Nowadays, it is popular that the dealer makes profits by selling a kind of discount coupons, which can be used as money to purchase commodities with total cost less than or equal to the face value of the coupon. We ca...
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Nanoimprint lithography offers the possibility to pattern wafer-scale surfaces with nm-sized structures in polymers reaching the 10 nm lateral size. Printable polymers can be tailored to have a surface upon which mole...
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A series of new microwave dielectric ceramics Ba3-nLa1+nTinNb3-nO12 (n=0,1,2) were prepared in the BaO-La2O3-TiO2-Nb2O5 system by high temperature solid-state reaction route. The phase and structure of the ceramics we...
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A series of new microwave dielectric ceramics Ba3-nLa1+nTinNb3-nO12 (n=0,1,2) were prepared in the BaO-La2O3-TiO2-Nb2O5 system by high temperature solid-state reaction route. The phase and structure of the ceramics were characterized by X-ray diffraction, scanning electron microscope, and microwave dielectric properties measurements. These samples were identified as single phase and adopted A4B3O12-type cation-deficient hexagonal perovskite structure, which can be described as consisting of identical perovskite-like blocks, three corner-sharing BO6 octahedra thick, separated by layers of vacant octahedral. These ceramics have high dielectric constants in the range of 48-42, high quality factors (Q×f) up to 38 000 GHz, and low temperature coefficient of resonant frequencies (τf) in the range of (-40-+6)×10-6℃-1. With increasing content of La and Ti, the dielectric constants slightly decrease butτf gradually increases.
We report on electrical and thermal properties in the temperature range from 328to958K of multiwall carbon nanotube (MWNT) bulk materials that were consolidated by spark plasma sintering. The rather dense MWNT bulk ma...
We report on electrical and thermal properties in the temperature range from 328to958K of multiwall carbon nanotube (MWNT) bulk materials that were consolidated by spark plasma sintering. The rather dense MWNT bulk materials show exclusively nonmetallic temperature dependence of electrical conductivity from 328to958K, owing to the absence of metallic conduction mechanism in such a highly disordered system. The conductivity exhibited extremely weak temperature dependence with only 35% increase of room-temperature conductivity at 958K, which was explained by a heterogeneous model considering both fluctuation-assisted tunneling between nanotubes or shells of MWNT and variable-range hopping between graphite microphases that were observed to be dispersed in MWNT bulk materials. The results suggest that fluctuation-assisted tunneling governed this weak conductivity-temperature dependence. Metallic diffusion behavior was observed from 328to958K, and it indicates that phonon drag contributed little to the thermoelectric power of MWNT bulk materials. By contrast, we further show that the increase in sample dimensionality from individual MWNT to bulk materials tends to increase the metallic temperature dependence of electrical conductivity and remarkably decrease the magnitude of thermal conductivity. The geometric shift from graphene sheet to tubular nanotube for carbon-related bulk materials changes the conduction from the combination of n and p types to absolute p type.
Three novel dielectric ceramics Ba5LnZnNb9O30 (Ln= La, Nd and Sm) were synthesized and characterized in the BaO-Ln2O3-ZnO-Nb2O5 quaternary system, which formed the filled tungsten-bronze structures. The present cerami...
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Three novel dielectric ceramics Ba5LnZnNb9O30 (Ln= La, Nd and Sm) were synthesized and characterized in the BaO-Ln2O3-ZnO-Nb2O5 quaternary system, which formed the filled tungsten-bronze structures. The present ceramics exhibit high dielectric constant (εr) up to 310, low dielectric loss in the level of 10 3 at 1 MHz. Meanwhile, the temperature coefficients of the dielectric constant (τε) of Ba5LnZnNb9O3o varies from -1 390×10-6 to -1 220×10-6/℃as the radius of Ln3+ increases. The present ceramics are promising candidates for high dielectric constant and low loss dielectric ceramics.
A new niobate compound was synthesized for the first time in Na2 O-BaO-Li2 O-ZnO-Nb2 O5 system by solid state reaction. The acw compound was studied by X-ray diffraction, electron probe, X-ray microanalysis, chemical ...
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A new niobate compound was synthesized for the first time in Na2 O-BaO-Li2 O-ZnO-Nb2 O5 system by solid state reaction. The acw compound was studied by X-ray diffraction, electron probe, X-ray microanalysis, chemical analysis and SEM. The result of X-ray powder diffraction shows that NaBa2 Li0.6 Nb4.8 Zn0.2 O15 belongs to orthorhombic tungsten bronze structure, with space group Pba2( 32 ) and lattice parameters a = 12.6115(2)A, b = 12.4981(2)A, C = 3.9479(3)A. The X-ray powder diffraction lines of the compoutid were well indexed.
The effect of Nb in (La0.5Ce0.5)(64-x)Al16Ni5Cu15Nbx (x=0-5, mole fraction) bulk metallic glasses was investigated by X-ray diffractometry, differential scanning calorimetry, and scanning electron microscopy. Fully am...
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The effect of Nb in (La0.5Ce0.5)(64-x)Al16Ni5Cu15Nbx (x=0-5, mole fraction) bulk metallic glasses was investigated by X-ray diffractometry, differential scanning calorimetry, and scanning electron microscopy. Fully amorphous rods up to 5 mm in diameter were obtained using copper mold. Their lower glass transition temperatures are of about 401-407 K and wide supercooled liquid regions are up to 75 K. The oxidation resistance of the LaCe-based glassy alloys can be largely enhanced by adding tiny Nb, which makes the developed LaCe-based bulk metallic glasses more attractive for potential industrial applications.
Amorphous ribbons of (Ni0.75Fe0.25)78-xNbxSi10B12 (x = 0, 5) were prepared by a single roller melt-spinning technique in air atmosphere. The crystallization kinetics of the alloys were investigated by means of con...
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Amorphous ribbons of (Ni0.75Fe0.25)78-xNbxSi10B12 (x = 0, 5) were prepared by a single roller melt-spinning technique in air atmosphere. The crystallization kinetics of the alloys were investigated by means of continuous heating, and the activation energies of the alloys were calculated using Kissinger plot method and Ozawa plot method on the basis of differential thermal analysis data. The crystallization products were analyzed by X-ray diffraction. After the (Ni0.75Fe0.25)78Si10B12 amorphous alloy was annealed at the temperatures 715 and 745 K, a single phase of γ-(Fe, Ni) solid solution with grain sizes of about 10.3 and 18.5 nm, respectively, precipitates in the amorphous matrix. The crystallized phases are γ-(Fe, Ni) solid solution, Fe2Si, Ni2Si, and Fe3B after annealing at 765 K. The (Ni0.75Fe0.25)73NbsSi10 B12 amorphous alloy was annealed at 720, 750, and 800 K; and the crystallization phases, γ(Fe, Ni) solid solution, (Fe, Ni)23B6. Ni31Si12 and Nb2NiB0.16 form simultaneously.
作者:
徐慢Key Laboratory of State Education
Ministry of Silicate Materials Science and Engineering Wuhan University of Technology Wuhan 430070ChinaKey Laboratory of Nonferrous Materials and New Processing Technology Ministry of EducationGuilin University of Technology Guilin 541004China
Three novel Ba5RNiNb9O30( R =La , Nd and Sm ) ceramics were prepared and characterized in the BaO-R2O3-NiO-Nb2O5 system. All three compounds are paraelectric phases adopting the filled tetragond tungsten bronze (TB...
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Three novel Ba5RNiNb9O30( R =La , Nd and Sm ) ceramics were prepared and characterized in the BaO-R2O3-NiO-Nb2O5 system. All three compounds are paraelectric phases adopting the filled tetragond tungsten bronze (TB) stracture at room temperature . At 1MHz , Ba5RNiNb9O30 ceramics have a high dielectric constants in the range 193-245.3, a low dielectric loss in range 0.0059-0.0087, and the temperature coefficientz of the dielectric constant (τε) in the range - 1 140- - 1 310×10^-6 ·℃^ -1 . Their temperature coefficients of the dielectric constant are significantly reduced compared to those of Ba5RTi3Ta7O30 ( R = La , Nd , Sm ) ceramics.
A bulk metal/ceramic composite material with a honeycomb-like micro-cell structure has been prepared by sintering the spherical Al90Mn9Ce1 alloy powders clad by Al2O3 nano-powder with the spark plasma sintering (SPS) ...
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A bulk metal/ceramic composite material with a honeycomb-like micro-cell structure has been prepared by sintering the spherical Al90Mn9Ce1 alloy powders clad by Al2O3 nano-powder with the spark plasma sintering (SPS) technique. The as-prepared material consists of Al90Mn9Ce1 alloy cell and closed Al2O3 ceramic cell wall. The diameter of the cells is about 20―40 μm, while a thickness of the cell wall is about 1―2 μm. The ultimate compressive strength of the as-sintered materials is about 514 MPa, while its fracture strain is up to about 0.65 %. This composite material might possess good anti-corrosion, thermal endurance and other potential properties due to its unique microstructure. The result shows that the Al90Mn9Ce1/Al2O3 composite powders can be sintered by spark plasma sintering technique despite the large difference in their sintering temperature. This work offers a way of designing and preparing metal/ceramic composite material with functional property.
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