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Nano-TiO_(2) coate d nee dle carbon fib er reinforced phenolic aerogel composite with low density, excellent heat-insulating and infrared radiation shielding performance

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Journal of Materials science & technology 2023年第21期152卷 181-189页

作者： Yiwu Pan Xiangyu Jin Hebing Wang He Huang Can Wu Xiaojie Yan Changqing Hong Xinghong Zhang National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Harbin Institute of TechnologyHarbin 150001China

High-performance thermal protection materials(TPMs)for spacecraft are becoming current research *** polymer-based ablators are considered to be the most promising candidates for TPMs due to their excellent designability and *** this study,a unique nano-TiO_(2) coated needled carbon fiber felt/phenolic resin aerogel composite(TiCF/PR)is *** the anatase nano-TiO_(2) was in-situ coated on the surface of carbon fibers uniformly through the sol-gel and calcination method,then,the phenolic resin aerogel was in-situ synthesized in the nano-TiO_(2) coated needled carbon fiber felt(TiCF)preform through vacuum impregnation and solvothermal *** as-prepared aerogel com-posite possesses a low density(0.30–0.32 g/cm^(3)),low thermal conductivity(0.034 and 0.312 W/(m K)in the z and xy directions),and excellent thermal stability with 13.86%residual weight at 1300℃ in *** is worthwhile to note that the TiCF/PR composite exhibits excellent antioxidant ablation and infrared(IR)radiation shielding properties in a high-temperature heating *** an oxygen-acetylene blaze heating of 1.5 MW/m^(2) for 150 s,the linear ablation rates decreased by 13.4%,and the backside temperature reduced from 322.3 to 179.1℃ compared to that of the sample without nano-TiO_(2) *** experimental and theoretical analysis showed that the present TiCF/PR nanocomposite has competitive and potential application prospects in the field of future TPMs.

关键词： Carbon fiber Opacifier Mechanical properties Thermal properties Ablation performance

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Multifunctional Nacre‑Like Nanocomposite Papers for Electromagnetic Interference Shielding via Heterocyclic Aramid/MXene Template‑Assisted In‑Situ Polypyrrole Assembly

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Nano-Micro Letters 2025年第3期17卷 37-54页

作者： Jinhua Xiong Xu Zhao Zonglin Liu He Chen Qian Yan Huanxin Lian Yunxiang Chen Qingyu Peng Xiaodong He National Key Laboratory of Science and Technology On Advanced Composites in Special Environments Center for Composite Materials and StructuresHarbin Institute of TechnologyHarbin 150080People’s Republic of China

Robust, ultra-flexible, and multifunctional MXene-basedelectromagnetic interference (EMI) shielding nanocomposite filmsexhibit enormous potential for applications in artificial intelligence,wireless telecommunication, and portable/wearable electronic *** this work, a nacre-inspired multifunctional heterocyclic aramid(HA)/MXene@polypyrrole (PPy) (HMP) nanocomposite paper withlarge-scale, high strength, super toughness, and excellent tolerance tocomplex conditions is fabricated through the strategy of HA/MXenehydrogel template-assisted in-situ assembly of PPy. Benefiting from the"brick-and-mortar" layered structure and the strong hydrogen-bondinginteractions among MXene, HA, and PPy, the paper exhibits remarkable mechanical performances, including high tensile strength (309.7 MPa),outstanding toughness (57.6 MJ m−3), exceptional foldability, and structural stability against ultrasonication. By using the template effect ofHA/MXene to guide the assembly of conductive polymers, the synthesized paper obtains excellent electronic conductivity. More importantly,the highly continuous conductive path enables the nanocomposite paper to achieve a splendid EMI shielding effectiveness (EMI SE) of 54.1 dBat an ultra-thin thickness (25.4 μm) and a high specific EMI SE of 17,204.7 dB cm2g−1. In addition, the papers also have excellent applicationsin electromagnetic protection, electro-/photothermal de-icing, thermal therapy, and fire safety. These findings broaden the ideas for developinghigh-performance and multifunctional MXene-based films with enormous application potential in EMI shielding and thermal management.

关键词： MXene Remarkable mechanical properties Heterocyclic aramid Electromagnetic interference shielding Polypyrrole Multifunctionality

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Polyarylacetylene as a novel graphitizable precursor for fabricating high-density C/C composite via ultra-high pressure impregnation and carbonization

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Journal of Materials science & technology 2024年第15期182卷 198-209页

作者： Jiaxin Feng Ping Hu Yuan Cheng Yiming Wang Nan Qu Lu Zheng Liancai Xun Chi Zhang Guangdong Zhao Xinghong Zhang National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Harbin Institute of TechnologyHarbin 150001China School of Materials Science and Engineering Harbin Institute of TechnologyHarbin 150001China

High-density carbon/carbon(C/C)composite plays a critical role in the aerospace industry owing to excellent mechanical properties and resistance to ***,traditional manufacturing relies on pitch precursor and hot isostatic pressure impregnation and carbonization(HIPIC)technology,which is time-consuming and *** this study,we report an innovative method utilizing polyarylacetylene(PAA)resin and ultra-high pressure impregnation and carbonization(UHPIC)*** extremely high char yield of PAA resin(85 wt.%)and high isotropic pressure of UHPIC(over 200 MPa)promote the densification of the *** a result,we achieve a high-density(1.90 g/cm^(3))C/C composite with a high degree of graphitization(81%).This composite exhibits impressive properties,including flexural strength of 146 MPa,compressive strength of 187 MPa,and thermal conductivity of 147 W/(m K).When exposed to oxyacetylene flame at 3000 K for 100 s,it displays minimal linear ablation,with a rate of 1.27×10^(-2)mm/*** study demonstrates the exceptional graphitizable characteristic of PAA resin,setting it apart from conventional *** time-saving and cost-effective approach holds significant promise for aerospace applications,particularly in harsh aerodynamic heating environments.

关键词： C/C composite Resistance to ablation Polyarylacetylene Ultra-high pressure impregnation and carbonization Graphitization

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Anti-stacking synthesis of MXene-reduced graphene oxide sponges for aqueous zinc-ion hybrid supercapacitor with improved performance

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Journal of Materials science & technology 2023年第23期154卷 22-29页

作者： Zonglin Liu Fuhua Xue Xu Zhao Zhong Chen Haowen Zheng Renjie Ding Pengyang Li Liangliang Xu Jinhua Xiong Qingyu Peng Xiaodong He National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Center for Composite Materials and StructuresHarbin Institute of TechnologyHarbin 150080China

Two‑dimensional MXenes with an enormous active surface area are considered to be significant cathode materials for Zn‑ion hybrid supercapacitors. However, the nanosheets are easily self-restacked during the assembly into macroscopic porous electrodes, resulting in a significantly reduced effective surface area, hindering their applications in energy storage. Here, MXenes are subtly distributed on the surface of the sponge in a coral-like structure rather than participating in the assembly of the framework, which has suppressed the self-restacking of MXene effectively, improved the hydrophilicity of the sponge, and provided fast diffusion channels for electrolyte ions. Therefore, the MXene-TiC-reduced graphene oxide sponge exhibits excellent electrical conductivity, an enormous specific surface area with abundant accessible electroactive sites, and superior electrochemical performance. The resulting sponge demonstrates an outstanding specific capacity, up to 501 mAh g–1 at 0.2 A g–1 , with excellent capacity retention (90%) after 3100 cycles as Zinc-ion hybrid supercapacitor cathodes. Furthermore, it exhibits an elegant gravimetric energy density of 486 mWh g–1 at 415 mW g–1 , which has surpassed most leading MXene-based Zn-ion cathodes. This work provides a new synthetic idea for MXene-based macro-composites and paves a new avenue for designing next-generation flexible and portable porous electrodes with high gravimetric and rate performances.

关键词： MXene Porous binder-free electrode Zinc-ion hybrid supercapacitors In-situ synthesis Self-restacking

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Ultra-fast synthesis and thermodynamic analysis of MoAlB by self-propagating high-temperature combustion synthesis

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Journal of advanced Ceramics 2023年第2期12卷 258-267页

作者： Hang YIN Xiaodong HE Guangping SONG Yongdong YU Yongting ZHENG Yuelei BAI National Key Laboratory of Science and Technology on Advanced Composites in Special Environments and Centre for Composite Materials and Structures Harbin Institute of TechnologyHarbin 150080China

MoAlB as a typical member of MAB phases has attracted much-growing attention due to its unique ***,the low production of MoAlB powders limits its further development and potential *** the present work,the ultra-fast preparation of high-purity MoAlB powders in a few seconds is achieved by self-propagating high-temperature synthesis(SHS)using a raw powder mixture at an atomic ratio of Mo:Al:B=1:1.3:*** reaction mechanism is obtained by analyzing the corresponding composition changes of starting ***,the thermodynamic prediction for the SHS reaction is consistent with the present experiments,where the preparation of MoAlB also conforms to two common self-propagating conditions of the *** enthalpy *** curve shows that the adiabatic temperature of the reaction decreases with the amount of excuse Al increasing but increases when pre-heating the ***,this thermodynamic calculation provides a new idea for the preparation of other MAB phases by the SHS.

关键词： MoAlB MAB phases combustion synthesis thermodynamics self-propagating hightemperature synthesis(SHS)

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Development of lutetium oxide continuous fibers with excellent mechanical properties

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Journal of advanced Ceramics 2023年第1期12卷 24-35页

作者： Yongshuai XIE Ying PENG Youmei WANG Dehua MA Yuan CHENG Luyi ZHU Jiecai HAN Xinghong ZHANG National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Harbin Institute of TechnologyHarbin 150001China State Key Laboratory of Crystal Materials Institute of Crystal MaterialsShandong UniversityJinan 250100China

The difficulty of reducing the diameter of lutetium oxide(Lu_(2)O_(3))continuous fibers below 50μm not only limits the flexibility of the sample but also seriously affects their application and development in high-energy *** this work,a Lu-containing precursor with high ceramic yield was used as raw material,fiberized into precursor fibers by dry *** pressure-assisted water vapor pretreatment(PAWVT)method was creatively proposed,and the effect of pretreatment temperature on the ceramization behavior of the precursor fibers was *** regulating the decomposition behavior of organic components in the precursor,the problem of fiber pulverization during heat treatment was effectively solved,and the Lu_(2)O_(3) continuous fibers with a diameter of 40μm were *** with the current reported results,the diameter was reduced by about 50%,successfully breaking through the diameter limitation of Lu_(2)O_(3) continuous *** addition,the tensile strength,elastic modulus,flexibility,and temperature resistance of Lu_(2)O_(3) continuous fibers were researched for the first *** tensile strength and elastic modulus of Lu_(2)O_(3) continuous fibers were 373.23 MPa and 31.55 GPa,*** as-obtained flexible Lu_(2)O_(3) continuous fibers with a limit radius of curvature of 3.5-4.5 mm had a temperature resistance of not lower than 1300℃,which established a solid foundation for the expansion of their application form in the field of high-energy lasers.

关键词： lutetium oxide(Lu_(2)O_(3)) continuous fibers tensile strength flexible temperature resistance

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Synergistic regulation of temperature resistance and thermal insulation performance of zirconia-based ceramic fibers

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Rare Metals 2023年第12期42卷 4189-4200页

作者： Yong-Shuai Xie Ying Peng Zhe-Zhe Deng Ze Zhu Yuan Cheng De-Hua Ma Lu-Yi Zhu Xing-Hong Zhang State Key Laboratory of Crystal Materials School of Crystal MaterialsShandong UniversityJinan 250100China National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Harbin Institute of TechnologyHarbin 150001China

ZrO_(2) fiber is a promising high-temperature resistant and heat-insulating fiber ***,the decrease in mechanical properties caused by grain growth at high temperatures seriously affects its *** to achieve the synergy of its temperature resistance and the thermal insulation performance is still the focus of the current *** this work,we started with doping inequivalent elements and studied the phase composition,temperature resistance,and thermal insulation properties of Y_(2)O_(3)-ZrO_(2) ceramic fibers by adjusting the Y/Zr molar *** results showed that Y_(2)O_(3) could enter the crystal lattice of ZrO_(2) and form a solid *** the increase in Y_(2)O_(3) content,the structure of fibers changed from a tetragonal phase to a cubic phase,and the configurational entropy of the system *** larger configuration entropy in the sample could produce a robust steric hindrance effect,inhibiting grain *** heat treatment at 1300℃,the grain size of Y_(2)Zr_(2)O_(7)(Y5Z5)fibers was only 61.8%that of Y_(0.1)Zr_(0.9)O_(1.95)(Y1Z9)*** smaller grain size made the Y5Z5 fibers still have excellent flexibility and deformation recovery performance after heat treatment at 1300℃and could still return to the original state after 85%compression or folded in *** addition,due to the larger configurational entropy,the mean free path of phonon scattering was shortened,thereby improving the thermal insulation performance of the *** short,this work achieves the synergistic effect of temperature resistance and thermal insulation properties of zirconia-based fiber materials only through simple inequivalent element doping.

关键词： Ceramics fiber ZrO_(2) Y_(2)O_(3) Thermal insulation Temperature resistance

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Lightweight quasi-layered elastic fibrous porous ceramics with high compressive stress and low thermal conductivity

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Journal of Materials science & technology 2023年第12期143卷 207-215页

作者： Ning Zhou Baosheng Xu Zhiliang Zhou Lijie Qu Yiguang Wang Wenbo Han Daining Fang National Key Laboratory of Science and Technology for National Defense on Advanced Composites in Special Environments Harbin Institute of TechnologyHarbin 150001China Institute of Advanced Structure Technology Beijing Institute of TechnologyBeijing 100081China

Fibrous porous ceramics are attractive for use as thermal insulation ***,the intrinsic brit-tleness of rigid materials has remained challenging and severely restricts their ***,we demonstrated a facile method for fabricating elastic fibrous porous ceramics(EFPCs)with high com-pressive strength and low thermal conductivity through ordinary press filtration and subsequent heat *** quasi-layered structure and the well-bonded bridging fibers between layers are the key points for the elasticity of *** advanced EFPCs exhibited low density(∼0.126 g cm^(−3)),high com-pressive stress(∼0.356 MPa),and low thermal conductivity(∼0.026 W m^(−1) K^(−1)).Compared with rigid porous fibrous materials,the EFPCs had deformability and excellent shape *** contrast to flexible materials,the EFPCs possessed high compressive stress,thus endowing them with good resistance to *** emergence of this fascinating material may provide new insights for candidate materials in thermal insulation and other fields.

关键词： Silica fiber Facile press filtration Elastic fibrous porous ceramics High compressive stress Thermal insulation

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Porous organic cages as a novel platform for second harmonic generation

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science China Chemistry 2024年第11期67卷 3669-3674页

作者： Feng Shui Yunqin Zhang Mao Yi Xiongli Liu Lin Li Shuo Zhang Yongshen Zheng Yongtao Yao Qiao Zhao Baiyan Li Xianhe Bu School of Materials Science and Engineering National Institute for Advanced MaterialsTKL of Metal and Molecule-Based Material ChemistryNankai UniversityTianjin 300350China National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Harbin Institute of TechnologyHarbin 150080China

Second harmonic generation(SHG) is one of the most extensively applied nonlinear optical phenomena. Compared to traditional inorganic SHG materials, organic SHG materials, including non-centrosymmetric small molecular crystals and organic polymers, have been extensively explored for SHG optics due to their advantageous properties, including high light-induced damage threshold, ultrafast response speed, high polarization ratio, wide transparency range, and elevated dielectric constant. However,in organic SHG materials, most small molecular crystals often show poor thermal stability(<200 ℃) due to their low molecular weight, which is an important obstacle for practical application under high temperatures. On the other hand, the difficulty in the growth of large-size crystals as well as the disorderly array of chromospheres on polymer chains associated with organic polymers have hindered their widespread application in SHG due to the requirements of processability and ***, it is significantly necessary to develop novel organic SHG material with high thermal stability, large-size crystals,excellent processability, high homogeneity, and a well SHG effect. In the contribution, we developed herein porous organic cages(POCs) as a novel platform for SHG optics. Thanks to its inherent macromolecular composition and zero-dimensional discrete structures, POCs can not only solve the instability problem of small molecule crystals but also overcome the drawbacks in growing large-size crystals for organic polymer. The obtained two POCs with chiral asymmetric centers(CPOC-R-5 and CPOCS-7) display advantageous features for SHG optics including well SHG performance, large-size crystal(5 mm×3 mm×1 mm),high thermal stability(≥250 ℃), wide transparency window(750–2,000 nm) and high polarization ratio(up to 94.5%). This work thus develops POCs as a new platform toward the construction of organic NLO materials with the potential application in sorts of SHG optics.

关键词： porous organic cages second harmonic generation novel SHG platform high thermal stability large-size single crystal

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Nanodiamond reinforced self-healing and transparent poly(urethane-urea)protective coating for scratch resistance

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International Journal of Smart and Nano Materials 2024年第1期15卷 75-94页

作者： Zhuochao Wang Wenxin Cao Chunqiang Sun Dongchao Ji Kunlong Zhao Gang Gao Xingchun Xu Yingqi Liu Tianyu Zhang Jiaqi Zhu Jiecai Han National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Harbin Institute of TechnologyHarbinChina School of future technology Harbin institute of TechnologyHarbinChina Key Laboratory of Micro-systems and Micro-structures Manufacturing Ministry of EducationHarbinChina

With increasing demand for scratch-resistant flexible electro-nics,the development of transparent coatings with good scratch resistance and self-healing properties has emerged as a key research *** this study,a high-strength self-healing poly(urethane-urea)(PUU)-based nanocomposite coating was prepared by introducing functionalized nanodiamond(ND)into a PUU matrix via solution *** PUU matrix had hard-segment repeating units and was constructed using iso-phorone diamine and isophorone *** ND particles were modifed using a silane coupling agent,3-aminopropyl-triethoxysilane,to obtain well-dispersed KH-ND ***-ND promoted microphase separation in the PU matrix,inducing the formation of dense and homogeneous hard domains that dissipated stress,prevented further crack devel-opment,and improved the mechanical properties and scratch resistance of the *** addition,the coating exhibited excellent self-healing ***-transform infrared spectroscopy,scanning electron microscopy,and atomic force microscopy were used to characterize the self-healing and hardening mechanisms of the *** environmentally friendly PUU/KH-ND coating is easy to prepare and has broad application prospects in transparent and anti-scratch coatings for flexible electronics,automobiles,and home appliances.

关键词： Nanocomposite coatings self-healing scratch resistance transparent poly(urethane-urea)

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