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Steam disinfection enhances bioaccessibility of metallic nanoparticles in nano-enabled silicone-rubber baby bottle teats,pacifiers,and teethers

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Journal of Environmental Sciences 2024年第2期136卷 161-171页

作者： Yu Su BinWang Xin Tong Shuchuan Peng Sijin Liu Baoshan Xing Rong Ji State Key Laboratory of Pollution Control and Resource Reuse School of the EnvironmentNanjing UniversityNanjing 210023China School of Resources and Environmental Engineering Hefei University of TechnologyHefei 230009China State Key Laboratory of Environmental Chemistry and Ecotoxicology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China Stockbridge School of Agriculture University of MassachusettsAmherstMA 01003USA

Nano-enabled silicone-rubber articles for feeding or chewing could be a source of metallic nanoparticles(NPs)directly exposed to infants and young ***,the impact of steam disinfection on release of NPs and the related potential risks to children's health are ***,we investigated contents and form of Ag and Zn in 57 nano-enabled silicone-rubber baby bottle teats,pacifiers,and teethers of seven countries and examined the impacts of steam disinfection on in vitro bioaccessibility(IVBA)of Ag and Zn in the *** 89%articles had a mixture of Ag-and Zn-containing NPs and the teethers had relatively high Ag and Zn contents(up to 501 and 254μg/g,respectively).Steam disinfection caused rubber decomposition into micro(nano)plastics(0.54-15.7μm)and NP release from the interior of bulk rubber and micro-sized plastics,thus enhancing the IVBA of Ag and Zn by up to 5.5 *** findings provide insights into mechanisms for NP release by steam *** oral exposure risk assessment suggested low health concerns on individual metal release,our study points out the need to assess the potential health risks of child co-exposure to metallic NPs and micro(nano)plastics.

关键词： Silicone rubber Metallic nanoparticles Micro(nano)plastics Bioaccessibility Children's health

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Simple fabrication of carboxymethyl cellulose and k-carrageenan composite aerogel with efficient performance in removal of fluoroquinolone antibiotics from water

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Frontiers of Environmental Science & Engineering 2022年第10期16卷 105-118页

作者： Na Li Boqiang Gao Ran Yang Hu Yang State Key Laboratory of Pollution Control and Resource Reuse School of the EnvironmentNanjing UniversityNanjing 210023China Department of Environmental Science School of Tropical and Laboratory MedicineHainan Medical UniversityHaikou 571199China

3D composite aerogels(CMC-CG)composed of carboxymethyl cellulose andκ-carrageenan were designed and fabricated using the one-pot synthesis *** optimized CMC-CG showed a good mechanical property and a high swelling ratio due to its superior textural properties with a proper chemically cross-linked interpenetrating network ***-CG was utilized for the removal of various fluoroquinolones(FQs)from water and exhibited high adsorption performance because of effective electrostatic attraction and hydrogen bonding ***(CIP),a popular FQ,was used as the *** optimized CMC-CG had a theoretically maximal CIP uptake of approximately 1.271 mmol/g at the pH of *** adsorption capacity of CMC-CG was improved in the presence of some cations,Cu2+and Fe3+ions,at a low concentration through the bridging effect but was reduced at a high *** investigation of adsorption mechanisms,based on the adsorption kinetics,isotherms and thermodynamic study,Fourier transform infrared spectrometry and X-ray photoelectron spectroscopy analyses before and after adsorption,and changes in the adsorption performance of CMC-CG toward two molecular probes,further indicated that electrostatic attraction was the dominant interaction rather than hydrogen bonding in this ***-CG after saturated adsorption of CIP could be easily regenerated using a dilute NaCl aqueous solution and reused ***,the disused aerogel could still be reused as a new adsorbent for effective adsorption of Cu2+***,this study suggested the promising applications of this composite aerogel as an eco-friendly,cost-effective,and recyclable adsorbent for thie efficient removal of FQs from water.

关键词： Composite aerogel of carboxymethy lcellulose andκ-carrageenan Fluoroquinolone antibiotics Adsorption performance Coexisting substances Adsorption mechanism Reusability

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Screening of indicator pharmaceuticals and personal care products in landfill leachates: a case study in Shanghai, China

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Frontiers of Environmental Science & Engineering 2023年第9期17卷 245-256页

作者： Xiping Kan Xia Yu Wentao Zhao Shuguang Lyu Shuying Sun Gang Yu Qian Sui State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process School of Resources and Environmental EngineeringEast China University of Science and TechnologyShanghai 200237China State Key Laboratory of Pollution Control and Resource Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China Advanced Interdisciplinary Institute of Environment and Ecology Beijing Normal University at ZhuhaiZhuhai 519087China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China

Identifying potential sources of pharmaceuticals and personal care products(PPCPs)in the environment is critical for the effective control of PPCP *** leachate is an important source of PPCPs in water;however,it has barely been involved in source apportionment due to the lack of indicator-PPCPs(i-PPCPs)in landfill *** study provides the first systematic framework for identifying i-PPCPs for landfill leachates based on the wide-scope target monitoring of *** number of target PPCPs increased from<20 in previous studies to 68 in the present ***-nine PPCPs were detected,with median concentrations in leachate samples ranging from below the method quantification limit(MQL)to 41μg/L,and 19 of them were rarely reported previously.A total of 29 target compounds were determined to be PPCPs of high concern by principal component analysis according to multiple criteria,including occurrence,exposure potential,and ecological *** with source-specificity and representativeness analysis,erythromycin,gemfibrozil,and albendazole showed a significant difference in their occurrence in leachate compared to other potential sources(untreated and treated municipal wastewater and livestock wastewater)and correlated with total PPCP concentrations;these were recommended as i-PPCPs for *** screening procedure can be used to develop a sophisticated source apportionment method to identify sources of PPCPs from adjacent landfills.

关键词： Landfill leachates PPCPs Indicator Screening criteria Source-specificity

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A review of the application of machine learning in water quality evaluation

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Eco-Environment & Health 2022年第2期1卷 107-116页

作者： Mengyuan Zhu Jiawei Wang Xiao Yang Yu Zhang Linyu Zhang Hongqiang Ren Bing Wu Lin Ye State Key Laboratory of Pollution Control and Resource Reuse School of EnvironmentNanjing UniversityNanjing 210023China

With the rapid increase in the volume of data on the aquatic environment,machine learning has become an important tool for data analysis,classification,and *** traditional models used in water-related research,data-driven models based on machine learning can efficiently solve more complex nonlinear *** water environment research,models and conclusions derived from machine learning have been applied to the construction,monitoring,simulation,evaluation,and optimization of various water treatment and management ***,machine learning can provide solutions for water pollution control,water quality improvement,and watershed ecosystem security *** this review,we describe the cases in which machine learning algorithms have been applied to evaluate the water quality in different water environments,such as surface water,groundwater,drinking water,sewage,and ***,we propose possible future applications of machine learning approaches to water environments.

关键词： Machine learning Water quality Evaluation Prediction

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Enhancing hydrogen evolution reaction performance of transition metal doped two-dimensional electride Ca_(2)N

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Chinese Chemical Letters 2023年第6期34卷 487-491页

作者： Baoyu Liu Ziqiang Chen Rui Xiong Xuhui Yang Yinggan Zhang Teng Xie Cuilian Wen Baisheng Sa Multiscale Computational Materials Facility and Key Laboratory of Eco-materials Advanced TechnologyCollege of Materials Science and EngineeringFuzhou UniversityFuzhou 350100China College of Environmental Science and Engineering Fujian Key Laboratory of Pollution Control&Resource ReuseFujian Normal UniversityFuzhou 350007China College of Materials Fujian Provincial Key Laboratory of Theoretical and Computational ChemistryXiamen UniversityXiamen 361005China

Two-dimensional electride Ca_(2)N has strong electron transfer ability and low work function,which is a potential candidate for hydrogen evolution reaction(HER)*** this work,based on density functional theory calculations,we adopt two strategies to improve the HER catalytic activity of Ca_(2)N monolayer:introducing Ca or N vacancy and doping transition metal atoms(TM,refers to Ti,V,Cr,Mn,Fe,Zr,Nb,Mo,Ru,Hf,Ta and W).Interestingly,the Gibbs free energyΔG_(H*)of Ca_(2)N monolayer after introducing N vacancy is reduced to-0.146 e V,showing good HER catalytic *** is highlighted that,the HER catalytic activity of Ca_(2)N monolayer can be further enhanced with TM doping,the Gibbs free energyΔG_(H*)of single Mo and double Mn doped Ca_(2)N are predicted to be 0.119 and 0.139 e V,*** present results will provide good theoretical guidance for the HER catalysis applications of two-dimensional electride Ca_(2)N monolayer.

关键词： Two-dimensional electride Ca_(2)N Density functional theory calculations Hydrogen evolution reaction Transition metal doping

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Getting insights into gas-phase sulfation effect on catalytic performance of praseodymium oxides in NH_(3)-SCR of NO

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Journal of Rare Earths 2023年第6期41卷 952-958,I0005页

作者： Yandi Cai Peng Yang Qinglong Liu Kaili Ma Wenxin Ma Wang Song Qiuhui Qian Fei Gao Wei Tan Lin Dong State Key Laboratory of Pollution Control and Resource Reuse School of EnvironmentJiangsu Key Laboratory of Vehicle Emissions ControlCenter of Modern AnalysisKey Laboratory of Mesoscopic Chemistry of MOESchool of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210023China Analysis and Testing Center Southeast UniversityNanjing 211189China National and Local Joint Engineering Laboratory of Municipal Sewage Resource Utilization Technology School of Environmental Science and EngineeringSuzhou University of Science and TechnologySuzhou 215009China

Sulfation treatment has been widely used to promote the catalytic performance of ceria(CeO_(2))based catalysts for the selective catalytic reduction of NO by NH_(3)(NH_(3)-SCR of NO).Praseodymium oxide(PrO_(x)),another commonly used rare earth material with similar structural properties as CeO_(2),also shows satistactory redox properties due to the facile redox cycle of Pr^(3+)■Pr^(4+).In this work,gas phase sulfation treatment with varied duration was performed on PrO_(x) at 200℃,and the NH_(3)-SCR activity of sulfated PrO_(x) was *** on the results of systematic characterizations(e.g.,N_(2)-physisorption,NH_(3) oxidation,NO oxidation,in situ diffuse Fourier transform infrared spectroscopy),it is revealed that the catalytic performance of sulfated PrO_(x)is highly dependent on the sulfation time(or the amount of sulfate species deposited on PrO_(x)),which has a significant impact on the competitive reaction between NH_(3) oxidation and NH_(3)-SCR of NO,thus determining the NH_(3)-SCR activity of PrO_(x).This work provides new insight into tuning the interaction between PrO_(x) surface and reactants(NO,NH_(3))via sulfation treatment,which cam guide the design and application of PrO_(x)based catalysts for NH_(3)-SCR of NO in the future.

关键词： NH_(3)-SCR Praseodymium oxides Sulfation treatment Surface acidity NH_(3)oxidation Rare earths

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Experimental and theoretical investigation on degradation of dimethyl trisulfide by ultraviolet/peroxymonosulfate: Reaction mechanism and influencing factors

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Journal of Environmental Sciences 2023年第5期127卷 824-832页

作者： Jianing Sun Xiaodong Xin Shaohua Sun Zhenqi Du Zhenxing Yao Mingquan Wang Ruibao Jia Shandong Province Water Supply and Drainage Monitoring Center Jinan 250101China School of Water Conservancy and Environment University of JinanJinan 250022China State Key Laboratory of Pollution Control and Resource Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China

With a large amount of domestic sewage and industrial wastewater discharged into the water bodies,sulfur-containing organicmatter inwastewater produced volatile organic sulfide,such as dimethyl trisulfide(DMTS)throughmicroorganisms,caused the potential danger of drinking water safety and human *** present,there is still a lack of technology on the removal of *** this study,the ultraviolet/peroxymonosulfate(UV/PMS)advanced oxidation processes was used to explore the degradation of *** than 90%of DMTS(30μg/L)was removed under the conditions of the concentration ratio of DMTS to PMS was 3:40,the temperature(T)was 25±2℃,and 10 min of irradiation by a 200 W mercury lamp(365 nm).The kinetics rate constant k of DMTS reacting with hydroxyl radical(HO·)was determined to be 0.2477 min^(−1).Mn^(2+),Cu^(2+)and NO_(3)^(-)promoted the degradation of DMTS,whereas humic acid and Cl-in high concentrations inhibited the degradation *** chromatography-mass spectrometry was used to analyze the degradation products and the degradation intermediates were dimethyl disulfide and *** functional theory was used to predict the possible degradation mechanism according to the frontier orbital theory and the bond breaking mechanism of organic *** results showed that the S–S,C–S and C–H bonds in DMTS molecular structure were prone to fracture in the presence of free radicals,resulting in the formation of alkyl radicals and sulfur-containing radicals,which randomly combined to generate a variety of degradation products.

关键词： Ultraviolet/peroxymonosulfate Dimethyl trisulfide Products Density functional theory Degradation mechanism

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MSWNet:A visual deep machine learning method adopting transfer learning based upon ResNet 50 for municipal solid waste sorting

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Frontiers of Environmental Science & Engineering 2023年第6期17卷 165-176页

作者： Kunsen Lin Youcai Zhao Lina Wang Wenjie Shi Feifei Cui Tao Zhou The State Key Laboratory of Pollution Control and Resource Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention(LAP3) Department of Environmental Science and EngineeringFudan UniversityShanghai 200433China Institute of Eco-Chongming(IEC) Shanghai 202150China Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 610054China

An intelligent and efficient methodology is needed owning to the continuous increase of global municipal solid waste(MSW).This is because the common methods of manual and semi-mechanical screenings not only consume large amount of manpower and material resources but also accelerate virus community *** the categories of MSW are diverse considering their compositions,chemical reactions,and processing procedures,etc.,resulting in low efficiencies in MSW sorting using the traditional *** machine learning can help MSW sorting becoming into a smarter and more efficient *** study for the first time applied MSWNet in MSW sorting,a ResNet-50 with transfer *** method of cyclical learning rate was taken to avoid blind finding,and tests were repeated until accidentally encountering a good *** of visualization were also considered to make the MSWNet model more transparent and *** showed transfer learning enhanced the efficiency of training time(from 741 s to 598.5 s),and improved the accuracy of recognition performance(from 88.50%to 93.50%);MSWNet showed a better performance in MSW classsification in terms of sensitivity(93.50%),precision(93.40%),F1-score(93.40%),accuracy(93.50%)and AUC(92.00%).The findings of this study can be taken as a reference for building the model MSW classification by deep learning,quantifying a suitable learning rate,and changing the data from high dimensions to two dimensions.

关键词： Municipal solid waste sorting Deep residual network Transfer learning Cyclic learning rate Visualization

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MOF-based materials facilitate efficient anaerobic digestion of organic wastes:integrating substrate bioavailability and microbial syntrophism

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Frontiers of Environmental Science & Engineering 2024年第8期18卷 153-157页

作者： Haoyu Liu Ying Xu Xiang Chen Xiankai Wang Hang Wang Xiaohu Dai State Key Laboratory of Pollution Control and Resource Reuse School of Environmental Science and EngineeringTongji UniversityShanghai 200092China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China YANGTZE Eco-Environment Engineering Research Center China Three Gorges CorporationWuhan 430010China National Engineering Research Center of Eco-Environment Protection for Yangtze River Economic Belt Wuhan 430010China

Anaerobic digestion(AD)of organic waste(OW)for methane production is generally *** of AD systems with traditional materials(e.g.,electroconductive materials)is a current focus of research and has been reported to assist methanogenesis by enhancing the productivity of microbial metabolism among syntrophic *** in the AD of organic wastewater,in which microbial cells come into direct contact with the dissolved substrate,in the complex multiphase AD system of OW,low substrate bioavailability is an inevitable obstacle to microbial syntrophism for ***,we propose that improving substrate bioavailability and microbial syntrophism is a powerful strategy for ensuring material-assisted efficient AD of *** on the above considerations,metal-organic frameworks(MOFs),with their exceptionally high porosity,outstanding multi-functionality,and tuneable structures,have excellent potential for application in multiphase anaerobic systems of OW to integrate substrate bioavailability and microbial syntrophism and drive efficient *** addition,MOFs with designable and tuneable natures have great potential for use in identifying suitable materials for anaerobic systems for different types of OW via machine-learning technologies,thereby effectively enhancing methanogenesis from ***,the sustainable application of MOFs in AD and the corresponding environmental risks warrant further investigation.

关键词： Anaerobic digestion Methane production Biodegradability Functional materials Metal-organic frameworks

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The simultaneous removal of methylene blue (MB) and Ca2+ by recyclable adsorbents based the scales derived from coal gasification system

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Environmental Science and pollution Research 2024年第22期31卷 32519-32537页

作者： An, Bai-Hong Xu, Da-Mao Wang, Run-Ting Wen, Ye-Xuan Geng, Rui Wu, Jia-Yun Tang, Xian-Chun Chen, Hong-Bin State Key Laboratory of Pollution Control and Resource Reuse College of Environmental Science and Engineering Tongji University Shanghai200092 China National Engineering Research Center for Urban Pollution Control Tongji University Shanghai200092 China Department of Materials Science Fudan University Shanghai200433 China Sinopec Ningbo Engineering Co. LTD Ningbo315103 China

The transformation of solid wastes from industrial production into effective adsorbents could significantly contribute to wastewater treatment. In this study, after acidizing and burning soft scale (SS) from coal gasification system, two magnetic adsorbents (mag-ASS and mag-BASS) were prepared via the combination of magnetite with ultrasonic, respectively. The treatment effects of mag-ASS and mag-BASS were then investigated for simulated wastewater containing macromolecular organic matter [i.e., methylene blue (MB)] and Ca2+. The results indicated that the pseudo second order kinetic, Elovich, Freundlich, Langmuir and Temkin model could well describe the adsorption behavior of MB and Ca2+ onto mag-ASS and mag-BASS. The maximum adsorption capacities of mag-ASS for MB and mag-BASS for Ca2+ were 600.53 mg/g and 102.54 mg/g, respectively. Surprisingly, the adsorption abilities of mag-ASS for MB and mag-BASS for Ca2+ show significantly higher than the others. The adsorption mechanisms of MB mainly included electrostatic interaction, π-π conjugate interaction and cation exchange, while those of Ca2+ were mainly electrostatic interaction and cation exchange. The diffusion of MB and Ca2+ onto the magnetic adsorbents might be controlled by the combined effects of intraparticle and liquid film diffusion. There was no significant reduction in adsorption capacity after 8 cycles of adsorption and desorption, indicating that SS-based magnetic adsorbents had good recyclability and stability. Moreover, the removal efficiency of mag-BASS for total hardness and total organic carbon in real coal gasification gray water (CGGW) was 82.60 and 64.10%, respectively. The treatment of CGGW and the resource of wastes would significantly promote the reasonable disposal of coal gasification scales. Graphical abstract: (Figure presented.) © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.

关键词： Metal ions

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