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Optimized preparation of Ni-Febm bimetallic particles by ball milling NiSO4 and iron powder for efficient removal of triclosan

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Chemosphere 2024年 360卷 142359页

作者： Zhou, Bingnan Fan, Bo Gong, Zhimin Shao, Shuai Zhou, Dongmei Gao, Shixiang State Key Laboratory of Pollution Control and Resource Reuse School of the Environment Nanjing University Nanjing210023 China

The excessive usage and emissions of triclosan (TCS) pose a serious threat to aquatic environments. Iron-based bimetallic particles (Pd/Fe, Ni/Fe, and Cu/Fe, etc.) were widely used for the degradation of chlorophenol pollutants. This study proposed a novel synthesis method for the preparation of Ni/Fe bimetallic particles (Ni-Febm) by ball milling microscale zero valent iron ZVI (mZVI) and NiSO4. Ball-milling conditions such as ball-milling time, ball-milling speed and ball-to-powder ratio were optimized to prepare high activity Ni-Febm bimetallic particles. During the ball-milling process, Ni2+ was reduced to Ni0 and formed a coupled structure with ZVI. The amount of Ni0 on ZVI significantly affected the activity of Ni-Febm bimetallic particles. The highest activity Ni-Febm bimetallic particles with Ni/Fe ratio of 0.03 were synthesized under optimized conditions, which could remove 86.56% of TCS (10 μM) in aerobic aqueous solution within 60 min. In addition, higher particle dosage, lower pH condition and higher reaction temperature were more conducive for TCS degradation. The higher corrosion current and lower electron transfer impedance of Ni-Febm bimetallic particles were the main reasons for its high activity. The hydrogen atom (•H) on the surface of Ni-Febm bimetallic particles was mainly contributed to the removal of TCS, as reductive transformation products of TCS were detected by LC-TOF-MS. Notably, a small amount of oxidation products were discovered. The total dechlorination rate of TCS was calculated to be 39.67%. After eight reaction cycles, the residual Ni-Febm bimetallic particles could still degrade 28.34% of TCS within 6 h. Low Ni2+ leaching during reaction indicated that Ni-Febm bimetallic particles did not pose potential environmental risks. The prepared environmental-friendly Ni-Febm bimetallic particles with high activity have great potential in the degradation of other chlorinated organic compounds in wastewater. © 2024 Elsevier Ltd

关键词： Sulfur compounds

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Degradation of iopamidol in the permanganate/sulfite process:Evolution of iodine species and effect on the subsequent formation of disinfection by-products

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Journal of environmental Sciences 2024年第1期135卷 345-352页

作者： Yimin Lin Hongyu Dong Yating Zhu Gongming Zhou Junlian Qiao Xiaohong Guan State Key Laboratory of Pollution Control and Resources Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China Department of Environmental Science School of Ecological and Environmental SciencesEast China Normal UniversityShanghai 200241China

Permanganate/sulfite(Mn(VII)/S(IV))process is a promising pre-oxidation technology for sequestering the emerging organic contaminants in drinking water treatment ***(IPM),a representative of iodinated X-ray contrast media,has been widely detected in water sources and has the risk of forming iodinated disinfection byproducts(I-DBPs)in water treatment *** this study,we investigated the evolution of iodine species during the IPM degradation by the Mn(VII)/S(IV)process and its effect on the subsequent formation of I-DBPs during chlorination at pH 7.0 and *** could be effectively degraded in the Mn(VII)/S(IV)process at environmentally relevant pH(pH 7.0 and 8.0).The results of quenching and competitive oxidation kinetic experiments revealed that SO^(·-)_(4)was the major reactive oxidizing species contributing to the degradation of IPM whereas the contributions of HO·and reactive manganese species were negligible in the Mn(VII)/S(IV)process.I–and IO–3were generated while no HOI was detected during the degradation of IPM in the Mn(VII)/S(IV)*** effects of IPM oxidation by Mn(VII)/S(IV)on the subsequent formation of chlorinated disinfection by-products(Cl-DBPs)during chlorination were related to the category of *** pre-oxidation of IPM by Mn(VII)/S(IV)resulted in the generation of I-DBPs during the disinfection process although no I-DBPs were detected if no pre-oxidation was *** finding of this study suggested that attention should be paid to the toxicity of DBPs when water containing iodinated organic contaminants is treated by Mn(VII)/S(IV)process or other pre-oxidation technologies.

关键词： Permanganate/sulfite Iopamidol Sulfate radical Iodinated disinfection byproducts Pre-oxidation

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Improved atmospheric mercury simulation using updated gas-particle partition and organic aerosol concentrations

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Journal of environmental Sciences 2022年第9期34卷 106-118页

作者： Kaiyun Liu Qingru Wu Shuxiao Wang Xing Chang Yi Tang Long Wang Tonghao Liu Lei Zhang Yu Zhao Qin’geng Wang Jinsheng Chen State Key Joint Laboratory of Environment Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing 100084China State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex Beijing 100084China Institute of Atmospheric Environment Guangdong provincial academy of environmental scienceGuangzhou 510045China China National Environmental Monitoring Centre Beijing 100012China State Key Laboratory of Pollution Control and Resource Reuse School of the EnvironmentNanjing UniversityNanjing210023China Center for Excellence in Regional Atmos.Environ. Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China

The gaseous or particulate forms of divalent mercury(HgⅡ) significantly impact the spatial distribution of atmospheric mercury concentration and deposition flux(FLX). In the new nested-grid GEOS-Chem model, we try to modify the HgⅡ gas-particle partitioning relationship with synchronous and hourly observations at four sites in China. Observations of gaseous oxidized Hg(GOM), particulate-bound Hg(PBM), and PM 2.5 were used to derive an empirical gas-particle partitioning coefficient as a function of temperature( T) and organic aerosol(OA) concentrations under different relative humidity(RH). Results showed that with increasing RH, the dominant process of HgⅡ gas-particle partitioning changed from physical adsorption to chemical desorption. And the dominant factor of HgⅡ gas-particle partitioning changed from T to OA concentrations. We thus improved the simulated OA concentration field by introducing intermediate-volatility and semi-volatile organic compounds(I/SVOCs) emission inventory into the model framework and refining the volatile distributions of I/SVOCs according to new filed tests in the recent literatures. Finally, normalized mean biases(NMBs) of monthly gaseous element mercury(GEM), GOM, PBM, WFLX were reduced from-33%–29%, 95%–300%, 64%–261%, 117%–122% to-13%–0%,-20%–80%,-31%–50%,-17%–23%. The improved model explains 69%–98% of the observed atmospheric Hg decrease during 2013–2020 and can serve as a useful tool to evaluate the effectiveness of the Minamata Convention on Mercury.

关键词： Nested GEOS-Chem model HgⅡgas-particle partitioning Organic aerosol Atmospheric mercury Mercury deposition flux

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Mechanisms of allicin exposure for the sludge fermentation enhancement:Focusing on the fermentation processes and microbial metabolic traits

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Journal of environmental Sciences 2022年第5期34卷 253-264页

作者： Feng Wang Jingyang Luo Shiyu Fang Wenxuan Huang Yunqi Zhang Le Zhang Xiaoshi Cheng Wei Du Fang Fang Jiashun Cao Yang Wu Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes Ministry of EducationHohai UniversityNanjing 210098China College of Environment Hohai UniversityNanjing 210098China State Key Laboratory of Pollution Control and Resource Reuse School of Environmental Science and EngineeringTongji UniversityShanghai 200092China

As a frequently used product with antimicrobial activity,consumed allicin might be dis-charged and concentrated in waste-activated sludge(WAS).However,the influence of al-licin(as an exogenous pollutant)on WAS fermentation has not been clearly *** study aimed to disclose the impacts of allicin on volatile fatty acid(VFA)generation dur-ing WAS *** results showed that the appropriate presence of allicin(10 mg/g TSS)significantly enhanced the VFA yield(1894 versus 575 mg COD/L in the control)with increased acetate proportion(24.3%).Further exploration found that allicin promoted WAS solubilization,hydrolysis and acidification *** analysis revealed that the key genes involved in extracellular hydrolysis metabolism(i.e.,CAZymes),mem-brane transport(i.e.,gtsA and ytfT),substrate metabolism(i.e.,yhdR and pfkC)and fatty acid synthesis(i.e.,accA and accD)were all highly *** also induced the bacteria to produce more signalling molecules and regulate cellular functions,thereby enhancing the microbial adaptive and regulatory capacity to the unfavourable ***,the variations in fermentative microbes and their contributions to the upregulation of func-tional genes(i.e.,ytfR,gltL,INV,iolD and pflD)for VFA generation were ***,the simultaneous stimulation of functional microbial abundances and metabolic activities contributed to VFA production in allicin-conditioned reactors.

关键词： Allicin Waste activated sludge(WAS) Anaerobic fermentation Metagenomic analysis Functional genes

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Organic peroxyl radicals from biacetyl accelerated the visible-light degradation of steroid estrogens in aqueous solution

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Chemosphere 2024年 351卷 141195页

作者： Jia, Yulu Zhang, Chengyang Zheng, Hongcen Zhang, Guoyang Zhang, Shujuan State Key Laboratory of Pollution Control and Resource Reuse School of Environment Nanjing University Nanjing210023 China

Indirect photodegradation is an important pathway for the reduction of steroid estrogens in sunlit surface waters. Nevertheless, the kinetics and mechanisms governing the interaction between coexisting carbonyl compounds and estrogens under visible light (Vis) remain unexplored. This study systematically investigates the Vis-induced photodegradation of 17β-estradiol (E2) in the presence of five specific carbonyl compounds—biacetyl (BD), acetone, glyoxal, pyruvic acid, and benzoquinone. The results demonstrate that, among these compounds, only BD significantly enhanced the photodegradation of E2 under Vis irradiation (λ > 400 nm). The pseudo-first order photodegradation rate constants (k1) of E2 in the Vis/BD system were 0.025 min−1 and 0.076 min−1 in ultrapure water and river water, respectively. The enhancing effect of BD was found to be pH-dependent, increasing the pH from 3.0 to 11.0 resulted in a 76% reduction in the k1 value of E2 in the Vis/BD system. Furthermore, the presence of humic acid, NO3−, or HCO3− led to an increase of more than 35% in the k1 value of E2, while NO2− exerted a pronounced inhibitory effect, resulting in a 92% decrease. Peroxyacetyl and peroxymethyl radicals, derived from BD in a yield ratio of 9, played a crucial role in the degradation of E2. These peroxyl radicals primarily targeted electron-rich hydroxyl sites of E2, initiating hydroxylation and ring-opening reactions that culminated in the formation of acidic byproducts. Notably, toxicity evaluation indicates that these hydroxylated and acidic products exhibited lower toxicity than the parent compound E2. This study highlights the important role of peroxyl radicals in estrogen degradation within aquatic environment, and also helps to design efficient visible light-responsive photo-activators for the treatment of estrogen-contaminated waters. © 2024 Elsevier Ltd

关键词： Photolysis

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Altitude-dependent gaseous emissions from freight trucks along the China-Pakistan Economic Corridor in Pakistan

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environmental Science and Ecotechnology 2023年第2期14卷 72-78页

作者： Asad Ali Shaikh Tingkun He Fanyuan Deng Zhenyu Luo Junchao Zhao Zhining Zhang Huan Liu State Key Joint Laboratory of ESPC State Environmental Protection Key Laboratory of Sources and Control of Air Pollution ComplexSchool of EnvironmentTsinghua UniversityBeijing100084China

Recent increases in emissions from freight transport have caused strong concerns about air quality in Pakistan,following the rapid development of projects related to the China-Pakistan Economic Corridor(CPEC).This study reported the first measurements of on-road truck emissions in Pakistan and investigated their dependence on altitude along CPEC *** from 70 trucks were measured on CPEC highways located in Islamabad(540 m above sea level),Sost(2800 m above sea level),and at the Khunjerab Pass(4693 m above sea level).Calculated emission factors for carbon monoxide,hydrocarbons,and nitrogen oxides from heavy-duty trucks in Islamabad were 12.94±1.46,15.21±1.67,and 10.69±1.34 g km^(-1)(95%confidence level),respectively,for pre-Pak-II trucks,and 12.75±2.80,14.24±3.53,and 10.24±2.34 g km^(-1)(95%confidence level),respectively,for Pak-II trucks,representing 2e20 times higher values than the emission standards in Pakistan and *** altitude increase of approximately 4000 m,with the associated changes in meteorology and fleet characteristics,induced an average increase of 103.6%,86.3%,124.5%,and 133.6%in the emission factors of carbon monoxide,hydrocarbons,nitrogen oxides,and carbon dioxide,***,on-road emissions along the CPEC were mainly influenced by truck *** study will support the budget evaluation of transport emissions from the CPEC trade fleet.

关键词： Truck emissions High altitude China-Pakistan Economic corridor Emission factors

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ZnS-embedded porous carbon for peroxydisulfate activation:Enhanced electron transfer for bisphenol A degradation

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environmental Science and Ecotechnology 2024年第3期19卷 161-169页

作者： Ying Liu Ningjie Du Xinru Liu Ducheng Yao Deli Wu Zhuo Li Shun Mao College of Environmental Science and Engineering Biomedical Multidisciplinary Innovation Research InstituteShanghai East HospitalState Key Laboratory of Pollution Control and Resource ReuseTongji University1239 Siping RoadShanghai200092China Shanghai Institute of Pollution Control and Ecological Security Shanghai200092China

Transition metal sulfides have garnered increasing attention for their role in persulfate activation,a crucial process in environmental ***,the function of metal sulfides without reversible valence changes,such as ZnS,remains largely unexplored in this *** we report ZnS-embedded porous carbon(ZnS-C),synthesized through the pyrolysis of Zn-MOF-74 and dibenzyl ***-C demonstrates remarkable activity in activating peroxydisulfate(PDS)across a wide pH range,enabling the efficient mineralization removal of bisphenol A(BPA).Through electrochemical investigation and theoretical simulations of charge density distributions,we unveil that the electron transfer from BPA to PDS mediated by the ZnS-C catalyst governs the *** study,both in theory and experiment,demonstrates metal sulfide as electron pump that enhances electron transfer efficiency in PDS *** findings redefine the role of metal sulfide catalysts,shedding new light on their potential for regulating reaction pathways in PDS activation processes.

关键词： Peroxydisulfate activation Reaction pathway regulation Electron transfer ZnS Bisphenol A

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Electronic regulation to achieve efficient anaerobic digestion of organic fraction of municipal solid waste(OFMSW):strategies,challenges and potential solutions

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Frontiers of environmental Science & Engineering 2024年第4期18卷 159-165页

作者： Yongdong Chen Hong Wang Parisa Ghofrani-Isfahani Li Gu Xiaoguang Liu Xiaohu Dai State Key Laboratory of Pollution Control and Resources Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China Shanghai Institute of Pollution Control and Ecological Security Tongji UniversityShanghai 200092China Department of Chemical and Biochemical Engineering Technical University of DenmarkKgs Lyngby DK-2800Denmark College of Environment and Ecology Chongqing UniversityChongqing 400045China

Anaerobic digestion(AD)of organic fraction of municipal solid waste(OFMSW)is prone to system breakdown under high organic loading rates(OLRs)condition,which subsequently reduces the efficiency of digestion process and results in substantial economic *** this perspective paper,the substances metabolisms,electrons flow,as well as microbial interaction mechanisms within AD process are comprehensively discussed,and the underlying bottleneck that causes inefficient methane production is identified,which is“electrons surplus”.Systems encountering severe electron surplus are at risk of process failure,making it crucial to proactively prevent this phenomenon through appropriate *** this basis,the present perspective proposes three potential electronic regulation strategies to prevent electrons surplus,namely,electron shunt,accelerating electron transfer and regulating methanogenic metabolism pathway,and presents specific methodologies for each ***,the potential solutions to challenges that may occur during the electronic regulation process are also presented in this *** perspective aims to provide innovative approaches to achieve the efficient and stable operation of OFMSW anaerobic digestion,especially under high OLRs condition.

关键词： Anaerobic digestion Electrons surplus Electronic regulation Electrons shunt Electron transfer Methanogenic metabolism pathway

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In-situ synthesis of layered double hydroxides with tunable basal spacing for efficient iodide over iodate adsorption selectivity

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Science China Chemistry 2025年第6期 2424-2432页

作者： Xiaolu Liu Muliang Xiao Pei Chen Yilun Zhou Yinghui Xie Mengjie Hao Liang Mao Hui Yang Geoffrey I.N.Waterhouse Shengqian Ma Xiangke Wang College of Environmental Science and Engineering North China Electric Power University State Key Laboratory of Pollution Control and Resource Reuse School of the Environment Nanjing University School of Chemical Sciences the University of Auckland Department of Chemistry University of North Texas

Separating I3-and IO3-from aqueous solutions is technically challenging due to their very similar charge density. Herein, we describe the in-situ synthesis of cobalt-based layered double hydroxides（Co-LDHs） by decomposition of zeolite imidazole framework（ZIF） nanocrystals, whilst modulating the basal spacing in the Co-LDHs through anion intercalation（such as Br-,NO3-, and Cl O4-）. Co-LDH-NO3-possesses an optimal basal spacing of ～4.69 ?, which is slightly smaller than the van der Waals diameter of IO3-（～4.79 ?）, thus enabling selective adsorption of linear I3-（diameter ～4.22 ?） via ion exchange in the LDH interlayer. Co-LDH-NO3-showed ultrafast I3-uptake kinetics involving strong “host-guest” interaction forces, achieving high dynamic uptake capacities of 119.94 and 127.18 mg/g in I3-/IO3-contaminated groundwater and tap water, respectively, and～100% separation efficiencies towards I3-over IO3-. Co-LDH-Br-with a smaller basal spacing（4.06 ?） exhibited much slower separation kinetics, and Co-LDH-ClO4-with a ～5.36 ? basal spacing demonstrated poor separation efficiency under similar conditions. Ab initio molecular dynamics（AIMD） simulations were used to visually simulate the ion exchange process, with the results being consistent with the experimental observations. Furthermore, Co-LDH-NO3-demonstrated excellent reusability during dynamic breakthrough tests and I3-/IO3-separation cycles due to a “special memory effect” of the 2D interlayer. This work guides adsorbent design for the efficient removal and separation of iodine species from contaminated water.

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Consuming probiotics protects against cadmium exposure from rice consumption while promotes gut health: An assessment based on a mouse model

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Science of the Total environment 2025年 958卷 177997页

作者： Xi, Jin-Feng Zhou, Lei Zhang, Yao-Sheng Lin, Xin-Ying Chen, Shan Xue, Rong-Yue Zhou, Dongmei Li, Hong-Bo State Key Laboratory of Pollution Control and Resource Reuse Jiangsu Key Laboratory of Vehicle Emissions Control School of Environment Nanjing University Nanjing210023 China

Cadmium (Cd) in rice constitutes a global health risk. It is crucial to develop strategies that not only reduce the bioavailability of Cd in rice but also confer additional health benefits. One potential approach involves the consumption of probiotics, which can bind Cd in the intestines and enhance gut health. The effects of consuming Akkermansia muciniphila, Bifidobacterium pseudolongum, and Psychrobacter sp. on the bioavailability of Cd in rice and gut health were evaluated using in vivo mouse bioassays and in vitro Cd immobilization assays. In mice fed Cd-contaminated rice without dietary calcium (Ca) and iron (Fe) supplementation (i.e., under conditions of mineral deficiency), the intake of these probiotics insignificantly reduced Cd accumulation in the kidneys and livers, although it did promote Cd excretion via feces. This outcome was primarily due to the competition for Ca and Fe between the probiotics and the host, which led to increased intestinal expression of Ca and Fe transporters under mineral-deficient conditions, thereby mitigating the probiotics' ability to reduce Cd bioavailability. Conversely, in mice fed Cd-contaminated rice with adequate dietary Ca and Fe (i.e., under conditions of mineral adequacy), probiotic intake significantly decreased Cd concentrations in the kidneys by 60.0 %–72.0 % compared to the control group exposed to Cd. Additionally, probiotic consumption fostered the growth of beneficial gut bacteria and strengthened intestinal tight junctions, reducing the inflammatory response in the intestines. These findings suggest that combining probiotics with sufficient Ca and Fe intake can effectively reduce dietary Cd exposure and enhance gut health. © 2024 Elsevier B.V.

关键词： Macroinvertebrates

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