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A Novel Self-Sourced Extracellular Polymeric Substances-Doped Residual Sludge-Based Biochar Loaded with Nano Zero-Valent Iron Reinforces Anaerobic Digestion Methanogenesis: Performance and Community Structure Succession

SSRN

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SSRN 2024年

作者： Li, Jibin Wu, Siqi Zhang, Weiming Pan, Bingcai Hua, Ming State Key Laboratory of Pollution Control and Resource Reuse School of Environment Nanjing University Nanjing210023 China

Anaerobic digestion is an effective wastewater energization technology, but suffers from low energy conversion efficiency. In this study, a novel composite of extracellular polymeric substances-doped residual sludge-based biochar loaded with nano zero-valent iron (NZVI@EPSBC) was successfully prepared, which had a significant promotion effect on anaerobic digestion methanogenesis. In comparison to the control, the methane yield with 100 mg/L NZVI@EPSBC was raised by approximately 1.4-fold. The NZVI@EPSBC did not significantly change the morphology of the inoculated granular sludge, but induced the secretion of proteins and humic substances in the extracellular EPS, which are beneficial for carbon conversion and extracellular electron transport at the microscopic scale. Meanwhile, the quantitative analysis of the electron transport system also confirmed that NZVI@EPSBC could significantly improve the electron transfer efficiency in microbial respiratory chain throughout the experimental cycle, in which the highest respiratory efficiency increase of 26.51% at 48 h. Taxonomic analysis of microbial communities showed that NZVI@EPSBC exhibited complete retention of bacteria and archaea compared to the raw sludge, while realizing an efficient cooperative pattern of syntrophic bacteria by regulating the relative abundance of specific functional bacteria, like Anaerolineaceae and Methanosaeta. Overall, the study offers a valuable strategy for achieving resourcefulness of residual sludge and extracellular polymeric substances along with facilitating efficient energy recovery from wastewater. © 2024, The Authors. All rights reserved.

关键词： Anaerobic digestion

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Tuning the primary selective nanochannels of MOF thin-film nanocomposite nanofiltration membranes for efficient removal of hydrophobic endocrine disrupting compounds

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Frontiers of environmental Science & Engineering 2022年第4期16卷 1-13页

作者： Ruobin Dai Hongyi Han Yuting Zhu Xi Wang Zhiwei Wang State Key Laboratory of Pollution Control and Resource Reuse Shanghai Institute of Pollution Control and Ecological SecuritySchool of Environmental Science and EngineeringTongji UniversityShanghai 200092China Tongji Architectural Design(Group)Co. Ltd.Environmental Engineering BranchShanghai 200092China

Metal organic framework(MOF)incorporated thin-film nanocomposite(TFN)membranes have the potential to enhance the removal of endocrine disrupting compounds(EDCs).In MOF-TFN membranes,water transport nanochannels include(i)pores of polyamide layer,(ii)pores in MOFs and(iii)channels around MOFs(polyamide-MOF interface).However,information on how to tune the nanochannels to enhance EDCs rejection is scarce,impeding the refinement of TFN membranes toward efficient removal of *** this study,by changing the polyamide properties,the water transport nanochannels could be confined primarily in pores of MOFs when the polyamide layer became ***,the improved rejection of EDCs was dependent on the water transport channels of the TFN *** low monomer concentration(i.e.,loose polyamide structure),the hydrophilic nanochannels of MIL-101(Cr)in the polyamide layer could not dominate the membrane separation performance,and hence the extent of improvement in EDCs rejection was relatively *** contrast,at high monomer concentration(i.e.,dense polyamide structure),the hydrophilic nanochannels of MIL-101(Cr)were responsible for the selective removal of hydrophobic EDCs,demonstrating that the manipulation of water transport nanochannels in the TFN membrane could successfully overcome the permeability and EDCs rejection *** results highlight the potential of tuning primary selective nanochannels of MOF-TFN membranes for the efficient removal of EDCs.

关键词： Porous metal organic framework Thin-film nanocomposite membrane Primary selective nanochannels Nanofiltration Endocrine disrupting compounds

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Making waste profitable: Efficient recovery of metallic iron from jarosite residues

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Chinese Journal of Chemical Engineering 2024年第7期71卷 66-76页

作者： Songshan Zhou Yunhui Han Rong Huang Yin Huang Qingyuan Dong Haiyin Gang Jinchuan Qin Xi Yu Xiangfei Zeng Wenxing Cao Jiqin Wang Shaoqin Chen Rong Wang Mengjun Chen Key Laboratory of Solid Waste Treatment and Resource Recycle(SWUST) Ministry of EducationSouthwest University of Science and TechnologyMianyang 621010China School of Environment Key Laboratory of Yellow River and Huai River Water Environment and Pollution ControlMinistry of EducationHenan Normal UniversityXinxiang 453007China School of National Defense Science and Technology College SWUST Ministry of EducationSouthwest University of Science and TechnologyMianyang 621010China

To address the hazardous by-product of zinc smelting and resource utilization of jarosite residue,this study applies an electric field-assisted hot acid treatment to completely recycle iron(Fe).This innovative approach aims to enhance the leaching efficiency of Fe from jarosite *** introduction of an electric field changes the charge distribution on the surface of the particles to enhance ions and electrons exchange and promotes the collision between particles to strengthen reaction *** on the above,the leaching efficiency of Fe in jarosite under sulfuric acid attack has improved *** result shows that Fe leaching efficiency reaches 98.83%,which is increased by 28%under the optimal experimental conditions:current density of 30 mA·cm^(-2),H_(2)SO_(4) concentration of 1.5 mol·L^(-1),solid-liquid ratio of 70 g·L^(-1),temperature of 80℃ and time of 12 *** kinetics calculations show that the apparent activation energy is 16.97 kJ·mol^(-1) and the leaching of jarosite residue is controlled by a mixture of chemical reaction and diffusion,as well as the temperature and concentration of the leaching solution have an influence on *** work provides a feasible idea for the efficient leaching of Fe from jarosite residue.

关键词： Jarosite residue Electric filed Leaching kinetics

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Enhanced removal of phosphonates from aqueous solution using PMS/UV/hydrated zirconium oxide process

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Chinese Chemical Letters 2023年第4期34卷 384-389页

作者： Shunlong Pan Xi Nie Xinrui Guo Hao Hu Biming Liu Yongjun Zhang School of Environmental Science and Engineering Nanjing Tech UniversityNanjing 210009China College of Environment Hohai UniversityNanjing 210098China State Key Joint Laboratory of Environment Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing 100084China

Traditional treatment processes cannot completely remove phosphonates in circulating cooling water by one-step method. Herein, we designed peroxymonosulfate/UV irradiation/hydrated zirconium oxide(PMS/UV/HZO) coupling process to enhance the phosphonates removal. In particular, nitrilotrismethylenephosphonic acid(NTMP) removal efficiency by PMS/UV/HZO process was much higher than that of PMS/UV process, UV/HZO process and other processes in comparison experiments. Specifically,almost 97.2% NTMP in water was degraded, and the total phosphorous(TP) reduced from 9.3 mg/L to 0.26 mg/L at pH 7 within 180 min. TP removal efficiency still reached above 90% after 5 cycles adsorptiondesorption of HZO. Moreover, Cl^(-), NO_(3)-and SO_(4)^(2-)ions all had negligible effect on NTMP removal. During the process, NTMP was first destroyed to form phosphates and other intermediates by the reactive oxygen species(ROS), then phosphates were in situ immobilized via HZO adsorption. Sulfate radical(SO_(4)^(·-))has been confirmed to be the major ROS in the reaction system by quenching experiment and electron paramagnetic resonance(EPR) characterization. And the excellent selective adsorption capacity of HZO for phosphate produced was attributed to the strong inner-sphere coordination between H_(2)PO_(4)-/HPO_(4)^(2-)and Zr-OH on the surface of HZO. These results suggest that PMS/UV/HZO process is a promising technique for enhanced phosphonates decontamination.

关键词： Phosphonates Peroxymonosulfate UV ROS Adsorption

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The regulating strategy of hierarchical structure and acidity in zeolites and application of gas adsorption: A review

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Chinese Chemical Letters 2024年第11期35卷 214-225页

作者： Jie Ma Jianxiang Wang Jianhua Yuan Xiao Liu Yun Yang Fei Yu Research Center for Environmental Functional Materials State Key Laboratory of Pollution Control and Resource ReuseCollege of Environmental Science and EngineeringTongji UniversityShanghai 200092China School of Civil Engineering Kashi UniversityKashi 844000China Shanghai Baoye Engineering Technology Ltd. Shanghai 200941China College of Marine Ecology and Environment Shanghai Ocean UniversityShanghai 201306China

Gas adsorption remains an attractive area of *** hierarchical structure can reduce diffusion limitations and facilitate molecular transport,while acid sites can be used as adsorption *** make zeolites widely used in the field of gas *** to obtain zeolite adsorbents with better adsorption properties by modulating the hierarchical structure and acid sites is a pressing issue *** review highlights the strategies to modulate the hierarchical structure as well as the acid sites;and then explains how these strategies are *** mechanism of zeolite adsorption on gases is then described in terms of these two ***,the adsorption properties of zeolites for certain gases under specific conditions are *** outlook of zeolite hierarchical structures and acid site modulation strategies is given.

关键词： Zeolite Regulation strategy Hierarchical structure Acid sites Gas adsorption

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Degradation of odorous 2,4,6-trichloroanisole in chlorinated water by UV-LED/chlorination: kinetics and influence factors

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environmental Science and pollution Research 2023年第15期30卷 44325-44336页

作者： Zhang, Yun-Lu Lin, Yi-Li Zhang, Tian-Yang Lu, Yong-Shan Zhou, Xiao-Yang Liu, Zhi Zheng, Zheng-Xiong Xu, Meng-Yuan Xu, Bin State Key Laboratory of Pollution Control and Resource Reuse Key Laboratory of Yangtze Water Environment Ministry of Education College of Environmental Science and Engineering Tongji University Shanghai200092 China Shanghai Institute of Pollution Control and Ecological Security Shanghai200092 China Department of Safety Health and Environmental Engineering National Kaohsiung University of Science and Technology Kaohsiung824 Taiwan

2,4,6-Trichloroanisole (2,4,6-TCA) has aroused a special concern for their odor problem and potential threats. In this study, the degradation of 2,4,6-TCA by UV/chlorination with different UV sources was compared, including low-pressure mercury lamp (LPUV, 254 nm) and ultraviolet light-emitting diode (UV-LED, 275 and 285 nm). The maximum removal of 2,4,6-TCA can be achieved by 275-nm UV-LED/chlorination in neutral and alkaline conditions which was 80.0%. The reaction, kinetics, and water matrix parameters on 2,4,6-TCA degradation were also evaluated. During UV-LED (275 nm)/chlorination, 2,4,6-TCA degradation was mainly caused by direct UV photolysis and indirect hydroxyl radical (HO·) oxidation, while reactive chlorine radicals (RCSs) had a negligible contribution. The second-order rate constant between HO· and 2,4,6-TCA was determined as 3.1 × 109 M−1 s−1. Increasing initial chlorine dosage and decreasing 2,4,6-TCA concentration or pH value significantly promoted 2,4,6-TCA degradation during UV/chlorination process. The presence of natural organic matter (NOM) and bicarbonate (HCO3−) can inhibit 2,4,6-TCA degradation, while chloride ion (Cl−) had a negligible effect. The kinetic model for 2,4,6-TCA degradation was established and validated, and the degradation pathways were proposed based on the identified intermediates. Furthermore, UV-LED (275 nm)/chlorination also exhibited a promising effect on 2,4,6-TCA removal in real water, which can be used to control 2,4,6-TCA pollution and odor problems. © 2023, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.

关键词： Alkalinity

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Nitrogen-enriched micro-mesoporous carbon derived from polymers organic frameworks for high-performance capacitive deionization

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Journal of environmental Sciences 2022年第1期34卷 282-291页

作者： Jianpei Zhang Xun-an Ning Danping Li Yi Wang Xiaojun Lai Weixuan Ou Guangzhou Key Laboratory of Environmental Catalysis and Pollution Control School of Environment Science and EngineeringInstitute of Environmental Health and Pollution ControlGuangdong University of TechnologyGuangzhou 510006China School of Land Resources and Environment Key Laboratory of Agricultural Resource and Ecology in the Poyang Lake Basin of Jiangxi ProvinceJiangxi Agricultural UniversityNanchang 330045China

Nitrogenization is an effective method for improving the capacitive deionization(CDI)performance of porous carbon *** particular,polymer organic frameworks with heteroatom doping,containing an ordered pore structure and excellent electrochemical stability,are ideal precursors for carbon materials for high-performance *** this study,a nitrogen-enriched micro-mesoporous carbon(NMC)electrode was fabricated by carbonizing a Schiff base network-1 at 500,600,and 700℃.Scanning electron microscopy,Fourier transform infrared spectroscopy,X-ray diffraction,N_(2) adsorption-desorption,the contact angle of water,cyclic voltammetry,and electrochemical impedance spectroscopy were used to characterize the morphological structure,wettability,Brunauer–Emmett–Teller surface areas,and electrochemical performance of the *** results showed that the NMC carbonized at 600℃ achieved the best specific capacitance(152.33 F/g),as well as a high electrosorption capacity(25.53 mg/g)because of its chemical composition(15.57%N)and surface area(312 m^(2)/g).These findings prove that NMC is viable as an electrode material for desalination by high-performance CDI applications.

关键词： Polymers organic frameworks Nitrogen-doped carbon Micro-mesoporous Carbon Capacitive deionization

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Mercury records from natural archives reveal ecosystem responses to changing atmospheric deposition

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National Science Review 2024年第12期11卷 213-225页

作者： Qinqin Chen Qingru Wu Yuying Cui Shuxiao Wang School of Environment Tsinghua University State Key Joint Laboratory of Environmental Simulation and Pollution Control State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex

Global ecosystems face mercury contamination, yet long-term data are scarce, hindering understanding of ecosystem responses to atmospheric Hg input changes. To bridge the data gap and assess ecosystem responses, we compiled and compared a mercury accumulation database from peat, lake, ice and marine deposits worldwide with atmospheric mercury deposition modelled by GEOS-Chem, focusing on trends,magnitudes, spatial–temporal distributions and impact factors. The mercury fluxes in all four deposits showed a 5-to 9-fold increase over 1700–2012, with lake and peat mercury fluxes that generally mirrored atmospheric deposition trends. Significant decreases in lake and peat mercury fluxes post-1950 in Europe evidenced effective environmental policies, whereas rises in East Asia, Africa and Oceania highlighted coal-use impacts, inter alia. Conversely, mercury fluxes in marine and high-altitude ecosystems did not align well with atmospheric deposition, emphasizing natural influences over anthropogenic impacts. Our study underscores the importance of these key regions and ecosystems for future mercury management.

关键词： mercury pollution natural archive GEOS-Chem ecosystem recovery policy evaluation

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A critical review on quantitative evaluation of aqueous toxicity in water quality assessment

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Chemosphere 2023年 342卷 140159页

作者： Zhang, Linyu Zhang, Yu Zhu, Mengyuan Chen, Ling Wu, Bing State Key Laboratory of Pollution Control and Resource Reuse School of Environment Nanjing University Nanjing210023 China

Conventional chemical techniques have inherent limitations in detecting unknown chemical substances in water. As a result, effect-based methods have emerged as a viable alternative to overcome these limitations. These methods provide more accurate and intuitive evaluations of the toxic effects of water. While numerous studies have been conducted, only a few have been applied to national water quality monitoring. Therefore, it is crucial to develop toxicity evaluation methods and establish thresholds based on quantifying toxicity. This article provides an overview of the development and application of bioanalytical tools, including in vitro and in vivo bioassays. The available methods for quantifying toxicity are then summarized. These methods include aquatic life criteria for assessing the toxicity of a single compound, comprehensive wastewater toxicity testing for all contaminants in a water sample (toxicity units, whole effluent toxicity, the potential ecotoxic effects probe, the potential toxicology method, and the lowest ineffective dilution), methods based on mechanisms and relative toxicity ratios for substances with the same mode of action (the toxicity equivalency factors, toxic equivalents, bioanalytical equivalents), and effect-based trigger values for micropollutants. The article also highlights the advantages and disadvantages of each method. Finally, it proposes potential areas for applying toxicity quantification methods and offers insights into future research directions. This review emphasizes the significance of enhancing the evaluation methods for assessing aqueous toxicity in water quality assessment. © 2023 Elsevier Ltd

关键词： Water quality

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Inhibition effect of magnetic field on nitrous oxide emission from sequencing batch reactor treating domestic wastewater at low temperature

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Journal of environmental Sciences 2020年第1期32卷 205-212页

作者： Dan Xu Hongmin Ji Hongqiang Ren Jinju Geng Kan Li Ke Xu State Key Laboratory of Pollution Control and Resource Reuse School of the EnvironmentNanjing University

This study aims to investigate the effect of a magnetic field on nitrous oxide(N2O)emission from a sequencing batch reactor treating low-strength domestic wastewater at low temperature(10℃).After running for 124 days in parallel,results indicated that the conversion rate of N2O for a magnetic field-sequencing batch reactor(MF-SBR)decreased by34.3%compared to that of a conventional SBR(C-SBR).Meanwhile,the removal efficiencies for total nitrogen(TN)and ammonia nitrogen(NH4-N)of the MF-SBR were 22.4%and 39.5%higher than those of the ***-throughput sequencing revealed that the abundances of AOB(Nitrosomonas),NOB(Nitrospira)and denitrifiers(Zoogloea),which could reduce N2O to N2,were promoted significantly in the *** activities(Nir)and gene abundances(nos Z nir S and nir K)for denitrification in the MF-SBR were also notably higher compared to *** study shows that application of a magnetic field is a useful approach for inhibiting the generation of N2O and promoting the nitrogen removal efficiency by affecting the microbial characteristics of sludge in an SBR treating domestic wastewater at low temperature.

关键词： Magnetic field Low temperature N2O emission Biological nitrogen removal High-throughput 16S rRNA gene sequencing

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