The effect of platinum addition on the interdiffusion behavior of gamma-Ni + gamma'-Ni3Al alloys was studied by using diffusion couples comprised of a Ni-Al-Pt alloy mated to a Ni-Al, Ni-Al-Cr, or Ni-based commerc...
The effect of platinum addition on the interdiffusion behavior of gamma-Ni + gamma'-Ni3Al alloys was studied by using diffusion couples comprised of a Ni-Al-Pt alloy mated to a Ni-Al, Ni-Al-Cr, or Ni-based commercial alloy. The commercial alloys studied were CMSX-4 and CMSX-10. Diffusion annealing was at 1150 degrees C for up to 100 hours. An Al-enriched gamma'-layer often formed in the interdiffusion zone of a given couple during diffusion annealing due to the uphill diffusion of Al. This uphill diffusion was ascribed to Pt addition decreasing the chemical activity of aluminum in the gamma + gamma', alloys. For a given diffusion couple end member, the thickening kinetics of the gamma' layer that formed increased with increasing Pt content in the Ni-Al-Pt gamma + gamma' alloy. The gamma'-layer thickening kinetics in diffusion couples with Cr showed less of a dependence on Pt concentration. Inference of a negative effect of Pt and positive effect of Cr on the Al diffusion in this system enabled explanation of the observed interdiffusion behaviors. There was no or minimal formation of detrimental topologically close-packed (TCP) phases in the interdiffusion zone of the couples with CMSX-4 or CMSX- 10. An overlay Pt-modified gamma + gamma' coating on CMSX-4 showed excellent oxidation resistance when exposed to air for 1000 hours at 1150 degrees C. Moreover, the Al content in the coating was maintained at a relatively high level due to Al replenishment from the CMSX-4 substrate.
X-ray photoelectron spectroscopy(XPS)was adopted to elucidate sorption mechanism of phenol and p-nitrophenol onto a weakly anion exchanger *** distribution of specific forms of tertiary amino group on D301 was obtaine...
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X-ray photoelectron spectroscopy(XPS)was adopted to elucidate sorption mechanism of phenol and p-nitrophenol onto a weakly anion exchanger *** distribution of specific forms of tertiary amino group on D301 was obtained and effect of free tertiary amino group on phenol sorption onto D301 was discussed. The result indicated that the percent of the protonated tertiary amine group on polymeric matrix was much lower than the reference compound N,N-dimethylbenzylamine at an identical pH value in solution due to the much lower activity degree of hydrogen ion in inner resin phase than in the external solution. Less free amino group on D301 results in less sorption capacity of phenol and p-nitrophenol in an acidic solution. Under the experimental conditions both phenol sorption onto D301 can be explained as solid extraction and the distribution coefficient varies linearly with the content of free amino group on D301.
The coating is prepared by Ti powder(diameter between 10 and 50 nm as additives of the coating)and epoxy *** the properties of corrosion/scaling of Ti nano-sized powder polymer coating are studied by XPS,infra-red sp...
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The coating is prepared by Ti powder(diameter between 10 and 50 nm as additives of the coating)and epoxy *** the properties of corrosion/scaling of Ti nano-sized powder polymer coating are studied by XPS,infra-red spectrum,X-ray diffraction,transmitting electron microscope and electrochemical impedance spectroscope(EIS),etc. Based on the study of the properties of the coating and some field tests of the coating On various industrial *** characteristics of the coating on prevention of corrosion and scaling are discussed in the paper.
The effect of platinum addition on the interdiffusion behavior of γ-Ni + γ'-Ni3Al alloys was studied by using diffusion couples comprised of a Ni-Al-Pt alloy mated to a Ni-Al, Ni-Al-Cr, or Ni-based commercial al...
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The effect of platinum addition on the interdiffusion behavior of γ-Ni + γ'-Ni3Al alloys was studied by using diffusion couples comprised of a Ni-Al-Pt alloy mated to a Ni-Al, Ni-Al-Cr, or Ni-based commercial alloy. The commercial alloys studied were CMSX-4 and CMSX-10. Diffusion annealing was at 1150°C for up to 100 hours. An Al-enriched γ'-layer often formed in the interdiffusion zone of a given couple during diffusion annealing due to the uphill diffusion of Al. This uphill diffusion was ascribed to Pt addition decreasing the chemical activity of aluminum in the γ + γ' alloys. For a given diffusion couple end member, the thickening kinetics of the γ' layer that formed increased with increasing Pt content in the Ni-Al-Pt γ + γ' alloy. The γ'-layer thickening kinetics in diffusion couples with Cr showed less of a dependence on Pt concentration. Inference of a negative effect of Pt and positive effect of Cr on the Al diffusion in this system enabled explanation of the observed interdiffusion behaviors. There was no or minimal formation of detrimental topologically close-packed (TCP) phases in the interdiffusion zone of the couples with CMSX-4 or CMSX-10. An overlay Pt-modified γ + γ' coating on CMSX-4 showed excellent oxidation resistance when exposed to air for 1000 hours at 1150°C. Moreover, the Al content in the coating was maintained at a relatively high level due to Al replenishment from the CMSX-4 substrate.
As more and more uranium mining and metallurgy facilities are facing decommissioning, studies on environmental impacts of uranium mill tailings are given much attention. It has become an important part of environmenta...
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As more and more uranium mining and metallurgy facilities are facing decommissioning, studies on environmental impacts of uranium mill tailings are given much attention. It has become an important part of environmental impact assessment of decommissioning uranium mining and metallurgy facilities. On the basis of many researches at home and abroad, this paper generalizes previous studies, presents the deficiencies existing and the research direction in the future.
The study of the radionuelide distribution in sediment is a very important aspect in environmental impact of the low level radioactive liquid waste (LLW) from coastal nuclear facilities or nuclear power plant. Even no...
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The study of the radionuelide distribution in sediment is a very important aspect in environmental impact of the low level radioactive liquid waste (LLW) from coastal nuclear facilities or nuclear power plant. Even now we do not know much about it. In this paper, a simple and useful method is put forward and it is used to estimate the nuclide distribution in sediment. The result showed that the LLW from nuclear facility or nuclear power plant will do a little harm to the sediment nearby. But the harm is not very serious. Much works have to be done before full understanding of the situation.
Abstract A bioassay system to evaluate adult cotton bollworm (CBW), Helicoverpa armigera, behavioral responses to plant volatiles was described. The system was comprised of a no-choice olfactometer, a wind tunnel, and...
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Groundwater deterioration due to enrichment with contaminants of either geogenic or anthropogenic origin has adversely affected safe water supply for drinking and irrigation, with pervasive impacts on human health and...
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Groundwater deterioration due to enrichment with contaminants of either geogenic or anthropogenic origin has adversely affected safe water supply for drinking and irrigation, with pervasive impacts on human health and ecosystem functions. However, the spatiotemporal evolution and public health effects of groundwater quality remain unclarified, posing a grand challenge for the safe and sustainable supply of global groundwater resources. This article provides a state-of-the-art review of the complexity and dynamics of groundwater quality, as well as the impacts of various groundwater substances on human health. In particular, knowledge is growing about the health impacts of key substances ranging from nutritional elements (e.g., Ca2+, Mg2+) to pollutants (e.g., heavy metals/metalloids, persistent organic pollutants, and emerging contaminants) and, further, to pathogenic microorganisms to which the human body can be exposed through multiple patterns of groundwater use. Proliferating concerns at the same time call for enhancing science-based governance directives, economic policies, and management strategies coordinating groundwater quality. We propose that safeguarding groundwater-dependent public health needs concerted efforts in source control, cross-scale rehabilitation, and social hydrology-based groundwater governance.
Brassica vegetable and oilseed crops are attacked by several different flea beetle species (Chrysomelidae: Alticini). Over the past decades, most research has focused on two Phyllotreta species, Phyllotreta striolata ...
Brassica vegetable and oilseed crops are attacked by several different flea beetle species (Chrysomelidae: Alticini). Over the past decades, most research has focused on two Phyllotreta species, Phyllotreta striolata and Phyllotreta cruciferae, which are major pests of oilseed rape in North America. More recently, and especially after the ban of neonicotinoids in the European Union, the cabbage stem flea beetle, Psylliodes chrysocephala, has become greatly important and is now considered to be the major pest of winter oilseed rape in Europe. The major challenges to flea beetle control are the prediction of population dynamics in the field, differential susceptibility to insecticides, and the lack of resistant plant cultivars and other economically viable alternative management strategies. At the same time, many fundamental aspects of flea beetle biology and ecology, which may be relevant for the development of sustainable control strategies, are not well understood. This review focuses on the interactions between flea beetles and plants and summarizes the literature on current management strategies with an emphasis on the potential for biological control in flea beetle management.
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