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Crystalline@amorphous core-shell structure of WO3@WO_(3-x)S_(x) established via doping strategy for enhancing magnesium ions storage performance

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Journal of Magnesium and Alloys 2025年第3期13卷 1353-1363页

作者： Shiqi Ding Yuxin Tian Jiankang Chen Guofeng Wang Bing Sun He Lv Lei Wang Guicun Li Alan Meng Zhenjiang Li College of Materials Science and Engineering Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life ScienceMOEShandong Key Laboratory of Biochemical AnalysisCollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042ShandongPR China Qingdao Engineering Research Center for New Metallic Functional Materials Characteristic Laboratory of Advanced Metal Functional Materials and Processing in Universities of ShandongQingdao Binhai UniversityQingdao 266555ShandongPR China

Designing cathode possessing crystalline@amorphous core-shell structure with both active core and shell is a meaningful work for resolving the low speciﬁc capacity,unstable cycling performance and sluggish reaction kinetics issues of rechargeable magnesium batteries(RMBs)by providing more active sites as well as releasing inner stress during ***,WO_(3)@WO_(3-x)S_(x) owning crystalline@amorphous core-shell structure containing both active core and active shell is constructed successfully by introducing S into metastable WO3 structure under temperatureﬁeld *** such structure,amorphous shell would provide continuous Mg^(2+)diffusion channels due to its isotropy property for most Mg^(2+)migrating rapidly to interface and then adsorb at ions reservoir formed by interfacial electricﬁeld for increasing speciﬁc *** also makes security for stable structure of WO_(3)@WO_(3-x)S_(x) by alleviating volume expansion of crystalline core WO_(3) during cycling to prolong cycling ***,“softer”ions S^(2-)would weaken interaction between hard acid Mg^(2+) and ionic lattice to enhance Mg^(2+)storage ***,WO_(3)@WO_(3-x)S_(x) delivers the superior cycling performance(1000 cycles with 83.3%),rate capability(88.5 mAh g^(-1) at 1000 mA g^(-1))and speciﬁc capacity(about 150 mAh g^(-1) at 50 mA g^(-1)),which is near 2 times higher than that of *** is believed that the crystalline@amorphous core-shell structure with both active core and shell designing via doping strategy is enlightening for the development of high-performance RMBs,and such design can be extended to other energy storage devices for better electrochemical performance.

关键词： Doping Sulfuration Crystalline@amorphous core-shell structure WO_(3) Rechargeable magnesium batteries

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One-step fabrication of ultrathin porous Janus membrane within seconds for waterproof and breathable electronic skin

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Science Bulletin 2025年第5期70卷 712-721页

作者： Yufeng Ni Bing Li Chengzhen Chu Shaofan Wang Yujie Jia Shichun Cao Rasoul Esmaeely Neisiany Chuanglong He Shuo Chen Zhengwei You State Key Laboratory of Advanced Fiber Materials Institute of Functional MaterialsCollege of Materials Science and EngineeringResearch Base of Textile Materials for Flexible Electronics and Biomedical Applications(China Textile Engineering Society)Shanghai Engineering Research Center of Nano-Biomaterials and Regenerative MedicineShanghai Key Laboratory of Lightweight CompositeDonghua UniversityShanghai 201620China College of Biological Science and Medical Engineering Donghua UniversityShanghai 201620China Department of Materials and Polymer Engineering Faculty of EngineeringHakim Sabzevari UniversitySabzevar***Iran Biotechnology Centre Silesian University of TechnologyGliwice44-100Poland

It remains a challenge for a simple and scalable method to fabricate ultrathin porous Janus membranes for stretchable on-skin ***,we propose a one-step droplet spreading phase separation strategy to prepare an ultrathin and easily collected Janus thermoplastic polyurethane(TPU)membrane within *** metal-ion solvation structure mitigated migration kinetics to delay TPU solution demixing,promoting the further penetration of the coagulating ***,the developed membranes,with an average preparation rate of 25.2 cm^(2)s^(−1),had a thickness of 5μm,and the water vapor transmission rate was determined to be 663 g m^(−2) d^(−1).The small pore layer having an average pore size of 1.7μm effectively blocked external liquid *** porous Janus TPU membrane coated by liquid metal served as a building block to develop a new generation of monolithic stretchable electronics with simultaneous high permeability and waterproofness.

关键词： porous polyurethane kinetics

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Fast deposition of Ni doped YSZ coatings by cathode plasma electrolysis for solid oxide fuel cell applications

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Ceramics International 2025年第13期51卷 17268-17277页

作者： Liu, Chenxu Du, Ke Song, Chen Song, Yang Zhou, Chenchen Zhang, Jin Liu, Min Tian, Yu Meng, Yonggang State Key Laboratory of Tribology in Advanced Equipment Tsinghua University Beijing100084 China Institute of New Materials Guangdong Academy of Sciences National Engineering Laboratory of Modern Materials Surface Engineering Technology Guangdong Provincial Key Laboratory of Modern Surface Engineering Technology Guangdong-Hong Kong Joint Laboratory of Modern Surface Engineering Technology Guangzhou510650 China School of Materials Science and Engineering Nanyang Technological University 639798 Singapore Beijing Key Laboratory for Corrosion Erosion and Surface Technology Institute of Advanced Materials and Technology University of Science and Technology Beijing Beijing100083 China

The fast fabrication of high-quality anode layers of solid oxide fuel cells (SOFCs) is a key factor for their efficient applications. In this work, a one-step method of cathode plasma electrolytic deposition (CPED) is developed to prepare Ni doped YSZ coatings with a thickness of 35–55 μm on porous stainless steel. Compared to the several hours required by traditional methods, a faster coating deposition that only takes 60 s is achieved owing to the effect of enormous energy of plasma arc at the solid-liquid interface in the CPED method. The preparation process is analyzed by recording the variation of current with voltage. The unique micro-structure of the coatings is observed, and the formation mechanism of the Ni doped YSZ coating during the CPED process is proposed. The deposited coatings show an excellent performance as the anode layers for SOFCs, with Sc2O3 stabilized ZrO2 coating prepared by atmospheric plasma spraying as electrolyte and La0.6Sr0.4Co0.2Fe0.8O3-δ as the cathode. The open circuit voltage of the cells reaches 1.000 V and the maximum power density reaches 817.4 mW cm−2 at 800 °C. The finding opens a novel pathway for the efficient preparation of anode materials for SOFCs. © 2025

关键词： Plasma spraying

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Engineering design of feedstock powder and relevant thermal-mechanical performance of thermal/environmental barrier coatings

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Journal of advanced Ceramics 2025年第2期14卷 37-56页

作者： Xinchang Feng Fangwei Guo Lirong Luo Yuzhang Wang Yun Long Xiaofeng Zhao Fei Pan Lei Guo Qingfeng Zeng Jing Feng Chunlei Wan Shanghai Key Laboratory of Advanced High-temperature Materials and Precision Forming School of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai 200240China National Engineering Research Center of Special Equipment and Power System for Ship and Marine Engineering Shanghai 200030China School of Mechanical Engineering Shanghai Jiao Tong UniversityShanghai 200240China State Key Laboratory of Advanced Nuclear Energy Technology Nuclear Power Institute of ChinaChengdu 610213China Innovative Sensor Technology IST AG Ebnat-Kappel 9642Switzerland School of Materials Science and Engineering Tianjin UniversityTianjin 300072China Tianmushan Laboratory Hangzhou 311115China School of Materials Science and Engineering Kunming University of Science and TechnologyKunming 650093China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China

The development of aeroengine with a high thrust-weight ratio poses great challenges for current top-coating thermal barrier coatings (TBCs) and environmental barrier coatings (EBCs) in service. Medium/high-entropy ceramics are highly promising candidate material for advanced TBCs/EBCs owing to their low thermal conductivity, high melting point, high-temperature stability, and calcium–magnesium–alumino–silicate (CMAS) resistance. Most feedstock powder used for medium/high-entropy TBCs/EBCs is prepared via traditional spray drying, which cannot fully exploit the advantages of multicomponent ceramics. The density, sphericity, inner structure, and flowability of feedstock powder affect their melting state during the thermal spraying process, which strongly affects the microstructure and properties of the deposited coatings. Therefore, the deposited coatings exhibit phase segregation, amorphous phases, and microstructure defects owing to unpredictable variations in feedstock powder with random morphologies and structures. Here, the structure and properties of feedstock powder prepared by state-of-the-art granulation technologies and their influences on the deposited coatings were systematically investigated, which can provide guidance for configuration optimization of feedstock powder and the manufacturing accuracy of the deposited coating. This review aims to bridge the gap between cutting-edge ceramics and advanced engineering technologies, thus providing concrete background knowledge and crucial guidelines for designing and developing TBCs/EBCs.

关键词： thermal/environmental barrier coatings(TBCs/EBCs) spraying ceramic powder multiscale structure control high-entropy ceramics thermal-mechanical performance

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Tunable vortex radiation source driven by free electrons

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Optics Letters 2025年第10期50卷 3333-3336页

作者： Li, Sirui Li, Tianyi Sun, Jingbo Wen, Yongzheng Zhou, Ji State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and Engineering Tsinghua University Beijing100084 China State Key Laboratory of Nuclear Physics and Technology Institute of Heavy Ion Physics School of Physics Peking University Beijing100871 China

In this Letter, we propose a scheme to generate tunable vortex radiation through the interaction of free electrons with a dual-layer metasurface. The metasurface combines a field-enhancement layer with a phase-modulation layer to produce enhanced Smith–Purcell radiation (SPR) while enabling gradient phase control. This configuration efficiently converts the free-electron evanescent field into a coherent vortex beam. Simulation results indicate that the proposed structure generates coherent radiation with approximately 4.5 times the intensity of conventional vortex radiation under identical electron-beam conditions. The frequency and direction of the vortex radiation can be tuned by varying the electron velocity. Moreover, the structure enables coherent vortex radiation generation with a small number of electrons, including low-velocity electrons, without requiring strong focusing magnetic fields or periodic electron bunching. This work establishes an innovative approach for developing compact, efficient, and tunable vortex radiation sources based on free electrons. © 2025 Optica Publishing Group. All rights, including for text and data mining (TDM), Artificial Intelligence (AI) training, and similar technologies, are reserved.

关键词： Particle beam bunching

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Understanding the iodine electrochemical behaviors in aqueous zinc batteries

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Journal of Energy Chemistry 2025年第2期101卷 402-415,I0009页

作者： Xuefang Xie Xiaoxin Xu Shuquan Liang Guozhao Fang College of Physical Science and Technology Xinjiang UniversityUrumqi 830017XinjiangChina Xinjiang Key Laboratory of Solid State Physics and Devices Xinjiang UniversityUrumqi 830046XinjiangChina School of Materials Science&Engineering Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan ProvinceCentral South UniversityChangsha 41003 HunanChina National Energy Metal Resources and New Materials Key Laboratory Central South UniversityChangsha 410083HunanChina

Iodine is widely used in aqueous zinc batteries(ZBs)due to its abundant resources,low cost,and active redox *** addition to the active material in zinc-iodine batteries,iodine also plays an important role in other ZBs,such as regulating the electrochemical behavior of zinc ions,promoting the reaction kinetic and reversibility of other redox pairs,catalytic behaviors related to iodine reactions,coupling with other halogen ions,shuttle behaviors of polyiodides,***,there is currently a lack of comprehensive discussion on these ***,this review provides a comprehensive overview of the electrochemical behaviors of iodide in the aqueous *** effect of iodine ions on the Zn^(2+)desolvation behaviors and the interfacial behaviors of Zn anode was *** redox pairs boosting other redox pairs,such as MnO_(2)/Mn^(2+)redox pair and vanadium redox pair to obtain high reversibility and capacity was also ***,the catalytic behaviors related to iodine reactions in aqueous ZBs,synergistic reaction with other halogen ions and suppression of shuttle behaviors for high performance zinc-iodine batteries were systematically ***,future prospects for designing effective iodine electrochemical behaviors with practicability are proposed,which will provide scientific guidance for the practical application of iodine-related aqueous ZBs.

关键词： lodide ion Redox pairs Catalytic behavior Shuttle effect Zinc batteries

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Experiment-driven simplification of Johnson-Champoux-Allard-Lafarge model for fibrous materials

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Journal of the Acoustical Society of America 2025年第5期157卷 3497-3507页

作者： Yang, Tao Eser, Martin Xiong, Xiaoman Groby, Jean-Philippe Schmid, Jonas M. Maeder, Marcus Chang, Yu-Hao Marburg, Steffen Department of Engineering Physics and Computation TUM School of Engineering and Design Technical University of Munich Boltzmannstrasse 15 Garching85748 Germany State Key Laboratory of New Textile Materials and Advanced Processing Wuhan Textile University Wuhan430200 China CNRS Le Mans Université France School of Aerospace Engineering Technical University of Munich Asia 510 Dover Road #05-01 139660 Singapore

Widely used empirical and semi-phenomenological models lack practicality due to unstable predictions, which exhibit poor reproducibility, or reliance on numerous parameters that are not directly measurable. This paper presents an experiment-driven method to simplify the Johnson-Champoux-Allard-Lafarge (JCAL) model using a two-microphone impedance tube. Bayesian inference is applied to determine the non-acoustical parameters (i.e., tortuosity, airflow resistivity, viscous and thermal characteristic lengths, and static thermal permeability), and the regression method is used to correlate porosity with these non-acoustical parameters. The simplified JCAL model is validated against the original model and experimental results for acrylic, silk, and wool fibers. The simplified JCAL model shows good agreement with the original model for acrylic and wool fibers. Both models perform reliably for porosities between 92% and 98%, but show a mismatch with experimental data at 99% porosity, likely due to frame vibration effects. The poroelastic behavior leads to the original and simplified JCAL models failure for silk fiber. This experiment-driven simplification method reduces the JCAL model to a single parameter, porosity, which significantly enhances computational efficiency and enables faster predictions. It also enhances the model's applicability to optimization strategies, such as tuning design parameters for optimal sound absorption while minimizing thickness and mass. © 2025 Author(s).

关键词： textile fibers

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Weakly solvating electrolyte enabling solvent-free co-intercalation for stable potassium-ion storage in graphite

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Nano Research 2025年第3期18卷 234-242页

作者： Chaojie Cheng Wencong Feng Feiyue Wang Jingke Ren Deyang Guan Wei Chen Jean-Jacques Gaumet Kai Fu Xiaobin Liao Wen Luo State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China School of Materials Science and Engineering Xinjiang UniversityUrumqi 830017China Laboratoire de Chimie et Physique:Approche Multi-échelles des Milieux Complexes(LCP-A2MC)Institut Jean BarriolUniversitéde LorraineMetz 57070France

Ether electrolytes for potassium-ion batteries exhibit a broader electrochemical window and greater applicability,yet most of them are high-concentration electrolytes with elevated *** this study,we propose the use of a weakly solvating cyclic ether electrolyte with tetrahydropyran(THP)as the *** approach induces the formation of a thin and dense inorganic-rich solid electrolyte interphase(SEI)film,which is accompanied by a decrease in the activation energy of electrode interfacial reactions due to the weak ligand binding of THP with K^(+).Density functional theory(DFT)simulations also corroborate the hypothesis that K^(+)has a lower binding energy with *** potassium storage process,the phenomenon of solvent co-intercalation of graphite does not occur,which greatly reduces the destruction of the graphite structure and enables a superior electrochemical performance and enhanced cycling stability at a lower concentration(2 M).At a current density of 0.2 C(55.8 mA·g^(-1)),the battery can be stably cycled for 800 cycles(approximately 8 months)with a specific capacity of 171.8 mAh·g^(-1).This study provides a new ether-based electrolyte for potassium ion batteries and effectively reduces the electrolyte cost,which is expected to inspire further development of energy storage batteries.

关键词： weakly solvating electrolyte co-intercalation graphite potassium ion batteries

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Comprehensive Chlorine Suppression:Advances in materials and System Technologies for Direct Seawater Electrolysis

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Nano-Micro Letters 2025年第5期17卷 297-325页

作者： Cenkai Zhao Zheyuan Ding Kunye Zhang Ziting Du Haiqiu Fang Ling Chen Hao Jiang Min Wang Mingbo Wu State Key Laboratory of Heavy Oil Processing College of New EnergyChina University of Petroleum(East China)Qingdao 266580People’s Republic of China Beijing National Laboratory for Molecular Sciences New Cornerstone Science LaboratoryCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871People’s Republic of China Key Laboratory for Ultrafine Materials of Ministry of Education School of Materials Science and EngineeringEast China University of Science and TechnologyShanghai 200237People’s Republic of China

Seawater electrolysis offers a promising pathway to generate green hydrogen,which is crucial for the net-zero emission *** seawater electrolysis is severely limited by high energy demands and system complexity,while the direct seawater electrolysis bypasses pre-treatment,offering a simpler and more cost-effective ***,the chlorine evolution reaction and impurities in the seawater lead to severe corrosion and hinder electrolysis’s ***,we review recent advances in the rational design of chlorine-suppressive catalysts and integrated electrolysis systems architectures for chloride-induced corrosion,with simultaneous enhancement of Faradaic efficiency and reduction of electrolysis’s ***,promising directions are proposed for durable and efficient seawater electrolysis *** review provides perspectives for seawater electrolysis toward sustainable energy conversion and environmental protection.

关键词： Direct seawater electrolysis Oxygen evolution reaction Hydrogen evolution reaction Chlorine suppression Seawater electrolysis system

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High-sensitivity and high-output voltage lead-free perovskite-based fiber optoelectronic devices

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Journal of Luminescence 2025年 284卷

作者： Zhang, Xueliang Zhang, Xiaoman Zhang, Xiaodong Mei, Lefu Wang, Luoxin Wang, Hua Li, Xiangming Nie, Kun School of Materials Science and Engineering Hubei Key Laboratory for New Textile Materials and Applications Research and State Key Laboratory of New Textile Materials & Advanced Processing Wuhan Textile University Wuhan430200 China Beijing100083 China Department of Functional Materials School of Materials Sciences and Technology Guangdong University of Petrochemical Technology Maoming525000 China

Lead-free halide perovskites have excellent optoelectronic properties and have been widely studied in the optoelectronic field. A kind of all-inorganic double perovskite crystals (PCs) with high output voltage and high sensitivity was successfully synthesized via a more energy-efficient crystallization method in this study. The luminescence intensity of the perovskite crystals was significantly enhanced by Bi3+ doping. These perovskite crystals were used to prepare red light-emitting diodes (LEDs) with color purity of up to 93.1 %. In addition, the perovskite crystals were used to modify aramid chopped fibers (ACFs)/polyphenylene sulfide (PPS) composite fibers to fabricate flexible luminescent fibers. The modified composite fibers also demonstrated exceptional piezoelectric properties. Therefore, the modified composite fiber was used to prepare a piezoelectric sensor. The maximum output voltage of the sensor could reach 50 V at room temperature with a response time of only 8 ms. The piezoelectric constant d33 of this piezoelectric sensor was 374 pC/N, indicating that the sensor had high sensitivity. When the temperature increased to 373 K, the output voltage gradually rose to 100 V. The red and white LED devices demonstrated the potential of perovskites for lighting and display applications. Meanwhile, the flexible light-emitting fibers and piezoelectric sensors further expanded the application scope of perovskite in multifunctional optoelectronic devices. © 2025 Elsevier B.V.

关键词： Aramid fibers

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