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Hydrometallurgical process and recovery of valuable elements for limonitic laterite:A review

Chinese Journal of Chemical engineering 2024年第9期73卷 189-201页

作者： Xinglong Xiong Baozhong Ma Xiang Li Jiancheng Yu Longfei Shi Chengyan Wang Yongqiang Chen State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing 100083China

Nickel is a strategic resource in social life and defense technology,playing an essential role in many fields,such as alloys and *** the decrease in nickel sulfide,it is of great significance to extract nickel from *** limonitic laterite is a kind of rich nickel-cobalt-scandium *** present,there are few reviews on the extraction of limonitic *** study reviews the hydrometallurgical processes for limonitic laterite ores and the methods of recovering valuable *** mineralogical characteristics are analyzed,and the typical mineral compositions are *** main hydrometallurgical processes are compared and discussed,including reduction roasting-ammonia leaching,sulfuric acid pressure leaching,nitric acid pressure leaching,and the atmospheric nitric acid leaching(DNi process).The methods of recovering nickel,cobalt,scandium,and iron are emphatically ***,reasonable suggestions are proposed for comprehensive *** study can provide a reference for industrial development and diversified applications.

关键词： Limonitic laterite Hydrometallurgy Comprehensive utilization Leaching Recovery Chemical processes

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Fabrication of bamboo-inspired continuous carbon fiber-reinforced SiC composites via dual-material thermally assisted extrusion-based 3D printing

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材料科学技术（英文版） 2025年第5期208卷 92-103页

作者： Sai Li Haitian Zhang Zhongliang Lu Fusheng Cao Ziyao Wang Yan Liu Xiaohui Zhu Shuai Ning Kai Miao Shaoyu Qiu Dichen Li State Key Laboratory for Manufacturing Systems Engineering School of Mechanical EngineeringXi'an Jiaotong UniversityXi'an 710049China State Key Laboratory for Manufacturing Systems Engineering School of Mechanical EngineeringXi'an Jiaotong UniversityXi'an 710049China School of Intelligent Manufacturing Modern Industry Xinjiang UniversityUrumqi 830046China Science and Technology on Reactor Fuel and Materials Laboratory Nuclear Power Institute of ChinaChengdu 610213China

Ceramic matrix composites(CMCs)structural components encounter the dual challenges of severe mechanical conditions and complex electromagnetic environments due to the increasing demand for stealth technology in aerospace *** address various functional requirements,this study integrates a biomimetic strategy inspired by gradient bamboo vascular bundles with a novel dual-material 3D print-ing *** distinct bamboo-inspired structural configurations Cf/SiC composites are designed and manufactured,and the effects of these different structural configurations on the CVI process are *** method is utilized to characterize the relationship between interface bonding strength and mechanical *** results reveal that the maximum flexural strength and fracture toughness reach 108.6±5.2 MPa and 16.45±1.52 MPa m1/2,respectively,attributed to the enhanced crack propagation resistance and path caused by the weak fiber-matrix ***,the bio-inspired configuration enhances the dielectric loss and conductivity loss,exhibiting a minimum reflection loss of-24.3 dB with the effective absorption band of 3.89 *** work introduces an innovative biomimetic strategy and 3D printing method for continuous fiber-reinforced ceramic composites,expanding the ap-plication of 3D printing technology in the field of CMCs.

关键词： 3D printing Cf/SiC composites Mechanical properties Electromagnetic wave absorption

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Preparation of lithium-ion battery anode materials from graphitized spent carbon cathode derived from aluminum electrolysis

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International Journal of Minerals,Metallurgy and Materials 2024年第11期31卷 2466-2475页

作者： Zhihao Zheng Mingzhuang Xie Guoqing Yu Zegang Wu Jingjing Zhong Yi Wang Hongliang Zhao Fengqin Liu State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing 100083China

Graphitized spent carbon cathode(SCC)is a hazardous solid waste generated in the aluminum electrolysis *** this study,a flotation-acid leaching process is proposed for the purification of graphitized SCC,and the use of the purified SCC as an anode material for lithium-ion batteries is *** flotation and acid leaching processes were separately optimized through one-way *** maximum SCC carbon content(93wt%)was achieved at a 90%proportion of−200-mesh flotation particle size,a slurry concentration of 10wt%,a rotation speed of 1600 r/min,and an inflatable capacity of 0.2 m^(3)/h(referred to as FSCC).In the subsequent acid leaching process,the SCC carbon content reached 99.58wt%at a leaching concentration of 5 mol/L,a leaching time of 100 min,a leaching temperature of 85°C,and an HCl/FSCC volume ratio of 5:*** purified graphitized SCC(referred to as FSCC-CL)was utilized as an anode material,and it exhibited an initial capacity of 348.2 mAh/g at 0.1 C and a reversible capacity of 347.8 mAh/g after 100 ***,compared with commercial graphite,FSCC-CL exhibited better reversibility and cycle ***,purified SCC is an important candidate for anode material,and the flotation-acid leaching purification method is suitable for the resourceful recycling of SCC.

关键词： graphitized spent carbon cathode hazardous solid waste flotation acid leaching lithium-ion batteries

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Regulation of Ti(C,N)deposition on hot surface of refractory in blast furnace hearth

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Journal of Iron and Steel Research International 2024年第6期31卷 1423-1435页

作者： Jian Cao Cui Wang Jjan-liang Zhang Ke-xin Jiao Guo-hua Zhang State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing 100083China

Ti(C,N)concentration was found to be lower on the hearth sidewall of a blast furnace and increased gradually toward the bottom of the blast *** Ti(C,N)protective layer in a blast furnace is ***,the formation of a Ti(C,N)protective layer was promoted by studying the heterogeneous nucleation principle of titanium compounds on different substances and regulation measures for the deposition process of titanium compounds on refractories or *** lattice disregistry between the titanium compounds and the main components in the refractory or the main impurities in the protective layer was calculated using a two-dimensional disregistry equation to study the heterogeneous nucleation principle of titanium *** results revealed that in refractory materials,the heterogeneous nucleation of carbonitride is weak when C,SiO_(2),and Al_(2)O_(3) are used as heterogeneous nucleation substrates,and the heterogeneous nucleation of carbonitride is strong when TiO_(2) and SiC are used as heterogeneous nucleation *** nucleation phases,TiC,TiN,Ti(C_(0.3),N_(0.7)),and Ti(C_(0.5),N_(0.5))have similar heterogeneous nucleation ability in single component refractory,and the type of carbonitride has little effect on the lattice *** impurities in the protective layer as the substrate phases are not conducive to the heterogeneous nucleation of *** CaS was used as the substrate phase,the heterogeneous nucleation ability of carbonitride was the *** carbon and alumina were not conducive to the heterogeneous nucleation of carbonitride,but carbon was more unfavourable than alumina.

关键词： Ti(C,N) Lattice disregistry Lattice constant Heterogeneous nucleation Regulation measure

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Unraveling the impacts of intermolecular interaction on morphology evolution for highly efficient organic solar cells and modules

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science China Chemistry 2025年第1期68卷 264-272页

作者： Xueqing Ma Yingying Cheng Yuqiang Liu Xinming Zheng Guangliu Ran Hongxiang Li Xinyue Cui Andong Zhang Wenkai Zhang Pei Cheng Wenchao Huang Zhishan Bo Beijing Key Laboratory of Energy Conversion and Storage Materials College of ChemistryBeijing Normal UniversityBeijing 100875China College of Textiles and Clothing State Key Laboratory of Bio-fibers and Eco-textilesQingdao UniversityQingdao 266071China Key State Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China Department of Physics and Applied Optics Beijing Area Major Laboratory Center for Advanced Quantum StudiesBeijing Normal UniversityBeijing 100875China State Key Laboratory of Polymer Materials Engineering College of Polymer Science and EngineeringSichuan UniversityChengdu 610065China

Understanding the effect of intermolecular interaction on the growth dynamic of active layers is critical for advancing organic solar cells(OSCs).However,the diverse structure of donors and acceptors makes the research *** with customizable structures and properties could simplify this ***,we meticulously tailor two additives of 3,4-ethylenedioxythiophene(EDOT)and 2,5-dibromo-3,4-ethylenedioxythiophene(DBEDOT),possessing distinct intermolecular interaction features to elaborate the inherent *** is found that varied interaction strengths can alter film formation *** enhanced intermolecular interaction between the DBEDOT and non-fullerene acceptor BTP-e C9-4F results in pre-aggregation and longer crystallization duration of BTP-e C9-4F,facilitating the formation of films with compact molecular packing and decent phase ***,exciton dissociation and charge transport become more ***,devices processed with DBEDOT exhibit a remarkable power conversion efficiency of 19.35%in small-area OSCs and 14.11%in bladecoated 5 cm×5 cm organic solar ***,OSCs can maintain 80%of their initial efficiency after continuous annealing at 85℃for over 2,100 h.

关键词： organic solar cell non-fullerene acceptor film growth molecular packing intermolecular interaction

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A closer look at the belief propagation algorithm in side-channel attack on CCA-secure PQC KEM

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science China(Information sciences) 2024年第11期67卷 317-334页

作者： Kexin QIAO Zhaoyang WANG Heng CHANG Siwei SUN Zehan WU Junjie CHENG Changhai OU An WANG Liehuang ZHU School of Cyberspace Science and Technology Beijing Institute of Technology State Key Laboratory of Cryptology School of Cryptology University of Chinese Academy of Sciences School of Cyber Science and Engineering Wuhan University

The implementation security of post-quantum cryptography(PQC) algorithms has emerged as a critical concern with the PQC standardization process reaching its end. In a side-channel-assisted chosen-ciphertext attack, the attacker builds linear inequalities on secret key components and uses the belief propagation(BP) algorithm to solve. The number of inequalities leverages the query complexity of the attack, so the fewer the better. In this paper, we use the PQC standard algorithm CRYSTALS-KYBER as a study case to construct bilateral inequalities on key variables with substantially narrower intervals using a side-channel-assisted oracle. For KYBER512, KYBER768, and KYBER1024, the average Shannon entropy carried by such inequality is improved from the previous 0.6094, 0.4734, and 0.8544 to 0.6418, 0.4777, and 1.2007. The number of such inequalities required to recover the key utilizing the BP algorithm for KYBER512 and KYBER1024 is reduced by 5.32% and 40.53% in theory and experimentally the reduction is even *** query complexity is reduced by 43%, 37%, and 48% for KYBER512, 768, and 1024 assuming reasonably perfect reliability. Furthermore, we introduce a strategy aimed at further refining the interval of *** into the BP algorithm, we discover a measure metric named JSD(Jensen-Shannon distance)-metric that can gauge the tightness of an inequality. We then develop a machine learning-based strategy to utilize the JSD-metrics to contract boundaries of inequalities even with fewer inequalities given, thus improving the entropy carried by the system of linear inequalities. This contraction strategy is at the algorithmic level and has the potential to be employed in all attacks endeavoring to establish a system of inequalities concerning key variables.

关键词： Kyber chosen-ciphertext attack side-channel belief propagation contraction strategy machine learning

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Ultralow charge-discharge voltage gap of 0.05 V in sunlight-responsive neutral aqueous Zn-air battery

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Carbon Energy 2024年第9期6卷 172-183页

作者： Zhimin Niu Yan Gao Tianhui Wu Fei Zhang Ran Zhao Zijia Chen Yiming Yuan Tifeng Jiao Jianmin Gu Li Lu Desong Wang State Key Laboratory of Metastable Materials Science and Technology(MMST) Hebei Key Laboratory of Applied ChemistryYanshan UniversityQinhuangdaoChina Department of Mechanical Engineering National University of SingaporeSingaporeSingapore School of Sciences Hebei University of Science and TechnologyShijiazhuangChina

Rechargeable neutral aqueous zinc-air batteries(ZABs)are a promising type of energy storage device with longer operating life and less corrosiveness compared with conventional alkaline ***,the neutral ZABs normally possess poor oxygen evolution reactions(OERs)and oxygen reduction reactions performance,resulting in a large charge–discharge voltage gap and low round-trip ***,we demonstrate a sunlight-assisted strategy for achieving an ultralow voltage gap of 0.05 V in neutral ZABs by using the FeOOH-decorated BiVO4(Fe-BiVO_(4))as an oxygen *** sunlight,the electrons move from the valence band(VB)of Fe-BiVO_(4) to the conduction band producing holes in VB to promote the OER process and hence reduce the ***,the photopotential generated by the Fe-BiVO_(4) compensates a part of the charging potential of neutral ***,the energy loss of the battery could be compensated via solar energy,leading to a record-low gap of 0.05 V between the charge and discharge voltage with a high round-trip efficiency of 94%.This work offers a simple but efficient pathway for solar-energy utilization in storage devices,further guiding the design of high energy efficiency of neutral aqueous ZABs.

关键词： neutral ZABs oxygen catalytic reactions photocatalysis round-trip efficiency solar energy

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“Blocking and rebalance”mechanism-guided design strategies of bimetallic doped 2D a-phosphorus carbide as efficient catalysts for N_(2) electroreduction

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Journal of Energy Chemistry 2024年第10期97卷 68-78,I0003页

作者： Cheng He Jianglong Ma Shen Xi Wenxue Zhang State Key Laboratory for Mechanical Behavior of Materials School of Materials Science and EngineeringXi'an Jiaotong UniversityXian 710049ShanxiChina School of Materials Science and Engineering Chang'an UniversityXi'an 710064ShaanxiChina

Compared to single atom catalysts(SACs),the introduction of dual atom catalysts(DACs)has a significantly positive effect on improving the efficiency in the electrocatalytic nitrogen reduction reaction(NRR)which provides an environmental alternative to the Haber-Bosch ***,the research on the mechanism and strategy of designing bimetallic combinations for better performance is still in its early ***,based on"blocking and rebalance"mechanism,45 combinations of bimetallic pair dopedα-phosphorus carbide(TM_(A)TM_(B)@PC)are investigated as efficient NRR catalysts through density functional theory and machine learning *** a multi-step screening,the combinations of TiV,TiFe,MnMo,and FeW exhibit highly efficient catalytic performance with significantly lower limiting potentials(-0.17,-0.18,-0.14,and-0.30 V,respectively).Excitingly,the limiting potential for CrMo and CrW combinations is 0 V,which are considered to be extremely suitable for the NRR *** mechanism of"blocking and rebalance"is revealed by the exploration of charge transfer for phosphorus atoms in electron blocking ***,the descriptorφis proposed with machine learning,which provides design strategies and accurate prediction for finding efficient *** work not only offers promising catalysts TM_(A)TM_(B)@PC for NRR process but also provides design strategies by presenting the descriptorφ.

关键词： DACs Nitrogen reduction reaction 2D a-phosphorus carbide Inherent attributes Machine learning

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Boron nitride silicone rubber composite foam with low dielectric and high thermal conductivity

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Chinese Journal of Chemical engineering 2024年第4期68卷 224-230页

作者： Shuilai Qiu Hang Wu Fukai Chu Lei Song College of Safety and Ocean Engineering China University of Petroleum-BeijingBeijing 102249China State Key Laboratory of Fire Science University of Science and Technology of ChinaHefei 230026China

Silicone rubber(SR)is widely used in the field of electronic packaging because of its low dielectric *** this work,the porosity of the SR was improved,and the dielectric constant of the SR foam was reduced by adding expanded microspheres(EM).Then,the thermal conductivity of the system was improved by combining the modified boron nitride(f-BN).The results showed that after the f-BN was added,the dielectric constant and dielectric loss were much lower than those of pure ***-sized modified boron nitride(f-mBN)improved the dielectric and thermal conductivity of the SR foam better than that of nano-sized modified boron nitride(f-nBN),but f-nBN improved the volume resistivity,tensile strength,and thermal stability of the SR better than *** the mass ratio of f-mBN and fnBN is 2:1,the thermal conductivity of the SR foam reaches the maximum value of 0.808 W·m^(-1)·K^(-1),which is 6.5 times that before the *** heat release rate and fire growth index are the lowest,and the improvement in flame retardancy is mainly attributed to the high thermal stability and physical barrier of f-BN.

关键词： Foam Composites Dielectric properties Thermal conductivity Mechanical properties Flame retardant

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Molecular Dynamics Simulation of Shock Response of CL-20 Co-crystals Containing Void Defects

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Defence Technology（防务技术） 2024年第1期31卷 364-374页

作者： Changlin Li Wei Yang Qiang Gan Yajun Wang Lin Liang Wenbo Zhang Shuangfei Zhu Changgen Feng State Key Laboratory of Explosion Science and Technology Beijing Institute of TechnologyBeijing 100081China School of Materials Science&Engineering Beijing Institute of TechnologyBeijing 100081China

To investigate the effect of void defects on the shock response of hexanitrohexaazaisowurtzitane(CL-20)co-crystals,shock responses of CL-20 co-crystals with energetic materials ligands trinitrotoluene(TNT),1,3-dinitrobenzene(DNB),solvents ligands dimethyl carbonate(DMC) and gamma-butyrolactone(GBL)with void were simulated,using molecular dynamics method and reactive force *** is found that the CL-20 co-crystals with void defects will form hot spots when impacted,significantly affecting the decomposition of molecules around the *** degree of molecular fragmentation is relatively low under the reflection velocity of 2 km/s,and the main reactions are the formation of dimer and the shedding of nitro *** existence of voids reduces the safety of CL-20 co-crystals,which induced the sensitivity of energetic co-crystals CL-20/TNT and CL-20/DNB to increase more *** has occurred under the reflection velocity of 4 km/s,energetic co-crystals are easier to polymerize than solvent co-crystals,and are not obviously affected by *** results show that the energy of the wave decreases after sweeping over the void,which reduces the chemical reaction frequency downstream of the void and affects the detonation performance,especially the solvent co-crystals.

关键词： CL-20 co-crystals Molecular dynamics simulation Reactive forcefield Impact response Hot spot Void defect

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