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Long-Term and Multi-Scale Assessment of Enhancing Mechanisms of Methanogenesis in Magnetite Nanoparticle-Mediated Anaerobic Digestion: From Digester Performance, Biochemical Parameters to Microbial Communities

SSRN

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SSRN 2024年

作者： Li, Jibin Sun, Desheng Wu, Siqi Yang, Wenlan Xiong, Lei Zhang, Weiming Hua, Ming Pan, Bingcai State Key Laboratory of Pollution Control and Resource Reuse School of the Environment Nanjing University Nanjing210023 China School of the Environmental Science and Engineering Yangzhou University Yangzhou225000 China

Magnetite nanoparticles (Fe3O4-NPs) have been demonstrated to be involved in direct interspecies electron transfer between syntrophic bacteria, yet a comprehensive assessment of the ability of Fe3O4-NPs to cope with process instability and volatile fatty acids (VFAs) accumulation in scaled-up anaerobic reactors is still lacking. Here, we investigated the start-up characteristics of an expanded granular sludge bed (EGSB) with Fe3O4-NPs as an adjuvant at high organic loading rate (OLR). The results showed that methane production rate of R1 (with Fe3O4-NPs) was approximately 1.65 folds of R0 (control), and effluent COD removal efficiency was maintained at approximately 98.32% upon 20 kg COD/(m3·d) OLR. The components of volatile fatty acids are acetate and propionate, and the rapid scavenging of propionate accumulation was the difference between R1 and the control. The INT-ETS activity of R1 was consistently higher than that of R0 and R2, and the electron transfer efficiencies increased by 68.78% and 131.44%, respectively. Meanwhile, the CV curve analysis showed that the current of R1 was 40% higher than R3 (temporary addition of Fe3O4-NPs ), indicating that multiple electron transfer modes might coexist. High-throughput analysis further revealed that it was difficult to reverse the progressive deterioration of system performance with increasing OLR by simply reconfiguring bacterial community structure and abundance, demonstrating that the Fe3O4-NPs-mediated DIET pathway is a prerequisite for establishing multiple electron transfer systems. This study provides a long-term and multi-scale assessment of the gaining effect of Fe3O4-NPs in anaerobic digestion scale-up devices, and provides technical support for their practical engineering applications. © 2024, The Authors. All rights reserved.

关键词： Magnetite

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Mechanistic investigation on Ag-Cu_(2)O in electrocatalytic CO_(2) to CH_(4) by in situ/operando spectroscopic and theoretical analysis

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Journal of Energy Chemistry 2024年第1期88卷 521-531,I0012页

作者： Min Sun Luxiao Zhang Fuli Tian Jiaxin Li Yanqiu Lei Heng Zhang Lifeng Han Zhihua Guo Yonghui Gao Fenrong Liu Yan Wang Luhui Wang Shanghong Zeng School of Chemistry and Chemical Engineering Inner Mongolia UniversityHohhot 010021Inner MongoliaChina Key Laboratory of Medicinal and Edible Plants Resources of Hainan Province Hainan Vocational University of Science and TechnologyHaikou 571126HainanChina State Key Laboratory of Baiyunobo Rare Earth Resource Research and Comprehensive Utilization Baotou Research Institute of Rare EarthsBaotou 014030Inner MongoliaChina Zhejiang Key Laboratory of Petrochemical Environmental Pollution Control Zhejiang Ocean UniversityZhoushan 316022ZhejiangChina

Silver-copper electrocatalysts have demonstrated effectively catalytic performance in electroreduction CO_(2) toward CH_(4),yet a revealing insight into the reaction pathway and mechanism has remained ***,we construct chemically bonded Ag-Cu_(2)O boundaries,in which the complete reduction of Cu_(2)O to Cu has been strongly impeded owing to the presence of surface Ag *** interfacial confinement effect helps to maintain Cu^(+)sites at the Ag-Cu_(2)O *** in situ/operando spectroscopy and theoretical simulations,it is revealed that CO_(2) is enriched at the Ag-Cu_(2)O boundaries due to the enhanced physisorption and chemisorption to CO_(2),activating CO_(2) to form the stable intermediate^(*)*** boundaries between Ag shell and the Cu_(2)O mediate local^(*)CO coverage and promote^(*)CHO intermediate formation,consequently facilitating CO_(2)-to-CH_(4) *** work not only reveals the structure-activity relationships but also offers insights into the reaction mechanism on Ag-Cu catalysts for efficient electrocatalytic CO_(2) reduction.

关键词： Ag shell Interfacial confinement effect Cu~+ Local*CO coverage CO_(2)reduction

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Improving Fugitive Dust Emission Inventory from Construction Sector Using UAV Images Recognition

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Aerosol and Air Quality Research 2024年第8期24卷 1-18页

作者： He, Yuyao Jang, Jicheng Zhu, Yun Chiang, Pen-Chi Xing, Jia Wang, Shuxiao Zhao, Bin Long, Shicheng Yuan, Yingzhi Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control College of Environment and Energy South China University of Technology Guangzhou Higher Education Mega Center Guangzhou510006 China Graduate Institute of Environmental Engineering Taiwan University Taipei10673 Taiwan Carbon Cycle Research Center National Taiwan University Taipei10672 Taiwan Department of Civil and Environmental Engineering University of Tennessee KnoxvilleTN37996 United States State Key Joint Laboratory of Environment Simulation and Pollution Control School of Environment Tsinghua University Beijing100084 China

Over rapidly developing and urbanizing countries, frequent construction activities are the primary drivers behind the substantial emissions and contributors of fugitive dust. In this study, an innovative method was developed to compile a high-resolution spatiotemporal emission inventory from construction sector, utilizing unmanned aerial vehicle (UAV) images. This methodology offered detailed activity level information by distinguishing various types of construction lands and equipment. Focusing on the Shunde District of Guangdong in China, the new emission inventory derived from this method highlighted that travel, topsoil excavation, and loading collectively contributed up to 90% of particulate matter (PM) emissions during the earthwork phase. Moreover, this new inventory rectified the tendency of traditional methods to underestimate PM10 emissions and overestimate PM2.5 emissions, while revealing the non-linear relationship between PM emissions and construction area. This improved PM emission inventory appeared to precisely identify major emission hotspots and enhanced performance of the Community Multi-scale Air Quality (CMAQ) model, and the correlation coefficient (R-value) is 0.08 ± 0.02 higher than that of the traditional emission inventory. Post integration of monitoring data through the Software for the Modeled Attainment Test-Community Edition (SMAT-CE), the contributions of construction dust to local PM10 and PM2.5 concentrations were estimated at 3.27 ± 0.8 µg m–3 and 1.11 ± 0.27 µg m–3, respectively, with more pronounced impacts observed in the central, northwestern, and south-central zones of the study region. This study provides valuable insight for improving construction dust and PM emission inventories, which should be benefiting the development of air pollution prevention and control strategies over this study area as well as other rapidly growing urban areas. © The Author(s).

关键词： Image enhancement

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Insights into photocatalytic mechanism over a novel Cu_(2)WS_(4)/MoS_(2) S-scheme heterojunction

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Rare Metals 2024年第7期43卷 3118-3133页

作者： Wei Zhao Ji-Hui Cao Jun-Jie Liao Yun Liu Xiao-Jun Zeng Jun-Yu Shen Xue-Kun Hong Yang Guo He-Hua Zeng Ya-Zi Liu School of Materials Engineering Jiangsu Key Laboratory of Advanced Functional MaterialsSchool of Electronic and Information EngineeringChangshu Institute of TechnologyChangshu215500China School of Chemistry and Chemical Engineering Changji UniversityChangji 831100China State Environmental Protection Key Laboratory of Soil Environmental Management and Pollution Control Ministry of Ecology and EnvironmentNanjing Institute of Environmental SciencesNanjing 210023China School of Environment Jiangsu Engineering Lab of Water and Soil Eco-RemediationNanjing Normal UniversityNanjing 210023China Department of Chemical Engineering Curtin UniversityPerthWA6845Australia

A novel efficient Cu_(2)WS_(4)/MoS_(2) step-scheme(S-scheme)heterojunction photocatalyst was constructed for the first time and applied in the removal of environmental *** the as-prepared photocatalysts,the Cu_(2)WS_(4)/MoS_(2)-8%heterojunc tion photoc atalyst demonstrates the optimal photocatalytic performance,with the catalytic oxidation efficiency of tetracycline(TC)and the catalytic reduction efficiency of Cr^(6+)reaching 93.3%and 82.1%,*** excellent catalytic properties of Cu_(2)WS_(4)/MoS_(2) heterojunction photocatalysts are attributed to the effective separation pathways of charges and the presence of S-scheme heterojunctions,together with stronger redox *** is speculated that the photogenerated carrier migration path of the Cu_(2)WS_(4)/MoS_(2) catalyst follows the typical S-scheme photocatalytic mechanism,which is verified by the in-depth experimental study and simulated calculations including the electron paramagnetic resonance(EPR)analysis,free radical quenching experiments,charge density distribution,and simulated built-in electric field formation at the interface,which acts as driving force to promote the separation of photoinduced electrons and ***,the photocatalytic mechanism of S-scheme photogenerated carrier migration for the Cu_(2)WS_(4)/MoS_(2) catalyst is revealed based on the systematic experimental techniques and simulated calculations,accounting for its superior photocatalytic oxidation and reduction *** study provides inspiring implications to develop high-efficient S-scheme photocatalytic systems for versatile applications in solarenergy conversion.

关键词： Cu_(2)WS_(4)/MoS_(2) S-scheme Heterojunction Photocatalysis

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Enhanced nitrous acid(HONO)formation via NO_(2)uptake and its potential contribution to heavy haze formation during wintertime

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Atmospheric and Oceanic Science Letters 2024年第6期17卷 15-20页

作者： Zirui Liu Rong Yang Jingyun Liu Keding Lu Guiqian Tang Yuepeng Pan Dongsheng Ji Yuesi Wang Bo Hu State Key Laboratory of Atmospheric Environment and Extreme Meteorology Institute of Atmospheric PhysicsChinese Academy of SciencesBeijingChina School of Atmospheric Sciences Chengdu University of Information TechnologyChengduChina College of Energy and Environmental Engineering Hebei Key Laboratory of Air Pollution Cause and ImpactHebei University of EngineeringHandanChina State Key Joint Laboratory or Environmental Simulation and Pollution Control College of Environmental Sciences and EngineeringPeking UniversityBeijingChina

full understanding of the sources of atmospheric nitrous acid(HONO)in the polluted urban atmosphere re-mains a *** this study,ambient HONO and relevant species were measured during January 2019 at an urban site in Beijing,China,and a budget analysis of HONO was conducted using a box model combined with field *** nighttime“missing sources”of HONO were identified on heavily polluted days based on traditional sources,which had a significant correlation with the relative humidity,ammonia(NH_(3)),and aerosol surface area,and the promotional effect of NH_(3)for nitrogen dioxide(NO_(2))uptake on the wet aerosol surface was ***,an updated parameterization scheme for quantifying the enhanced heterogeneous reactions of NO_(2)on aerosol surfaces is proposed,and the missing nighttime sources of HONO could be substantially com-pensated after the new scheme was *** evaluation on the contributions of HONO to hydroxyl radicals was conducted,and the authors found that the photolysis of HONO played a dominant role in the primary OH production on the polluted days(78%-90%).The study reveals great potential of an NH3-enhanced uptake coefficient of NO_(2)on the aerosol surface in the nocturnal HONO budget,and highlights the significance of HONO in the strong atmospheric oxidation capability during episodes with a heavily polluted atmosphere.

关键词： Nitrous acid Budget analysis Heterogeneous reactions of NO_(2) Heavy pollution episodes Atmospheric oxidation capacity

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Mixed-valence Cu-based metal-organic framework for selective CO_(2) electroreduction to C_(1) liquid fuels with high energy conversion efficiency

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Nano Research 2025年第4期18卷 153-160页

作者： Luyao Wang Fengting Li Yifan Gu College of Environmental Science and Engineering State Key Laboratory of Pollution Control and Resource ReuseTongji UniversityShanghai 200092China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China Key Laboratory of Cities’Mitigation and Adaptation to Climate Change ShanghaiChina Meteorological Administration(CMA)Tongji UniversityShanghai 200092China

Efficient CO_(2) electroreduction requires catalysts for enhanced energy conversion efficiency and carbon product selectivity with low overpotential,in consideration of the interference of competitive H_(2) evolution reaction and complex intermediate species *** proposed that adaptive electronic structures based on dynamic mixed-valence interconversion would facilitate electron transfer and intermediate turnover during the catalysis,ensuring high activity,selectivity,and ***,a novel mixed-valence Cu-based metal-organic framework was prepared using an electron-rich linker for electrocatalytic reduction of CO_(2).The designed material delivered a remarkable Faradaic efficiency of 99.2%for C_(1) liquid fuels at a low reduction potential of -0.1 V versus reversible hydrogen electrode,considerably higher than that of the commercial copper foam and competitive to the Cu-based electrocatalysts *** experimental data and theoretical calculations verified the Cu(Ⅰ)/Cu(Ⅱ)interconversion and the much higher energy barrier of H2 evolution than carbon product *** a feasible strategy,simultaneously improving energy conversion efficiency,carbon product selectivity,and structural robustness,provides great insights into rational catalyst customization for sustainable CO_(2) conversion.

关键词： metal-organic frameworks CO_(2)electroreduction mixed-valence energy conversion efficiency liquid fuels catalysis

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Degradation of Enrofloxacin Antibiotic by Ultraviolet Activated Persulfate Advanced Oxidation Process: Inorganic Anions Effects and Mechanisms 6th

Degradation of Enrofloxacin Antibiotic by Ultraviolet Activa...

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6th International Symposium on Water resource and environmental Management, WREM 2023

作者： Chen, Juxiang Wang, Kai Xie, Wanying Gao, Yuqiong Liao, Zhenliang Gao, Naiyun College of Civil Engineering and Architecture Xinjiang University Xinjiang Urumqi830017 China School of Environment and Architecture Shanghai University of Technology Shanghai200093 China State Key Laboratory of Pollution Control and Resources Reuse College of Environmental Science and Engineering Tongji University Shanghai200092 China

ISBN: (纸本)9783031559884

Enrofloxacin (ENR) is continually detected in natural water environment, becoming one threaten if treating untimely. Performance and mechanism of ENR degradation by ultraviolet (UV)/persulfate (PDS) technology was systematically investigated. Degradation efficiency by UV/PDS was 5.4 times of UV alone, due to the higher rate constant (kobs) of 5.848 × 10–2 min−1. Quencher experiments showed, ·SO4- and ·OH were the major free radicals generated by UV/PDS, and the corresponding contribution rate on degrading ENR was 65.2 and 17.2%. Results of electrical energy per order (EE/O) demonstrated, UV/PDS was less energy consumption and more economical. Moreover, when high concentration of Cl- (10 mM) or low concentration of NO3- (1 mM) co-existed with ENR, the degradation capability by UV/PDS process was slightly promoted, while the negatively effect of CO32- was obvious. Using density functional theory (DFT) and Fukui functions to analyze the possible active sites of ENR, and the results illustrated that C28 and C30 on piperazine ring of ENR was attacked by UV/PDS process, according to the effect of substitution and de-alkylation. © The Author(s), under exclusive license to Springer Nature Switzerland AG 2024.

关键词： Free radicals

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Removing microplastics from aquatic environments:A critical review

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environmental Science and Ecotechnology 2023年第1期13卷 37-53页

作者： Yusheng Pan Shu-Hong Gao Chang Ge Qun Gao Sijing Huang Yuanyuan Kang Gaoyang Luo Ziqi Zhang Lu Fan Yongming Zhu Ai-Jie Wang School of Chemistry and Chemical Engineering Harbin Institute of TechnologyHarbin150090China State Key Laboratory of Urban Water Resource and Environment School of Civil&Environmental EngineeringHarbin Institute of Technology ShenzhenShenzhen518055China State Key Joint Laboratory of Environment Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing100084China Department of Ocean Science and Engineering Southern University of Science and TechnologyShenzhenChina Southern Marine Science and Engineering Guangdong Laboratory(Guangzhou) GuangzhouChina Key Laboratory of Environmental Biotechnology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing100085China

As one of the typical emerging contaminants,microplastics exist widely in the environment because of their small size and recalcitrance,which has caused various ecological *** paper summarizes current adsorption and removal technologies of microplastics in typical aquatic environments,including natural freshwater,marine,drinking water treatment plants(DWTPs),and wastewater treatment plants(WWTPs),and includes abiotic and biotic degradation technologies as one of the removal ***,numerous studies have shown that enrichment technologies have been widely used to remove microplastics in natural freshwater environments,DWTPs,and *** removal of microplastics via WWTPs is critical to reduce the release to the natural environment as a key connection point to prevent the transfer of microplastics from society to natural water *** technology has outstanding pre-degradation effects on microplastics,and the isolated microbial strains or enriched communities can degrade up to 50%or more of pre-processed ***,more research focusing on microplastic degradation could be carried out by combining physical and chemical pretreatment with subsequent microbial *** addition,the current recovery technologies of microplastics are introduced in this *** is incredibly challenging because of the small size and dispersibility of microplastics,and the related technologies still need further *** paper will provide theoretical support and advice for preventing and controlling the ecological risks mediated by microplastics in the aquatic environment and share recommendations for future research on the removal and recovery of microplastics in various aquatic environments,including natural aquatic environments,DWTPs,and WWTPs.

关键词： Aquatic environment Enrichment and removal Microplastics Wastewater treatment plants

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Black carbon, soil organic matter molecular signatures under different land uses in Shenyang, China and relationship with PAHs

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Chemosphere 2023年 342卷 140089页

作者： Gao, Han Li, Huixin Shi, Jiaqi Huang, Jianbo Wei, Jing Qu, Xiaolei Long, Tao State Environmental Protection Key Laboratory of Soil Environmental Management and Pollution Control Nanjing Institute of Environmental Sciences Ministry of Ecology and Environment of China Jiangsu Nanjing210042 China State Key Laboratory of Pollution Control and Resource Reuse School of the Environment Nanjing University Jiangsu Nanjing210023 China

The content, composition and molecular signatures of soil organic matter (SOM) have important influences on the cycle of soil organic carbon (SOC) and the partitioning of polycyclic aromatic hydrocarbons (PAHs) in soil. Seventy-nine soil samples from farmland, forest and urban areas were collected in Shenyang, China to investigate black carbon (BC) content, SOM molecular signatures varied with land use patterns, as well as the relationship with PAHs. The content of BC in urban soils was significantly higher than that of farmland and forest. BC was a key contributor of urban SOM which accounted for 0.35 ± 0.31 of SOC in urban soil. Based on BC/SOC ratio, the main sources of BC were identified as fossil fuel combustion for urban soils, while for farmland and forest soils, it is the mixed results of fossil fuel combustion and biomass burning. All categories of PAHs in urban soils showed the highest level compared to farmland and forest soils. Pearson's correlation analysis results showed there were significant positive correlations between BC and PAHs categories in urban soils, indicating the important role of BC in the accumulation of PAHs in soil. SOM from each of the two different land use patterns can be distinguished by molecular signatures. Urban SOM had abundant molecular markers derived from condensed organic carbon inputs, which was consistent with the BC/SOC value. Farmland SOM had abundant carbon from vegetation and microorganisms, and forest SOM was rich in organic carbon from fresh plant materials. The markers enriched in urban SOM showed significant correlations with most PAHs categories, highlighting the affinity of urban SOM for PAHs at the molecular level. This study contributed to understanding the impact of land management methods on SOM molecular composition signatures and its influence on PAHs occurrence in soil, providing a theoretical basis for regional soil pollution management. © 2023 Elsevier Ltd

关键词： Polycyclic aromatic hydrocarbons

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Enhanced Biodegradation of High-Salinity and Low- Temperature Crude-Oil Wastewater by Immobilized Crude-Oil Biodegrading Microbiota

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Journal of Ocean University of China 2022年第1期21卷 141-151页

作者： HUANG Xiao ZHOU Ting CHEN Xi BAI Jie ZHAO Yangguo Collaborative Innovation Center of Atmospheric Environment and Equipment Technology Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution ControlSchool of Environmental Science and EngineeringNanjing University of Information Science and TechnologyNanjing 210044China The Key Laboratory of Marine Environmental Science and Ecology Ministry of EducationOcean University of ChinaQingdao 266100China Harbin Institute of Technology(Shenzhen) Shenzhen Key Laboratory of Water Resource Utilization and Environmental Pollution ControlShenzhen 518055China

High salt and low temperature are the bottlenecks for the remove of oil contaminants by enriched crude-oil degrading microbiota in Liaohe Estuarine Wetland(LEW),*** improve the performance of crude-oil removal,microbiota was further immobilized by two methods,i.e.,sodium alginate(SA),and polyvinyl alcohol and sodium alginate(PVA+SA).Results showed that the crude oil was effectively removed by the enrichment with an average degrading ratio of 19.42-31.45 mg(L d)^(−1).The optimal inoculum size for the n-alkanes removal was 10%and 99.89%.Some members of genera Acinetobacter,Actinophytocola,Aquabac-terium,Dysgonomonas,Frigidibacter,Sphingobium,Serpens,and Pseudomonas dominated in crude-oil degrading *** the removal efficiency was lower than free bacteria when the temperature was 15℃,SA and PVA+SA immobilization im-proved the resistance to *** composite crude-oil degrading microbiota in this study demonstrated a perspective potential for crude oil removal from surface water under high salinity and low temperature conditions.

关键词： crude-oil degrading microbiota microbial community immobilization high salinity low temperature

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