, with syngas production rates reaching 13.71 mL·min-1·g-1. Notably, the H2/CO molar ratio in syngas stabilizes ~1.6, aligns with iron-based Fischer-Tropsch and methanol synthesis to produce valuable fuels. This integrated system maintains >80% syngas purity with © 2025, The Authors. All rights reserved.

关键词： Activation energy

An Experimental Study on Ash Deposition Problem of Low-Low Temperature Flue Gas System 9th

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An Experimental Study on Ash Deposition Problem of Low-Low T...

9th International Symposium on Coal Combustion, ISCC 2019

作者： Yan, Yu Jiang, Jiahao Guo, Jin Li, Yuesheng Deng, Lei Che, Defu State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an710049 China Guangdong Institue of Special Equipment Inspection and Research Foshan528251 China Guangdong Institue of Special Equipment Inspection and Research Shunde Institue of Inspection Foshan528300 China

ISBN: (纸本)9789811616563

In order to achieve the ultra-clean emission standards, many power plants in China have completed the installation of low-low temperature flue gas system. However, during the operation of this system, many problems have emerged, such as the ash deposition problem in the heat exchanger and dry ESP (electrostatic precipitator). In this paper, the fixed adsorption system and entrained flow experimental system were built to study the ash deposition characteristics in low-low temperature flue gas system under different temperatures and particle sizes. The repose angle was measured to evaluate the flowability and adhesion capacity of ash particles. The results show that as the increase of adsorption time, the particle size increased gradually, and the agglomeration effect is attenuated after the particles have reached adsorption saturation. The time at which the ash particles began to agglomerate with each other was defined as the agglomeration threshold. As the adsorption temperature decreased, the particle size growth rate increased. The smaller the size of ash particles, the more significant the agglomeration effect. Large particles were easy to adsorb small particles, but the agglomeration effect between large particles was weak. In addition, in the initial stage of particle agglomeration, it was mainly included the adhesion between smaller particles and the adhesion of smaller particles on the surface of large particles. The followability of the ash particles was greatly reduced after the adsorption and agglomeration process. The repose angle of the ash particles increased as the temperature of the flue gas decreased. The smaller the particle size, the larger the repose angle changes, and the more pronounced the repose angle is influenced by the adsorption temperature. The flue gas temperature cannot be blindly dropped in pursuit of high sulfur oxide removal efficiency and dust removal efficiency. © 2022, Tsinghua University Press.

关键词： Particle size