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Understanding Copper Corrosion in Bentonite-Enriched Environments: Insights from the Point Defect Model

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SSRN 2024年

作者： Ning, Zhiyuan Zhou, Qulan Li, Na Macdonald, Digby D. Zhou, Jie State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China Departments of Nuclear Engineering and Materials Science and Engineering University of California at Berkeley BerkeleyCA94720 United States Xi’an Aerospace Propulsion Institution Xi’an China

The laboratory simulated copper corrosion in a bentonite/groundwater solution, analyzing the kinetics of metal passivation through potentiodynamic polarization, potentiostatic polarization, and electrochemical impedance spectroscopy experiments. Corrosion development patterns were inferred from morphological characterization, and the mechanisms by which bentonite affects copper corrosion were comprehensively elucidated based on the point defect model. The research revealed that bentonite affects copper corrosion resistance through Donnan exclusion, cation adsorption, and hydrolysis of salts. Based on the point defect model, the study elucidated the microscopic mechanism of pitting corrosion induced by bentonite hydrolysis salts, calculating the polarizability of the passive layer/outer layer interface as α = 0.1. The reliability of the cation adsorption and adsorption-desorption mechanisms was confirmed through experimental data fitting, point defect model fitting, and theoretical analysis. © 2024, The Authors. All rights reserved.

关键词： Hydrolysis

Thermodynamic Analysis on Supercritical Water Gasification of Oily Sludge Using a Continuous Two-Step Method

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SSRN 2024年

作者： Wang, Gaoyun Zhang, Chenghao Zhao, Qiuyang Gao, Yunbo Jin, Hui Guo, Liejin State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University No. 28 Xianning West Road Xi’an710049 China Technical Inspection Center Sinopec Shengli Oilfield Company Dongying257000 China

A large amount of oily sludge is produced every year around the world and the traditional treatment techniques for oily sludge have deficiencies of incomplete processing and high energy consumption. Supercritical water gasification (SCWG) technology can cleanly convert oily sludge into hydrogen-rich gas and does not require an energy-consuming drying process. This work constructed the desorption-gasification two-step SCWG system based on the previous experimental study and investigated the influences of feed concentration, gasification temperature and sludge compositions on the energy efficiency and exergy efficiency of the system. The results showed that the two-step system had higher energy efficiency and exergy efficiency, as well as better adaptability to various sludge compositions under maintaining high efficiency conditions. The energy efficiency and exergy efficiency of the two-step system were 61.2% and 45.3% respectively under the gasification temperature of 600 ℃ and the feed concentration of 100wt%, which were 91.95% and 93.67% higher than those of the single-step system. Additionally, the desorption unit of two-step system operated at lower temperature, resulting in decreased use of high-temperature resistant materials and reduced economic costs. This research provides valuable insights into the construction and optimization of two-step SCWG of oily sludge. © 2024, The Authors. All rights reserved.

关键词： Desorption

Influence of Bi3+ Doping on the Electrochemical Properties of Ti/Sb-Sno2/Pbo2 Electrode for Zinc Electrowinning

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SSRN 2024年

作者： Wu, Jia Kang, Xuanqi Xu, Shuangwen Wei, Zhen Xu, Shangyuan Liu, Kang Feng, Qing Jia, Bo Wang, Yunhai Xían Taijin New Energy & Materials Sci-Tech CO. Ltd Xi’an710016 China Department of Environmental Science and Engineering State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiao tong University Xi’an710049 China

Bi3+ doped Ti/Sb-SnO2/PbO2 electrode materials were fabricated by electrodeposition to improve its electrochemical performance in zinc electrowinning. The surface morphology, chemical composition and hydrophilicity of the as-prepared electrodes are characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and contact angle. The electrochemical measurement and the accelerate lifetime experiment are also conduct to investigate the electrocatalytic performance and stability of the electrodes. The results showed that Bi3+ modification electrode has an important effect on the coating morphology, crystal structure, surface hydrophilicity, electrocatalytic activity and stability. The electrode prepared from the solution containing 2 mmol·L-1 Bi(NO3)3 (marked as the Ti/Sb-SnO2/2Bi-PbO2 electrode) exhibits the best hydrophilicity performance (θ=21.6°) and the longest service life (1196 h). During the electrochemical characterization analysis, the Ti/Sb-SnO2/2Bi-PbO2 electrode showed the highest oxygen evolution activity, which can be attributed to the highest electroactive surface (qT*=21.20 C·cm-2) and the best charge transfer efficiency. DFT calculation demonstrate that the doping of Bi lead to the decrease in the OER reaction barrier and increase the DOS of the electrode, which further enhanced the catalytic activity and conductivity of the electrode. Moreover, the simulated zinc electrowinning experiment demonstrate that the Ti/Sb-SnO2/2Bi-PbO2 electrode consume less energy than other electrodes. Therefore, it is expected that the Bi modified electrodes may become a very promising electrode material for zinc electrowinning in the future. © 2024, The Authors. All rights reserved.

关键词： Hydrophilicity

Rate-limiting factors in thin-film evaporative heat transfer processes

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arXiv

arXiv 2024年

作者： Zhao, H. Poole, R. Zhou, Z. Wolfson School of Mechanical Electrical and Manufacturing Engineering Loughborough University Loughborough LeicestershireLE11 3TU United Kingdom State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

In this paper, we present a theoretical study aimed at investigating the rate-limiting factors in thin-film evaporative heat transfer processes, considering the finite-rate evaporation kinetics. The problems of evaporation of a flat thin-film in either pure vapours or vapour-inert-gas mixtures are analysed based on the non-dimensionalised macroscopic transport equations for continuum fluids, coupled with out-of-equilibrium kinetic boundary conditions. Both the full numerical solutions and asymptotic analytical solutions at slow evaporation limit are provided and applied to analyse thin water film evaporation. Existing solutions, assuming negligible heat transfer in the gas domain, or negligible temperature jump across the non-equilibrium kinetic layer, or more boldly a thermodynamically equilibrial interface (i.e. its temperature is at the saturation temperature), can be fully recovered from the more general solutions presented here. Our results show that while these assumptions hold in special cases, they can lead to significant errors in many conditions, especially when the film thickness δ is reduced to a few micrometers or thinner. We show that the conventional views that the rate-limiting factors in thin-film evaporative heat transfer is either the heat diffusion through the liquid film or the mass transfer in the gas domain only apply to thick film (i.e. δ λ where λ is the mean free path in the vapour phase). As δ decreases to a few micrometer or smaller (more precisely when the Knudsen number Kn increases beyond O(1) in an pure vapour environment or when the kinetic Peclet number Pe is reduced below O(1) in inert gases), the interfacial thermal resistance due to the evaporation kinetics can be on the same orders of magnitude as the thermal resistance in the liquid film. The analysis also allow us to compare the heat transfer processes during the evaporation of a thin-film in pure vapours to those in inert gases, providing deeper insight into the effectiveness

关键词： Thin films

Curvature-property coupling governed heat transfer deterioration in supercritical helically coiled tubes: Mechanistic insights and mitigation strategies via structural parametrization

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International Journal of Thermal Sciences 2025年 215卷

作者： Chang, Fucheng Xin, Jiaxing Wu, Xiaoyi Li, Liwei Li, Huixiong Zhu, Yanlin National Key Lab of Aerospace Power System and Plasma Technology School of Mechanical Engineering Xi'an Jiaotong University Xi'an710049 China China Special Equipment Testing and Research Institute Beijing100029 China State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'an Jiaotong University Xi'an710049 China Shanghai Nuclear Engineering Research & Design Institute Co. Ltd Shanghai200233 China

The unique thermo-hydrodynamic coupling phenomena in the helically coiled tube (HCT) handling supercritical fluids present both opportunities and challenges for next-generation compact heat exchangers. While the pronounced thermophysical property variations near pseudo-critical temperatures (Tpc) and curvature-induced secondary flows synergistically enhance heat transfer coefficient (HTC), their nonlinear coupling mechanisms may unexpectedly provoke severe heat transfer deterioration (HTD). Through systematic numerical investigations, this study reveals that circumferential wall temperature inhomogeneity (CWTI) exhibits an inverted N-shaped evolution, providing valuable insights for thermal homogenization design near Tpc. The secondary flow Reynolds number (Se), quantifying secondary flow intensity, shows a monotonic increase with decreasing coil diameter (Dc) or inner diameter (Di), reaching saturation in high-enthalpy regions. Notably, CWTI demonstrates non-monotonic behavior, achieving minimum values near Tpc before manifesting distinct rebound characteristics near Tpc conditions. Parametric analysis establishes that: (1) Elevating heat flux (q) increases Se, reducing Dc boosts it by 50.3 %, and decreasing Di raises it by 60.0 %. (2) HTD predominantly initiates at the outer wall under high-q conditions, with Dc reduction achieving HTD suppression and 26.9 % enhancement in the local HTC;(3) Reducing the Di results in a reduction of maximum CWTI by 22.5 %–28.6 %, suggesting that structural parametrization effectively mitigates wall temperature non-uniformity, thus suppressing the HTD. While centered on supercritical water, the dimensionless scaling relationships demonstrate extendibility to other media, with the curvature-property coupling mechanism both elucidating fundamental interactions and guiding robust heat exchanger design. © 2025 Elsevier Masson SAS

关键词： Electric heating

Experimental study on the contribution of included/excluded minerals to particulate formation during coal char combustion

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Fuel 2023年第1期346卷

作者： Shang, Yimin Liu, Siqi Niu, Yanqing Zhu, Guangqing Cheng, Zening Hui, Shi'en State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'an Jiaotong University Shaanxi710049 China China Nuclear Power Technology Research Institute Shenzhen518031 China Zhundong Energy Research Institute Xinjiang Tianchi Energy Co. Ltd. Xinjiang831100 China

The contributions of included and excluded minerals to particulate matter formation are quantified in this work. By devolatilization of three typical Chinese coals, three coal chars with low (LA), moderate (MA), and high ash (HA) content (with both included and excluded minerals) were prepared, from which three float coal chars with low (LA−), moderate (MA−), and high ash (HA−) content (without excluded minerals) were separated by density differentiation method. The coal chars before and after separation were burned in a drop-tube furnace at 1600 K, the results of three float coal chars can directly reveal the contribution of included minerals, and the comparison of two kinds of chars with and without excluded minerals would reveal the excluded mineral contribution to ash distribution. The size distributions of the combustion-generated ash particle were obtained from the combination of ELPI+ and laser particle-size analyzer. The fractions of included/excluded minerals were obtained from SEM images. The results from the combustion of the float chars indicate the physical transformation of included minerals, while the results from original coal chars involve the transformation of both included and excluded minerals. Results indicate that the distribution of ash particles from included minerals for HA− char possesses a single peak, while the ash distributions of MA− and LA− char show a bi-modal shape. The excluded minerals in LA and MA chars mainly contribute to the ash emissions with sizes larger than 80 μm. The contribution from excluded minerals reach 86% to the ash particles of 205 μm for HA char, 54% for MA char and 51% for LA char. The number fractions of included minerals continuously decrease with a transformation into excluded minerals during char dynamic combustion. © 2023 Elsevier Ltd

关键词： Minerals

X-ray computed tomography (XCT) study of jetting in a fluidized bed: Effects of two-component fluidization

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Particuology 2025年 102卷 264-274页

作者： Xiang, Zhong Chen, Xi Liu, Shuguang Heindel, Theodore J. School of Energy and Environment Southeast University Nanjing210096 China State Key Laboratory of Low-carbon Smart Coal-fired Power Generation and Ultra-clean Emission Southeast University Nanjing210096 China Center for Multiphase Flow Research and Education and Department of Mechanical Engineering Iowa State University AmesIA50011 United States

Fluidization of non-spherical particles is commonly found in the biomass and solid waste processing industry, and the jetting characteristic above the aeration plate is critical to the fluidization performance of these particles. In this study, cylindrical particles are used as typical non-spherical particles and co-fluidized with small bed material particles. X-ray computed tomography (XCT) is used to reconstruct the 3D structure of the aeration plate region, allowing for the identification of individual aeration jets. The effects of jet velocity (Uj), cylindrical particle mass fraction (ω), cylindrical particle density (ρi), and the cylindrical particle sphericity () on jet shape and volume are investigated. The experimental results indicate that decreasing the cylindrical particle mass fraction (ω) and particle density (ρi) increases the jet length (L), maximum jet diameter (D), and maximum jet volume (V), but have little effect on the jet half angle (θ). The cylindrical particle density (ρi) is the most sensitive factor for jet shape, while the effect of cylinder particle sphericity () on jet shape is insignificant. A correlation of jet length (L) in a two-component fluidized bed with cylindrical particles and bed material is proposed based on all the experimental results. © 2025 Chinese Society of Particuology and Institute of Process engineering, Chinese Academy of Sciences

关键词： Binary fluidized bed Cylindrical particle fluidization Jetting X-ray computed tomography

Experimental Study and Theoretical Development of Liquid Entrainment in T-Junction with Double Inlets and Single Inlet of Gas Phase

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SSRN 2023年

作者： Li, Kepiao Shi, Yanggen Zhang, Kui Tian, Wenxi Qiu, Suizheng State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi’an710049 China School of Nuclear Science and Technology Shaanxi Key Laboratory of Advanced Nuclear Energy and Technology Xi'an Jiaotong University Xi’an710049 China

The liquid phase entrainment through vertical-up branch had been analyzed through scaled and full size of experiment since ADS-4 (the fourth-stage Automatic Depressurization System) valve adopted in advanced PWR (Pressurized Water Reactor). Most of the existed studies focus on the single inlet of gas whereas steam may flow from two sides of the T-junction during the blowdown of primary system. Hence the experimental study on liquid entrainment with double end inlets are carried out. The data on the onset of entrainment (OLE) turns out that double end inlets show small difference with single inlet, whereas the entrainment rate research have great difference with single inlet and there is more than 50% error between the data and existing theoretical models. According to the visible flow phenomenon and flow instability, a new entrainment rate model was proposed which can well predict the double-end inlets and single-inlet entrainment phenomenon with the error within ±20%. © 2023, The Authors. All rights reserved.

关键词： Pressurized water reactors

On Accelerative Propagation of Premixed Hydrogen/Air Laminar and Turbulent Expanding Flames

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SSRN 2022年

作者： Zhao, Haoran Wang, Jinhua Cai, Xiao Dai, Hongchao Liu, Xiao Huang, Zuohua State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong Universit Xi’an710049 China College of Power and Energy Engineering Harbin Engineering University Harbin150001 China

The accelerative propagation of laminar and turbulent premixed hydrogen/air flames are investigated using a constant volume combustion chamber. Turbulent burning velocity ( S T ) of hydrogen/air mixtures are determined in a wide range of conditions, more importantly the flame propagation dynamics and acceleration exponents are analyzed in detail. Results show that three distinct stages, namely quasi steady, transition acceleration and saturation acceleration stages are distinguished in laminar flame propagation process, and transient acceleration exponent ( a R ) increases in transition acceleration stage while nearly remains as a constant between 1.1~1.25 in saturation acceleration stage. Turbulent flame propagation follows a self-similar acceleration law, and transient acceleration exponent increases continuously as flame propagates outwardly. Furthermore, the empirical correlatio n is obtained to describe the development of turbulent flame acceleration with flame radius. Additionally, global acceleration exponents ( a ) of turbulent flames increase continuously with u ’ / S L and no significant trend variation occurs in different regimes. It appears that the accelerative propagation of turbulent expanding flames is mainly controlled by turbulence stretch, while the effect of flame intrinsic instability is nearly covered in current study. © 2022, The Authors. All rights reserved.

关键词： Acceleration