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Efficient and Stable Photoassisted Lithium‑Ion Battery Enabled by Photocathode with Synergistically Boosted Carriers Dynamics

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Nano-Micro Letters 2025年第3期17卷 440-454页

作者： Zelin Ma Shiyao Wang Zhuangzhuang Ma Juan Li Luomeng Zhao Zhihuan Li Shiyuan Wang Yazhou Shuang Jiulong Wang Fang Wang Weiwei Xia Jie Jian Yibo He Junjie Wang Pengfei Guo Hongqiang Wang State Key Laboratory of Solidification Processing Center for Nano Energy MaterialsSchool of Materials Science and EngineeringNorthwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene(NPU)Xi’an 710072People’s Republic of China State Key Laboratory of Solidification Processing School of Materials Science and Engineering DepartmentNorthwestern Polytechnical UniversityXi’an 710072People’s Republic of China State Key Laboratory of Solidification Processing Center of Advanced Lubrication and Seal MaterialsSchool of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi’an 710072People’s Republic of China Research and Development Institute of Northwestern Polytechnical University in Shenzhen Shenzhen 518063People’s Republic of China Key Laboratory of Applied Surface and Colloid Chemistry Shaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringNational Ministry of EducationShaanxi Normal UniversityXi’an 710119People’s Republic of China

Efficient and stable photocathodes with versatility are of significance in photoassisted lithium-ion batteries(PLIBs),while there is always a request on fast carrier transport in electrochemical active *** work proposes a general approach of creating bulk heterojunction to boost the carrier mobility of photocathodes by simply laser assisted embedding of plasmonic *** employed in PLIBs,it was found effective for synchronously enhanced photocharge separation and transport in light charging ***,experimental photon spectroscopy,finite difference time domain method simulation and theoretical analyses demonstrate that the improved carrier dynamics are driven by the plasmonic-induced hot electron injection from metal to TiO_(2),as well as the enhanced conductivity in TiO2 matrix due to the formation of oxygen vacancies after Schottky *** from these merits,several benchmark values in performance of TiO2-based photocathode applied in PLIBs are set,including the capacity of 276 mAh g^(−1) at 0.2 A g^(−1) under illumination,photoconversion efficiency of 1.276%at 3 A g^(−1),less capacity and Columbic efficiency loss even through 200 *** results exemplify the potential of the bulk heterojunction strategy in developing highly efficient and stable photoassisted energy storage systems.

关键词： Photoassisted lithium-ion batteries Bulk heterojunction Carrier dynamics TiO2 nanofiber Plasmonic metal nanocrystals

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Promoting effect of d-band center and in-situ precipitation strategy on sulfur evolution reaction

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Journal of Energy Chemistry 2025年第5期104卷 740-748页

作者： Jun Pu Yun Tan Jiasen Yin Zihan Shen Shoujie Liu Kai Zhang Lei Zhou Yagang Yao Key Laboratory of Functional Molecular Solids Ministry of Education Anhui Provincial Engineering Laboratory for New-Energy Vehicle Battery Energy-Storage Materials College of Chemistry and Materials Science Anhui Normal University National Laboratory of Solid State Microstructures College of Engineering and Applied Sciences Jiangsu Key Laboratory of Artificial Functional Materials Collaborative Innovation Center of Advanced Microstructures Nanjing University State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences School of Materials Science and Engineering Anhui University School of Energy and Power Engineering Jiangsu University Department of Electrical Engineering Eindhoven University of Technology

The slow conversion of polyphase in lithium-sulfur （Li-S） batteries not only intensifies the shuttle effect of lithium polysulfides （LiPSs）,but also causes the continuous accumulation of inactive sulfur species,resulting in rapid capacity attenuation and sluggish dynamic ***,the promoting effect of atomic interface stress on sulfur reaction was investigated via CoFe-CoFe2O4heterogeneous nanosheets with a cavity *** strain force induced by the in-situ precipitation of Co Fe bimetallic alloy in oxide matrix increased the d-band center,which was conducive to the interaction between catalyst and Li *** sulfur cathode based on this two-dimensional （2D） nanosheet design showed an extremely high capacity of 751 mAh g-1at 4 *** with a sulfur loading of 5.55 mg cm-2,its area capacity was still as high as 7.15 mAh ***,the enhanced stability greatly improved the practical potential of Li-S batteries.

关键词： 2D nanosheets D-band center In-situ precipitation Li-S batteries Strain effect

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Effect of electrochemical hydrogen charging on the microstructure and mechanical behavior of a duplex structured Mg-8wt.%Li alloy

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Journal of Magnesium and Alloys 2025年第2期13卷 668-680页

作者： Shuo Wang Daokui Xu Baojie Wang Dongliang Wang Zhiqiang Zhang Li Liu Jie Chen Key Lab of Electromagnetic Processing of Materials Ministry of EducationNortheastern UniversityShenyang110819China Key Laboratory of Nuclear Materials and Safety Assessment Institute of Metal ResearchChinese Academy of SciencesShenyang110016China Engineering Research Center of Advanced Materials Preparing Technology Ministry of EducationNortheastern UniversityShenyang110819China Binzhou Institute of Technology BinzhouShandong Province256606China Shandong Key Laboratory of Advanced Aluminium Materials and Technology BinzhouShandong Province256606China School of Environmental and Chemical Engineering Shenyang Ligong UniversityShenyang110159China Spallation Neutron Source Science Center Dongguan523803China

In this work,through performing microstructural characterization,tensile testing and failure analysis,the influence of electrochemical hydrogen charging on the microstructure and mechanical behavior of an as-cast Mg-8wt.%Li alloy was *** revealed that after being hydrogen charged at 50 mA/cm2 for respectively 3 h,6 h and 18 h in 0.1 M NaCl solution,obvious HID occurred and the damage degree was gradually increased with the hydrogen charging *** the sample being hydrogen charged for 3 h,micro pores with the diameter ranging from 10~30µm were formed and preferentially present inα-Mg ***,micro cracks with the length ranging from 10~50µm mainly initiated inα-Mg phase,atα-Mg/β-Li interfaces and the peripheries of *** the increase of hydrogen charging time,the numbers of pores and cracks were obviously *** results revealed that the hydrogen charging can simultaneously decrease the tensile strength and ductility of the *** with the uncharged sample,the tensile yield strength,ultimate tensile strength and the elongation ratio to failure were respectively reduced by 5.7%,7.3%,31.7%for the 3h-charged sample and 24.6%,24.8%,67.0%for the 18h-charged *** analysis indicated that hydrogen charging can induce the brittle cracking of the alloy and the size of brittle cracking region being composed of quasi-cleavage facets and interfacial cracks on the fracture surfaces was increased with the hydrogen charging time.

关键词： Magnesium-lithium alloy Microstructure Hydrogen-induced damage Hydrogen embrittlement Mechanical behavior

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LaVO_(4)prepared by a high-yield method for superior catalysis to the hydrogen storage of MgH_(2)

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Journal of Magnesium and Alloys 2025年第2期13卷 613-625页

作者： Meihong Wu Mingxia Gao Shanqing Qu Yongfeng Liu Wenping Sun Xin Zhang Chu Liang Xiaoyu Zhang Yaxiong Yang Hongge Pan State Key Laboratory of Silicon and Advanced Semiconductor Materials Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province&School of Materials Science and EngineeringZhejiang UniversityHangzhou 310027PR China Institute of Science and Technology for New Energy Xi'an Technological UniversityXi'an 710021PR China Zhejiang Carbon Neutral Innovation Institute Zhejiang University of TechnologyHangzhou 310014PR China

MgH_(2)is a promising solid-state hydrogen storage ***,its high thermodynamics and sluggish kinetics hinder its practical *** strategy is effective in improving its kinetic ***,the highly efficient catalysts or additives are normally of low-yield in fabrication with high *** this work,a novel structural LaVO_(4)fabricated by a low-cost method of spraying dry followed by a calcination is used as a catalytic additive for the hydrogen storage of MgH_(2).With an optimized addition of LaVO_(4),the overall hydrogen storage performances of MgH_(2)are significantly *** onset dehydrogenation temperature of only 183℃is obtained after an initial activation of dehydrogenation and *** system can desorb 5.7 wt%H_(2)at 250℃within 10 min and maintains a dehydrogenation capacity of 5.0 wt%H_(2)after 50 *** is found that LaVO_(4)is transferred to lanthanum hydride and metallic vanadium in the initial dehydrogenation process,the former acts as a highly effective catalyst for the hydrogen storage of MgH_(2)and the latter undergoes reversible hydrogenation and dehydrogenation in the subsequent *** structural design of the catalyst and its scalable fabrication are highly valuable in realizing the practical application of catalytic strategy for the hydrogen storage of MgH_(2).

关键词： Magnesium hydride Hydrogen storage properties Catalysis,Bimetallic oxide Spray drying

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Strength and toughness mechanism of single Ti microalloyed steels

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Journal of Iron and Steel Research International 2025年第3期32卷 769-782页

作者： Yi Wang Zhi-chao Che Yu-feng Chen Shu-feng Yang Jun-fen Zhang Qi-he Xue School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing100083China State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing100083China HBIS Group Chengde Steel Company Chengde067000HebeiChina

The mechanism of strength and toughness variation in Ti microalloyed steel within the range of 0.04–0.157 wt.%was *** adding 0.13 wt.%Ti,the steel achieves higher strength while maintaining a certain level of elongation and low-temperature impact *** increasing Ti content,the grain size in the steel decreased from 17.7 to 8.9μ*** decrease in grain size is accompanied by an increase in the percentage of low-angle grain boundaries and dislocations,which act as barriers to hinder crack *** Ti microalloyed steel exhibits a 20%increase in yield strength and a 14%increase in tensile *** transformation of steel plasticity occurs when the Ti content exceeds 0.102 wt.%.The low-temperature impact toughness of the steel gradually decreases with increasing Ti *** low Ti content,the low-temperature impact toughness is reduced due to crack initiation by large-size *** high Ti content,the low-temperature impact toughness of the steel deteriorates due to several *** include the narrower tough–brittle transition zone,grain boundary embrittlement caused by small-sized grains,and the decrease in the solid solution strengthening effect.

关键词： Ti microalloyed steel Second phase Tensile property Low-temperature impact property Strengthening mechanism

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Effect of initial microstructure on microstructure evolution and mechanical properties of 0.12C martensitic steels during quenching and tempering

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Journal of Iron and Steel Research International 2025年第1期32卷 260-269页

作者： Ya-ru Wang Zi-yong Hou He Yang Jun Zhao Zhi-yuan Chang Fan-mao Meng Ling Zhang Gui-lin Wu Xiao-xu Huang State Key Laboratory of Vanadium and Titanium Resource Comprehensive Utilization Panzhihua 617000SichuanChina State Key Laboratory of Advanced Special Steel Shanghai Key Laboratory of Advanced FerrometallurgySchool of Materials Science and EngineeringShanghai UniversityShanghai 200444China International Joint Laboratory for Light Alloys(Ministry of Education) College of Materials Science and EngineeringChongqing UniversityChongqing 400044China Institute of Steel Technology for Automobile and Household Appliance Pangang Group Co.Ltd.Panzhihua 617000SichuanChina ATB Motor(Shanghai)Co. Ltd.Keen International CenterShanghai 200041China Beijing Advanced Innovation Center for Materials Genome Engineering University of Science and Technology BeijingBeijing 100083China

The microstructure evolution and mechanical properties of a Fe-0.12C-0.2Si-1.6Mn-0.3Cr-0.0025B(wt.%)steel with different initial microstructures,i.e.,hot rolled(HR)and cold rolled-annealed(CRA),were studied through optical microscopy,scanning electron microscopy,electron channeling contrast imaging,microhardness and room temperature uniaxial tensile *** water quenching from 930℃ to room temperature,a fully martensitic microstructure was obtained in both as-quenched HR and CRA specimens,which shows a microhardness of 480±5 HV,and no significant difference in microstructure and microhardness was *** test results show that the product of tensile strength and total elongation(UTS×TE)of the as-quenched HR specimen,i.e.,24.1 GPa%,is higher than that of the as-quenched CRA specimen,i.e.,18.9 GPa%.While,after being tempered at 300℃,the martensitic microstructures and mechanical properties of the two as-quenched specimens change significantly due to the synergy role of the matrix phase softening and the precipitation *** the maximum UTS×TE,it is 18.9 GPa%obtained in the as-quenched CRA one,while that is 24.4 GPa%obtained in the HR specimen after tempered at 300℃ for 5 min.

关键词： Initial microstructure Lath martensite Quenching Tempering Mechanical property

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Plasma-assisted fabrication of multiscale materials for electrochemical energy conversion and storage

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Carbon Energy 2025年第2期7卷 144-171页

作者： Chen Li Tengfei Zhang Zhong Qiu Beirong Ye Xinqi Liang Xin Liu Minghua Chen Xinhui Xia Chen Wang Wangjun Wan Yongqi Zhang Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengduChina Key Laboratory of Engineering Dielectric and Applications(Ministry of Education) School of Electrical and Electronic EngineeringHarbin University of Science and TechnologyHarbinChina State Key Laboratory of New Textile Materials and Advanced Processing Technology Wuhan Textile UniversityWuhanChina College of Materials Science and Engineering Zhejiang University of TechnologyHangzhouChina School of Materials Science and Engineering Zhejiang UniversityHangzhouChina Zhejiang Academy of Science and Technology for Inspection and Quarantine HangzhouChina

Plasma,the fourth state of matter,is characterized by the presence of charged particles,including ions and *** has been shown to induce unique physical and chemical ***,there have been increased applications of plasma technology in the field of multiscale functional materials'preparation,with a number of interesting *** review will begin by introducing the basic knowledge of plasma,including the definition,typical parameters,and classification of plasma *** this,we will provide a comprehensive review and summary of the applications(phase conversion,doping,deposition,etching,exfoliation,and surface treatment)of plasma in common energy conversion and storage systems,such as electrocatalytic conversion of small molecules,batteries,fuel cells,and *** article summarizes the structure-performance relationships of electrochemical energy conversion and storage materials(ECSMs)that have been prepared or modified by *** also provides an overview of the challenges and perspectives of plasma technology,which could lead to a new approach for designing and modifying electrode materials in ECSMs.

关键词： electrocatalysts energy conversion and storage nanomaterials plasma

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Role of iron ore in enhancing gasification of iron coke:Structural evolution,influence mechanism and kinetic analysis

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 58-69页

作者： Jie Wang Wei Wang Xuheng Chen Junfang Bao Qiuyue Hao Heng Zheng Runsheng Xu School of Chemistry and Materials Science Hubei Engineering UniversityXiaogan 432000China Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education Wuhan University of Science and TechnologyWuhan 430081China Institue of Ironmaking Technology Baosteel Central Research InstituteShanghai 201999China State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China

The utilization of iron coke provides a green pathway for low-carbon *** uncover the influence mechanism of iron ore on the behavior and kinetics of iron coke gasification,the effect of iron ore on the microstructure of iron coke was ***,a comparative study of the gasification reactions between iron coke and coke was conducted through non-isothermal thermogravimetric *** findings indicate that compared to coke,iron coke exhibits an augmentation in micropores and specific surface area,and the micropores further extend and *** provides more adsorption sites for CO_(2) molecules during the gasification process,resulting in a reduction in the initial gasification temperature of iron *** the heating rate in non-isothermal gasification can enhance the reactivity of iron *** metallic iron reduced from iron ore is embedded in the carbon matrix,reducing the orderliness of the carbon structure,which is primarily responsible for the heightened reactivity of the carbon *** kinetic study indicates that the random pore model can effectively represent the gasification process of iron coke due to its rich pore ***,as the proportion of iron ore increases,the activation energy for the carbon gasification gradually decreases,from 246.2 kJ/mol for coke to 192.5 kJ/mol for iron coke 15wt%.

关键词： low-carbon ironmaking iron coke gasification structural evolution kinetic model

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Effect of ion solvation energy on electrohydrodynamic behavior of ionic liquid droplets in electrospray thrusters

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Chinese Journal of Aeronautics 2025年第3期38卷 222-233页

作者： Yipeng FAN Chong CHEN Huifeng KANG Guangqing XIA Chang LU Yajie HAN State Key Laboratory of Structural Analysis Optimization and CAE Software for Industrial EquipmentDalian University of TechnologyDalian 116024China Key Laboratory of Advanced Technology for Aerospace Vehicles of Liaoning Province Dalian University of TechnologyDalian 116024China Collaborative Innovation Center of Micro&Nano Satellites of Hebei Province North China Institute of Aerospace EngineeringLangfang 065000China

The electrospray thruster supplied by ionic liquid is a promising micro-propulsion thruster with small size and precise thrust, which can emit both cations and anions to achieve self-neutralization. In order to further investigate the effect of ion solvation energy on the evaporation of cations and anions from ionic liquid under the action of a uniform electric field, this paper establishes a transient Electrohydrodynamic (EHD) model for free ionic liquid droplets undergoing ion evaporation. The dynamic processes of droplet deformation and ion evaporation are simulated. And the study further focuses on the influence of different ion solvation energies for cations on the droplet morphology and the ion evaporation characteristics at the positively charged end and negatively charged end of the droplet. The results indicate that, when the ion solvation energy for cations is higher than that of anions, it will cause the ion evaporation at the positively charged end of the droplet to lag behind the ion evaporation at the negatively charged end. And the higher the ion solvation energy for the cations, the longer the evaporation lag time at the positively charged end of the droplet, which will lead to a higher peak of surface charge density that can be reached, resulting in a larger evaporation current and sharper droplet stretching deformation. Additionally, the peak surface charge density of the positively charged end of the droplet is linearly related to the ion solvation energy for cations, while the peak surface charge density of the negatively charged end remains almost unchanged and is not significantly affected by the ion solvation energy for cations.

关键词： Ionic liquid Electrospray Electrohydrodynamics Ion solvation energy Ion evaporation

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Incommensurate modulated structure and its influence on the martensitic transformation temperature span of single phase multielement Ni-Cu-Co-Mn-Ga two-way shape memory single crystals

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材料科学技术（英文版） 2025年第5期208卷 230-240页

作者： Qijjia Yu Yang Liu Chen Si Wenjia Wang Jiaxi Meng Jingmin Wang Jinghua Liu Chengbao Jiang Key Laboratory of Advanced Aerospace Materials and Performance(Ministry of Education) School of Materials Science and EngineeringBeihang UniversityBeijing 100191PR China Center of Microstructure Science Frontier Institute of Science and TechnologyState Key Laboratory for Mechanical Behavior of MaterialsXi'an Jiaotong UniversityXi'an 710049PR China

Significant two-way shape memory effect(TWSME)was achieved in single crystals of single-phase mul-tielement Ni42-xCu8CoxMn37Ga13(8 ≤ x ≤ 12)alloys by performing thermomechanical ***,anomalous dependence of the martensitic transformation temperature span on Co content was *** training,quite a narrow temperature span of the martensitic transformation,nearly independent of the Co content,was observed in all single *** training the temperature span was still narrow for 8 ≤ x ≤ 10.9 but was obviously expanded for 10.9＜x ≤ ***-resolution transmission electron microscopy revealed that at the atomic scale,there exists incommensurate modulated structure in the single phase single crystals,as evidenced by nonperiodic satellite spots in the selected area electronic diffraction ***,the modulated wave vector of the satellite spots was increased by higher Co *** first principal calculations it was considered that the incommensurate modulated structure originates from the formation of Co-Co *** training arrays of ordered dislocations with the same Burgers vector were introduced for 8 ≤ x ≤ 10.9 but the network of dislocations was formed for 10.9＜x ≤ *** on analysis of transmission electron microscopy,geometric phase,thermody-namics,and Landau theory,it was considered that the austenite/martensite phase interface was pinned by the network of dislocations,expanding the temperature span of the martensitic *** work supplies new insights for understanding the microstructure and martensitic transformation of Ni-Mn-Ga-based alloys.

关键词： Martensitic transformation Incommensurate modulated structure Temperature span Dislocation Two-way shape memory effect

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