检索结果-内蒙古大学图书馆

Solar Hydrocarbons: Single-Step, Atmospheric-Pressure Synthesis of C2−C4Alkanes and Alkenes from CO2

Angewandte Chemie 2023年第27期135卷

作者： Rui Song Zhao Li Jiuli Guo Paul N. Duchesne Chenyue Qiu Chengliang Mao Jia Jia Sanli Tang Yang-Fan Xu Wenzhe Zhou Lu Wang Wei Sun Xiaoliang Yan Liejin Guo Dengwei Jing Geoffrey A. Ozin International Research Center for Renewable Energy & State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an Shaanxi 710049 China Solar Fuels Group Department of Chemistry University of Toronto 80 St. George Street Toronto Ontario M5S 3H6 Canada Contribution: Conceptualization (equal) Data curation (lead) Formal analysis (lead) Investigation (lead) Methodology (lead) Writing - original draft (equal) Contribution: Data curation (supporting) Formal analysis (equal) Writing - original draft (supporting) School of Chemistry and Chemical Engineering Anyang Normal University Anyang Henan 455000 P. R. China Contribution: Data curation (supporting) Formal analysis (supporting) Methodology (equal) Software (supporting) Writing - original draft (supporting) Contribution: Data curation (supporting) Software (lead) Department of Materials Science and Engineering University of Toronto Toronto Ontario M5S 3E4 Canada Contribution: Data curation (supporting) Contribution: Conceptualization (supporting) Contribution: Formal analysis (supporting) Contribution: Methodology (supporting) State Key Laboratory of Silicon Materials and School of Materials Science and Engineering Zhejiang University Hangzhou Zhejiang 310058 China Contribution: Project administration (supporting) Contribution: Conceptualization (lead) Formal analysis (lead) Funding acquisition (equal) Project administration (equal) Supervision (equal) Writing - original draft (lead) Contribution: Conceptualization (lead) Funding acquisition (equal) Project administration (equal) Writing - original draft (lead)

Cobalt ferrite (CoFe 2 O 4 ) spinel has been found to produce C 2 −C 4 hydrocarbons in a single-step, ambient-pressure, photocatalytic hydrogenation of CO 2 with a rate of 1.1 mmol g −1 h −1 , selectivity of 29.8 % and conversion yield of 12.9 %. On stream the CoFe 2 O 4 reconstructs to a CoFe−CoFe 2 O 4 alloy-spinel nanocomposite which facilitates the light-assisted transformation of CO 2 to CO and hydrogenation of the CO to C 2 −C 4 hydrocarbons. Promising results obtained from a laboratory demonstrator bode well for the development of a solar hydrocarbon pilot refinery.

关键词： C2−C4 Hydrocarbons CO2 Hydrogenation Cobalt Ferrite Photocatalysis

来源：评论

学校读者我要写书评

暂无评论

A mesh mapping method for MCNP and fluent coupling simulation

A mesh mapping method for MCNP and fluent coupling simulatio...

引用

2017 Transactions of the American Nuclear Society, ANS 2017

作者： Wang, Xinan Zhang, Dalin Wang, Mingjun Tian, Wenxi Qiu, Suizheng Su, Guanghui State Key Laboratory of Multiphase Flow in Power Engineering School of Nuclear Science and Technology Xi'an Jiaotong University Xi'an710049 China

来源：评论

学校读者我要写书评

暂无评论

Kinetics of hydrogen abstraction and addition reactions of 3-hexene by H radical

Kinetics of hydrogen abstraction and addition reactions of 3...

引用

11th Asia-Pacific Conference on Combustion, ASPACC 2017

作者： Yang, Feiyu Sun, Wuchuan Pan, Youshun Deng, Fuquan Jiang, Xue Zhang, Yingjia Huang, Zuohua State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xianning West Road Xi’anShaanxi710049 China

Rate coefficients of H-atom abstraction and addition reactions of 3-hexene by the hydroxyl radical (H) were determined using canonical variational transition-state theory, with potential energy surface evaluated at the CCSD/CBS//BHandHLYP/6311G (d, p) level and quantum mechanical effect corrected by the multi-dimensional small-curvature tunneling method. Results reveal that accounting for approximate 70% of the overall H-atom abstractions occur in the allylic site via both direct and indirect channels. The indirect channel containing two Van der Waals pre-reactive complexes exhibits two times higher rate coefficient relative to the direct one. The H-addition reaction also contains two Van der Waals complexes, and its submerged barrier results in a negative temperature coefficient behavior at low temperatures. In contrast, the H-addition pathway dominates only at the temperatures below 590 K whereas the H-atom abstraction reactions dominate overwhelmingly at the temperature over 590 K. All of the rate coefficients calculated with an uncertainty of a factor of 5 were estimated. Analyses on the potential energy surface and minimum reaction path were also performed in this study. © 2018 Combustion Institute. All Rights Reserved.

关键词： Addition reactions

来源：评论

学校读者我要写书评

暂无评论

Optimization design of flue gas temperature for Low-Low Temperature Electrostatic Precipitator

引用

Journal of Physics: Conference Series 2019年第1期1300卷

作者： Ke Sun Yu Yan Jiahao Jiang Lei Deng State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'an Jiaotong University Xi'an 710049 China Huadian Electric Power Research Institute Co. LTD. Hangzhou 310030 China

Low temperature corrosion is one of the key issues in application of low-low temperature electrostatic precipitator. The concentration of SO3 affects the acid dew point temperature of flue gas. The exhaust temperature after the air preheater should be higher than the acid dew point temperature. The residual heat of flue gas is fully utilized by the low-temperature economizer. The efficiency of low-low temperature electrostatic precipitator is improved by the comprehensive effect of the condensation of SO3 on the surface of the fine particles, the decrease of the specific resistance of the particles and the agglomeration of the fine particles.

关键词：

来源：评论

学校读者我要写书评

暂无评论

Flame front evolution and self-acceleration of hydrogen spherically expending flames 11

Flame front evolution and self-acceleration of hydrogen sphe...

引用

11th Asia-Pacific Conference on Combustion, ASPACC 2017

作者： Cai, Xiao Wang, Jinhua Zhao, Haoran Huang, Zuohua State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University NO.28 Xianning West Road Xi’an710049 China

An experimental study on flame front evolution and self-acceleration of hydrogen spherically expending flames was conducted on a constant volume combustion chamber over a wide range of Lewis number at elevated pressures. Flame morphology, onset of flame acceleration and flame self-similar acceleration were analyzed. The results shows that the critical radius for onset of flame acceleration increases with the increase in effective Lewis number and the decrease in initial pressure. And the critical Peclet number increases nonlinearly with the increasing Markstein length. Thus, the onset of flame acceleration is controlled by the couple effects of hydrodynamic and diffusional-thermal instabilities. Furthermore, the self-similar acceleration exponent increases with the decrease in the effective Lewis number (or Markstein number) and almost keeps constant with initial pressure. It is concluded that the self-similar acceleration exponent is mainly affected by diffusional-thermal instability. © 2018 Combustion Institute. All Rights Reserved.

关键词： Acceleration

来源：评论

学校读者我要写书评

暂无评论

Performance of V-Cone flowmeter applied to cryogenic fluid measurement considering cavitation

引用

IOP Conference Series: Earth and Environmental Science 2019年第6期240卷

作者： Denghui He Bofeng Bai Senlin Chen Jie Zhang Pengcheng Guo State Key Laboratory of Eco-hydraulic in Northwest Arid Region Xi'an University of Technology Xi'an 710048 Shaanxi China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 Shaanxi China

The V-Cone flowmeter is a promising differential pressure flowmeter for metering the cryogenic fluid for its many advantages. When the cryogen velocity increases to a certain value, the cavitation may occur in flowmeter, which may significantly affect the performance of V-Cone flowmeter. However, the effect of cavitation on performance of V-Cone flowmeter remains unclear and there are no published studies to our knowledge on this issue. Here we investigate the performance of V-Cone flowmeter when measuring the cryogenic fluids, especially the effects of cavitation on the discharge coefficient and pressure loss coefficient of the flowmeter. Two cryogenic fluids are investigated, including liquid nitrogen (LN2) and liquid hydrogen (LH2). For comparison, the water is also investigated. The realizable κ-ε model is used to describe the turbulence. The Schnerr-Sauer cavitation model is used to investigate the effect of cavitation on the performance of the V-Cone flowmeter. The results show that there was little effect of cavitation on the discharge coefficient and pressure loss coefficient at the initial stage of cavitation. When the cloud cavitation occurred downstream of V-Cone, the discharge coefficient decreases rapidly with Reynolds number increasing, while the pressure loss coefficient rises quickly. The average discharge coefficient is almost the same for different fluids in the stable region; while the cryogenic fluids have wider stable Reynolds number ranges than the water. The lower limits of the Reynolds number for the constant discharge coefficient is very close for three fluids, however, for the upper limits of Reynolds number are quite different. We conclude that measurement range of the cryogenic fluid is much larger than that of the water, which shows that the V-Cone flowmeter exhibits great potential in the measurement of cryogenic fluid. This study provides insights into the effect of cavitation on the measurement of V-Cone flowmeter and opens a new aven

关键词：

来源：评论

学校读者我要写书评

暂无评论

Numerical Analysis of flow Instability in the Water Wall of a Supercritical CFB Boiler with Annular Furnace

引用

Journal of Thermal Science 2016年第4期25卷 372-379页

作者： XIE Beibei YANG Dong XIE Haiyan NIE Xin LIU Wanyu State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University

In order to expand the study on flow instability of supercritical circulating fluidized bed(CFB) boiler,a new numerical computational model considering the heat storage of the tube wall metal was presented in this *** lumped parameter method was proposed for wall temperature calculation and the single channel model was adopted for the analysis of flow *** on the time-domain method,a new numerical computational program suitable for the analysis of flow instability in the water wall of supercritical CFB boiler with annular furnace was *** verify the code,calculation results were respectively compared with data of commercial *** to the comparisons,the new code was proved to be reasonable and accurate for practical engineering application in analysis of flow *** on the new program,the flow instability of supercritical CFB boiler with annular furnace was simulated by time-domain *** 1.2 times heat load disturbance was applied on the loop,results showed that the inlet flow rate,outlet flow rate and wall temperature fluctuated with time eventually remained at constant values,suggesting that the hydrodynamic flow was *** results also showed that in the case of considering the heat storage,the flow in the water wall is easier to return to stable state than without considering heat storage.

关键词： supercritical CFB with annular furnace heat storage flow instability wall temperature numerical analysis

来源：评论

学校读者我要写书评

暂无评论

Cover Feature: Coupling Photothermal Effect into Efficient Photocatalytic H2Production by Using a Plate-like Cu@Ni Core-shell Cocatalyst (ChemCatChem 10/2020)

引用

ChemCatChem 2020年第10期12卷 2648-2648页

作者： Xinyang Guo Dr. Fei Xue Shikai Xu Prof. Shaohua Shen Prof. Hongwen Huang Prof. Maochang Liu International Research Center for Renewable Energy & State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an Shaanxi 710049 P.R. China Suzhou Academy of Xi'an Jiaotong University Suzhou Jiangsu 215123 P.R. China College of Materials Science and Engineering Hunan University Changsha Hunan 410082 P.R. China

来源：评论

学校读者我要写书评

暂无评论

Pressure drops and model modification for two-phase flow in porous beds with coarse particles 25

Pressure drops and model modification for two-phase flow in ...

引用

2017 25th International Conference on Nuclear engineering, ICONE 2017

作者： Li, Xumao Zou Liangxing Wang, Liubo Kong Huasheng State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xianning West Road 28# Xi'an city710049 China

ISBN: (纸本)9780791857823

Motivated by reducing the uncertainties in coolability analysis of a debris bed, this paper proposed a modified model for the pressure drops of two phase flow through packed beds with coarse particles based on the experimental studies. The experiments are carried out on the test facility of DEBECO-LT (DEbris BEd COolability-Low Temperature), which was designed to investigate single / two-phase flow in porous beds. The coarse particles are packed in the cylindrical test section with the inner diameter of 120 mm and the height of 600 mm. Through single-phase flow tests in homogeneous beds, the reliability of the whole experimental system is ensured. Then two-phase flow tests are performed to investigate the flow characteristics, to provide basic data for verifying and modifying the existing models. The results show that, the interfacial drag in beds with coarse particles will result in a decreasing tendency in the pressure drop curves along with the fluid velocity, and the the effect of interfacial drag should be considered in the debris coolability analysis models for beds with coarse particles. Compared with the existing models, the new model shows relatively satisfactory forecasting ability, and the predictions have favorable agreement with existing experimental data under various conditions. This modified model could be applied to calculate the pressure drops of twophase flow in coarse-particle beds. © Copyright 2017 ASME.

关键词： Pressure drop

来源：评论

学校读者我要写书评

暂无评论

Experimental Research on flow Pulse Characteristics of Pressurized-Liquid-Screen Bed

引用

Kung Cheng Je Wu Li Hsueh Pao/Journal of engineering Thermophysics 2017年第10期38卷 2183-2189页

作者： Hu, Zheng-Tao Li, Lian Li, Na Zhou, Qu-Lan State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China

The experimental monitoring system of pressurized-liquid-screen bed was designed and set in this paper. The flow characteristics were studied especially the analysis of differential pressure pulse characteristics and friction factors variation by the way of adjusting gas flow, liquid flow and operation pressure parameters. According to the analysis of comparing experiment data and theory, the variation principle of pressure pulse intensity and friction factors under different gas flow, liquid flow and operation pressure was revealed as well as the optimal operation parameter was analyzed through combining the principle of fume desulfurization gas-liquid interactive reaction. This paper provides the crucial design references to the industrial application of pressurized-liquid-screen gas-liquid reaction system. © 2017, Science Press. All right reserved.

关键词： flow of gases

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：