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Unprecedented strong and reversible atomic orbital hybridization enables a highly stable Li-S battery

国家科学评论（英文版） 2022年第7期9卷 109-119页

作者： Min Yan Wenda Dong Fu Liu Lihua Chen Tawfique Hasan Yu Li Bao-Lian Su State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Hubei Key Laboratory of Plasma Chemistry and Advanced Materials Hubei Engineering Technology Research Center of Optoelectronic and New Energy MaterialsSchool of Materials Science and EngineeringWuhan Institute of TechnologyWuhan 430205China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China School of Materials Science and Engineering Zhejiang UniversityHangzhou 310027China Cambridge Graphene Centre University of CambridgeCambridge CB3 OFAUK State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Laboratory of Inorganic Materials Chemistry(CMI) University of NamurNamur B-50000 Belgium

The shuttle effect and excessive volume change of the sulfur cathode severely impede the industrial implementation of Li-S *** is still highly challenging to find an efficient way to suppress the shuttle effect and volume ***,we report,for the first time,an innovative atomic orbital hybridization concept to construct the hierarchical hollow sandwiched sulfur nanospheres with double-polyaniline layers as the cathode material for large-scale high-performance Li-S *** hierarchically 3D,cross-linked and stable sulfur-polyaniline backbone with interconnected disulfide bonds provides a new type and strong intrinsic chemical confinement of sulfur owing to the atomic orbital hybridization of Li 2s,S 3p,C 2p and N ***,such atomic orbital hybridization of sulfur sandwiched in the double sulfur-polyaniline network is highly reversible during the discharge/charge process and can very efficiently suppress the shuttle effect and volume expansion,contributing to a very high capacity of 1142 mAh g-1 and an excellent stabilized capacity of 886 mAh g-1 at 0.2 C after 500 cycles with a suppressed volume expansion and an unprecedented electrode *** innovative atomic orbital hybridization concept can be extended to the preparation of other electrode materials to eliminate the shuttle effect and volume expansion in battery *** present work also provides a commercially viable and up-scalable cathode material based on this strong and highly reversible atomic orbital hybridation for large-scale high-performance Li-S batteries.

关键词： atomic orbital hybridization hierarachical hollow sandwiched sulfur nanosphere double sulfur–polyaniline networks lithium–sulfur batteries insitu vulcanization

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Large‑scale Fabrication of Snake‑skin‑inspired Protective Composite textiles

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advanced Fiber materials 2024年第4期6卷 978-992页

作者： Qing Liu Fengxiang Chen Tingting Dong Woong‑Ryeol Yu Chaoyu Chen Gaoming Jiang Zhijia Dong Pibo Ma Engineering Research Center of Knitting Technology Ministry of EducationCollege of Textile Science and EngineeringJiangnan UniversityWuxi 214122P.R.China State Key Laboratory of New Textile Materials and Advanced Processing Technologies/National Local Joint Laboratory for Advanced Textile Processing and Clean Production/Hubei Key Laboratory of Digital Textile Equipment Wuhan Textile UniversityWuhan 430200P.R.China Department of Materials Science and Engineering and Research Institute of Advanced Materials Seoul National UniversitySeoul 08826Republic of Korea

Inspired by the overlapping structure of snake scales,a reinforced scale-like knitted fabric(R-SLKF)was created in this *** achieve this,short carbon fibers in an epoxy resin(ER)matrix were incorporated into the scales of an *** resulting textile is a highly stable protective composite that is flexible,warm,and thermally *** addition,supe-rior stab-resistance is ensured through rigid protective blocks in the R-SLKF,making up a hard overlapping scale region,besides satisfactory flexibility via soft twisted ultra-high-molecular-weight polyethylene yarn-based *** R-SLKF achieves high stab resistance(peak load of approximately 600 N for a single scale thickness of 2 mm),good flexibility(~290 mN cm),and breathability(100 MPa,423 mm/s),coupled with good warmth retention and thermal insulation prop-erties(0.28℃/s),which are superior to previously reported protective composite *** the results,the combination of desirable individual protection,excellent wearability and comfort enables human beings to survive in extremely danger-ous *** element simulations provided valuable insights into the factors influencing the stab resistance of R-SLKF and elucidated the underlying anti-puncture mechanism in accordance with the experimental *** study presents a novel strategy for the facile industrial fabrication of flexible and lightweight protective composite textiles,which is expected to enhance the structure and material design for future innovations and provide advantages for personal protec-tive equipment in various industrial fields.

关键词： Scale-like knitted fabric Stab-resistance Flexibility Air permeability Warmth retention and thermal insulation properties

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Probing the interlayer mechanical coupling of 2D layered materials-A review

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Progress in Natural Science:materials International 2022年第5期32卷 528-537页

作者： Yinghui Sun Yufei Sun Rongming Wang Kai Liu Beijing Advanced Innovation Center for Materials Genome Engineering Beijing Key Laboratory for Magneto-Photoelectrical Composite and Interface Science School of Mathematics and Physics University of Science and Technology Beijing State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and Engineering Tsinghua University Key Laboratory of Advanced Materials of Ministry of Education School of Materials Science and Engineering Tsinghua University

Two-dimensional(2D) layered materials are assembled through the intralayer covalent bonds and interlayer van der Waals(vdWs) interactions. The relatively weak interlayer vdWs interactions result in the weak interlayer mechanical coupling between layers, which strongly impacts the overall mechanical properties of multilayer 2D materials or heterostructures. Experimentally probing the interlayer mechanical coupling is of vital importance on the accumulation of fundamental parameters for their applications in flexible and stretchable devices, yet there are hardly comprehensive reviews in this research field. In this review, we firstly introduce the probing methods of interlayer mechanical coupling, including high-frequency and ultralow-frequency Raman characterizations,nanoindentation of multilayer 2D materials or heterostructures, surface indentation, pressurized blister test,characterization of spontaneously formed nanoblisters, and nano-friction tests. Based on the analysis and comparison of the existing methods and results, we also discuss the advantages and limitations of each ***, the challenges and opportunities in this promising field are discussed. This review summarizes the recent progress in the probing of interlayer mechanical coupling of 2D layered materials and will provide important reference for the rational design of flexible and stretchable devices.

关键词： van der Waals interaction Mechanical properties Indentation Heterostructures

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Rare-earth-niobate high-entropy ceramic foams with enhanced thermal insulation performance

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Journal of materials Science & technology 2022年第21期116卷 94-102页

作者： R.W.Yang Y.P.Liang J.Xu X.Y.Meng J.T.Zhu S.Y.Cao M.Y.Wei R.X.Zhang J.L.Yang F.Gao State Key Laboratory of Solidification Processing MIIT Key Laboratory of Radiation Detection Materials and DevicesSchool of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi’an710072China NPU-QMUL Joint Research Institute of Advanced Materials and Structure Northwestern Polytechnical UniversityXi’an710072China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing100084China State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan430074China

The introduction of porous structures into high-entropy ceramics is expected to further improve its thermal insulation *** this work,a series of novel rare-earth-niobate high-entropy ceramic foams((Dy_(0.2)Ho_(0.2)Y_(0.2)Er_(0.2)Yb_(0.2))_(3)NbO_(7))with hierarchical pore structures were prepared by a particle-stabilized foaming ***-scale analysis reveals that high entropy causes atom displacement and lattice *** high-entropy ceramic foams exhibit high porosity(90.13%-96.13%)and ultralow thermal conductivity(0.0343-0.0592 W/(m·K))at room ***-entropy ceramic foam prepared by a 20 wt%slurry sintered at 1500℃has the porosity of 96.12%and extremely low thermal conductivity of 0.0343 W/(m·K).The existence of walls and secondary pores contributes to reduced thermal *** is a temperature difference of over 800℃between frontside and backside of the sample under fire resistance *** research indicates that these as-prepared high-entropy ceramic foams are expected to be promising thermal insulation materials.

关键词： Rare-earth niobate High-entropy ceramic foams Particle-stabilized foaming Atomic-scale analysis Thermal conductivity

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Operando reconstruction towards stable CuI nanodots with favorable facets for selective CO_(2) electroreduction to C2H4

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Science China Chemistry 2023年第6期66卷 1834-1843页

作者： Wenjie Xue Hongxia Liu Xinqing Chen Xiaoju Yang Ruoou Yang Youwen Liu Minghao Li Xuan Yang Bao Yu Xia Bo You Key Laboratory of Material Chemistry for Energy Conversion and Storage Ministry of EducationHubei Key Laboratory of Material Chemistry and Service FailureSchool of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan 430074China School of Chemistry and Chemical Engineering Wuhan Textile UniversityWuhan 430200China Shanghai Advanced Research Institute Chinese Academy of SciencesShanghai 201210China State Key Laboratory of Materials Processing and Die&Mold Technology and School of Materials Science and Engineering Huazhong University of Science and TechnologyWuhan 430074China

Cu-based electrocatalysts with favorable facets and Cu^(+)can boost CO_(2) reduction to valuable multicarbon ***,the inevitable Cu^(+)reduction and the phase evolution usually result in poor ***,we fabricate CuI nanodots with favorable(220)facets and a stable Cu^(+)state,accomplished by operando reconstruction of Cu(OH)_(2) under CO_(2)-and I--containing electrolytes for enhanced CO_(2)-to-C_(2)H_(4) *** X-ray absorption spectroscopy(XAS),in-situ Raman spectroscopy and thermodynamic potential analysis reveal the preferred formation of *** gas electroresponse and density functional theory(DFT)calculations reveal that CO_(2)-related species induce the exposure of the(220)plane of Cu ***,the small size of nanodots enables the adequate contact with I^(-),which guarantees the rapid formation of Cu I instead of the electroreduction to Cu^(0).As a result,the resulting catalysts exhibit a high C2H4 Faradaic efficiency of 72.4%at a large current density of 800 m A cm^(-2) and robust stability for 12 h in a flow *** in-situ ATR-SEIRS spectroscopic characterizations and DFT calculations indicate that the(220)facets and stable Cu^(+) in CuI nanodots synergistically facilitate CO_(2)/*CO adsorption and*CO dimerization.

关键词： CO_(2)reduction reaction cuprous iodide favorable facets halogen electrolyte reconstruction

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Engineering design of feedstock powder and relevant thermal-mechanical performance of thermal/environmental barrier coatings

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Journal of advanced Ceramics 2025年第2期14卷 37-56页

作者： Xinchang Feng Fangwei Guo Lirong Luo Yuzhang Wang Yun Long Xiaofeng Zhao Fei Pan Lei Guo Qingfeng Zeng Jing Feng Chunlei Wan Shanghai Key Laboratory of Advanced High-temperature Materials and Precision Forming School of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai 200240China National Engineering Research Center of Special Equipment and Power System for Ship and Marine Engineering Shanghai 200030China School of Mechanical Engineering Shanghai Jiao Tong UniversityShanghai 200240China State Key Laboratory of Advanced Nuclear Energy Technology Nuclear Power Institute of ChinaChengdu 610213China Innovative Sensor Technology IST AG Ebnat-Kappel 9642Switzerland School of Materials Science and Engineering Tianjin UniversityTianjin 300072China Tianmushan Laboratory Hangzhou 311115China School of Materials Science and Engineering Kunming University of Science and TechnologyKunming 650093China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China

The development of aeroengine with a high thrust-weight ratio poses great challenges for current top-coating thermal barrier coatings (TBCs) and environmental barrier coatings (EBCs) in service. Medium/high-entropy ceramics are highly promising candidate material for advanced TBCs/EBCs owing to their low thermal conductivity, high melting point, high-temperature stability, and calcium–magnesium–alumino–silicate (CMAS) resistance. Most feedstock powder used for medium/high-entropy TBCs/EBCs is prepared via traditional spray drying, which cannot fully exploit the advantages of multicomponent ceramics. The density, sphericity, inner structure, and flowability of feedstock powder affect their melting state during the thermal spraying process, which strongly affects the microstructure and properties of the deposited coatings. Therefore, the deposited coatings exhibit phase segregation, amorphous phases, and microstructure defects owing to unpredictable variations in feedstock powder with random morphologies and structures. Here, the structure and properties of feedstock powder prepared by state-of-the-art granulation technologies and their influences on the deposited coatings were systematically investigated, which can provide guidance for configuration optimization of feedstock powder and the manufacturing accuracy of the deposited coating. This review aims to bridge the gap between cutting-edge ceramics and advanced engineering technologies, thus providing concrete background knowledge and crucial guidelines for designing and developing TBCs/EBCs.

关键词： thermal/environmental barrier coatings(TBCs/EBCs) spraying ceramic powder multiscale structure control high-entropy ceramics thermal-mechanical performance

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Interface optimization and defects suppression via Na F introduction enable efficient flexible Sb_(2)Se_(3) thin-film solar cells

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Journal of Energy Chemistry 2024年第3期90卷 165-175,I0006页

作者： Mingdong Chen Muhammad Ishaq Donglou Ren Hongli Ma Zhenghua Su Ping Fan David Le Coq Xianghua Zhang Guangxing Liang Shuo Chen Shenzhen Key Laboratory of Advanced Thin Films and Applications Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong ProvinceCollege of Physics and Optoelectronic EngineeringShenzhen UniversityShenzhen 518060GuangdongChina State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures MOE Key Laboratory of New Processing Technology for Nonferrous Metals and MaterialsSchool of ResourcesEnvironment and MaterialsGuangxi UniversityNanning 530004GuangxiChina CNRS ISCR(Institut des Sciences Chimiques de Rennes)UMR 6226Universitéde RennesRennes F-35000France

Sb_(2)Se_(3) with unique one-dimensional(1D) crystal structure exhibits exceptional deformation tolerance,demonstrating great application potential in flexible ***,the power conversion efficiency(PCE) of flexible Sb_(2)Se_(3) photovoltaic devices is temporarily limited by the complicated intrinsic defects and the undesirable contact ***,a high-quality Sb_(2)Se_(3) absorber layer with large crystal grains and benign [hkl] growth orientation can be first prepared on a Mo foil *** NaF intermediate layer is introduced between Mo and Sb_(2)Se_(3),which can further optimize the growth of Sb_(2)Se_(3)thin ***,positive Na ion diffusion enables it to dramatically lower barrier height at the back contact interface and passivate harmful defects at both bulk and *** a result,the champion substrate structured Mo-foil/Mo/NaF/Sb_(2)Se_(3)/CdS/ITO/Ag flexible thin-film solar cell delivers an obviously higher efficiency of 8.03% and a record open-circuit voltage(V_(OC)) of 0.492 *** flexible Sb_(2)Se_(3) device also exhibits excellent stability and flexibility to stand large bending radius and multiple bending times,as well as superior weak light photo-response with derived efficiency of 12.60%.This work presents an effective strategy to enhance the flexible Sb_(2)Se_(3) device performance and expand its potential photovoltaic applications.

关键词： Sb_(2)Se_(3) Flexible solar cells NaF intermediate layer Interface optimization Defects suppression

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Role of grain boundary character on Bi segregation-induced embrittlement in ultrahigh-purity copper

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Journal of materials Science & technology 2023年第28期159卷 52-61页

作者： Y.X.Hua K.X.Song H.T.Liu J.W.Wang C.M.Zhang Y.J.Zhou B.Pang J.T.Song J.L.He H.L.Zhao School of Materials Science and Engineering Henan University of Science and TechnologyLuoyang 471023China Henan Academy of Sciences Zhengzhou 450000China Henan Key Laboratory of Advanced Conductor Materials Zhengzhou 450046China Provincial and Ministerial Co-construction of Collaborative Innovation Center of Nonferrous New Materials and Advanced Processing Technology Luoyang 471023China Center of Electron Microscopy and State Key Laboratory of Silicon Materials School of Materials Science and EngineeringZhejiang UniversityHangzhou 310027China College of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001China

Bismuth(Bi),as an impurity element in copper and copper-based alloys,usually has a strong tendency of grain boundary(GB)segregation,which depends on the GB ***,the influence of such a segregation on the properties of ultrahigh-purity copper has been rarely reported and the exact structural arrangements of Bi atoms at different GBs remain largely *** this study,we investigated the influ-ence of trace amounts of Bi(50-300 wt ppm)on the ductility of an ultrahigh-purity copper(99.99999%)in the range of room temperature to 900°*** tensile results show that the addition of Bi seriously damages the ductility of the ultrahigh-purity copper at temperatures of 450-900°C,which is due to the GB segregation of *** this basis,such a segregation behavior at different types of GBs,including high and low angle GBs(HAGBs/LAGBs),and twin boundaries(TBs),via the scanning electron microscope-electron backscattered diffraction(SEM-EBSD)and aberration-corrected scanning transmission electron microscope(AC-STEM)investigations,combined with the first-principles calculations were systematically *** atomistic characterizations demonstrate an anisotropic Bi segregation,where severe enrich-ment of Bi atoms typically occurs at the HAGBs,while the absence of Bi adsorption prevails at LAGBs or *** particular,the segregated Bi at random HAGBs exhibited the directional bilayer adsorption,while the special symmetrical7 HAGB presented a unique Bi-rich cluster *** findings pro-vide a comprehensive experimental and computational understanding on the atomic-scale segregation of impurities in metallic materials.

关键词： Grain boundary character Embrittlement Bi segregation Atomic configuration Ultrahigh-purity copper

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Inner Co Synergizing Outer Ru Supported on Carbon Nanotubes for Efficient pH-Universal Hydrogen Evolution Catalysis

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Nano-Micro Letters 2022年第11期14卷 275-289页

作者： Jian Chen Yuan Ha Ruirui Wang Yanxia Liu Hongbin Xu Bin Shang Renbing Wu Hongge Pan Institute of Science and Technology for New Energy Xi’an Technological UniversityXi’an 710021People’s Republic of China School of Advanced Materials and Nanotechnology Xidian UniversityXi’an 710126People’s Republic of China Department of Materials Science Fudan UniversityShanghai 200433People’s Republic of China State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430073People’s Republic of China State Key Laboratory of Silicon Materials and School of Materials Science and Engineering Zhejiang UniversityHangzhou 310027People’s Republic of China

Exploring highly active but inexpensive electrocatalysts for the hydrogen evolution reaction(HER)is of critical importance for hydrogen production from electrochemical water ***,we report a multicomponent catalyst with exceptional activity and durability for HER,in which cobalt nanoparticles were in-situ confined inside bamboo-like carbon nanotubes(CNTs)while ultralow ruthenium loading(~2.6μg per electrode area~cm^(−2))is uniformly deposited on their exterior walls(Co@CNTsǀRu).The atomic-scale structural investigations and theoretical calculations indicate that the confined inner Co and loaded outer Ru would induce charge redistribution and a synergistic electron coupling,not only optimizing the adsorption energy of H intermediates(ΔGH*)but also facilitating the electron/mass *** as-developed Co@CNTsǀRu composite catalyst requires overpotentials of only 10,32,and 63 mV to afford a current density of 10 mA cm^(−2) in alkaline,acidic and neutral media,respectively,representing top-level catalytic activity among all reported HER *** current work may open a new insight into the rational design of carbon-supported metal catalysts for practical applications.

关键词： Cobalt nanoparticles Carbon nanotubes Ru nanoclusters Hydrogen evolution reaction

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Optimizing energy harvesting performance by tailoring ferroelectric/relaxor behavior in KNN-based piezoceramics

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Journal of advanced Ceramics 2022年第6期11卷 935-944页

作者： Yu HUAN Xinjian WANG Wenyu YANG Limin HOU Mupeng ZHENG Tao WEI Xiaohui WANG School of Materials Science and Engineering University of JinanJinan 250022China Key Laboratory of Advanced Functional Materials Faculty of Materials and ManufacturingBeijing University of TechnologyBeijing 100124China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China

Piezoelectric energy harvesters(PEHs)fabricated using piezoceramics could convert directly the mechanical vibration energy in the environment into electrical *** high piezoelectric charge coefficient(d_(33))and large piezoelectric voltage coefficient(g_(33))are key factors for the high-performance ***,high d_(33)and large g_(33)are difficult to simultaneously achieve with respect to g_(33)=d_(33)/(e_(0)e_(r))and d_(33)=2Qe_(0)e_(r)P_(r).Herein,the energy harvesting performance is optimized by tailoring the CaZrO_(3)content in(0.964−x)(K_(0.52)Na_(0.48))(Nb_(0.96)Sb_(0.04))O_(3)-0.036(Bi_(0.5)Na_(0.5))ZrO_(3)-xCaZrO_(3)***,the doping CaZrO_(3)could enhance the dielectric relaxation due to the compositional fluctuation and structural disordering,and thus reduce the domain size to~30 nm for x=0.006 *** nanodomains switch easily to external electric field,resulting in large ***,the rhombohedral-orthorhombic-tetragonal phases coexist in x=0.006 sample,which reduces the polarization anisotropy and thus improves the piezoelectric *** multiphase coexistence structures and miniaturized domains contribute to the excellent piezoelectric properties of d_(33)(354 pC/N).Furthermore,the dielectric relative permittivity(ε_(r))reduces monotonously as the CaZrO_(3)content increases due to the relatively low ion polarizability of Ca^(2+)and Zr^(4+).As a result,the optimized energy conversion coefficient(d_(33)×g_(33),5508×10^(−15)m^(2)/N)is achieved for x=0.006 *** importantly,the assembled PEH with the optimal specimen shows the excellent output power(~48 mW)and lights up 45 red commercial light-emitting diodes(LEDs).This work demonstrates that tailoring ferroelectric/relaxor behavior in(K,Na)NbO_(3)-based piezoelectric ceramics could effectively enhance the electrical output of PEHs.

关键词： piezoelectric energy harvesters(PEHs) potassium sodium niobate(KNN) relaxor ferroelectric miniaturized domains multiphase coexistence

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