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Drilling-based measuring method for the c-φ parameter of rock and its field application

International Journal of Mining science and Technology 2024年第1期34卷 65-76页

作者： Bei Jiang Fenglin Ma Qi Wang Hongke Gao Dahu Zhai Yusong Deng Chuanjie Xu Liangdi Yao State Key Laboratory for Tunnel Engineering China University of Mining and Technology-BeijingBeijing 100083China State Key Laboratory of Explosion Science and Technology Beijing Institute of TechnologyBeijing 100081China Research Center of Geotechnical and Structural Engineering Shandong UniversityJinan 250061China

The technology of drilling tests makes it possible to obtain the strength parameter of rock accurately in situ. In this paper, a new rock cutting analysis model that considers the influence of the rock crushing zone(RCZ) is built. The formula for an ultimate cutting force is established based on the limit equilibrium principle. The relationship between digital drilling parameters(DDP) and the c-φ parameter(DDP-cφ formula, where c refers to the cohesion and φ refers to the internal friction angle) is derived, and the response of drilling parameters and cutting ratio to the strength parameters is analyzed. The drillingbased measuring method for the c-φ parameter of rock is constructed. The laboratory verification test is then completed, and the difference in results between the drilling test and the compression test is less than 6%. On this basis, in-situ rock drilling tests in a traffic tunnel and a coal mine roadway are carried out, and the strength parameters of the surrounding rock are effectively tested. The average difference ratio of the results is less than 11%, which verifies the effectiveness of the proposed method for obtaining the strength parameters based on digital drilling. This study provides methodological support for field testing of rock strength parameters.

关键词： Digital drilling Rock crushing zone c-u parameter Measurement method Field application

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An Improved YOLOv5s-Based Smoke Detection System for Outdoor Parking Lots

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Computers, Materials & Continua 2024年第8期80卷 3333-3349页

作者： Ruobing Zuo Xiaohan Huang Xuguo Jiao Zhenyong Zhang State Key Laboratory of Public Big Data College of Computer Science and TechnologyGuizhou UniversityGuiyang550025China School of Information and Control Engineering Qingdao University of TechnologyQingdao266520China State Key Laboratory of Industrial Control Technology College of Control Science and EngineeringZhejiang UniversityHangzhou310027China Key Laboratory of Computing Power Network and Information Security Ministry of EducationQilu University of Technology(Shandong Academy of Sciences)Jinan250353China Text Computing&Cognitive Intelligence Engineering Research Center of National Education Ministry Guizhou UniversityGuiyang550025China

In the rapidly evolving urban landscape,outdoor parking lots have become an indispensable part of the city’s transportation *** growth of parking lots has raised the likelihood of spontaneous vehicle combus-tion,a significant safety hazard,making smoke detection an essential preventative ***,the complex environment of outdoor parking lots presents additional challenges for smoke detection,which necessitates the development of more advanced and reliable smoke detection *** paper addresses this concern and presents a novel smoke detection technique designed for the demanding environment of outdoor parking ***,we develop a novel dataset to fill the gap,as there is a lack of publicly available *** dataset encompasses a wide range of smoke and fire scenarios,enhanced with data augmentation to ensure robustness against diverse outdoor ***,we utilize an optimized YOLOv5s model,integrated with the Squeeze-and-Excitation Network(SENet)attention mechanism,to significantly improve detection accuracy while maintaining real-time processing ***,this paper implements an outdoor smoke detection system that is capable of accurately localizing and alerting in real time,enhancing the effectiveness and reliability of emergency *** show that the system has a high accuracy in terms of detecting smoke incidents in outdoor scenarios.

关键词： YOLOv5s smoke detection deep learning SENet

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A comprehensive review of deactivation and modification of selective catalytic reaction catalysts installed in cement kilns

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Journal of Environmental sciences 2025年第2期148卷 451-467页

作者： Yang Zheng Yi Xing Guoliang Li Jiajia Gao Rui Li Qi Liu Tao Yue School of Energy and Environmental Engineering University of Science and Technology BeijingBeijing 100083China State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China

After the ultralow emission transformation of coal-fired power plants,cement production became China’s leading industrial emission source of nitrogen *** gas dust contents at the outlet of cement kiln preheaters were as high as 80-100 g/m^(3),and the calcium oxide content in the dust exceeded 60%.Commercial V_(2)O_(5)(-WO_(3))/TiO_(2) catalysts suitable for coal-fired flue gas suffer from alkaline earth metal Ca poisoning of cement kiln flue *** studies have also identified the poisoning of cement kiln selective catalytic reaction(SCR)catalysts by the heavy metals lead and *** of the poisoning process is the primary basis for analyzing the catalytic *** review summarizes and analyzes the SCR catalytic mechanism and chronicles the research progress concerning this poisoning *** on the catalytic and toxification mechanisms,it can be inferred that improving the anti-poisoning performance of a catalyst enhances its acidity,surface redox performance-active catalytic sites,and shell layer *** data provide support in guiding engineering practice and reducing operating costs of SCR ***,future research directions for SCR denitrification catalysts in the cement industry are *** study provides critical support for the development and optimization of poisoning-resistant SCR denitrification catalysts.

关键词： Cement Flue Gas NH_(3)-SCR CaO Poisoning Mechanism Anti-poisoning Modification

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engineering oxygen vacancies on Tb-doped ceria supported Pt catalyst for hydrogen production through steam reforming of long-chain hydrocarbon fuels

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Chinese Journal of Chemical engineering 2024年第4期68卷 181-192页

作者： Zhourong Xiao Changxuan Zhang Peng Li Desong Wang Xiangwen Zhang Li Wang Jijun Zou Guozhu Li State Key Laboratory of Metastable Materials Science and Technology(MMST) Hebei Key Laboratory of Applied ChemistryCollege of Environmental and Chemical EngineeringYanshan UniversityQinhuangdao 066004China Key Laboratory for Green Chemical Technology of Ministry of Education School of Chemical Engineering and TechnologyTianjin UniversityTianjin 300072China

Steam reforming of long-chain hydrocarbon fuels for hydrogen production has received great attention for thermal management of the hypersonic vehicle and fuel-cell *** this work,Pt catalysts supported on CeO_(2)and Tb-doped CeO_(2)were prepared by a precipitation *** physical structure and chemical properties of the as-prepared catalysts were characterized by powder X-ray diffraction,scanning electron microscopy,transmission electron microscopy,Raman spectroscopy,H_(2)temperature programmed reduction,and X-ray photoelectron *** results show that Tb-doped CeO_(2)supported Pt possesses abundant surface oxygen vacancies,good inhibition of ceria sintering,and strong metal-support interaction compared with CeO_(2)supported *** catalytic performance of hydrogen production via steam reforming of long-chain hydrocarbon fuels(n-dodecane)was *** with 2Pt/CeO_(2),2Pt/Ce_(0.9)Tb_(0.1)O_(2),and 2Pt/Ce_(0.5)Tb_(0.5)O_(2),the 2Pt/Ce_(0.7)Tb_(0.3)O_(2)has higher activity and stability for hydrogen production,on which the conversion of n-dodecane was maintained at about 53.2%after 600 min reaction under 700℃at liquid space velocity of 9 ml·g^(-1)·h^(-1).2Pt/CeO_(2)rapidly deactivated,the conversion of n-dodecane was reduced to only 41.6%after 600 min.

关键词： Steam reforming n-Dodecane Hydrogen production Pt-based catalyst Oxygen vacancy CeO_(2)

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Heteroatom anchors Fe-Mn dual-atom catalysts with bi-functional oxygen catalytic activity for low-temperature rechargeable flexible Zn-air batteries

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Journal of Energy Chemistry 2024年第3期90卷 610-620,I0014页

作者： Yuting He Hongtao Li Yi Wang Yufei Jia Yongning Liu Qiang Tan State Key Laboratory for Mechanical Behaviour of Materials School of Materials Science&EngineeringXi’an Jiaotong UniversityXi’an 710049ShaanxiChina

M-N-C(M=Fe,Co,Ni,etc.) catalyst owns high catalytic activity in the oxygen catalytic reaction which is the most likely to replace the Pt-based *** it is still a challenge to further increase the active site *** article constructs the high-efficiency FeMn-N/S-C-1000 catalyst to realize ORR/OER bifunctional catalysis by hetero-atom,bimetal(Fe,Mn) doped simultaneously *** evaluated it as bi-functional electro-catalysts,FeMn-N/S-C-1000 exhibits excellent catalytic activity(E_(1/2)=0.924 V,E_(j=10)=1.617 V) in alkaline media,outperforms conventional Pt/C,RuO_(2) and most non-precious-metal catalysts reported recently,Such outstanding performance is owing to N,S co-coordinated with metal to form multi-types of single atom,dual atom active sites to carry out ***,nitrite poison test provides the proof that the active sites of FeMn-N/S-C are more than that of single-atom catalysts to promote catalytic reactions *** better understand the local structure of Fe and Mn active sites,XAS and DFT were employed to reveal that FeMn-N_5/S-C site plays the key role during ***,the FeMn-N/S-C-1000 based low-temperature rechargeable flexible Zn-air also exhibits superior discharge performance and extraordinary durability at-40℃.This work will provide a new idea to design diatomic catalysts applied in low-temperature rechargeable batteries.

关键词： Fe Mn-N/S-C-1000 ORR OER Rechargeable flexible Zn-air batteries

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High thermal conductivity dielectric polymers show record high capacitive performance at high temperatures

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National science Review 2023年第11期10卷 85-86页

作者： Yang Shen Ce-Wen Nan School of Materials Science and Engineering State Key Laboratory of New Ceramics and Fine Processing Tsinghua University

Electrostatic capacitors are the most widely used components in modern electrical and electronic systems ranging from integrated circuits, electrical energy storage and pulsed power *** are the preferred dielectrics for electrostatic capacitors owing to their unique self-healing ability, high breakdown strength and ease of processing[1,2]. However, as the operating temperature increases, dielectric polymers exhibit substantially increased conduction loss,

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Polyaniline spaced MoS_(2)nanosheets with increased interlayer distances for constructing high-rate dual-ion batteries

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Journal of Materials science & Technology 2024年第15期182卷 220-230页

作者： Xuhui Liu Xingdong Ma Guoshun Liu Xiaobin Zhang Xiaoqi Tang Chao Li Xiaobei Zang Ning Cao Qingguo Shao School of Materials Science and Engineering State Key Laboratory of Heavy Oil ProcessingChina University of Petroleum(East China)Qingdao 266580China

Dual-ion batteries(DIBs)have attracted great attention due to their affordable prices,environmentalfriendliness,and high operating ***,the conventional graphite anode in DIBs has draw-backs such as unsatisfactory capacity and worrying ***_(2)is considered to be a competitive anodematerial that exhibits large capacity due to its unique layered structure for cation insertion/***,the sluggish reaction kinetics of MoS_(2)does not match the cathode side,which makes theconstructed full DIBs show poor rate ***,a flower-like MoS_(2)/polyaniline composite electrode(MoS_(2)-PANI)where PANI was grown in situ between layers of MoS_(2)nanosheets was *** thisdesign,the inserted PANI can broaden the layer distance of MoS_(2)to facilitate cation diffusion and pre-vent the restacking of ***,PANI is also expected to increase the conductivity andrelieve the volume changes during repeated charge/discharge *** from that,the MoS_(2)-PANIelectrode delivered a reversible capacity of 561.91 mA h g^(-1) at 5 A g^(-1) in half-cell ***,whencoupled with a mildly expanded graphite(MEG)cathode,the obtained MEG//MoS_(2)-PANI DIB shows ex-cellent rate ability with a reversible discharge capacity of 86.62 mA h g^(-1) and a desirable energy densityof 308.83 W h kg-1 at 20 *** results provide some inspiration for the design of high-rate DIBs.

关键词： Dual-ion Battery Anode materials MoS_(2) High rate performance

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π-conjugated chromophore functionalized high-nuclearity titanium-oxo clusters containing structural unit of anatase for photocatalytic selective oxidation of sulfides

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Rare Metals 2024年第4期43卷 1736-1746页

作者： Ling-Rong Liao Dong-Chun Zheng Pin-Xi Ou Qi-Xin Zhao Wei-Min Xuan Qi Zheng State Key Laboratory for Modification of Chemical Fibers and Polymer Materials&College of Materials Science and Engineering Donghua UniversityShanghai201620China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials and College of Chemistry and Chemical Engineering Donghua UniversityShanghai 201620China

N-doping has significant influence in manipulating the properties of TiO_(2),and this has stimulated the development of N-donor-functionalized titanium-oxo clusters(TOCs)as molecular models to study the structure-property ***,the structural type and photoresponsive application are still limited for such TOCs,especially regarding the high-nuclearity TOCs that contain structure unit of TiO_(2)for ***,we showed the synthesis of a series of high-nuclearity TOCs 1-3 compounds usingπ-conjugated 1,10-phenanthroline(phen)as chromophore and N-donor functional *** 1 features cocrystal structure composed of one[Ti_(26)]~(2+)and half[Ti_(22)]~(2+),which renders it as the first cocrystallized TOC containing two positively charged species and phen-functionalized TOC showing the highest nuclearity up to 37 Ti *** adjusting the synthetic conditions,the individual{Ti_(22)}and{Ti_(26)}clusters can also be isolated as Compounds 2 and 3,*** core structure of{Ti_(22)}is mainly constructed from four lacunary{Ti_(4)}derived from pentagonal{Ti(Ti)_5}unit,while{Ti_(26)}is built from four complete{Ti(Ti)_5}***,a{Ti_8O_(14)}structure unit of anatase TiO_(2)can be identified in{Ti_(26)}.Based on the unique structural features and proper photophysical and photochemical properties of Compounds 1-3,they are applied for photocatalytic *** to the presence of anatase structure unit in{Ti_(26)}and the synergistic effect from{Ti_(22)}and{Ti_(26)},the catalytic performance presents in the order of Compound 1>Compound 3>Compound *** work provides excellent models to understand the structureproperty relationship from the perspective of cocrystallization and Ti-O binding model and will further promote the application of TOCs as functional catalysts for organic transformation.

关键词： Titanium-oxo cluster Molecular model of anatase TiO_(2) High nuclearity π-conjugated chromophore Photocatalytic sulfoxidation

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Enhanced steelmaking cost optimization and real-time alloying element yield prediction: a ferroalloy model based on machine learning and linear programming

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Journal of Iron and Steel Research International 2025年第4期32卷 904-919页

作者： Rui-xuan Zheng Yan-ping Bao Li-hua Zhao Li-dong Xing State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing100083China School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing100083China

The production of ferroalloys is a resource-intensive and energy-consuming *** mitigate its adverse environmental effects,steel companies should implement a range of measures aiming at enhancing the utilization rate of ***,a comprehensive ferroalloy model was proposed,incorporating a prediction model for alloying element yield based on case-based reasoning and support vector machine(CBR-SVM),along with a ferroalloy batching model employing an integral linear programming *** simulation calculations,the prediction model exhibited exceptional predictive performance,with a hit rate of 96.05%within 5%.The linear programming ingredient model proved effective in reducing costs by 20.7%,which was achieved through accurate adjustments to the types and quantities of *** proposed method and system were successfully implemented in the actual production environment of a specific steel plant,operating seamlessly for six *** implementation has notably increased the product quality of the enterprise,with the control rate of high-quality products increasing from 46%to 79%,effectively diminishing the consumption and expenses associated with *** reduced usage of ferroalloys simultaneously reduces energy consumption and mitigates the adverse environmental impact of the steel industry.

关键词： Steel industry Ferroalloy Case-based reasoning Energy conservation Consumption reduction

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Extremum seeking control for UAV close formation flight via improved pigeon-inspired optimization

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science China(Technological sciences) 2024年第2期67卷 435-448页

作者： YUAN GuangSong DUAN HaiBin State Key Laboratory of Virtual Reality Technology and Systems School of Automation Science and Electrical EngineeringBeihang University(BUAA)Beijing 100083China

This paper proposes a comprehensive design scheme for the extremum seeking control(ESC)of the unmanned aerial vehicle(UAV)close formation *** proposed design scheme combines a Newton-Raphson method with an extended Kalman filter(EKF)to dynamically estimate the optimal position of the following UAV relative to the leading *** reflect the wake vortex effects reliably,the drag coefficient induced by the wake vortex is considered as a performance ***,the performance function is parameterized by the first-order and second-order terms of its Taylor series *** the excellent performance of nonlinear estimation,the EKF is used to estimate the gradient and the Hessian matrix of the parameterized performance *** output feedback of the proposed scheme is determined by iterative calculation of the Newton-Raphson *** with the traditional ESC and the classic ESC,the proposed design scheme avoids the slow continuous time integration of the *** allows a faster convergence of relative position ***,the proposed method can provide a smoother command during the seeking process as the second-order term of the performance function is taken into *** convergence analysis of the proposed design scheme is accomplished by showing that the output feedback is a supermartingale *** improve estimation performance of the EKF,a improved pigeon-inspired optimization(IPIO)is proposed to automatically tune the noise covariance *** Carlo simulations for a three-UAV close formation show that the proposed design scheme is robust to the initial position of the following UAV.

关键词： unmanned aerial vehicle close formation extremum seeking control Newton-Raphson method improved pigeon-inspired optimization

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