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Thermal Mechanical Response Analysis of the First Wall in Laser Initial Confinement Fusion Reactors

International Journal of Advanced Nuclear Reactor Design and Technology 2025年

作者： Xinze LI Bingqian ZHANG Chengcheng TONG Ronghua CHEN Dalin Zhang Wenxi TIAN Suizheng QIU State Key Laboratory of Multiphase Flow in Power Engineering Shaanxi Key Laboratory of Advanced Nuclear Energy and Technology School of Nuclear Science and Technology Xi’an Jiaotong University Xi’an 710049 China

This paper investigates the thermo-mechanical response characteristics of the first wall of a laser initial confinement fusion reactor under periodic transient heat flux loads. The first wall of the reactor experiences extremely high instantaneous heat loads during the target compression process, leading to temperature oscillations and thermal stresses, which can cause material fatigue damage. Finite element analysis is employed to model the first wall under various chamber sizes and target energies, and the thermal-mechanical response characteristics of W, W/Cu functional gradient materials, and cladding materials are studied under thermal shock and cyclic loading conditions. The results indicate that W/Cu functional gradient materials can effectively alleviate thermal stresses on the first wall, especially in addressing the stress concentration at the interface. Fatigue life of the first wall is assessed using the Basquin model, and it is found that increasing the chamber size and reducing the target energy can significantly reduce temperature oscillations and thermal stresses, thus extending the service life of the first wall. This study provides valuable design references for the optimization and design of the first wall in laser initial confinement fusion reactor.

关键词： Laser Inertial Confinement Fusion Reactor First Wall Heat Oscillation Thermal Fatigue

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Experimental and kinetic study on laminar flame speeds of ammonia/syngas/air at a high temperature and elevated pressure

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Frontiers in Energy 2022年第2期16卷 263-276页

作者： Geyuan YIN Chaojun WANG Meng ZHOU Yajie ZHOU Erjiang HU Zuohua HUANG State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China Key Laboratory for Thermal Science and Power Engineering of the Ministry of Education Department of Thermal EngineeringTsinghua UniversityBeijing 100084China

The laminar flame speeds of ammonia mixed with syngas at a high pressure, temperature, and different syngas ratios were measured. The data obtained were fitted at different pressures, temperatures, syngas ratios, and equivalence ratios. Four kinetic models (the Glarborg model, Shrestha model, Mei model, and Han model) were compared and validated with experimental data. Pathway, sensitivity and radical pool analysis are conducted to find out the deep kinetic insight on ammonia oxidation and NO formation. The pathway analysis shows that H abstraction reactions and NHi combination reactions play important roles in ammonia oxidation. NO formation is closely related to H, OH, the O radical produced, and formation reactions. NO is mainly formed from reaction, HNO+ H= NO+ H2. Furthermore, both ammonia oxidation and NO formation are sensitive to small radical reactions and ammonia related reactions.

关键词： ammonia mixed with syngas laminar flame speed kinetic model sensitivity analysis pathway analysis

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Hierarchical growth of a novel Mn-Bi coupled BiVO4 arrays for enhanced photoelectrochemical water splitting

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Nano Research 2019年第3期12卷 575-580页

作者： Lu Wang Jinzhan Su Liejin Guo International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering School cf Energy & Power Engineering Xian Jiaotong University Xian 710049 China

Oxygen evolving catalyst (OEC) is a critical determinant for the efficiency of photoelectrochemical (PEC) water splitting. Here we report an approach to depositing a novel manganese borate (Mn-Bi) OER catalyst on BiVO4 nanocone photoanode by photodeposition in sodium borate buffer solution containing Mn(Ⅱ) ions. Due to the spontaneous photo-electric-field-enhancement effect at the vertically oriented BiVO4 nanocone structure, spherical Mn-Bi nanoparticle was selectively photodeposited at the apex of BiVO4 nanocone. Significant improvement of photocurrent was observed for the obtained hierarchical Mn-Bi/BiVO4 photoanode which could be ascribed to enhanced hole injection efficiency, especially in low bias region. It was observed that the injection efficiency of Mn-Bi/BiVO4 is 98% which gave a photocurrent of 0.94 mA/cm^2 at 1.5 V vs. RHE.

关键词： bismuth vanadate photoelectrochemistry solar water splitting oxygen evolution

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Room-temperature photodeposition of conformal transition metal based cocatalysts on BiVO4 for enhanced photoelectrochemical water splitting

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Nano Research 2020年第1期13卷 231-237页

作者： Lu Wang Tao Zhang Jinzhan Su Liejin Guo International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringSchool of Energy&Power EngineeringXi’an Jiaotong UniversityXi’an710049China

Photoelectrochemical(PEC)water splitting using semiconductors offers a promising way to convert renewable solar energy to clean hydrogen ***,due to the sluggish reaction kinetics of water oxidation,significant charge recombination occurred at the photoanode/electrolyte interface and cause decrease of its PEC *** reduce the surface recombination,we deposit different transition metal complexes on BiVO4 nanocone arrays by a versatile light driven in-situ two electrode photodeposition approach without applied *** cobalt phosphate“Co-Pi”,nickel borate“Ni-Bi”and manganese phosphate“Mn-Pi”complexes were deposited on BiVO4 nanocone arrays to form core-shell structure photoanode,all of which lead to enhanced photoelectrochemical *** photocurrent of the Co-Pi/BiVO4 photoanode under front-side illumination for 5 min is increased by 4 folds comparing to that of bare BiVO4 photoanode at 0.6 V ***,reaching a hole transfer efficiency as high as 94.5%at 1.23 V *** proposed photodeposition strategy is simple and efficient,and can be extended to deposite cocatalyst on other semiconductors with a valence band edge located at a potential more positive than the oxidation potential of transition metal ion in the cocatalyst.

关键词： bismuth vanadate photoelectrochemcial water splitting conformal photodeposition cocatalyst

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Implementation of an efficient segregated algorithm-IDEAL on 3D collocated grid system

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Chinese Science Bulletin 2009年第6期54卷 929-942页

作者： SUN DongLiang QU ZhiGuo HE YaLing Tao WenQuan State Key Laboratory of Multiphase Flow in Power Engineering School of Energy & Power Engineering Xi'an Jiaotong University Xi'an 710049 China

The segregated algorithm-IDEAL (inner doubly-iterative efficient algorithm for linked-equations) is an efficient and stable algorithm. In this algorithm, there exist inner doubly-iterative processes for pres-sure equation, which almost completely overcome two approximations in SIMPLE algorithm. Thus the coupling between velocity and pressure is fully guaranteed, greatly enhancing the convergence rate and stability of iteration process. In this paper, implementation of the IDEAL algorithm on a 3D collo-cated grid system is conducted. The interface velocity is calculated by the modified momentum inter-polation method (MMIM), by which the converged result is independent of the under-relaxation factor. Finally, five three-dimensional incompressible fluid flow and heat transfer problems are provided to compare the convergence rate and robustness between the IDEAL and three other most widely-used algorithms (SIMPLER, SIMPLEC and PISO). By the comparison it can be concluded that the IDEAL al-gorithm is more robust and efficient than the three other algorithms.

关键词：隔离算法网格系统理想 SIMPLE算法 3D 压力方程收敛速度迭代过程

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Synthesis and application of transition metal phosphides as electrocatalyst for water splitting

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Science Bulletin 2017年第9期62卷 633-644页

作者： Jinzhan Su Jinglan Zhou Lu Wang Cong Liu Yubin Chen International Research Center for Renewable Energy (IRCRE) State Key Laboratory for Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

With continuous research on photocatalytic water splitting, searching for efficient catalyst for hydrogen evolution reaction(HER) becomes popular topic in addition to main catalyst research. Transition metal phosphides are receiving intense attention due to its abundance in the Earth's crust and comparable catalytic properties to noble metals. In this review, the synthesis approaches, HER reaction mechanism,photocatalytic activity, approaches to improve the activity of transition metal phosphides were reviewed and discussed. It was showed that the transition metal phosphides have great potential to reduce the cost of photocatalyst and promising application on water splitting. The stability problem and participation of poisonous reactant and product in its synthesis reaction limit its application and developing in a certain extent, but with the continuous efforts on the development and improvement of the synthesis methods,transition metal phosphides will find wide application in water splitting.

关键词： Transition metal phosphide Electrocatalyst HER Photocatalytic water splitting

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Toward practical photoelectrochemical water splitting and CO_(2) reduction using earth-abundant materials

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Journal of Energy Chemistry 2021年第10期30卷 469-488,I0013页

作者： Yubin Chen Ya Liu Feng Wang Xiangjiu Guan Liejin Guo International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an 710049ShaanxiChina

Photoelectrochemical(PEC)fuel generation from water splitting and CO_(2)reduction(CO_(2)R)utilizing solar energy holds immense potential to solve the current energy and environmental *** the past decades,numerous studies have been devoted to this fast-growing research field,and it is essential to develop efficient photoelectrodes with earth-abundant materials for the practical application of PEC systems.A thorough review of earth-abundant materials and associated devices for PEC fuel generation is beneficial to uncover the inherent obstacles and pave the way for future ***,we summarize the recent progress of earth-abundant light-absorbers and cocatalysts in the PEC *** unbiased configurations and scaling-up strategies of PEC devices using earth-abundant materials are examined.A comparison between PEC water splitting and CO_(2)R is carried out to promote better understanding of the design principles for practical materials and ***,the prospects on advanced materials,underlying mechanisms,and reaction systems of PEC water splitting and CO_(2)R are proposed.

关键词： Solar energy Photoelectrochemical technology Water splitting CO_(2)reduction Earth-abundant materials

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Experimental analysis on adjusting performance of vapor-liquid two-phase flow controller

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Journal of Harbin Institute of Technology(New Series) 2006年第5期13卷 525-530页

作者：李慧君屠珊 School of Energy and Power Engineering North China Electric Power UniversityBaoding 071003ChinaState Key Laboratory of Multiphase Flow in Power EngineeringXi'an Jiaotong UniversityXi'an 710049China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an 710049China

The vapor-liquid self-adjusting controller is an innovative automatic regulating *** order to ensure adjusted objects run safely and economically,the controller automatically adjusts the liquid flux to keep liquid level at a required level according to physical properties of vapor-liquid two-phase *** adjusting mechanics,the controller’s performance and influencing factors of its stability have been analyzed in this *** theoretical analysis and successful applications have demonstrated this controller can keep the liquid level steady with good *** actual application in industry has shown that the controller can satisfactorily meet the requirement of industrial production and has wide application areas.

关键词： vapor-liquid two-phase flow adjusting performance liquid level controller

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Synergy of porous structure and cation doping in Ta3N5 photoanode towards improved photoelectrochemical water oxidation

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Journal of Energy Chemistry 2021年第1期30卷 343-350,I0011页

作者： Yubin Chen Hongyu Xia Xiaoyang Feng Ya Liu Wenyu Zheng Lijing Ma Rui Li International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an 710049ShaanxiChina

Herein,a cross-linked porous Ta3N5 film was prepared via a simple solution combustion route followed by a high-temperature nitridation process for photoelectrochemical(PEC) water ***,the metal cations(Mg2+ and Zr4+) were incorporated into the porous Ta3N5 to enhance the PEC *** porous Mg/Zr co-doped Ta3N5 photoanode yielded a photocurrent density of 1.40 mA cm^(-2) at 1.23 V vs RHE,which is 5.6 times higher than that of the dense Ta3N5 *** enhanced performance should be ascribed to the synergistic effect of porous structure and cation doping,which can enlarge the electrochemical active surface area and accelerate the charge transfer by introducing ON substitution ***,Co(OH)2 cocatalyst was loaded on the Mg/Zr-Ta3N5 photoanode to negatively shift the onset potential to 0.45 V vs RHE and further improve the photocurrent density to 3.5 mA cm^(-2)at 1.23 V ***,with a maximum half-cell solar to hydrogen efficiency of 0.45%.The present study provides a new strategy to design efficient Ta3N5 photoelectrodes via the simultaneous control of the morphology and composition.

关键词： Photoelectrochemical water oxidation Ta3N5 Porous structure Doping Solution combustion

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Transient gas/liquid two-phase flow in a pipeline-riser system after the change of inlet flow rates

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multiphase Science and Technology 2020年第2期32卷 25-46页

作者： Zou, Suifeng Liu, Weizhi Xu, Qiang Xie, Xiangdong Guo, Liejin State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an China Wuhan Second Ship Design and Research Institute Wuhan China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China

Transient gas/liquid two-phase flow caused by the change of inlet gas and/or liquid flow rates was experimentally studied in a 380-meter-long pipeline-riser system with a vertical riser of 21.5 meters in height. Results showed that, for the transient processes with the same median flow rates, the rise of flow rates was likely to result in shorter duration time compared to the fall of flow rates. Apart from the manner of change, the duration time was also closely related to the flow mechanism, which varied with the global flow regime. As a consequence, the transient process lasted a longer time around the transition boundary of stable regime and the severe slugging regime;whereas, the transient process would be shorter if the regime was an irregular oscillation;and the longest transient process was found at very low gas and liquid flow rates. As for the prediction of duration time of both the entire transient process and the transition to undesirable flow regimes, the support vector machine turned out to be much more suitable than the log-linear regression. In addition, some similarities of pressure drop signals were found between the transition to unstable and irregular flow regimes and the steady state of these regimes. Since the method for fast recognition of a steady global flow regime has already been developed, it becomes possible to forecast the transition to these undesirable flow regimes through the modification of the recognition method. © 2020 Begell House Inc.. All rights reserved.

关键词： flow rate

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