检索结果-内蒙古大学图书馆

New sustainable polymers with on-demand depolymerization property

science China Chemistry 2024年第9期67卷 2803-2841页

作者： Yangyang Sun Zesheng An Yanshan Gao Rongrong Hu Ye Liu Hua Lu Xiao-Bing Lu Xuan Pang Anjun Qin Yong Shen Youhua Tao Yu-Zhong Wang Junpeng Wang Gang Wu Guang-Peng Wu Tie-Qi Xu Xing-Hong Zhang Yuetao Zhang Zhenbiao Zhang Jian-Bo Zhu Miao Hong Zhibo Li State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghai 200032China State Key Laboratory Base of Eco-Chemical Engineering College of Chemical EngineeringQingdao University of Science and TechnologyQingdao266042China State Key Laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchun 130012China State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular AggregatesSouth China University of TechnologyGuangzhou 510640China State Key Laboratory of Fine Chemicals Frontiers Science Center for Smart MaterialsDalian University of TechnologyDalian 116024China Beijing National Laboratory for Molecular Sciences Center for Soft Matter Science and EngineeringKey Laboratory of Polymer Chemistry and Physics of Ministry of EducationCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871China Key Laboratory of Polymer Ecomaterials Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China The Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric Materials(MoE) National Engineering Laboratory of Eco-Friendly Polymeric Materials(Sichuan)College of ChemistryState Key Laboratory of Polymer Materials EngineeringSichuan UniversityChengdu 610064China School of Polymer Science and Polymer Engineering the University of AkronAkronOH 44325USA MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027China State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials Jiangsu Key Laboratory of Advanced Functional Polymer Design and ApplicationSuzhou Key Laboratory of Macromolecular Design and Precision SynthesisCollege of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123China

To combat the crisis of today's synthetic polymers arising from unsustainable production and disposal,it is essential for the synthetic polymer community to reshape the current polymer industry with sustainable *** an emerging class of sustainable polymers,the development of chemically depolymerizable polymers(CDPs),which can undergo closed-loop depolymerization/repolymerization cycles to reproduce virgin polymers without the loss of properties from recovered monomers,offers an ideal solution to preserve finite natural resources,provides a feasible solution to the end-of-life issue of polymer waste,and thereby establishes a circular materials ***,two grand key challenges have been encountered in the establishment of practically useful CDPs:how to balance polymerization and depolymerization ability and how to unify conflicted depolymerizability and physical ***,this critical review article presents our vision for summarizing feasible strategies to overcome the above two significant challenges and the design principles for constructing an ideal CDP by highlighting selected major progress made in this rapidly expanding field.

关键词： chemically depolymerizable polymers sustainable polymers depolymerization monomer recovery degradation plastics

来源：评论

学校读者我要写书评

暂无评论

RECONSTRUCTION-BASED A POSTERIORI ERROR ESTIMATES FOR THE L1 METHOD FOR TIME FRACTIONAL PARABOLIC PROBLEMS

引用

Journal of Computational Mathematics 2025年第2期43卷 345-368页

作者： Jiliang Cao Aiguo Xiao Wansheng Wang Department of Mathematics Shanghai Normal UniversityShanghai 200234China Hunan Key Laboratory for Computation and Simulation in Science and Engineering&Key Laboratory of Intelligent Computing and Information Processing of Ministry of Education Xiangtan UniversityXiangtan 411105China

In this paper,we study a posteriori error estimates of the L1 scheme for time discretizations of time fractional parabolic differential equations,whose solutions have generally the initial *** derive optimal order a posteriori error estimates,the quadratic reconstruction for the L1 method and the necessary fractional integral reconstruction for the first-step integration are *** using these continuous,piecewise time reconstructions,the upper and lower error bounds depending only on the discretization parameters and the data of the problems are *** numerical experiments for the one-dimensional linear fractional parabolic equations with smooth or nonsmooth exact solution are used to verify and complement our theoretical results,with the convergence ofαorder for the nonsmooth case on a uniform *** recover the optimal convergence order 2-αon a nonuniform mesh,we further develop a time adaptive algorithm by means of barrier function recently *** numerical implementations are performed on nonsmooth case again and verify that the true error and a posteriori error can achieve the optimal convergence order in adaptive mesh.

关键词： Time fractional parabolic differential equations A posteriori error estimates Ll method Fractional integral reconstruction Quadratic reconstruction

来源：评论

学校读者我要写书评

暂无评论

SPIDER:Speeding up Side-Channel Vulnerability Detection via Test Suite Reduction

引用

Tsinghua science and Technology 2023年第1期28卷 47-58页

作者： Fei Yan Rushan Wu Liqiang Zhang Yue Cao Key Laboratory of Aerospace Information Security and Trusted Computing Ministry of EducationSchool of Cyber Science and EngineeringWuhan UniversityWuhan 430072China

Side-channel attacks allow adversaries to infer sensitive information,such as cryptographic keys or private user data,by monitoring unintentional information leaks of running *** side-channel detection methods can identify numerous potential vulnerabilities in cryptographic implementations with a small amount of execution traces due to the high diffusion of secret inputs in crypto ***,because non-cryptographic programs cover different paths under various sensitive inputs,extending existing tools for identifying information leaks to non-cryptographic applications suffers from either insufficient path coverage or redundant *** address these limitations,we propose a new dynamic analysis framework named SPIDER that uses fuzzing,execution profiling,and clustering for a high path coverage and test suite reduction,and then speeds up the dynamic analysis of side-channel vulnerability detection in non-cryptographic *** analyze eight non-cryptographic programs and ten cryptographic algorithms under SPIDER in a fully automated way,and our results confirm the effectiveness of test suite reduction and the vulnerability detection accuracy of the whole framework.

关键词： side-channel detection test suite reduction dynamic analysis

来源：评论

学校读者我要写书评

暂无评论

Ultrafast investigation of room temperature valley polarization in“optical bilayer”WS_(2)

引用

science China(Technological sciences) 2024年第1期67卷 91-97页

作者： ZHAO LeYi WANG Hai LIU TianYu LI FangFei ZHOU Qiang WANG HaiYu Synergetic Extreme Condition High-Pressure Science Center State Key Laboratory of Superhard MaterialsCollege of PhysicsJilin UniversityChangchun 130012China State Key Laboratory of Integrated Optoelectronics College of Electronic Science and EngineeringJilin UniversityChangchun 130012China

Monolayer transition metal dichalcogenides(TMDCs)have become a promising platform in valleytronics due to possessing the regulatable valley degrees of ***,as a result of the rapid intervalley scattering,it is difficult to measure the PL valley polarization of monolayer TMDCs at room temperature,which limits their application in valleytronics ***,we report a room temperature photoluminescence(PL)valley polarization up to 3.73%in an“optical bilayer”WS_(2)formed by transferring monolayer WS_(2)onto flat Ag ***,in the transient absorption(TA)measurements,a remarkably long valley depolarization lifetime is ***,we demonstrate the valley properties of such“optical bilayer”WS_(2)resemble actual bilayer WS_(2),in which the robust valley polarization can be attributed to the phonons depletion effect and the blocked interlayer hopping *** peculiar valley features in“optical bilayer”WS_(2)provide a particularly simple method to enhance valley control at room temperature.

关键词： valleytronics optical bilayer transient absorption tungsten disulfide

来源：评论

学校读者我要写书评

暂无评论

Large-Scale Multi-Objective Optimization Algorithm Based on Weighted Overlapping Grouping of Decision Variables

引用

Computer Modeling in engineering & sciences 2024年第7期140卷 363-383页

作者： Liang Chen Jingbo Zhang Linjie Wu Xingjuan Cai Yubin Xu Shanxi Key Laboratory of Big Data Analysis and Parallel Computing Taiyuan University of Science and TechnologyTaiyuan030024China School of State Key Laboratory of Novel Software Technology Nanjing UniversityNanjing210008China

The large-scale multi-objective optimization algorithm(LSMOA),based on the grouping of decision variables,is an advanced method for handling high-dimensional decision ***,in practical problems,the interaction among decision variables is intricate,leading to large group sizes and suboptimal optimization effects;hence a large-scale multi-objective optimization algorithm based on weighted overlapping grouping of decision variables(MOEAWOD)is proposed in this ***,the decision variables are perturbed and categorized into convergence and diversity variables;subsequently,the convergence variables are subdivided into groups based on the interactions among different decision *** the size of a group surpasses the set threshold,that group undergoes a process of weighting and overlapping ***,the interaction strength is evaluated based on the interaction frequency and number of objectives among various decision *** decision variable with the highest interaction in the group is identified and disregarded,and the remaining variables are then reclassified into ***,the decision variable with the strongest interaction is added to each *** minimizes the interactivity between different groups and maximizes the interactivity of decision variables within groups,which contributed to the optimized direction of convergence and diversity exploration with different *** was subjected to testing on 18 benchmark large-scale optimization problems,and the experimental results demonstrate the effectiveness of our *** with the other algorithms,our method is still at an advantage.

关键词： Decision variable grouping large-scale multi-objective optimization algorithms weighted overlapping grouping direction-guided evolution

来源：评论

学校读者我要写书评

暂无评论

Nanoscale zero-valent iron integrated with bioreactor for recalcitrant antimony-Congo red dyeing wastewater treatment

引用

Progress in Natural science:Materials International 2023年第5期33卷 569-574页

作者： Jing Liu Airong Liu Yi Wei Jiahui Fu Wei-xian Zhang State Key Laboratory for Pollution Control and Resource Reuse College of Environmental Science and Engineering Tongji University

Antimony（Sb） and recalcitrant organic dyes often coexist in dyeing wastewater, and the simultaneous removal of Sb and dyes has been a challenge for traditional biological method in the treatment of Sb-dyeing *** zero-valent iron（n ZVI） is particularly suitable for separating heavy metals and enhancing the biodegradability of recalcitrant organic compounds. Herein, n ZVI is integrated with bioreactors（n ZVI-bio system） to achieve enhanced removal of Sb and degradation of Congo red（CR） in wastewater. The n ZVI-bio system achieves a reduction in Sb levels from 2.5 g L-1to 0.064 mg L-1, with a color removal efficiency of up to 98.60 % and a reduction in COD from 167 mg L-1to 55 mg L-1. The excellent performance is mainly attributed to n ZVI pretreatment, which removes Sb and degrades CR into smaller and more biodegradable organic compounds,providing favorable environmental conditions for the subsequent biotreatment system. This suggests that integrated n ZVI-bio system has potential for the treatment of complex wastewater containing heavy metals and recalcitrant organic dyes.

关键词： Nanoscale zero-valent iron Biotreatment Antimony Congo red nZVI-bio system

来源：评论

学校读者我要写书评

暂无评论

A robust & weak-nucleophilicity electrocatalyst with an inert response for chlorine ion oxidation in large-current seawater electrolysis

引用

Journal of Energy Chemistry 2024年第3期90卷 486-495,I0011页

作者： Junting Dong Chang Yu Hui Wang Lin Chen Hongling Huang Yingnan Han Qianbing Wei Jieshan Qiu State Key Laboratory of Fine Chemicals Frontier Science Center for Smart MaterialsSchool of Chemical EngineeringDalian University of TechnologyDalian 116024LiaoningChina College of Chemical Engineering State Key Laboratory of Chemical Resource EngineeringBeijing University of Chemical TechnologyBeijing 100029China

Seawater splitting into hydrogen,a promising technology,is seriously limited by the durability and tolerance of electrocatalysts for chlorine ions in seawater at large current densities due to chloride oxidation and ***,we present a robust and weak-nucleophilicity nickel-iron hydroxide electrocatalyst with excellent selectivity for oxygen evolution and an inert response for chlorine ion oxidation which are key and highly desired for efficient seawater *** a weak-nucleophilicity electrocatalyst can well match with strong-nucleophilicity OH-compared with the weak-nucleophilicity Cl^(-),resultantly,the oxidation of OH-in electrolyte can be more easily achieved relative to chlorine ion oxidation,confirmed by ethylenediaminetetraacetic acid disodium probing ***,no strongly corrosive hypochlorite is produced when the operating voltage reaches about 2.1 V ***,a potential that is far beyond the thermodynamic potential of chlorine ion oxidatio *** concept and approach to reasonably designing weaknucleophilicity electrocatalysts that can greatly avoid chlorine ion oxidation under alkaline seawater environments can push forward the seawater electrolysis technology and also accelerate the development of green hydrogen technique.

关键词： Nickel-iron hydroxide electrocatalysts Highly selective seawater electrolysis Weak nucleophilicity Oxygen evolution reaction Hydrogen

来源：评论

学校读者我要写书评

暂无评论

Au/TS-1 catalyst for propylene epoxidation with H_(2)and O_(2):Effect of surface property and morphology of TS-1 zeolite

引用

Nano Research 2023年第5期16卷 6278-6289页

作者： Jialun Xu Zhihua Zhang Daiyi Yu Wei Du Nan Song Xuezhi Duan Xinggui Zhou State Key Laboratory of Chemical Engineering East China University of Science and TechnologyShanghai 200237China

The catalytic performances over propylene epoxidation with H_(2)and O_(2)(HOPO process)are significantly affected by the properties(e.g.,surface properties,Ti coordination,morphology)of titanosilicate *** urea into zeolite synthesis is a simple and convenient method to modify these properties of titanosilicate *** pore-blocked titanium silicalite-1(TS-1,i.e.,TS-1-B)with the lower urea dosage possesses more defective structure and unsaturated coordinated Ti sites verified by 29Si nuclear magnetic resonance(NMR)and X-ray photoelectron spectroscopy(XPS)analysis,which results in a high initial activity and hydrogen efficiency;while the high surface acidity generated by these Ti species leads to a continuous decrease in the activity and the propylene oxide(PO)selectivity during the *** the amount of urea gradually increases,the TS-1-B samples present the reduced surface defects and defective and unsaturated Ti ***,TS-1-B-0.30U presents the weaker PO adsorption on PO-diffusion reflectance infrared Fourier transform spectra(DRIFTS),thus results in the high stable PO formation rate and selectivity over its Au ***,a flat-plate-like shape with a shorter thickness of 100 nm along the b-axis direction is observed on the urea-modified *** with the conventional ellipsoidal TS-1 with crystal sizes of 200 and 500 nm,the flat-plate-like TS-1-0.30U displays the less surface defects,unsaturated Ti species,the weaker Lewis acid,which is favorable for the desorption and intracrystalline diffusion of PO,thus reduces the occurrence of side reactions for the improved selectivity and *** work may provide a reference for developing titanium-containing materials with high activity and stability over HOPO reaction.

关键词： propylene epoxidation titanium silicalite-1(TS-1) surface properties Ti species morphological regulation diffusion

来源：评论

学校读者我要写书评

暂无评论

Accurate manipulation of anthropomorphic robotic arm based on 3D human eye gazing with posture error compensation

引用

science China(Technological sciences) 2025年第2期68卷 178-198页

作者： Quanlin LI Xianzong WANG Jiaji MA Qianjun HUANG Qizhi JIANG Wenbin CHEN Caihua XIONG State Key Laboratory of Intelligent Manufacturing Equipment and Technology School of Mechanical Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China Institute of Medical Equipment Science and Engineering Huazhong University of Science and TechnologyWuhan 430074China

As humans and robots work closer together than ever,anthropomorphic robotic arms with intuitive human-robot interaction interfaces have drawn massive attention to improving the quality of robot-assisted *** pursuit of this,we designed a dedicated 7-degrees-of-freedom(DoF)anthropomorphic robotic arm having three compact differential joints and a head-mounted gaze tracker enabling head-pose-tracked 3D gaze ***,two key challenges were addressed to achieve accurate robot-assisted manipulation of the object indicated by the direction of human ***,a novel predictive pupil feature was proposed for 3D gaze *** from most existing features subjected to the common paraxial approximation assumption,the proposed novel predictive pupil feature considered the light refraction at two corneal surfaces with a more realistic eye model,significantly improving the 3D gaze estimation accuracy when the eyeball rotates at large ***,a novel optimization-based approach was developed to efficiently compensate for the posture errors of the designed 7-DoF anthropomorphic robotic arm for accurate *** with the existing Jacobian-based or optimization-based approaches with nominal joint values as iteration initial,the proposed approach computed the optimal iteration initial and realized faster convergence for real-time posture error *** the posture error compensation in real time and 3D gaze estimated accurately,the human can command accurate robot-assisted manipulation using his eyes *** proposed system was successfully tested on five healthy subjects.

关键词： anthropomorphic robotic arm differential joint posture error compensation 3D gaze estimation corneal refraction head-mounted gaze tracker

来源：评论

学校读者我要写书评

暂无评论

BaCe_(0.8)Fe_(0.1)Ni_(0.1)O_(3−δ)-impregnated Ni-GDC by phase-inversion as an anode of solid oxide fuel cells with on-cell dry methane reforming

引用

Journal of Advanced Ceramics 2024年第6期13卷 834-841页

作者： Yanya Liu Jun Luo Cheng Li Bo Liu Dong Yan Jian Li Lichao Jia School of Materials Science and Engineering State Key Laboratory of Materials Processing and Die&Mould TechnologyHuazhong University of Science and TechnologyWuhan 430074China

BaCe_(0.8)Fe_(0.1)Ni_(0.1)O_(3−δ)(BCFN)in a perovskite structure is impregnated consecutively by BCFN solution and BCFN suspension into a phase-inversion prepared NiO–Gd_(0.1)Ce_(0.9)O_(2−δ)(GDC)scaffold as an anode for solid oxide fuel cells(SOFCs)with on-cell dry reforming of methane(DRM).The whole pore surface of the scaffold is covered by small BCFN particles formed by BCFN solution impregnation;the large pores near the scaffold surface are filled by BCFN aerogels with a high specific surface area produced by BCFN suspension impregnation,which act as a catalytic layer for on-cell *** reduction,the anode consists of a Ni–GDC scaffold and BCFN particles with exsolved FeNi3 *** BCFN-impregnated Ni–GDC anode has higher electrical conductivity,electrochemical activity,and resistance to carbon deposition,with which the cell shows maximum power densities between 1.44 and 0.92 W·cm^(−2) when using H_(2) and between 1.09 and 0.50 W·cm^(−2) when using CO_(2)–CH_(4) at temperatures ranging from 750 to 600℃.A stable performance at 400 mA·cm^(−2) and 700℃is achieved using 45%CO_(2)–45%CH_(4)–10%N_(2) for more than 400 h without carbon deposition,benefiting from the impregnated BCFN aerogel with a high specific surface area and water adsorbability.

关键词： aerogel solid oxide fuel cells(SOFCs) phase-inversion dry reforming of methane(DRM) carbon resistance

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：