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Constructing heterostructures of ZIF-67 derived C,N doped Co_(2)P and Ti_(2)VC_(2)T_(x)MXene for enhanced OER

Journal of Materials science & Technology 2023年第14期145卷 74-82页

作者： Jinzhou Li Chao Chen Zepeng Lv Wansen Ma Meng Wang Qian Li Jie Dang College of Materials Science and Engineering Chongqing UniversityChongqing 400044China College of Materials Science and Engineering Taiyuan University of TechnologyTaiyuan 030024China State Key Laboratory of Advanced Special Steels&Shanghai Key Laboratory of Advanced Ferrometallurgy School of Materials Science and EngineeringShanghai UniversityShanghai 200444China

Oxygen evolution reaction(OER)is central to technologies such as electrochemical water splitting,and developing efficient and low-cost non-precious metal electrocatalysts for OER is of great significance to reducing cell voltage and developing hydrogen production by electrochemical water ***,we prepared a carbon,nitrogen co-doped porous Co_(2)P derived from the metal-organic framework(ZIF-67),which is anchored on bimetallic MXene nanosheets(named MX@MOF-Co_(2)P).It was used as the OER catalyst and exhibited great electrocatalytic performance with very small overpotentials(246 mV at 10 mA^(-2)and 407 mV at 200 mA cm^(-2))as well as ultralow Tafel slope(28.18 mV dec^(-1)).Combining charac-terizations and theoretical calculations,it was found that the remarkable performance was from follows:the obtained MX@MOF-Co_(2)P inherited the porous structure of the pristine MOF with a large number of open active sites;carbon and nitrogen doping also modulated the electronic structure of the active center;the synergistic effect between cobalt phosphide and MXenes booted the electronic *** work represents a promising strategy for the development of non-precious metal catalysts derived from metal-organic frameworks to achieve efficient energy conversion.

关键词： Mxene mof doping cobalt phosphide electrocatalysts

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Digital CEOs in Digital Enterprises:Automating,Augmenting,and Parallel in Metaverse/CPSS/TAOs

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IEEE/CAA Journal of Automatica Sinica 2024年第4期11卷 820-823页

作者： Juanjuan Li Rui Qin Sangtian Guan Xiao Xue Peng Zhu Fei-Yue Wang with State Key Laboratory of Multimodal Artificial Intelligence Systems Institute of AutomationChinese Academy of SciencesBeijing 100190China the College of Intelligence and Computing Tianjin UniversityTianjin 300072China School of Economics and Management Nanjing University of Science and TechnologyNanjing 210094China the State Key Laboratory for Management and Control of Complex Systems Chinese Academy of SciencesBeijing 100190 Faculty of Innovation Engineering Macao University of Science and TechnologyMacao 999078China

BIG models or foundation models are rapidly emerging as a key force in advancing intelligent societies[1]–[3]Their significance stems not only from their exceptional ability to process complex data and simulate advan... 详细信息

关键词： exceptional Auto advancing

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Li-air batteries:air stability of lithium metal anodes

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science China Chemistry 2024年第1期67卷 122-136页

作者： Renfei Cao Kai Chen Jianwei Liu Gang Huang Wanqiang Liu Xinbo Zhang School of Materials Science and Engineering Changchun University of Science and TechnologyChangchun 130022China State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied ChemistryChangchun 130022China

Aprotic rechargeable lithium-air batteries(LABs)with an ultrahigh theoretical energy density(3,500 Wh kg^(-1))are known as the‘holy grail’of energy storage systems and could replace Li-ion batteries as the next-generation high-capacity batteries if a practical device could be ***,only a few researches focus on the battery performance and reactions in the ambient air environment,which is a major obstacle to promote the practical application of ***,we have summarized the recent research progress on LABs,especially with respect to the Li metal *** chemical and electrochemical deteriorations of the Li metal anode under the ambient air are discussed in detail,and the parasitic reactions involving the cathode and electrolyte during the charge-discharge processes are *** also provide stability perspectives on protecting the Li metal anodes and propose design principles for realizing high-performance LABs.

关键词： parasitic reaction lithium metal anode anode protection Li-air batteries

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CO_(2)-gasification of corncob in a molten salt environment

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Chinese Journal of Chemical engineering 2025年第2期78卷 58-66页

作者： Zhiying Feng Kaifeng Liu Tao Zhu Dongfang Li Xing Zhu State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization Faculty of Metallurgical and Energy EngineeringKunming University of Science and TechnologyKunming 650093China

Molten salt gasification is a promising technology for biomass conversion due to its advantages of superior heat transfer and the ability of utilizing solar energy to reduce carbon *** this study,the characteristics of corncob CO_(2)-gasification in molten salt environments is thoroughly investigated,and the approach of introducing Fe_(2)O_(3) as catalyst to enhance the syngas yield is *** results showed that the molten salts significantly promoted the conversion of corncob into gaseous products with very low tar and char *** to O_(2) and H_(2)O atmospheres,utilizing CO_(2) as gasifying agent enhanced the yield of gaseous products during the corncob gasification,especially the yields of CO and H_(2).The introduction of Fe_(2)O_(3) as a catalyst could further increase the yield of gaseous products and the cold gas efficiency(CGE),and the yield of syngas was increased into 2258.3 ml·g^(−1) with a high CGE of 105.8%in 900℃.The findings evidenced that CO_(2) gasification in the molten salt environment with Fe_(2)O_(3) addition can promote the cracking of tar,increasing the syngas yield ***,the energy required to drive the gasification process was calculated,and the total energy consumption was calculated as 16.83 GJ·t^(−1).The study opened up a new solution for the biomass gasification,exhibiting a great potential in distributed energy or chemical systems.

关键词： Molten carbonate Biomass gasification Transition metal oxides Energy consumption

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Experimental study on the influence of roadway shape on the evolution of outburst fluid static pressure

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International Journal of Coal science & Technology 2024年第4期11卷 274-289页

作者： Jiang Xu Xiaomei Wang Liang Cheng Shoujian Peng Hailin Yang Bin Zhou Feng Jiao State Key Laboratory of Coal Mine Disaster Dynamics and Control Chongqing UniversityChongqing 400030China College of Safety Science and Engineering Xian University of Science and TechnologyXian 710054ShaanxiChina

To explore the static pressure dynamic disaster mechanism of coal-and-gas outburst(CGO)fluid,the self-developed multifield coupling large-scale physical simulation test system of coal mine dynamic disaster was used to carry out gas outburst and CGO physical simulation tests in straight,L-shaped and T-shaped *** influence of roadway shape on the evolution of static pressure was explored,and the role of pulverized coal in the process of static pressure dynamic disaster was *** results indicated that the static pressure showed a fluctuating downward trend during the outburst *** gas outburst,the middle and front parts of the roadway in the straight section roadway were the most serious areas of static pressure disasters in the three shapes of *** duration and range of high static pressure disaster in L-shaped roadway were larger than those in T-shaped and straight roadways in *** CGO,the most serious area of static pressure disaster in L-shaped and T-shaped roadways moved backward to the middle of the straight section roadway,and there was a rebound phenomenon in the process of static pressure fluctuation decline,which showed the pulse characteristics of *** the outburst,the static pressure dynamic disaster hazard of L-shaped roadway was higher than that of T-shaped roadway,and the static pressure at the bifurcation structure decayed faster than that at the turning structure,which indicated that T-shaped roadway was more conducive to the release of static pressure in roadway,thus reduced the risk of static pressure *** gas outburst,the static pressure attenuation of the fuid in the roadway before and after the turning and bifurcation structure was greater than that of *** peak static pressure and impulse of the fluid during gas outburst were 2 times and 4-5 times that of CGO *** presence of pulverized coal reduced the attenuation of static pressure and the hazard of dynamic disaster,prolonged

关键词： Gas outburst Coal-and-gas outburst.Static pressure Roadway shape Dynamic disaster.Outburst fluid

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Solar evaporation for simultaneous oil-water separation and electricity generation with Janus wood-based absorbers

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Frontiers of Environmental science & engineering 2024年第2期18卷 13-23页

作者： Yue Yang Ze Fu Qi Zhang Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse School of Environmental and Biological EngineeringNanjing University of Science&TechnologyNanjing 210094China Key Laboratory of Industrial Ecology and Environmental Engineering(Ministry of Education) School of Environmental Science and TechnologyDalian University of TechnologyDalian 116024China National Laboratory of Solid State Microstructures Collaborative Innovation Center of Advanced MicrostructuresCollege of Engineering and Applied SciencesKey Laboratory of Intelligent Optical Sensing and Manipulation(Ministry of Education)Jiangsu Key Laboratory of Artificial Functional MaterialsNanjing UniversityNanjing 210093China

Oily wastewater from ocean oil spills endangers marine ecosystems and human health. Therefore, developing an effective and sustainable solution for separating oil-water mixtures is urgent. Interfacial solar photothermal evaporation is a promising approach for the complete separation of two-phase mixtures using only solar energy. Herein, we report a carbonized wood-based absorber with Janus structure of comprising a hydrophobic top-layer and an oleophobic bottom-layer for simultaneous solar-driven oil-water separation and electricity generation. Under sunlight irradiation, the rapid evaporation of seawater will induce a separation of oil-water mixtures, and cause a high salt concentration region underlying the interface, while the bottom “bulk water” maintains in a low salt concentration, thus forming a salinity gradient. Electricity can be generated by salinity gradient power. Therefore, oil-water separation efficiency of > 99% and derived extra electricity power of ~0.1 W/m2 is achieved under solar radiation, demonstrating the feasibility of oil-water separation and electricity production synchronously directly using solar energy. This work provides a green and cost-effective path for the separation of oil-water mixtures.

关键词： Oily wastewater Carbonized wood Salinity gradient Electricity generation Solar irradiation

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Flexible nanocomposite electrodes with optimized hybrid structure for improved low-grade heat harvest via thermocells

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science China Chemistry 2023年第6期66卷 1814-1823页

作者： Ziwei Mo Jiaqian Zhou Xin Lu Lirong Liang Fusheng Liu Zhuoxin Liu Guangming Chen College of Materials Science and Engineering Shenzhen UniversityShenzhen 518055China State Key Laboratory of Polymer Materials Engineering Sichuan UniversityChengdu 610065China

Thermal energy is ubiquitous and constantly generated in nature and ***(TECs)represent a promising energyconversion technology that can directly translate thermal energy into electricity with a large thermopower,thus having attracted considerable attention in recent ***,the use of noble platinum electrodes in TECs has substantially limited their widespread applications,as the scarcity of platinum element increases the cost of materials,and its intrinsic rigidity is not conducive to flexible and wearable applications under heat sources with complex surface ***,we propose a facile hybridizing route to constructing flexible electrodes with optimized *** flexible composite electrode is fabricated by decorating a single-walled carbon nanotube network with conducting polypyrrole nanospheres through controlled electrochemical *** refined interfacial nanostructures,the resultant composite film can facilitate carrier transport/transfer at the electrolyte-electrode interface,and thereby shows superior overall thermoelectrochemical performance to noble platinum *** TEC employing the flexible composite electrodes yields a maximum output power of 2.555μW under the temperature difference of 30 K,and a device comprising 6 TEC units is assembled to efficiently utilize waste heat and human body heat,revealing the high potential of low-grade heat harvesting.

关键词： nanocomposites thermocells carbon nanotubes polymers

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A Review on Particle Reinforced Mg Matrix Composites Fabricated by Powder Metallurgy

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Acta Metallurgica Sinica(English Letters) 2024年第3期37卷 391-400页

作者： Zhiyuan Liu Li Jin Jian Zeng Fulin Wang Fenghua Wang Shuai Dong Jie Dong National Engineering Research Center of Light Alloy Net Forming and State Key Laboratory of Metal Matrix Composite School of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai 200240China

This paper provides a comprehensive review of research progress in particle-reinforced Mg matrix composites prepared via powder *** article discusses different strategies,such as micro-sized,nano-sized particles,and multi-particle hybridization,which has been employed to enhance the performance of the *** addition,a range of preparation techniques that optimize the dispersion of the reinforcing particles are *** paper also highlights how the different configurations between the reinforcements and matrix alloy impact the composites’***,the article outlines the prospects of particles reinforced Mg matrix composites fabricated via powder metallurgy and recommends modification methods that could be explored to further develop these materials for various applications.

关键词： Magnesium matrix composites Reinforcing particle Powder metallurgy Mechanical properties Configuration

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Research on Improving the Thermal Conductivity of Epoxy Resin with Flexible Assisted Rigid Groups

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Chinese Journal of Polymer science 2024年第11期42卷 1845-1854,I0015页

作者： Hong-Yu Zhu Yan-Ji Zhu Di Bao Lu-Chao Pei Fei Xu Zhe Wang Huai-Yuan Wang School of Materials Science and Engineering Tianjin UniversityTianjin300050China Collaborative Innovation Centre of Chemical Science and Engineering(Tianjin) Tianjin UniversityTianjin300072China Tianjin Key Laboratory of Chemical Process Safety and Equipment Technology Tianjin UniversityTianjin300072China School of Chemical Engineering and Technology and State Key Laboratory for Chemical Engineering Tianjin UniversityTianjin300350China

Epoxy resins are cross-linked polymeric materials with typically low thermal ***,the introduction of rigid groups into epoxy resins is the main method to improve their intrinsic thermal *** researchers explored the relationship between the flexible chains of epoxy monomers and the thermal conductivity of the modified epoxy resins(MEP).The effect of flexible chain length on the introduction of rigid groups into the cross-linked structure of epoxy is worth investigating,which is of great significance for the improvement of thermal conductivity of polymers and related *** prepared a small molecule liquid crystal(SMLC)containing a long flexible chain via a simple synthesis reaction,and introduced rigid mesocrystalline units into the epoxy resin via a curing *** high-temperature curing,the introduced mesocrystalline units underwent orientational stacking and were immobilized within the *** and TGA tests showed that the ordering within the modified epoxy resin was increased,which improved the thermal conductivity of the epoxy ***,during the above process,the flexible chains of SMLC provide space for the biphenyl groups to align and therefore affect the thermal conductivity of the ***,the MEP-Ⅵcured with SMLC-Ⅵcontaining six carbon atoms in the flexible chain has the highest thermal conductivity of 0.40W·m^(-1)·K^(-1),which is 125%of the thermal conductivity of SMLC-IV of 0.32 W·m^(-1)·K^(-1),111%of the thermal conductivity of SMLC-Ⅷof 0.36W·m^(-1)·K^(-1),and 182%of the thermal conductivity of pure epoxy of 0.22 W·m^(-1)·K^(-1).The introduction of appropriate length flexible chains for SMLC promotes the stacking of rigid groups within the resin while reducing the occurrence of chain *** study will provide new ideas for the enhancement of thermal conductivity of cross-linked polymeric materials.

关键词： Epoxy Resin Polymer Thermal conductivity Rigid group Flexible chain

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A comprehensive review on catalysts for seawater electrolysis

Advanced Powder Materials

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Advanced Powder Materials 2024年第5期3卷 111-134页

作者： Jihong Li Genyuan Fu Xiaokun Sheng Guodong Li Hui Chen Kaiqian Shu Yan Dong Tongzhou Wang Yida Deng State Key Laboratory of Marine Resource Utilization in South China Sea School of Materials Science and Engineering Hainan UniversityHaikou570228China State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of ChemistryJilin UniversityChangchun130012China State Key Laboratory of Environment-Friendly Energy Materials School of Materials Science and EngineeringSouthwest University of Science and TechnologyMianyang621010China Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjin300071China

Seawater electrolysis is a sustainable energy conversion technology that generates clean energy by splitting seawater into hydrogen and ***,the catalysts used in seawater electrolysis often face significant stability challenges because of the high concentration of salt ions and other impurities present in *** review aims to discern the pivotal factors influencing catalyst stability in seawater electrolysis,elucidate the corrosion and electrochemical degradation mechanisms,and delve into the various strategies employed to enhance catalyst *** strategies encompass catalyst material selection,surface modification techniques,catalyst support materials,and catalyst design *** gaining deeper insights into the obstacles and innovations concerning catalyst stability in seawater electrolysis,this review strives to expedite progress toward the commercialization and widespread adoption of this technology as a renewable and feasible approach for hydrogen ***,the goal is to foster a cleaner and more sustainable future by enabling the efficient and enduring generation of hydrogen from seawater.

关键词： Seawater electrolysis Green hydrogen Stability Catalyst corrosion Selectivity

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