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Numerical simulation of bubble behavior in a quasi-2D fluidized bed using a bubble-based EMMS model

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Particuology 2019年第5期17卷 40-54页

作者： Hao Wang Youjun Lu State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi'an 710049 Shaanxi China

Bubbles formed during chemical processes in fluidized beds govern the bed hydrodynamics and opera-tional efficiency, thereby having a significant impact on their design and scale-up. In this study, a two-fluid model was used to simulate the bubble behavior in a quasi-two-dimensional fluidized bed within the bubble-based energy minimization multiscale (EMMS) approach. We performed experiments to verify the model and proposed a correlation of the heterogeneous index for various parameters to calculate the coefficient of drag for the bubble-based EMMS model. Moreover, the simulation results obtained from the homogeneous drag models and EMMS bubbling model were compared with experimental data and empirical correlations. The simulation results of the EMMS approach showed good agreement with the experimental data in the distribution of the vertical bubble velocity with chord length. Compared with the results from the homogeneous models, the distributions of vertical velocity and diameter of the bubbles predicted by the EMMS-bubbling model were in better agreement with empirical correlations. Moreover, the frequency distributions of bubble properties including bubble diameter, aspect ratio, and shape factor for different gas-inlet velocities were obtained.

关键词： Energy minimization multi-scale approach Heterogeneous index Fluidized bed Bubble

Modeling Study on Anisotropic Transport Properties of Pemfc Gdls Facilitated by Xct

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SSRN 2025年

作者： Liu, Hang Li, Yang Huang, Heng Zhou, Zhifu Wu, Wei-Tao Wei, Lei Lyu, Jizu Hu, Chengzhi Li, Yubai Song, Yongchen Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education Dalian University of Technology Dalian116024 China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi’an710049 China School of Mechanical Engineering Nanjing University of Science and Technology Nanjing210094 China Department of Mechanical and Energy Engineering Southern University of Science and Technology Shenzhen518055 China School of Mechanical Engineering Guangdong Ocean University Zhanjiang524088 China

The gas diffusion layer (GDL) of proton exchange membrane fuel cells (PEMFCs) is a critical component for the transport of reactants. The efficiency of reactant gas transport remains a major technical challenge in the field today. The anisotropic structure of the GDL gives rise to substantial variations of gas diffusion as well as permeability in different directions. The study employs X-CT technology to obtain the actual GDL’s geometry, aiming to investigate a spatial structure at the microscale and its gas transport characteristics. CFD method is used to simulate and study the gas diffusivity and gas permeability of GDL with four different thicknesses. The numerical simulation results show the diffusivity and permeability in the Through-plane (TP) direction are lower than those in the In-plane (IP) direction. Moreover, the effective diffusion coefficient decreases with increasing thickness, but is also dependent on the solid fibre structure of GDL. Horizontal alignment of the carbon fibers and the disc-shaped adhesive contributes to the anisotropy between the TP and IP directions, resulting in anisotropic gas transport. The purpose of the study is to supply critical references for manufacturing techniques and optimization of gas transport in GDLs. © 2025, The Authors. All rights reserved.

关键词： Gas permeability

Kinetic Characteristics of Passivation Behavior in OFP-Cu and OF-Cu

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SSRN 2024年

作者： Ning, Zhiyuan Wen, Du Zhou, Qulan Li, Na Macdonald, Digby D. State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China Departments of Nuclear Engineering and Materials Science and Engineering University of California at Berkeley BerkeleyCA94720 United States Industrial Process and Energy Systems Engineering Ećole Polytechnique Fédérale de Lausanne EPFL SionCH-1951 Switzerland

This research presents a comprehensive comparative analysis of the passivation kinetics of OFP-Cu and OF-Cu in simulated repository electrolyte. The study employs a range of techniques, including potentiodynamic polarization, multi-step potentiostatic polarization, electrochemical impedance spectroscopy, and Mott-Schottky analysis, to explore the intricacies of corrosion behavior. The Point Defect Model (PDM) is used to interpret the steady-state physicochemical processes. Utilizing the results of PDM optimization, defect distribution diagrams within the passivation film were constructed, shedding light on the pivotal transition from p-type to n-type semiconductor properties of the film. The study concludes with an interpretation of the experimental data, highlighting the enhancement of copper's corrosion resistance due to phosphorus doping, as elucidated by the Solute-Vacancy Interaction Model. © 2024, The Authors. All rights reserved.

关键词： Copper corrosion

Stability and Emission Characteristics of Ammonia/Air Premixed Swirling Flames with Rotating Gliding Arc Discharge Plasma

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SSRN 2022年

作者： Ju, Rongyuan Wang, Jinhua Zhang, Meng Mu, Haibao Zhang, Guanjun Yu, Jinlu Huang, Zuohua State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China State Key Laboratory of Electrical Insulation and Power Equipment School of Electrical Engineering Xi’an Jiaotong University Xi’an710049 China School of Aeronautics Engineering Air Force Engineering University Xi’an710038 China

Ammonia received increased attention as a carbon-free fuel and hydrogen carrier. Poor combustion stability and high NOx emission are the main issue for ammonia combustion. Effects of rotating gliding arc (RGA) discharge plasma on the flame stability and NOx emission of NH3/air premixed swirling flames were investigated. The discharge characteristics of the RGA were studied. The flame stabilization mechanisms by plasma were revealed and analyzed according to the flame structure transition and the distribution of key intermediate OH radicals. The NOx emissions were measured by the Gasmet DX4000 Fourier Transform Infrared (FTIR) gas analyzer. Results showed that the RGA discharge plasma can enhance the stability and extend the lean blow-off (LBO) limits from 0.6 to approximately 0.43-0.57. A hysteresis phenomenon about the transition between the lift-off flame and the attached flame was observed without plasma and disappeared with plasma activation. The plasma reduces NO and NO2 emissions mainly due to the kinetic and cracking effects of plasma. Extremely low NO emission below 300 ppm can be observed for very lean ammonia flames with an equivalence ratio (f) lower than 0.6, which are stabilized by plasma, while a large amount of unburned NH3 emission is accompanied. © 2022, The Authors. All rights reserved.

关键词： Ammonia

Corrigendum to “Experimental study on flow boiling and circumferential non-uniform heat transfer characteristics in helically-coiled tube under coupled heat transfer conditions” [Appl. Therm. Eng. 258(Part C) (2025) 124844]

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Applied Thermal engineering 2025年 261卷

作者： Hengyuan Wang Qiyu Xuan Hailin Lei Xi Li Zhibin Li Huixiong Li State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an 710049 China

Experimental Study on the Performance Difference of Pulsating Heat Pipe Using R170 and R134a as Working Fluids

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SSRN 2023年

作者： Song, Yuxin Chen, Xi Zhan, Jingru Zhang, Hua School of Energy and Power Engineering University of Shanghai for Science and Technology 516 Jungong Road Shanghai200093 China Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering University of Shanghai for Science and Technology 516 Jungong Road Shanghai200093 China

The pulsating heat pipe (PHP), as a type of heat pipes, is a flexible heat transport device with highly efficient conduction, which is widely used in many fields including aerospace, waste heat recovery, cryogenic refrigerator and so on. The working fluids have an important effect on the thermal performance of PHPs. This study experimentally compares a PHP with R170 and R134a as the working fluids, respectively, examining temperature fluctuations, thermal resistance, and temperature differentials. Findings indicate that R170 PHP exhibits sensitivity to heat input (HI), with temperature fluctuations stagnating at 70 W. Increasing the filling ratio (FR) from 30% to 60% results in a steady rise in R170 PHP thermal resistance. While R170 PHP thermal resistance increases with higher inclination angles (IAs), it does so to a lesser extent compared to R134a PHPs. In the temperature region of -20 ℃ to 0 ℃, both R170 and R134a perform similarly. However, as the working temperature (WT) decreases, R170 PHP outperforms R134a PHP. Overall, the thermal performance of R170 PHP is superior to R134a PHP. This study provides reference value for the future research of PHPs in the temperature region of -60 ℃ to 0 ℃. © 2023, The Authors. All rights reserved.

关键词： Heat resistance

Study on thermo-fluid-chemical coupling simulation and characteristic fields evolution during in-situ pyrolysis of tar-rich coal

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International Journal of Heat and Fluid flow 2025年 116卷

作者： Meijing Chen Yongbo Du Chang’an Wang Yujie Hou Tianlin Yuan Liujun Chang Lei Deng Defu Che State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an 710049 China

Underground in-situ pyrolysis of tar-rich coal is an effective approach to expand the supply channels of oil and gas while ensuring energy security, and it has currently aroused wide attention in the academic community. The coupling of multiple interdependent physical fields causes the in-situ pyrolysis process and related phenomena. However, existing studies usually only have focused on a single process. The study proposed a three-dimensional (3D) model for the in-situ pyrolysis of tar-rich coal employing external high-temperature fluids. Numerical simulation was used to achieve the transient calculation of the coupling model of chemical reaction, fluid flow, and heat transfer. The impacts of medium type, medium temperature, inlet rate, well patterns, and the number of horizontal fractures were investigated by characterizing the temperature and concentration fields. The results indicate that, under the basic working condition, the pyrolysis reaction of tar-rich coal in the formation has been completed after ∼28.5 months of heat injection. Both N 2 and CO 2 are heat carriers with greater advantages in heat transfer as compared to H 2 O (g). The threshold of injection rate is 5 m·s −1 . The heat transfer effect of coal seams with 4 injection wells is obviously better than that of 1 and 2 injection wells. The number of 3 horizontal fractures is superior to 1 and 2 fractures, which can effectively enhance heat transfer and promote the thermal decomposition. The present study has emphatically investigated the evolution of characteristic fields of tar-rich coal seams under thermo-fluid-chemical coupling conditions during the in-situ pyrolysis process, providing substantial reference significance to guide the in-situ conversion mining.

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High-Entropy (Cocrfemnni)3o4 Catalysts for Propane Catalytic Destruction: Effect of the Precipitation Agent

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SSRN 2023年

作者： Ma, Yue Zhang, Yun Jian, Yanfei Jiang, Zeyu Chai, Shouning Li, Lu Xia, Lianghui He, Chi State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Shaanxi Xi’an710049 China Department of Physics and Information Technology Baoji University of Arts and Sciences Shaanxi Baoji721016 China National Engineering Laboratory for VOCs Pollution Control Material & Technology University of Chinese Academy of Sciences Beijing101408 China

Efficient catalytic destruction of light alkane with ultra-stable and highly symmetric structure is still an intractable issue. High entropy oxides (HEOs) with high chemical disorder and lattice distortion and superior stability have shown great potential in heterogeneous thermocatalysis. Herein, spinel-type HEOs are synthesized via a scalable co-precipitation method with different precipitants (NaOH, Na2CO3, and NaHCO3) and firstly adopted in catalytic destruction of propane. Results demonstrate that the HEO-NaOH possesses the best activity, achieving 90% of propane conversion at 325 °C with an apparent activation energy of 56 kJ·mol-1. Compared with other two HEOs, HEO-NaOH system has larger quantities of surface oxygen vacancies and easily forming several reactive oxygen species (OOH-, O2-, and OH-, etc.), which significantly contribute to the catalytic performance. Moreover, the excellent water resistance of HEOs is verified due to their high conformational entropy and structural stability. Reaction mechanism reveals that OOH- and O2- are the key species in the oxidation of C3H8, which break C-H and C-C bonds in sequence, and are then converted to oxygenated compounds via oxygen oxidation before the final mineralization. The present work provides new insights into the fabrication of efficient catalysts for light alkane destruction as well as other thermocatalytic applications. © 2023, The Authors. All rights reserved.

关键词： Sodium hydroxide

ȮH insights into the interaction of hydrogen-rich methane and water: Laser absorption experiments and chemical kinetics

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Combustion and Flame 2025年 278卷

作者： Xin Zhang Zilong Feng Congjie Hong Wuchuan Sun Zuohua Huang Yingjia Zhang State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an 710049 PR China

Flue gas recirculation and steam injection are employed in hydrogen-rich gas turbines to stabilize fuel reactivity and improve cycle efficiency, introducing high water vapor content into the combustion chamber and thereby necessitating an investigation of water-fuel interactions at elevated temperatures. This study employed UV laser absorption diagnostics behind reflected shock waves to conduct in situ measurements of the ȮH concentration time-histories during the oxidation of CH 4 /H 2 /H 2 O/O 2 /Ar mixtures at pressures of approximately 1.3, 5.0, and 15.2 atm and temperatures ranging from 1225 to 1888 K with varying hydrogen blending and water addition ratios. The absorption lineshapes of the ȮH R 1 (5) transition in the A-X(0,0) vibronic band were characterized after broadening and shifting in Ar at different pressures, with diagnostic center wavelengths set at 306.6868 nm (1.3 atm), 306.6874 nm (5.0 atm), and 306.6886 nm (15.2 atm), respectively. The obtained ȮH concentration time-history data were compared in detail with predictions from eight representative reaction kinetic models, and the predictive capability of the models for ȮH behavior was quantitatively assessed using the error function method. NUIGMech1.1 exhibited superior performance in predicting ȮH behavior and was subsequently selected for kinetic analysis to elucidate stage-specific micro-mechanisms and identify key reactions driving the concentration evolution. The activating effect of H 2 on ȮH behavior during CH 4 oxidation was investigated. Results indicate that higher hydrogen levels intensify hydrogen-related reaction pathways, expanding the radical pools (H, ȮH, and Ö), thereby promoting fuel consumption through Ḣ-atom abstraction reactions. Additionally, by introducing weak collision H 2 O* and inert H 2 O**, the thermodynamic and kinetic effects of water were distinguished. The results show that under the current conditions, H 2 O primarily affects ȮH behavior through direct participatio

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