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Mechanically Robust and Degradable Poly(urethane-urea) Plastics Derived from Tannic Acid and Castor Oil for Enhanced Fruit Preservation

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Chinese Journal of Polymer Science 2025年第3期43卷 447-456页

作者： Hong-Yu Pan Xu Fang Yi-Xuan Li Si-Heng Li Xiang Li Jun-Qi Sun State Key Laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchun 130012China

Traditional packaging plastics derived from fossil fuels for perishable foods have caused severe environmental pollution and resource *** promote sustainable development and reduce wastage of perishable products,there is a significant challenge in developing biobased packaging plastics that offer excellent preservation,satisfactory mechanical performance,and inherent *** this study,poly(urethane-urea)(PUU)plastics are fabricated using a one-pot polyaddition reaction involving castor oil(CO),tannic acid(TA),lysine-derived ethyl 2,6-diisocyanatohexanoate(LDI),and *** resulting PUU plastics demonstrate a high breaking strength of about 32.7 MPa and a strain at break of ca.102%.Due to the reversibility of hydrogen bonds,PUU plastics can be easily shaped into various *** are non-cytotoxic and suitable for food *** a high TA content of ca.38.2 wt%,PUU plastics exhibit excellent antioxidant ***,PUU plastics show outstanding freshness preservation performance,extending the shelf life of cherry tomatoes and winter jujubes for at least 8 days at room ***,PUU plastics can autonomously degrade into non-toxic substances within ca.298 days when buried in soil.

关键词： Bio-based plastics Degradable plastics Food packaging plastics materials science

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Polymer-to-Monomers Chemically Recyclable Poly(imide-imine)Plastics with Extreme-Condition Resistance and Flame Retardancy

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Chinese Journal of Polymer Science 2024年第10期42卷 1525-1535,I0012页

作者： Zhen-Yu Wang Xiao-Kong Liu State Key Laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchun130012China

Polyimides are a family of high-tech plastics that have irreplaceable applications in the fields of aerospace,defense,and opto-electronics,but polyimides are difficult to be reprocessed and recycled at the end of their service life,resulting in a significant waste of ***,it is of great significance to develop recyclable polyimides with comparable properties to the commercial ***,we report a novel polymer-to-monomers chemically recyclable poly(imide-imine)(PtM-CR-PII)plastic,synthesized by cross-linking the amine-terminated aromatic bisimide monomer and the hexa-vanillin terminated cyclophosphazene monomer via dynamic imine *** PtM-CR-PII plastic exhibits comparable mechanical and thermal properties as well as chemical stability to the commercial *** PtM-CR-PII plastic possesses a high Young’s modulus of≈3.2 GPa and a tensile strength as high as≈108 MPa,which also exhibits high thermal stability with a glass transition temperature of≈220℃.Moreover,the PtM-CR-PII plastic exhibits outstanding waterproofness,acid/alkali-resistance,and solvent-resistance,its appearance and mechanical properties can be well maintained after long-term soaking in water,highly concentrated acid and base,and various organic ***,the cyclophosphazene moieties endow the PtM-CR-PII plastic with excellent flame *** PtM-CR-PII plastic exhibits the highest UL-94 flame-retarding rating of V-0 and a limiting oxygen index(LOI)value of 45.5%.Importantly,the PtM-CR-PII plastic can be depolymerized in an organic solvents-acid mixture medium at room temperature,allowing easy separation and recovery of both monomers in high *** recovered pure monomers can be used to regenerate new PtM-CR-PII plastics,enabling sustainable polymer-monomers-polymer circulation.

关键词： Chemical recyclability Polyimides Polyimines Dynamic imine bonds Mechanical properties Chemical stability

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Living/controlled polymerization of vinylpyridines into sequence-regulated copolymers by Lewis pair

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Science China Chemistry 2024年第8期67卷 2737-2746页

作者： Qiankun Ding Wuchao Zhao Fukuan Li Jianghua He Yuetao Zhang Department of State Key Laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchun 130012China

The poly(vinylpyridine)(PVP) based(co)polymers are of particular interest in materials science, due to their multifunctionality and diverse applications. So far, there is no report on the sequence-regulated copolymerization of vinylpyridines(VPs) and methacrylate monomer in one-step manner yet. Here we designed and synthesized a series of guanidine phosphines as Lewis base(LB), which is combined with bulky organoaluminium to construct Lewis pairs(LPs) for polymerization of VPs. The living/controlled polymerization of 4-vinylpyridine(4-VP) or 2-vinylpyridine(2-VP) can be accomplished with remarkable efficiency by such Lewis pair polymerization(LPP), furnishing polymers with high molecular weight(up to 288 kg/mol) and narrow molecular weight distribution(as low as 1.17). Mechanistic studies reveal the interaction of LPs and formation of zwitterionic intermediates, providing solid evidences to support the proposed polymerization mechanism. More importantly, by simply adjusting the LA dosage, this LPP strategy realizes the unprecedented control over the sequence regulation of 2-VP-based copolymers from gradient to block in one-step manner, regardless of the monomer ratio, which greatly expands the versatility of the LPP.

关键词： guanidine phosphine Lewis pair polymerization living/controlled polymerization vinyl pyridine sequence regulation

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Research progress in the living/controlled polymerization of(meth)acrylate monomers by Lewis pair

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Science China Chemistry 2023年第8期66卷 2256-2266页

作者： Wuchao Zhao Jianghua He Yuetao Zhang State Key Laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchun130012China

Lewis pair polymerization(LPP)has demonstrated its unique advantages,such as high activity,high stability,and adjustable variability,towards the polymerization of(meth)acrylate monomers in comparison with the other polymerization *** combination of Lewis acid(LA)and Lewis base(LB)to construct Lewis pairs(LPs)with appropriate Lewis basicity,Lewis acidity,and steric effects would significantly impact the polymerization process,including chain initiation,propagation,termination and chain transfer reaction,as well as polymerization manner of *** this feature article,we briefly review recent progress made by our research group towards the living/controlled polymerization of(meth)acrylate monomers,which were accomplished by a series of newly designed LPs,including monofunctional LPs,dual-initiating LPs and intramolecular tethered trifunctional *** article is divided into three parts:(1)the development of monofunctional living/controlled LP polymerization system;(2)the design and preparation of dual-initiating LPs in synthesizing thermoplastic elastomers;(3)the application of intramolecular trifunctional LP to the synthesis of cyclic *** developed LPPs have demonstrated their powerful capability in precise control over the molecular weight,molecular weight distribution,and monomer sequence as well as the topology of *** review will serve as a good resource or guideline for researchers currently working in the area of LPP and for those who are interested in synthesizing new materials by LPP.

关键词： frustrated Lewis pair living polymerization precision polymer synthesis sequence-controlled polymer

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Construction of metallo-complexes with 2,2′:6′,2″-terpyridine substituted triphenylamine in different modified positions and their photophysical properties

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Chinese Chemical Letters 2024年第7期35卷 301-305页

作者： Shengwen Guan Zhaotong Wei Ningxu Han Yude Wei Bin Xu Ming Wang Junjuan Shi State Key Laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchun 130012China

The stable coordinated metallo-complexes based on 2,2′:6′,2″-terpyridine(tpy)and its derivatives have been widely researched for various wide-ranging applications in photoelectronics,catalysis,sensor,photoluminescence,and so ***,the most reported studies ignored the comprehensive comparison between structures modified by different positions and ***,we design a series of metallo-complexes which were assembled with tpy substituted triphenylamine(TPA)at different positions and metal ions and explored their photophysical *** the solution state,MLE_(2)based on the 5,5″-positions modification showed the highest PLQYs and PL *** the increase of solvent polarity,MLB2exhibit the largest *** the solid state,from MLA_(2)to MLE_(2),the emission colours are gradually red-shifted from yellow to *** findings in this work may pave a new way to design functional metallo-complexes,not just for PL properties.

关键词： Metallo-complexes 2,2′:6′,2″-terpyridine Triphenylamine Different modified positions Photophysical properties

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Controlled Ring-opening(Co)Polymerization of Renewable Macrolactones by Al-based Catalysts with Different Sidearms

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Chinese Journal of Polymer Science 2023年第11期41卷 1706-1713,I0006页

作者： Wu-Chao Zhao Jing Yuan Jiang-Hua He Yue-Tao Zhang State Key Laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchun 130012China

It remains a challenging task to achieve ring-opening(co)polymerization(ROP)of ***,we synthesized a series of Al-based catalysts and systemically investigated the effect of N-containing substituent on the sidearms on ROP of ***3 possessing Nmethyl group could effectively achieve controlled ROP of pentadecalactone(PDL)and macro(di)lactone ethylene brassylate(EB)in combination with BnOH,furnishing polyethylene-like PPDL and PEB with M_(W)up to 90.3 and 321 kg/mol,*** copolymerization of PDL and small-ring lactonesε-caprolactone(e-CL)andδ-valerolactone(δ-VL)could prepare random copolyesters with tailored T_(m)in the range of 57-94℃by controlling the ratios of PDL and e-CL,*** importantly,well-defined block copolyesters could be obtained by sequential adding PDL andε-CL,δ-VL,which have been proved by GPC-MALLS,DSC and^(13)C-NMR.

关键词： Ring-opening(co)polymerization Macrolactones Polyethylene-like polymers Sidearm effect Aluminum complex

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Bulk CsPbCl_(x)Br_(3-x)(1≤x≤3)perovskite nanocrystals/polystyrene nanocomposites with controlled Rayleigh scattering for light guide plate

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Light(Science & Applications) 2023年第11期12卷 2468-2479页

作者： Chongming Liu Zhicheng Zhu Kaibo Pan Yuan Fu Kai Zhang Bai Yang State Key Laboratory of Supramolecular Structure and Materials College of ChemistryJilin University130012 ChangchunChina

Perovskite nanocrystals(PNCs)/polymer nanocomposites can combine the advantages of each other,but extremely few works can achieve the fabrication of PNCs/polymer nanocomposites by bulk *** originally adopt a two-type ligand strategy to fabricate bulk PNCs/polystyrene(PS)nanocomposites,including a new type of synthetic polymerizable *** CsPbCl_(3)PNCs/PS nanocomposites show extremely high transparency even the doping content up to 5 wt%.The high transparency can be ascribed to the Rayleigh scattering as the PNCs distribute uniformly without obvious *** on this behavior,we first exploit the potential of PNCs to serve as scatters inside light guided plate(LGP),whose surface illuminance and uniformity can be improved,and this new kind of LGP is compatible with the advanced liquid crystal display *** to the facile composition adjustment of CsPbCl_(x)Br_(3-x)(1≤x≤3)PNCs,the Rayleigh scattering behavior can also be adjusted so as to the performance of *** best-performing 5.0-inch LGP based on CsPbCl_(2.5)Br_(0.5)PNCs/PS nanocomposites shows 20.5 times higher illuminance and 1.8 times higher uniformity in display than the *** LGP based on PNCs/PS nanocomposite exhibits an enormous potential in commercialization no matter based on itself or combined with the LGP-related technology.

关键词： scattering plate nanocomposites

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Lewis Acid-catalyzed Regioselective Addition of Allenoates to Indoles for Synthesis of Bisindolylesters

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Chemical Research in Chinese Universities 2025年第1期41卷 48-58页

作者： XIE Fuyu HE Jianghua ZHANG Yuetao State Key Laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchun130012P.R.China

Indole derivatives,especially bisindolylesters,have attracted intense attention due to their important applications in medicinal chemistry and organic *** we develop a Lewis acid-catalyzed efficient and regioselective strategy to prepare a series of symmetric and unsymmetric bisindolylesters in high to excellent yields under mild *** systematic investigations,which include stoichiometric nuclear magnetic resonance(NMR)experiments and structural characterization of intermediates,have provided insights into the possible reaction mechanism for this B(C_(6)F_(5))_(3)-catalyzed addition ***,the sequential employment of Al(C_(6)F_(5))_(3)and B(C_(6)F_(5))_(3)as catalysts enabled us to successfully prepare the unsymmetric bisindolyl-compounds in one-pot two-step manner without the separation step.

关键词： B(C_(6)F_(5))_(3) Al(C_(6)F_(5))_(3) Indole Allenoate Indolylester

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A new function of photochromic spiropyran: an efficient photoinitiator for two-photon polymerization

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Light(Science & Applications) 2023年第7期12卷 1176-1177页

作者： Xuanhang Wang Bin Xu Wenjing Tian State Key Laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchunChina

Photochromic spiropyran molecule shows a brand new function for serving as an efficient photoinitiator to activate two-photon photopolymerization,thus paving the way for developing a fast 3D printing technology.

关键词： initiator function photon

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A highly reduced Mo_(74) polyoxometalate featuring high proton conductivity accessed by building block strategy

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Science China Chemistry 2024年第3期67卷 862-868页

作者： Shi-Yi Liu Xue-Xin Li Wei-Chao Chen Kui-Zhan Shao Xin-Long Wang Chao Qin Zhong-Min Su Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education Department of ChemistryNortheast Normal UniversityChangchun 130024China State Key Laboratory of Supramolecular Structure and Materials Institute of Theoretical ChemistryCollege of ChemistryJilin UniversityChangchun 130021China

Highly reduced polyoxometalates(POMs) are predicted to be used as rather high energy density materials;however,it still suffers from the limited cluster species and reduction *** we demonstrate that it is possible to employ the building block strategy to generate a highly reduced polyoxomolybdate(C_(2)H_(8)N)_(14)(NH_(4))_(4)H_(14)[Mo_(48)-ⅤMo_(26)ⅥO_(202)(OH)_(12)(SO_(4))_(6)]·46H_(2)O(Mo_(74)).The fundamental Mo-based{Mo_x}(x=4,5,and 6) building blocks,which are templated by tetra-coordinated anions{MoO_(4)}or{SO_(4)},not only lay foundation for the formation of Mo_(74) featuring an unprecedented reduction ratio of 65%,but also give rise to SBBs-mediated(secondary building blocks) supramolecular dense packing interactions among the isolated Mo_(74) clusters that are favorable for proton ***,high proton conductivity(2.04×10^(-2)S cm^(-1)) had been realized at 50℃ and 90% relative humidity,revealing one of the well-known POMs-based crystalline proton conducting *** result highlights that this building block approach possesses great potential in producing highly reduced POM systems that can achieve controllable reduced ratio and desirable properties.

关键词： polyoxometalate building block molybdenum highly reduced state proton conduction

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