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Rare-earth-niobate high-entropy ceramic foams with enhanced thermal insulation performance

Journal of materials Science & technology 2022年第21期116卷 94-102页

作者： R.W.Yang Y.P.Liang J.Xu X.Y.Meng J.T.Zhu S.Y.Cao M.Y.Wei R.X.Zhang J.L.Yang F.Gao State Key Laboratory of Solidification Processing MIIT Key Laboratory of Radiation Detection Materials and DevicesSchool of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi’an710072China NPU-QMUL Joint Research Institute of Advanced Materials and Structure Northwestern Polytechnical UniversityXi’an710072China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing100084China State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan430074China

The introduction of porous structures into high-entropy ceramics is expected to further improve its thermal insulation *** this work,a series of novel rare-earth-niobate high-entropy ceramic foams((Dy_(0.2)Ho_(0.2)Y_(0.2)Er_(0.2)Yb_(0.2))_(3)NbO_(7))with hierarchical pore structures were prepared by a particle-stabilized foaming ***-scale analysis reveals that high entropy causes atom displacement and lattice *** high-entropy ceramic foams exhibit high porosity(90.13%-96.13%)and ultralow thermal conductivity(0.0343-0.0592 W/(m·K))at room ***-entropy ceramic foam prepared by a 20 wt%slurry sintered at 1500℃has the porosity of 96.12%and extremely low thermal conductivity of 0.0343 W/(m·K).The existence of walls and secondary pores contributes to reduced thermal *** is a temperature difference of over 800℃between frontside and backside of the sample under fire resistance *** research indicates that these as-prepared high-entropy ceramic foams are expected to be promising thermal insulation materials.

关键词： Rare-earth niobate High-entropy ceramic foams Particle-stabilized foaming Atomic-scale analysis Thermal conductivity

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Fast deposition of Ni doped YSZ coatings by cathode plasma electrolysis for solid oxide fuel cell applications

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Ceramics International 2025年第13期51卷 17268-17277页

作者： Liu, Chenxu Du, Ke Song, Chen Song, Yang Zhou, Chenchen Zhang, Jin Liu, Min Tian, Yu Meng, Yonggang State Key Laboratory of Tribology in Advanced Equipment Tsinghua University Beijing100084 China Institute of New Materials Guangdong Academy of Sciences National Engineering Laboratory of Modern Materials Surface Engineering Technology Guangdong Provincial Key Laboratory of Modern Surface Engineering Technology Guangdong-Hong Kong Joint Laboratory of Modern Surface Engineering Technology Guangzhou510650 China School of Materials Science and Engineering Nanyang Technological University 639798 Singapore Beijing Key Laboratory for Corrosion Erosion and Surface Technology Institute of Advanced Materials and Technology University of Science and Technology Beijing Beijing100083 China

The fast fabrication of high-quality anode layers of solid oxide fuel cells (SOFCs) is a key factor for their efficient applications. In this work, a one-step method of cathode plasma electrolytic deposition (CPED) is developed to prepare Ni doped YSZ coatings with a thickness of 35–55 μm on porous stainless steel. Compared to the several hours required by traditional methods, a faster coating deposition that only takes 60 s is achieved owing to the effect of enormous energy of plasma arc at the solid-liquid interface in the CPED method. The preparation process is analyzed by recording the variation of current with voltage. The unique micro-structure of the coatings is observed, and the formation mechanism of the Ni doped YSZ coating during the CPED process is proposed. The deposited coatings show an excellent performance as the anode layers for SOFCs, with Sc2O3 stabilized ZrO2 coating prepared by atmospheric plasma spraying as electrolyte and La0.6Sr0.4Co0.2Fe0.8O3-δ as the cathode. The open circuit voltage of the cells reaches 1.000 V and the maximum power density reaches 817.4 mW cm−2 at 800 °C. The finding opens a novel pathway for the efficient preparation of anode materials for SOFCs. © 2025

关键词： Plasma spraying

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Special issue on electrochemical conversion and utilization of hydrogen energy

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Frontiers in Energy 2024年第3期18卷 263-264页

作者： Yun ZHENG Bo YU Xiaogang FU Jiujun ZHANG Institute of New Energy Materials and Engineering School of Materials Science and EngineeringFuzhou UniversityFuzhou 350108China State Key Laboratory of Solidification Processing Atomic Control&Catalysis Engineering LaboratorySchool of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi’an 710072China Institute of Nuclear and New Energy Technology Tsinghua UniversityBeijing 100084China

The concerns over energy crisis and climate change caused by the excessive consumption of fossil fuels and the associated emission of greenhouse gases, have driven many countries to develop policies for an energy transition into zero-carbon energy sources, essentially aiming at decarbonizing their energy systems. Among various renewable sources, hydrogen has been hailed as an ideal alternative to provide secure, cost-effective, and non-polluting energy. In recent years, there has been noteworthy progress in hydrogen electrochemical conversion and utilization techniques and devices, including water electrolyzers, proton-exchange membrane fuel cells (PEMFCs), solid oxide fuel cells (SOFCs), etc. Each of these technologies has yielded a series of encouraging advances. To showcase these recent advances, Frontiers in Energy is launching a special issue titled “electrochemical conversion and utilization of hydrogen energy”.

关键词： hydrogen energy. electrochemical

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Probing the Nucleation and Growth Kinetics of Bismuth Nanoparticles via In-situ Transmission Electron Microscopy

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Journal of Wuhan University of technology(materials Science) 2024年第4期39卷 877-887页

作者：王浪李超凡 RAN Maojin YUAN Manman 胡执一 LI Yu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Nanostructure Research Centre(NRC) Wuhan University of TechnologyWuhan 430070China Institute of Chemistry Henan Academy of SciencesZhengzhou 450002China Henan Academy of Sciences Zhengzhou 450046China

The nucleation and growth mechanism of nanoparticles is an important theory,which can guide the preparation of ***,it is still lacking in direct observation on the details of the evolution of intermediate state structure during nucleation and *** this work,the evolution process of bismuth nanoparticles induced by electron beam was revealed by in-situ transmission electron microscopy(TEM)at atomic *** experimental results demonstrate that the size,stable surface and crystallographic defect have important influences on the growth of Bi *** non-classical growth paths including single crystal growth and polycrystalline combined growth,as well as,corresponding layer-by-layer growth mechanism along{012}stable crystal plane of Bi nanoparticles with dodecahedron structure were revealed by in-situ TEM *** results provide important guidance and a new approach for in-depth understanding of the nucleation and growth kinetics of nanoparticles.

关键词： bismuth nanoparticles crystal growth transmission electron microscopy in-situ electron microscopy

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High donor-number and low content electrolyte additive for stabilizing zinc metal anode

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Journal of Energy Chemistry 2024年第8期95卷 626-635,I0014页

作者： Yuxin Gong Ruifan Lin Bo Wang Huaizheng Ren Lei Wang Han Zhang Jianxin Wang Deyu Li Yueping Xiong Dianlong Wang Huakun Liu Shixue Dou MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage State Key Laboratory of Urban Water Resource and EnvironmentSchool of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbin 150001HeilongjiangChina Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) College of ChemistryNankai UniversityTianjin 300071China Institute of Energy Material Science University of Shanghai for Science and TechnologyShanghai 200093China

The aqueous zinc ion batteries(AZIBs)are thought as promising competitors for electrochemical energy storage,though their wide application is curbed by the uncontrollable dendrite growth and gas evolution side ***,to stabilize both zinc anodes and water molecules,we developed a modified electrolyte by adding a trace amount of N,N-diethylformanmide(DEF)into the ZnSO_(4)electrolyte for the first time in zinc ion *** effectiveness of DEF is predicted by the comparison of donor number and its preferential adsorption behavior on the zinc anode is further demonstrated by several spectroscopy characterizations,electrochemical methods,and molecular dynamics *** modified electrolyte with 5%*** content can ensure a stable cycling life longer than 3400 h of Zn‖Zn symmetric cells and an ultra-reversible Zn stripping/plating process with a high coulombic efficiency of 99.7%.The Zn‖VO_(2)full cell maintains a capacity retention of 83.5%and a 104 mA h g^(-1)mass capacity after *** work provides insights into the role of interfacial adsorption behavior and the donor number of additive molecules in designing low-content and effective aqueous electrolytes.

关键词： Aqueous zinc ion batteries Zinc anode Electrolyte additives Donor number Zinc dendrites

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Operando reconstruction towards stable CuI nanodots with favorable facets for selective CO_(2) electroreduction to C2H4

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Science China Chemistry 2023年第6期66卷 1834-1843页

作者： Wenjie Xue Hongxia Liu Xinqing Chen Xiaoju Yang Ruoou Yang Youwen Liu Minghao Li Xuan Yang Bao Yu Xia Bo You Key Laboratory of Material Chemistry for Energy Conversion and Storage Ministry of EducationHubei Key Laboratory of Material Chemistry and Service FailureSchool of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan 430074China School of Chemistry and Chemical Engineering Wuhan Textile UniversityWuhan 430200China Shanghai Advanced Research Institute Chinese Academy of SciencesShanghai 201210China State Key Laboratory of Materials Processing and Die&Mold Technology and School of Materials Science and Engineering Huazhong University of Science and TechnologyWuhan 430074China

Cu-based electrocatalysts with favorable facets and Cu^(+)can boost CO_(2) reduction to valuable multicarbon ***,the inevitable Cu^(+)reduction and the phase evolution usually result in poor ***,we fabricate CuI nanodots with favorable(220)facets and a stable Cu^(+)state,accomplished by operando reconstruction of Cu(OH)_(2) under CO_(2)-and I--containing electrolytes for enhanced CO_(2)-to-C_(2)H_(4) *** X-ray absorption spectroscopy(XAS),in-situ Raman spectroscopy and thermodynamic potential analysis reveal the preferred formation of *** gas electroresponse and density functional theory(DFT)calculations reveal that CO_(2)-related species induce the exposure of the(220)plane of Cu ***,the small size of nanodots enables the adequate contact with I^(-),which guarantees the rapid formation of Cu I instead of the electroreduction to Cu^(0).As a result,the resulting catalysts exhibit a high C2H4 Faradaic efficiency of 72.4%at a large current density of 800 m A cm^(-2) and robust stability for 12 h in a flow *** in-situ ATR-SEIRS spectroscopic characterizations and DFT calculations indicate that the(220)facets and stable Cu^(+) in CuI nanodots synergistically facilitate CO_(2)/*CO adsorption and*CO dimerization.

关键词： CO_(2)reduction reaction cuprous iodide favorable facets halogen electrolyte reconstruction

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TPMS_Scaffold_Generator:A Scaffold-Structure Generator Based on Triply Periodic Minimal Surfaces

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Additive Manufacturing Frontiers 2024年第2期3卷 181-191页

作者： Di Lin Cong Zhang Xiyong Chen Nannan Wang Lei Yang School of Transportation and Logistics Engineering Wuhan University of TechnologyWuhan430070China MOE Key Laboratory of New Processing Technology for Non-ferrous Metals and Materials Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured MaterialsGuangxi UniversityNanning530004China State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan430074China

With the rapid development of additive manufacturing(AM),scaffold architectures based on triply periodic minimal surfaces(TPMS)have attracted increasing interest in various engineering ***,they are limited because of the complexity of the design process when adopted in different research and engineer-ing *** this work,we present a free and easy-to-use software package called TPMS_Scaffold_Generator,which is coded using MATLAB(Mathworks,Inc.,USA).It offers three function tabs which are homogeneous tab,heterogeneous tab and multisymmetrical tab,*** of the tabs include the volume frac-tion,topology type,unit cell size,the length of architecture in X,Y,Z direction,accuracy,and the style of gradient and so ***_Scaffold_Generator can generate various TPMS scaffolds,especially ultralight and multisymmetrical *** latest version of the TPMS_Scaffold_Generator is freely available at:https://***/LeveeLin/TPMS_Scaffold_***.

关键词： TPMS scaffold generator Ultra-light scaffolds Triply periodic minimal surfaces(TPMS) Multisymmetrical scaffolds

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Floret-like Fe-N_(x)nanoparticle-embedded porous carbon superstructures from a Fe-covalent triazine polymer boosting oxygen electroreduction

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Frontiers of Chemical Science and Engineering 2023年第5期17卷 525-535页

作者： Yong Zheng Mingjin Li Yongye Wang Niu Huang Wei Liu Shan Chen Xuepeng Ni Kunming Li Siwei Xiong Yi Shen Siliang Liu Baolong Zhou Niaz Ali Khan Liqun Ye Chao Zhang Tianxi Liu College of Materials and Chemical Engineering Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion MaterialsChina Three Gorges UniversityYichang 443002China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and EngineeringDonghua UniversityShanghai 201620China College of Materials Science and Engineering Hubei Key Laboratory for New Textile Materials and ApplicationsWuhan Textile UniversityWuhan 430200China Hubei Three Gorges Laboratory Yichang 443007China College of Environment Zhejiang University of TechnologyHangzhou 310032China College of Light-Textile Engineering and Art Anhui Agricultural UniversityHefei 230036China School of Pharmacy Weifang Medical UniversityWeifang 261053China Key Laboratory of Textile Fiber and Products(Wuhan Textile University) Ministry of EducationWuhan 430200China

Fe–N_(x)nanoparticles-embedded porous carbons with a desirable superstructure have attracted immense attention as promising catalysts for electrochemical oxygen reduction ***,we employed Fe-coordinated covalent triazine polymer for the fabrication of Fe–N_(x)nanoparticle-embedded porous carbon nanoflorets(Fe/N@CNFs)employing a hypersaline-confinement-conversion *** of tailored N types within the covalent triazine polymer interwork in high proportions contributes to the generation of Fe/N coordination and subsequent Fe–N_(x)*** to the utilization of NaCl crystals,the resultant Fe/N@CNF-800 which was generated by pyrolysis at 800℃showed nanoflower structure and large specific surface area,which remarkably suppressed the agglomeration of high catalytic active *** expect,the Fe/N@CNF-800 exhibited unexpected oxygen reduction reaction catalytic performance with an ultrahigh half-wave potential(0.89 V *** hydrogen electrode),a dominant 4e–transfer approach and great cycle stability(>92%after 100000 s).As a demonstration,the Fe/N-PCNF-800-assembled zinc–air battery delivered a high open circuit voltage of 1.51 V,a maximum peak power density of 164 mW·cm^(-2),as well as eminent rate performance,surpassing those of commercial Pt/*** contribution offers a valuable avenue to exploit efficient metal nanoparticles-based carbon catalysts towards energy-related electrocatalytic reactions and beyond.

关键词： Fe–N_(x)nanoparticles hypersaline-confinement conversion floret-like carbon covalent triazine polymers oxygen reduction reaction

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Engineering design of feedstock powder and relevant thermal-mechanical performance of thermal/environmental barrier coatings

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Journal of advanced Ceramics 2025年第2期14卷 37-56页

作者： Xinchang Feng Fangwei Guo Lirong Luo Yuzhang Wang Yun Long Xiaofeng Zhao Fei Pan Lei Guo Qingfeng Zeng Jing Feng Chunlei Wan Shanghai Key Laboratory of Advanced High-temperature Materials and Precision Forming School of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai 200240China National Engineering Research Center of Special Equipment and Power System for Ship and Marine Engineering Shanghai 200030China School of Mechanical Engineering Shanghai Jiao Tong UniversityShanghai 200240China State Key Laboratory of Advanced Nuclear Energy Technology Nuclear Power Institute of ChinaChengdu 610213China Innovative Sensor Technology IST AG Ebnat-Kappel 9642Switzerland School of Materials Science and Engineering Tianjin UniversityTianjin 300072China Tianmushan Laboratory Hangzhou 311115China School of Materials Science and Engineering Kunming University of Science and TechnologyKunming 650093China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China

The development of aeroengine with a high thrust-weight ratio poses great challenges for current top-coating thermal barrier coatings (TBCs) and environmental barrier coatings (EBCs) in service. Medium/high-entropy ceramics are highly promising candidate material for advanced TBCs/EBCs owing to their low thermal conductivity, high melting point, high-temperature stability, and calcium–magnesium–alumino–silicate (CMAS) resistance. Most feedstock powder used for medium/high-entropy TBCs/EBCs is prepared via traditional spray drying, which cannot fully exploit the advantages of multicomponent ceramics. The density, sphericity, inner structure, and flowability of feedstock powder affect their melting state during the thermal spraying process, which strongly affects the microstructure and properties of the deposited coatings. Therefore, the deposited coatings exhibit phase segregation, amorphous phases, and microstructure defects owing to unpredictable variations in feedstock powder with random morphologies and structures. Here, the structure and properties of feedstock powder prepared by state-of-the-art granulation technologies and their influences on the deposited coatings were systematically investigated, which can provide guidance for configuration optimization of feedstock powder and the manufacturing accuracy of the deposited coating. This review aims to bridge the gap between cutting-edge ceramics and advanced engineering technologies, thus providing concrete background knowledge and crucial guidelines for designing and developing TBCs/EBCs.

关键词： thermal/environmental barrier coatings(TBCs/EBCs) spraying ceramic powder multiscale structure control high-entropy ceramics thermal-mechanical performance

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Covalent-architected molybdenum disulfide arrays on Ti_(3)C_(2)T_(x) MXene fiber towards robust capacitive energy storage

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Journal of materials Science & technology 2023年第8期139卷 23-30页

作者： Suya Sun Xiaolin Zhu Xingjiang Wu Meigui Xu Ying Hu Ningzhong Bao Guan Wu State Key Laboratory of Materials Oriented Chemical Engineering College of Chemical EngineeringNanjing Tech UniversityNanjing 210009China National Engineering Lab for Textile Fiber Materials&Processing Technology School of Materials Science and EngineeringZhejiang Sci-Tech UniversityHangzhou 310018China The State Key Laboratory of Chemical Engineering Department of Chemical EngineeringTsinghua UniversityBeijing 100084China Institute of Industry and Equipment Technology Hefei University of TechnologyHefei 230009China

Ti_(3)C_(2)T_(x)MXene fiber has shown extraordinary potential for supercapacitor electrode in wearable elec-tronics and textile energy storage,but realizing high energy density and practical-powered applications remains a great ***,we report a covalent-architected molybdenum disulfide-Ti_(3)C_(2)T_(x)(MoS_(2)-Ti_(3)C_(2)T_(x))core-shell fiber for high-performance *** from the microfluidic and micro-reaction strategies,the ordered MoS_(2)arrays are strongly bridged on Ti_(3)C_(2)T_(x)fiber via Ti-O-Mo bond,re-sulting in large exposed surface,enhanced porosity and excellent interfacial conduction for charges high diffusion and faradaic *** MoS_(2)-Ti_(3)C_(2)T_(x)fiber exhibits ultra-large capacitance of 2028 F cm^(-3)and admirable reversibility in 1 M H_(2)SO_(4)aqueous ***,MoS_(2)-Ti_(3)C_(2)T_(x)fiber-based solid-state supercapacitor presents high energy density of 23.86 mWh cm^(-3),capacitance of 1073.6 F cm^(-3)and superior cycling ability of 92.13%retention after 20,000 cycles,which can realize stable energy supply for wearable watch,LEDs,electric fans,toy ship and self-powered *** work may provide an insight-ful guidance for the advanced design of structural fiber towards robust new energy and next-generation wearable industry.

关键词： Molybdenum disulfide Ti_(3)C_(2)T_(x)fiber Covalent-architecture Supercapacitors High energy density

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