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Science China Materials 2024年第6期67卷 1684-1705页

作者：赵雯刘娟王光滔王新天杨传举李剑王鋙葶孙晓莲林日琛左淦丞朱文磊 State Key Laboratory of Pollution Control and Resource Reuse Frontiers Science Center for Critical Earth Material CyclingState Key Laboratory of Pollution Control and Resource Reusethe Frontiers Science Center for Critical Earth Material CyclingSchool of the EnvironmentNanjing UniversityNanjing 210023China State Key Laboratory of Analytical Chemistry for Life Science School of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210023China State Key Laboratory of Natural Medicines Key Laboratory of Drug Quality Control and PharmacovigilanceSchool of PharmaceuticsChina Pharmaceutical UniversityNanjing 210009China Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education School of Energy and EnvironmentSoutheast UniversityNanjing 211189China Jiangsu Engineering Lab of Water and Soil Eco-remediation School of EnvironmentNanjing Normal UniversityNanjing 210023China

电化学二氧化碳还原(ECO_(2)R)是一种将碳和可再生能源的能量储存在多碳产品(C_(2+))的化学键中的有效途径.然而,反应涉及的复杂步骤为CO_(2)直接转化为C_(2+)设置了巨大的障碍.一种利用CO作为“中转站”,通过串联ECO_(2)R和电化学CO还... 详细信息

电化学二氧化碳还原(ECO_(2)R)是一种将碳和可再生能源的能量储存在多碳产品(C_(2+))的化学键中的有效途径.然而,反应涉及的复杂步骤为CO_(2)直接转化为C_(2+)设置了巨大的障碍.一种利用CO作为“中转站”,通过串联ECO_(2)R和电化学CO还原(ECOR)以提高生产C_(2+)的选择性和反应速率的策略引起了人们的广泛关注.本文总结了铜基电催化剂在ECOR中催化特定C_(2+)生成的设计策略.其次,从各个方面总结了催化剂工程的代表性设计策略,并介绍了电解反应器改进方面的最新进展.最后,阐述了该研究领域面临的主要挑战和未来前景.这些见解和观点将为铜基电催化剂的设计提供有益指导.

关键词： CO electroreduction Cu-based catalysts multi-car-bon products

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Advanced capacitive deionization for ion selective separation: Insights into mechanism over a functional classification

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Chemosphere 2024年 346卷 140601页

作者： Sun, Xiaoqi Hao, Zewei Zhou, Xuefei Chen, Jiabin Zhang, Yalei State Key Laboratory of Pollution Control and Resources Reuse College of Environmental Science and Engineering Tongji University Shanghai200092 China

Due to the diversity and variability of harmful ions in polluted water bodies, the selective removal and separation for specific ions is of great significance in water purification and resource processes. Capacitive deionization (CDI), an emerging desalination technology, shows great potential to selectively remove harmful ionic pollutants and further recover valuable ions because of the simple operation and low energy consumption. Researchers have done a lot of work to investigate ion selectivity utilizing CDI, including both theoretical and experimental studies. Nevertheless, in the investigation of selective mechanisms, phenomena where carbon materials exhibit entirely opposite selectivity require further analysis. Furthermore, there is a need to summarize the specific chemical reaction mechanisms, including the formation of hydrogen bonds, complexation reactions, and ligand exchanges, within selective electrodes, which have not been thoroughly examined in detail previously. In order to fill these gaps, in this review, we summarized the recent progress of CDI technologies for ion selective separation, and explored the selective separation mechanism of CDI from three aspects: selective physical adsorption, specific chemical reaction, and the utilization of selective barriers. Additionally, this review analyzes in detail the formation process of chemical bonds and ion conversion pathways when ions interact with electrode materials. Finally, some significant development prospects and challenges were offered for the future selective CDI systems. We believe the review will provide new insights for researchers in the field of ion selective separation. © 2023 Elsevier Ltd

关键词： Ions

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Interface-induced charge transfer pathway switching of a Cu_(2)O-TiO_(2)photocatalyst from p-n to S-scheme heterojunction for effective photocatalytic H_(2)evolution

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Journal of Materials Science & Technology 2024年第26期193卷 98-106页

作者： Kaihui Huang Guijie Liang Shaolong Sun Haobin Hu Xiaoming Peng Rongchen Shen Xin Li Institute of Biomass Engineering Key Laboratory of Energy Plants Resource and UtilizationMinistry of Agriculture and Rural AffairsSouth China Agricultural UniversityGuangzhou 510642China Hubei Key Lab Low Dimens Optoelect Mat&Devices Hubei University of Arts and ScienceXiangyang 441053China College of Natural Resources and Environment South China Agricultural UniversityGuangzhou 510642China Key Laboratory of Efficient Utilization of Oil and Gas Resources in Longdong College of Petroleum and Chemical EngineeringLongdong UniversityQingyang 745000China State Key Laboratory of Pollution Control and Resource Reuse School of the EnvironmentNanjing UniversityNanjing 210023China

Photocatalytic hydrogen evolution from water splitting is an appealing method for producing clean chemical ***_(2)O,with a suitable bandgap,holds promise as a semiconductor for this ***,the strong photo-corrosion and rapid charge recombination of Cu_(2)O strongly limit its application in the photocatalytic ***,an S-scheme heterojunction photocatalyst composed of TiO_(2)and Cu_(2)O was rationally designed to effectively avoid the photo-corrosion of Cu_(2)*** introduction of an interfacial nitrogen-doped carbon(NC)layer switches the heterojunction interfacial charge transfer pathway from the p-n to S-scheme heterojunction,which avoids excessive accumulation of photogenerated holes on the surface of Cu_(2)***,the hybrid structure shows a broad spectral response(300-800 nm)and efficient charge separation and transfer ***,the highest photocatalytic hydrogen evolution rate of TiO_(2)-NC-3%Cu_(2)O-3%Ni is 13521.9μmol g^(-1)h^(-1),which is approximately 664.1 times higher than that of pure Cu_(2)***-situ X-ray photoelectron spectroscopy and Kelvin probe confirm the charge transfer mechanism of S-scheme *** formation of S-scheme heterojunctions effectively accelerates the separation of photogenerated electron-hole pairs and enhances redox capacity,thereby improving the photocatalytic performance and stability of Cu_(2)*** study provides valuable insights into the rational design of highly efficient Cu_(2)O-based heterojunction photocatalysts for hydrogen production.

关键词： Photocatalytic hydrogen evolution Cu_(2)O S-scheme heterojunction Charge separation mechanism Nitrogen doped carbon

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Springs Emerging along the Elevation Gradient Indicate Intensive Groundwater-Surface Water Exchange in an Alpine Headwater Catchment, Northwestern China

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Journal of Earth Science 2023年第1期34卷 181-193页

作者： Yalu Hu Ziyong Sun Rui Ma School of Environmental Studies China University of GeosciencesWuhan430078China Laboratory of Basin Hydrology and Wetland Eco-Restoration China University of GeosciencesWuhan430078China State Environmental Protection Key Laboratory of Source Apportionment and Control of Aquatic Pollution Ministry of Ecology and EnvironmentWuhan430078China Hubei Key Laboratory of Yangtze Catchment Environmental Aquatic Science China University of GeosciencesWuhan430078China

Groundwater plays an important role in sustaining the streamflow in cold alpine area, but is poorly understood due to a lack of direct access. About 98 groups of springs are observed at the upper reaches of Heihe River Basin, which provide an opportunity to explore the main aquifers. Springs are clustered in three groups according to locations:(1) springs on the moraine and talus deposits;(2) springs at the end of alluvial plain in lower topography;(3) springs along the river bank. The hydrometric, geochemical and isotopic data of springs in a representative catchment were integrated and used to elucidate the groundwater flow paths. Results indicate the Quaternary porous aquifers in the alpine catchment have a profound influence on the regional groundwater flow paths and the groundwater and surface water(GW-SW) interactions. The aquifer consisting of alluvial-pluvial deposits has a great capacity of groundwater storage and plays a vital role in regulating discharge by attenuating the seasonal variation and maintaining the main stream in cold seasons. This is different from the fast recharge and discharge mode of the moraine and talus deposits. Our work highlights the importance of loose deposits in controlling the GW-SW interactions in the cold alpine area.

关键词： springs alpine catchments groundwater groundwater-surface water interactions alluvial plain

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A new method to determine composition of sphalerite without secondary pollution based on CIELAB color space

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SusMat 2023年第5期3卷 671-681页

作者： Yong Liu Ning Duan Linhua Jiang Hongping He Han Cheng Jiaqi Liao Yanli Xu Wen Cheng Ying Chen Guangbin Zhu Fuyuan Xu School of Materials Science and Engineering Anhui University of Science&TechnologyHuainanAnhuiChina State Key Laboratory of Pollution Control and Resources Reuse College of Environmental Science and EngineeringTongji UniversityShanghaiChina Shanghai Institute of Pollution Control and Ecological Security ShanghaiChina College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhenChina School of Environmental Science and Engineering Tianjin UniversityTianjinChina

Currently,most of the methods formineral materials analysis generate secondary pollution,which is detrimental to human *** instance,traditionalmethods for sphalerite analysis in the zinc(Zn)smelting industry including chemical titration,atomic absorption spectrometry,and inductively coupled atomic emission *** indicators and toxic heavy metals are used in the analytical processes,causing severe *** some methods,liquid is transformed into gaseous plasma,which is more dangerous to human *** to large quantities of sphalerite being used,secondary pollution cannot be *** study proposes a green analysis method for the detection of sphalerite based on colorimetry,which does not generate secondary *** results show that the strong substitution ability of iron(Fe)for Zn contributes to their inverse correlation in *** lattice parameters decrease with the increasing Fe content,resulting in a darker ***,key colorimetry parameters of L*,a*,and b*show clear linear correlations with the Zn and Fe *** with traditional approaches,this new method is environmental friendly with high sensitivity and *** relative error and relative standard deviation were less than 10%and 5%,*** study provides a significant reference for nonpollution determination of other mineral materials.

关键词： analytical method for sphalerite CIELAB colorimetry no secondary pollution original state detection

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Micropollutant removal and disinfection byproduct control by sequential peroxymonosulfate-UV treatment in water: A case study with sulfamethoxazole

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Journal of Environmental Sciences 2022年第7期34卷 141-150页

作者： Tian-Yang Zhang Yong-Shan Lu Zhen-Ning Luo Wen-Jun Sun Bin Xu Chen-Yan Hu Yu-Lin Tang Zheng-Yu Dong Xiao-Meng Ren State Key Laboratory of Pollution Control and Resource Reuse Key Laboratory of Yangtze Water EnvironmentMinistry of EducationCollege of Environmental Science and EngineeringTongji UniversityShanghai 200092China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China School of Environment Tsinghua UniversityBeijing 100084China College of Environmental and Chemical Engineering Shanghai University of Electric PowerShanghai 200090China PLA Naval Medical Center Shanghai 200433China

UV/peroxymonosulfate(UV/PMS) advanced oxidation process has attracted significant attention for removal of micropollutants in water. However, during practical water treatment applications, the PMS treatment must be performed before the UV treatment to achieve full contact. In this study, sulfamethoxazole(SMX) was selected as the target micropollutant. Four different operational approaches, including UV alone, PMS alone, simultaneous UV/PMS and sequential PMS-UV, were compared for their differences in SMX removal and disinfection by-product(DBP) formation potentials during chlorine-driven disinfection. Among the four approaches, UV/PMS and PMS-UV achieved over 90% removal efficiencies for SMX without substantial differences. For raw water, the trichloronitromethane(TCNM) formation potential after treatment with PMS-UV was lower than that after UV/PMS treatment. The time interval over which the PMS-UV process was conducted had little effect on the final removal efficiency for SMX. However, a brief(5 min) pre-PMS treatment significantly reduced the TCNM formation potential and the genotoxicity from DBPs. The formation risk for TCNM during chlorination increased markedly with increasing PMS dosages, and the appropriate dosage under these experimental conditions was suggested to be 0.5–1.0 mmol/L. Under alkaline conditions, PMS-UV treatment can enhance SMX degradation as well as dramatically reduced the formation potentials for haloketones, haloacetonitriles and halonitromethanes. This study suggests that proper optimization of UV/PMS processes can remove SMX and reduce its DBP formation.

关键词： Peroxymonosulfate-UV(PMS-UV) Sulfamethoxazole(SMX) Disinfection by-products(DBPs) Operational approaches Water treatment

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Hybrid energy harvesting systems for self-powered sustainable water purification by harnessing ambient energy

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Frontiers of Environmental Science & Engineering 2023年第10期17卷 1-16页

作者： Zhengyang Huo Young Jun Kim Yuying Chen Tianyang Song Yang Yang Qingbin Yuan Sang Woo Kim School of Environment and Natural Resources Renmin University of ChinaBeijing 100872China School of Advanced Materials Science and Engineering Sungkyunkwan University(SKKU)Suwon 16419Republic of Korea State Key Laboratory of Pollution Control and Resource Reuse School of the EnvironmentNanjing UniversityNanjing 210023China Institute of Scientific and Technical Information of China Beijing 100038China

The development of self-powered water purification technologies for decentralized applications is crucial for ensuring the provision of drinking water in resource-limited regions. The elimination of the dependence on external energy inputs and the attainment of self-powered status significantly expands the applicability of the treatment system in real-world scenarios. Hybrid energy harvesters, which convert multiple ambient energies simultaneously, show the potential to drive self-powered water purification facilities under fluctuating actual conditions. Here, we propose recent advancements in hybrid energy systems that simultaneously harvest various ambient energies (e.g., photo irradiation, flow kinetic, thermal, and vibration) to drive water purification processes. The mechanisms of various energy harvesters and point-of-use water purification treatments are first outlined. Then we summarize the hybrid energy harvesters that can drive water purification treatment. These hybrid energy harvesters are based on the mechanisms of mechanical and photovoltaic, mechanical and thermal, and thermal and photovoltaic effects. This review provides a comprehensive understanding of the potential for advancing beyond the current state-of-the-art of hybrid energy harvester-driven water treatment processes. Future endeavors should focus on improving catalyst efficiency and developing sustainable hybrid energy harvesters to drive self-powered treatments under unstable conditions (e.g., fluctuating temperatures and humidity).

关键词： Piezocatalysis Solar energy Waste heat Decentralized water treatment Point-of-use Nanogenerator

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Response of soil organic carbon stocks and soil microbial biomass carbon to natural grassland conversion: A global meta-analysis

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Science of the Total Environment 2025年 965卷 178481页

作者： Cai, Yijun Yang, Yuwen Jiang, Jinlin Long, Tao Gu, Xueyuan Guo, Yang Li, Ming Xie, Yufeng Key Laboratory of Soil Environmental Management and Pollution Control Nanjing Institute of Environmental Sciences Ministry of Ecology and Environment Nanjing210042 China State Key Laboratory of Pollution Control and Resource Reuse School of Environment Nanjing University Nanjing210023 China

Natural grasslands worldwide are increasingly being converted into other land-use types, such as cropland and forest, thereby impacting soil carbon cycles and stocks. Soil organic carbon (SOC) is essential for regulating soil properties and microbial communities, while microbial biomass carbon (MBC) is the most active fraction of the SOC pool, both of which play pivotal roles in the global carbon cycle. Here, we performed a meta-analysis on 623 and 85 individual observations from 85 peer-reviewed articles to quantitatively evaluate the effect of grassland conversion on SOCS and MBC. Overall, conversions significantly reduced SOCS and MBC by 10.11 % and 30.63 %, respectively. Notably, the impact varied by conversion type: converting grassland to forest, cropland, and plantation reduced SOCS by 7.69 %, 16.47 %, and 20.55 %, respectively. Meanwhile, converting grassland to cropland and abandoned land decreased MBC by 47.80 % and 38.74 %, respectively. Environmental factors such as mean annual temperature (MAT), mean annual precipitation (MAP), soil total nitrogen (TN), and soil carbon-to‑nitrogen ratio (C/N) influenced these changes. SOCS and MBC were positively correlated with MAT, soil C/N and TN. Specifically, when the C/N or TN of the converted soil exceeded 1.21 or 1.11 times that of the original grassland, SOCS would exhibit a trend of carbon sequestration. Our findings provide valuable insights for global soil carbon sequestration and land use management policies. © 2025

关键词： Carbon sequestration

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Insight into the formation of iodinated tr ihalomethanes dur ing chlor ination,monochloramination, and dichloramination of iodide-containing water

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Journal of Environmental Sciences 2022年第7期34卷 285-294页

作者： Shuang Zhang Yi-Li Lin Tian-Yang Zhang Chen-Yan Hu Zhi Liu Zheng-Yu Dong Meng-Yuan Xu Bin Xu State Key Laboratory of Pollution Control and Resource Reuse Key Laboratory of Yangtze Water EnvironmentMinistry of EducationCollege of Environmental Science and EngineeringTongji UniversityShanghai 200092China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China Department of Safety Health and Environmental Engineering“National”Kaohsiung University of Science and TechnologyKaohsiung 824Chinese Taipei College of Environmental and Chemical Engineering Shanghai University of Electric PowerShanghai 200090China

In this study, the formation of iodinated trihalomethanes(I-THMs) was systematically evaluated and compared for three treatment processes-(i) chlorination,(ii) monochloramine, and(iii) dichloramination-under different p H conditions. The results demonstrated that ITHM formation decreased in the order of monochloramination > dichloramination > chlorination in acidic and neutral p H. However, the generation of I-THMs increased in the dichloramination < chlorination < monochloramination order in alkaline condition. Specifically, the formation of I-THMs increased as p H increased from 5 to 9 during chlorination and monochloramination processes, while the maximum I-THM formation occurred at pH 7 during dichloramination. The discrepancy could be mainly related to the stability of the three chlor(am) ine disinfectants at different p H conditions. Moreover, in order to gain a thorough insight into the mechanisms of I-THM formation during dichloramination, further investigation was conducted on the influencing factors of DOC concentration and Br/Imolar ratio. I-THM formation exhibited an increasing and then decreasing trend as the concentration of DOC increased from 1 to 7 mg-C/L, while the yield of I-THMs increased with increasing Br/Imolar ratio from 5:0 to 5:10. During the three processes mentioned above, similar I-THM formation results were also obtained in real water, which indicates that the excessive generation of I-THMs should be paid special attention during the disinfection of iodide-containing water.

关键词： Inorganic chloramine Iodinated trihalomethanes(I-THMs) Chlorination Monochloramination Dichloramination Bromide to iodide ratio

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Resistance of Biological Magnetic Ion Exchange Resin to Norfloxacin on the Advanced Treatment of Wastewater

SSRN

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SSRN 2024年

作者： Han, Liqin Shan, Cong Shuang, Chendong Xu, Shanshan Zhou, Qing Ji, Rong Li, Aimin Pan, Yang State Key Laboratory of Pollution Control and Resource Reuse School of the Environment Nanjing University Nanjing210023 China

In this work, a biological magnetic anion exchange (B-MAEX) system was established for removal of dissolved organic carbon (DOC) and triclosan in advanced treatment of wastewater. Activated sludge (AS) system was employed for comparison in the same experimental conditions. In AS system, the presence of norfloxacin had no significant impact on DOC removal at concentrations below 5.00 mg/L. But DOC removal decreased from 43±8% to 16±5% as norfloxacin concentration increased from 5.00 to 50.00 mg/L. Triclosan removal was found to be more susceptible to norfloxacin compared to DOC removal, with the removal decreasing from 22±8% to 12±8% as norfloxacin concentration increased from 0.05 to 0.50 mg/L. Further reduction in triclosan removal to 3±5% was observed with norfloxacin raised to 50.00 mg/L. In contrast to the AS system, the B-MAEX system demonstrated significantly enhanced removal of both DOC and triclosan at equivalent norfloxacin concentrations. With norfloxacin increasing from 5.00 to 50.00 mg/L, DOC removal dropped from 71±12% to 60±11%. Triclosan removal decreased from 70±5% to 64±6% when norfloxacin concentration increased from 0.50 to 5.00 mg/L. Even at norfloxacin concentration of 50.00 mg/L, triclosan removal remained 61±12%. The enhanced resistance of the B-MAEX system to norfloxacin could be attributed primarily to its elevated biological activity and a more diverse microbial community, suggesting the potential application on the advanced wastewater treatment. © 2024, The Authors. All rights reserved.

关键词： Ion exchange resins

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