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Enhancement of weathered crust elution-deposited rare earth ores leaching process with PQ-10 addition

Journal of Rare Earths 2025年第1期43卷 180-190,I0007页

作者： Aoyang Sha Huifang Yang Zhengyan He Zhigao Xu Chenjie Wu Ming Wu Ru'an Chi Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education Key Laboratory of Resources Conversion and Pollution Control of the State Ethnic Affairs Commission&Hubei Key Laboratory of Catalysis and Materials ScienceCollege of Resources and Environmental ScienceSouth-Central Minzu UniversityWuhan430074China Key Laboratory for Green Chemical Process of Ministry of Education School of Resources&Safety EngineeringWuhan Institute of TechnologyWuhan 430073China

To solve the problems of the long development period,low mass transfer efficiency and high impurity conte nt in the in-situ leaching process of weathe red crust elution-deposited rare earth ores(WCE-DREO),cationic hydroxyethyl cellulose(PQ-10)was composited with conventional leaching agent ammonium sulfate((NH_(4))_(2)SO_(4))to form a novel composite leaching *** effects of PQ-10 concentration,leaching temperature and leaching flow rate of the composite leaching agent on the leaching kinetics and mass transfer processes of rare earth(RE)and aluminum(Al)were *** to the single leaching agent(NH_(4))_(2)SO_(4),the composite leaching agent(2 wt%(NH_(4))_(2)SO_(4)+0.02 wt%PQ-10)can reduce the RE leaching equilibrium time from 465 to 130 min and increase the RE leaching efficiency and decrease the Al leaching *** also facilitates the leaching process of WCE-DREO by increasing the peak concentrations of RE and Al,reducing the theoretical tower plate height(HETP)and improving the leaching mass transfer *** is indicated that PQ-10 can promote the leaching of *** leaching process of the composite leaching system conforms to the diffusion kinetic control *** the PQ-10 concentration is in the range of 0.005 wt%-0.020 wt%,the reaction orders of RE and Al are 0.73 and 0.54,respectively,which shows a positive effect on the leaching velocity;when the PQ-10 concentration is in the range of 0.030 wt%-0.060 wt%,the reaction orders of RE and Al are-1.16 and-0.75,respectively,which show a negative effect on the leaching *** the range of 10-50℃,the apparent activation energies of RE and Al are 15.02 and 17.31 kJ/mol,respectively,and the higher the leaching temperature,the smaller the HETP and the higher the leaching velocity and mass transfer *** increase in leaching flow rate contributes to the increase in the longitudinal diffusion velocity of the leaching agent within WCE-DREO,causing a shorter time for RE

关键词： Cationic hydroxyethyl cellulose Weathered crust elution-deposited rare earthores Leaching Novel compositeagent

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Effective approaches for enhancing the stability of ruthenium-based electrocatalysts towards acidic oxygen evolution reaction

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Chinese Chemical Letters 2024年第10期35卷 126-138页

作者： Qiyan Wu Ruixin Zhou Zhangyi Yao Tanyuan Wang Qing Li State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan430074China

Water splitting with proton exchange membrane water electrolyzers(PEMWE)is regarded as a promising pathway for sustainable hydrogen ***,oxygen evolution reaction(OER)is considered as the dominant factor during the whole process due to the sluggish *** the catalysts,Rubased catalysts draw special attention because of their excellent activity and relatively low ***,the limited stability impedes their further commercialization and tremendous efforts have been devoted to overcome this *** review firstly introduces the basic mechanisms of *** the evaluation protocols and techniques to investigate the stability of Ru-based catalysts are summarized.A detailed elucidation of the possible degradation mechanisms is also critically ***,effective strategies to design durable Ru-based catalysts for acidic OER are *** as heteroatom doping,phase and facet engineering,heterostructure building and support ***,promises,perspectives and challenges in developing highly durable Ru-based catalysts for acidic OER are outlined.

关键词： Acidic oxygen evolution Ru-based catalysts Stability Degradation mechanisms Optimization strategies

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Chemical Synthesis of Globo H and Mannobiose Glycopolymers and their Immunological Stimulation

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Chinese Journal of Polymer science 2024年第11期42卷 1661-1667,I0007页

作者： Zhi Zhang Ce-Ce Xue Ying-Le Feng Guo-Song Chen The State Key Laboratory of Molecular Engineering of Polymers and Department of Macromolecular Science Fudan UniversityShanghai200433China School of Chemistry and Chemical Engineering Shaanxi Normal UniversityXi’an710119China

Tumor-associated carbohydrate antigens(TACAs)provide a special class of tumor-specific antigens that show promising applications in cancer ***,the weak immunogenicity and structural complexity of TACAs are obstacles to their clinical ***,based on a fast and low-cost purification strategy for oligosaccharide synthesis,the synthesis of tumour-associated carbohydrate antigens Globo H and mannobiose which resembles repeat unit of mannan was *** enhance the immunogenicity and multivalent effect,Globo H and mannobiose were covalently attached to degradable polymer backbones.2D spindle-like lamellar micelle and globular micelle were obtained from glycopolymer through a solvent-exchange method of *** glyconanoparticle showed good biocompatibility and *** functions of these glyconanoparticles such as stimulation of BMDC to cause upregulation of inflammatory factors were preliminarily explored.

关键词： Globo-H Mannobiose Glycopolymer Convergent Synthesis Tumor-associated carbohydrate antigens

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Accurately predicting hypersonic transitional flow on cone via a symmetry approach

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Chinese Journal of Aeronautics 2023年第7期36卷 337-347页

作者： Weitao BI Kexin ZHENG Zhou WEI Zhensu SHE State Key Laboratory for Turbulence and Complex Systems and Department of Mechanics and Engineering Science College of EngineeringPeking UniversityBeijing 100871China State Key Laboratory of Aerodynamics and Computational Aerodynamics Institute China Aerodynamics Research and Development CenterMianyang 621000China

A new algebraic transition model is proposed based on a Structural Ensemble Dynamics(SED)theory of wall turbulence,for accurately predicting the hypersonic flow heat transfer on *** model defines the eddy viscosity in terms of a two-dimensional multi-regime distribution of a Stress Length(SL)function,and hence is named as *** paper presents clear evidence of precise predictions of transition onset location and peak heat flux of a wide range of hypersonic Transitional Boundary Layers(TrBL)around straight cone at zero incidence,to an unprecedented accuracy as validated by over 70 measurements for varying five crucial influential factors(Mach number,temperature ratio,cone half angle,nose Reynolds number and noise level).The results demonstrate the universality of the postulated multi-regime similarity structure,in characterizing not only the spatial non-uniform distribution of the eddy viscosity in hypersonic TrBL on cone,but also the dependence of the transition onset location on the five influential *** latter yields a novel correlation formula for transition center Reynolds number which takes similar functional form as the SL function within the symmetry *** is concluded that the SED-SL model simulates TrBL around cone with uniformly high accuracy,and then points out to an optimistic alternative way to construct hypersonic transition model.

关键词： Cones Heat flux Hypersonic boundary layers Transition flow Turbulence models

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Hybrid data-driven and physics-based modeling for viscosity prediction of ionic liquids

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Green Energy & Environment 2024年第12期9卷 1878-1890页

作者： Jing Fan Zhengxing Dai Jian Cao Liwen Mu Xiaoyan Ji Xiaohua Lu State Key Laboratory of Materials-Oriented and Chemical Engineering Nanjing Tech UniversityNanjing211816China Energy Engineering Division of Energy ScienceLulea University of TechnologyLulea97187Sweden

Viscosity is one of the most important fundamental properties of ***,accurate acquisition of viscosity for ionic liquids(ILs)remains a critical *** this study,an approach integrating prior physical knowledge into the machine learning(ML)model was proposed to predict the viscosity *** method was based on 16 quantum chemical descriptors determined from the first principles calculations and used as the input of the ML models to represent the size,structure,and interactions of the *** strategies based on the residuals of the COSMO-RS model were created as the output of ML,where the strategy directly using experimental data was also studied for *** performance of six ML algorithms was compared in all strategies,and the CatBoost model was identified as the optimal *** strategies employing the relative deviations were superior to that using the absolute deviation,and the relative ratio revealed the systematic prediction error of the COSMO-RS *** CatBoost model based on the relative ratio achieved the highest prediction accuracy on the test set(R^(2)=0.9999,MAE=0.0325),reducing the average absolute relative deviation(AARD)in modeling from 52.45% to 1.54%.Features importance analysis indicated the average energy correction,solvation-free energy,and polarity moment were the key influencing the systematic deviation.

关键词： Viscosity Fundamental property Ionic liquids COSMO-RS Machine learning

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Characterization of the interfacial structure and fracture behavior of in situ synthesized ceramics to reinforce Ni-based composite coatings

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材料科学技术（英文版） 2025年第5期208卷 11-25页

作者： Yuxin Wang Yanchun Dong Yun Tian Jianing Liu Dongyao Zhang Chunli Qiu Yanqi Zhao Yong Yang School of Materials Science and Engineering Hebei University of TechnologyTianjin 300132China Key Lab.for New Type of Functional Materials in Hebei Province School of Materials Science and EngineeringState Key Laboratory of Reliability and Intelligence of Electrical EquipmentHebei University of TechnologyTianjin 300132China

This work used the in-situ synthesis of molten-state nitride ceramic phase-reinforced Ni-based alloy coat-ings,aiming to improve the phase-interface bonding through the interdependent co-solidification be-tween molten *** XRD was used to analyze the physical phases of the composite *** microstructure and phase-interface structure were characterized in detail by combining SEM,TEM,HRTEM,FFT,and SAED *** tester and microforce microhardness tester were em-ployed to measure the surface hardness and elastic modulus of the composite *** fracture be-havior of the composite coatings was characterized by observing the fracture morphology of the coatings using SEM combined with the EDS *** was found that the formation mechanisms of inter-facial misfit dislocation assistance,lattice distortion,aggregation of stacking faults,and specific growth orientation between the y-Ni matrix phase and each ceramic phase in NiCrBSi-TiCrN composite coat-ings improved the lattice matching between the two-phase interface,which resulted in the formation of atomically corresponding coherent lattice relations and stepped interfacial semi-coherent lattice relations,and enhanced the degree of phase-interface *** this basis,the composite coatings with high Cr content further inhibited the expansion of interphase penetration cracks due to the existence of Cr-rich zones at the phase interface,thus exhibiting high fracture *** work provides new opinions on the improvement of phase-interface bonding and composition design of Ni-based composite coatings.

关键词： In situ synthesis NiCrBSi-TiCrN composite coating Phase interface Fracture behavior

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Micro/nano flow chemistry by Beyond Limits Manufacturing

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Chinese Chemical Letters 2024年第5期35卷 3-12页

作者： Peiwen Liu Fang Zhao Jing Zhang Yunpeng Bai Jinxing Ye Bo Bao Xinggui Zhou Li Zhang Changlu Zhou Xinhai Yu Peng Zuo Jianye Xia Lian Cen Yangyang Yang Guoyue Shi Lin Xu Weiping Zhu Yufang Xu Xuhong Qian State Key Laboratory of Bioreactor Engineering Shanghai Key Laboratory of Chemical BiologySchool of PharmacyEast China University of Science and TechnologyShanghai 200237China State Key Laboratory of Chemical Engineering School of Chemical EngineeringEast China University of Science and TechnologyShanghai 200237China State Key Laboratory of Bioreactor Engineering Shanghai Collaborative Innovation Center for BiomanufacturingEast China University of Science and TechnologyShanghai 200237China School of Biomedical and Pharmaceutical Sciences Guangdong University of TechnologyGuangzhou 510006China School of Mechanical and Power Engineering East China University of Science and TechnologyShanghai 200237China Shanghai Key Laboratory of Green Chemistry and Chemical Processes Department of ChemistrySchool of Chemistry and Molecular EngineeringEast China Normal UniversityShanghai 200241China

In September 2018,we proposed the cutting-edge concept of“Beyond Limits Manufacturing”(BLM).BLM technology is based on the three-dimensional inner engraving or precise outer engraving of ultra-fast laser,to invent micro/nano scale flow chips or devices,which makes it possible for the microform,integration,economy,safety,high efficiency,green and intelligence of research,development and manufacturing process,so as to realize transformational manufacturing in the era of Industry *** this paper,we reviewed the representative results we made in the field of micro/nano flow chemistry during the implementation of the BLM major project(December 2019 to August 2023),and discussed its application prospects in micro/nano flow chemistry.

关键词： Beyond Limits Manufacturing Flow chemistry Pharmaceutical manufacturing Microreactor

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Fabrication and characterization of mullite fiber-based porous ceramics with mixed fiber lengths for high-temperature gas filtration

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Ceramics International 2025年第17期51卷 23214-23223页

作者： Zheng, Dazhi Zhu, Ruijian Hu, Yuwen Liang, Shiou Sun, Huiying Wang, Zengmei State Key Laboratory of Engineering Materials for Major Infrastructure Jiangsu Key Lab. of Construction Materials School of Materials Science and Engineering Southeast University Nanjing211189 China School of Materials Science and Engineering Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology Nanjing Institute of Technology Nanjing211167 China

The emissions and particulate pollutants (PM) from industrialization and other human activities have become a significant threat to human health. Researchers have experimented with various fiber-bonded filters, but there are still relatively few products with good high-temperature resistance. In this paper, a fiber-bonded porous ceramic with high porosity was prepared by vacuum filtration combined with freeze-drying using two homemade mullite fibers with different length-to-diameter ratios as raw materials and mullite sol as binder. When the content of fine fibers is 40 %, the product has a better overall performance, its density is 0.63g/cm3, porosity is 74 %, strength is 0.77 MPa, thermal conductivity is 0.153 W m−1 K−1. When the airflow rate of 2 L/min, the pressure drop is 80 Pa, the filtration efficiency of about 99 %, the QF is 0.08 pa−1, The mullite fiber-bonded porous ceramics prepared through a simple process exhibit excellent filtration performance, offering a wide range of potential applications. © 2025

关键词： Thermal conductivity of gases

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Enzymatic self-assembly/disassembly turns “ON”/“OFF” the mimetic hydrolytic activity of histidine nanofibers

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science China Chemistry 2024年第2期67卷 517-522页

作者： Xianbao Sun Manli Wang Xiaoyang Liu Wenjun Zhan Guangqiong Xu Qiaochu Jiang Hai-Dong Xu Fuqiang Wang Gaolin Liang State Key Laboratory of Digital Medical Engineering School of Biological Science and Medical EngineeringSoutheast UniversityNanjing210096China Analysis Center Nanjing Medical UniversityNanjing210029China

Mimetic enzymes are devised as alternates or supplements of natural enzymes in broad fields but regulating their activities in a switchable manner remains ***,we proposed an enzymatic self-assembly/disassembly strategy to address this issue.A peptide molecule Nap FFEYIH(YH) was rationally designed which,after self-assembling into nanofibers,lined up the histidine moieties to form active hydrolysis centers for mimicking hydrolase *** dephosphorylation of Nap FFEYp IH(Yp H) by alkaline phosphatase to yield YH also turned “ON” the hydrolase *** turn,phosphorylation of YH by phosphokinase epidermal growth factor receptor to yield Yp H disassembled the nanofibers and thus turned the activity “OFF”.As such,the “ON”/“OFF” of the mimetic hydrolase activities could be regulated under physiological conditions through ALP/EGFR-mediated self-assembly/disassembly of histidine *** work provides a feasible strategy for the on-demand fabrication of artificial enzymes with controllable and superior activities.

关键词： disassembly hydrolytic activity mimetic enzyme phosphorylation self-assembly

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TS-GGNN: Combining Graph and Sequence Features for Vulnerability Detection in Source Code 5

TS-GGNN: Combining Graph and Sequence Features for Vulnerabi...

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5th International Conference on Communications, Information System and Computer engineering, CISCE 2023

作者： Zhou, Xin Pang, Jianmin Zhang, Chunyan Yue, Feng Wang, Junchao Liu, Guangming State Key Laboratory of Mathematical Engineering and Advanced Computing Zhengzhou China

ISBN: (纸本)9798350326796

Software vulnerability detection is crucial for maintaining the security and stability of software systems. In this paper, we propose a novel neural network model called TS-GGNN to address the problem of vulnerability detection in source code slices. The TS-GGNN model effectively captures both local and global features of vulnerable code by fusing sequence features with graph features. To achieve this, we utilize graph structure and sequence structure learning approaches to comprehensively extract valuable information from the source code slices. Our experiments are conducted on the SARD dataset, which consists of 61,638 code samples annotated for the presence or absence of vulnerabilities. The results demonstrate that TS-GGNN has the best vulnerability detection performance, with an accuracy of 99.4%, a precision of 98.81%, and an F1 score as high as 99.4% thereby validating the effectiveness of the TS-GGNN model in capturing features relevant to software vulnerabilities. © 2023 IEEE.

关键词： Network coding

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