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Customizable Ligand Exchange for Tailored Surface Property of Noble Metal Nanocrystals

Research 2020年第1期2020卷 292-303页

作者： Qikui Fan Hao Yang Juan Ge Shumeng Zhang Zhaojun Liu Bo Lei Tao Cheng Youyong Li Yadong Yin Chuanbo Gao Frontier Institute of Science and Technology State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’anShaanxi 710054China Institute of Functional Nano&Soft Materials(FUNSOM) Jiangsu Key Laboratory for Carbon-Based Functional Materials&DevicesJoint International Research Laboratory of Carbon-Based Functional Materials and DevicesSoochow UniversitySuzhouJiangsu 215123China Department of Chemistry University of CaliforniaRiversideCalifornia 92521USA

It is highly desirable,while still challenging,to obtain noble metal nanocrystals with custom capping ligands,because their colloidal synthesis relies on specific capping ligands for the shape control while conventional ligand exchange processes suffer from“the strong replaces the weak”limitation,which greatly hinders their ***,we report a general and effective ligand exchange approach that can replace the native capping ligands of noble metal nanocrystals with virtually any type of ligands,producing flexibly tailored surface *** key is to use diethylamine with conveniently switchable binding affinity to the metal surface as an intermediate *** a strong ligand,it in its original form can effectively remove the native ligands;while protonated,it loses its binding affinity and facilitates the adsorption of new ligands,especially weak ones,onto the metal *** this means,the irreversible order in the conventional ligand exchange processes could be *** efficacy of the strategy is demonstrated by mutual exchange of the capping ligands among cetyltrimethylammonium,citrate,polyvinylpyrrolidone,and *** novel strategy significantly expands our ability to manipulate the surface property of noble metal nanocrystals and extends their applicability to a wide range of fields,particularly biomedical applications.

关键词： properties replace mutual

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Bowl-Shaped Carbon Loaded Co9s8 Nanoparticles Connected by Carbon Nanotubes with Excellent Rate Performance for Sodium-Ion Batteries

SSRN

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SSRN 2022年

作者： Yang, Guorui Zhou, Ziyi Liu, Xiaofeng Zhang, Yue Wang, Silan Yan, Wei Ding, Shujiang School of Chemistry Engineering Research Center of Energy Storage Materials and Devices Ministry of Education "Four Joint Subjects One Union" School Enterprise Joint Research Center for Power Battery Recycling & Circulation Utilization Technology Xi’an Jiaotong University Xi’an710049 China Xi'an Key Laboratory of Solid Waste Recycling and Resource Recovery State Key Laboratory of Multiphase Flow in Power Engineering Department of Environmental Science and Engineering Xi'an Jiaotong University Xi'An710049 China

Sodium-ion batteries (SIBs) are expected to replace lithium-ion batteries in the energy storage sector owing to their low cost and abundant resources. However, developing suitable anode materials to meet the high energy density requirements of SIBs remains an ongoing challenge. Herein, we design a hollow nitrogen-doped bowl-like carbon decorated with Co9S8 nanoparticles linked by carbon nanotubes (HNBC@Co9S8@CNTs) as an anode material for SIBs. The HNBC@Co9S8@CNTs electrode exhibits impressive rate performance (280.9 mAh g-1 at 5 A g-1) and cycling stability (426.5 mAh g-1 after 500 cycles at high current density of 1 A g-1) due to the advantages of highly conductive three-dimensional (3D) interconnected structures. In addition, its pseudo-capacitance and sodium storage diffusion kinetics are analyzed in depth using Cyclic Voltammetry (CV) and galvanostatic intermittent titration technique (GITT). The results elucidate that the partially surface-induced capacitive sodium storage, highly conductive 3D interconnected structures, and fast reaction kinetics synergistically contribute to the high-rate performance. This work may provide new insights for the fabrication of various metal sulﬁde or sulﬁde composites with high sodium storage capacity. © 2022, The Authors. All rights reserved.

关键词： Sodium-ion batteries

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Boiling of Water Droplet in Glass-Oil-Water multiphase System

SSRN

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SSRN 2022年

作者： He, Xiaotian Cheng, Yiwei Xu, Jinliang Yu, Xiongjiang Xie, Jian Ma, Xiaojing Ren, Yong Beijing Key Laboratory of Multiphase Flow and Heat Transfer for Low Grade Energy Utilization North China Electric Power University Beijing102206 China Key Laboratory of Power Station Energy Transfer Conversion and System of Ministry of Education North China Electric Power University Beijing102206 China Research Group for Fluids and Thermal Engineering University of Nottingham Ningbo China Ningbo315100 China

Boiling of a volatile droplet in a non-volatile liquid becomes complex due to various interface interactions in a solid-liquid-liquid system. Available studies reported explosive boiling and attributed the phenomenon to heterogeneous nucleation due to solid-liquid contact. Here, we investigate boiling of ~2 mm diameter water droplet in a silicon oil pool with glass container. Two transition temperatures are observed, with one as the transition from evaporation to boiling (122.5 o C), and the other as the transition from bubble growth in oil side to that in both oil and water side (160.0 o C). Correspondingly, four boiling modes of evaporation (E), boiling in water (BIW: bubble nucleation at glass-water interface and growth inside drop), boiling in oil (BIO: nucleation at oil-water interface and growth in oil), and boiling in oil and water (BIOW: nucleation at oil-water interface and growth in oil and water), are identified. For the first time, boiling bifurcation is found for drop boiling in a three-phase system. For oil temperature T b in the range of (122.5~160.0) o C, boiling mode switches in between BIW and BIO. On the contrary, for T b beyond of 160.0 o C, either BIW or BIOW occurs. This bifurcation is explained by the fact that a droplet prefers to choose smaller activation energy between that for bubble nucleation at solid-water interface and that for bubble nucleation at oil-water interface. Interfacial instabilities are analyzed to explain why BIOW boils more violently than BIW. Our work presents a comprehensive understanding of droplet boiling in the three-phase system. © 2022, The Authors. All rights reserved.

关键词： Bifurcation (mathematics)

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Thermal-mechanical coupling behavior analysis of solid-state constrained component in advanced nuclear energy system

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Energy 2025年 330卷

作者： Xuan Yang Quan Li Jing Zhang Yingwei Wu Yanan He Chenxi Li Mingjun Wang Kailun Guo Chenglong Wang G.H. Su Wenxi Tian Suizheng Qiu State Key Laboratory of Multiphase Flow in Power Engineering School of Nuclear Science and Technology Xi'an Jiaotong University Xi'an 710049 China Science and Technology on Reactor System Design Technology Laboratory Nuclear Power Institute of China Chengdu 610213 China

With the advantage of phase change heat transfer, heat pipes have the potential to replace flowing coolants for removing fission heat from nuclear reactors. However, the solid-state constrained heat transfer configuration poses mutual constraints between mechanical properties and heat transfer, and their long-term thermal-mechanical coupling behavior requires further investigation. Currently, research on long-term behavior is limited to either individual/local system components or a single physical field. In this paper, an analysis method for coupled thermal-mechanical behavior is proposed and verified, comprehensively considering thermal-mechanical properties, interactions between components, and the fission gas release. This method is employed to analyze the operating characteristics of a solid-state constrained component. The results indicate that prolonged operation leads to complete contact between structural components, generating high contact pressure that enhances heat transfer but increases creep. The release of gaseous fission products, accumulated over operating time, results in a synchronous increase in both gap and external contact pressures, reaching 5.2 MPa and 4.8 MPa, respectively. This process reduces the gas gap conductance, leading to elevated system peak temperatures and a reduction in temperature safety margins by 43 K. After heat pipe failure, continued operation significantly increases the local creep strain, up to 3.9 times that under normal conditions. The gap size and fuel gap pressure should be optimized to enhance gap heat transfer and reduce component creep. Excessive fission gas release should be avoided in fuel configuration. Reducing the system power following a single heat pipe failure can mitigate component creep and extend the operational lifespan.

关键词： Electric heating

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Film levitation and central jet of droplet impact on nanotube surface at superheated conditions

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Physical Review E 2020年第4期102卷 043108-043108页

作者： Dongdong Zhou Yuhui Zhang Yu Hou Xin Zhong Jian Jin Lidong Sun State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Shaanxi 710049 China State Key Laboratory of Mechanical Transmission School of Materials Science and Engineering Chongqing University Chongqing 400044 China

Influences of surface nanotubes at high temperatures are investigated on droplet impact dynamics and Leidenfrost effect. Five distinct regimes of impact droplets are found on the nanotube surface, including contact boiling, film levitation, central jet levitation, central jet, and Leidenfrost phenomenon. The regimes of film levitation, central jet levitation, and central jet are characterized by either film levitation and/or liquid central jet. The regime of Leidenfrost phenomenon is characterized by droplet bounce-off behavior free of any liquid jets. Film levitation is driven by the vaporization of two parts of the droplet, with one as the droplet bottom layer over the contact area above the nanotube structure, and the other as the hemiwicking liquid in nanotubes. Both the vaporization is impaired by increasing the surface temperature, which is attributed to the reduced contact time and less extent of spread of the droplet at a higher surface temperature. The central jet phenomenon is driven by the vapor stream produced by hemiwicking liquid in the central area upon impact. It is enhanced and then suppressed by elevating the surface temperature, resulting from the collective effects of the vapor pressure in nanotubes which increases with the surface temperature, and the cross-sectional area of the vapor stream, which increases and then decreases with the surface temperature. At a high Weber number, the Leidenfrost temperature can be increased by 125∘C on the nanotube surface, implying a great potential in heat transfer enhancement for droplet-based applications.

关键词： Drop & bubble phenomena Drop breakup multiphase flows

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Mxene-Derived Ni/Tio2-X/Ti3c2 Catalyst for Enhanced Photothermal Co2 Methanation: Unraveling the Roles of Photoexcited Carriers

SSRN

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SSRN 2025年

作者： Sun, Fan Xin, Yu Xing, Xueli Lou, Jiahui Wang, Qiliang Hong, Hui International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China Institute of Engineering Thermophysics Chinese Academy of Sciences Beijing100190 China School of Aeronautics and Astronautics University of Chinese Academy of Sciences Beijing100049 China Huaneng Clean Energy Research Institute Beijing102209 China Shandong Institute of Advanced Technology Jinan250100 China Department of Architecture and Built Environment University of Nottingham NottinghamNG7 2RD United Kingdom Institute of Engineering Thermophysics China

Photothermal catalysis has emerged as a promising approach for CO2 conversion, which combines photo and thermal energy to drive catalytic reactions efficiently. While light can lower activation barriers and enhance reaction rates, the interplay between light and heat within the catalytic framework remains largely unexplored. In this study, we investigate the critical role of photoexcited carriers in enhancing catalytic performance under solar irradiation, unraveling their contribution to the CO2-to-CH4 conversion process. A multilayer accordion-like Ni/TiO2-x/Ti3C2 catalyst, which exhibits excellent photothermal and photoelectric response characteristics was fabricated for efficient photothermal CO2 methanation. Experimental results demonstrated that introduction of light during thermal catalysis markedly enhanced the CO2 conversion rate, with a 55% increase achieved at 275 ºC. Furthermore, the required temperature for maximum CO2 conversion rate was reduced by 50 ºC compared to the thermal-driven process. Meanwhile, the effects of concentrated ratio and incident wavelength on CO2 conversion were also examined, revealing a synergistic effect between photogenerated carriers and thermal energy. Further characterizations, including steady-state and transient photoluminescence spectroscopy, in-situ XPS, in-situ EPR, in-situ DRITFs, were employed to elucidate the enhancement mechanisms of photogenerated carriers in the catalytic reaction. At the same time, an outdoor experimental prototype was developed to verify the feasibility of photogenerated carrier-thermal synergistically driven CO2 methanation. The findings provide valuable insights into the role of photo-generated carriers in photothermal CO2 methanation, offering new perspectives for the design of efficient photothermal catalysts and advancing solar catalytic CO2 conversion technologies. © 2025, The Authors. All rights reserved.

关键词： Methanation

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Experimental and modeling study of low temperature ignition characteristics of methylcyclohexane/ethanol binary fuel 12

Experimental and modeling study of low temperature ignition ...

引用

12th Asia-Pacific Conference on Combustion, ASPACC 2019

作者： Liu, Yang Tang, Chenglong Huang, Zuohua State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an China

The purpose of this work is to investigate the effect of ethanol blending into methylcyclohexane during the ignition at low temperatures. The ignition delay times of the binary fuels with ethanol blending ratio varied from 0% to 100% at = 1.0, Pc = 20 bar, Tc = 680 - 890 K were measured with the rapid compression machine, and the mechanism of Bissoonauth et al. (Proc Combust Inst 2018) well predicts the experimental results. Based on the high quality of the model, the effects of ethanol blending on the pressure and heat release are studied. Both of the maximum pressure and the heat release during the ignition decrease with the ethanol blending ratio increases. The interaction of MCH and ethanol happens in the competition of active radicals like OH, and MCH dominates the ignition process as it occupies about two thirds of the OH to form the fuel radical. © Asia-Pacific Conference on Combustion, ASPACC *** right reserved.

关键词： Ethanol

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Corrigendum to ‘Experimental investigation of the microlayer and dry spot dynamic characteristics in a small channel flow boiling by laser interferometry method’ [International Journal of Heat and Mass Transfer 201 (2023) 123585]

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International Journal of Heat and Mass Transfer 2023年 209卷

作者： Zhong-Xiang Shen Ming Gao Wu-han Dong Li-xin Zhang Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering School of Energy and Power Engineering University of Shanghai for Science and Technology Shanghai 200093 China

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Thermal management matters in photovoltaic–electrocatalysis for solar hydrogen production

EcoEnergy

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EcoEnergy 2024年

作者： Jie Chen Xin Chen Jie Sun Jingkuo Qu Xiangjiu Guan Shaohua Shen School of Chemical Engineering and Technology Xi'an Jiaotong University Xi'an China International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an China

Photovoltaic–electrolysis (PV-EC) system currently exhibits the highest solar to hydrogen conversion efficiency (STH) among various technical routes. This perspective shifts the focus from the materials exploration in photovoltaics and electrolysis to the critical aspect of thermal management in a PV-EC system. Initially, the theoretical basis that elucidates the relationships between temperature and the performance of both photovoltaics and electrolyzers are presented. Following that, the impact of thermal management on the performance of PV-EC for solar hydrogen production is experimentally demonstrated by designing variables-controlling experiments. It is observed that while utilizing identical PV and EC cells under varying thermal conditions, the highest STH can reach 22.20%, whilst the lowest is only 15.61%. This variation underscores the significance of thermal management in optimizing PV-EC systems. Finally, increased efforts to enhancing heat transfer and optimizing heat distribution are proposed, thus facilitating the design of more efficient PV-EC systems with minimized thermal energy losses.

关键词： device design photovoltaic-electrolysis solar to hydrogen thermal management water electrolyzer

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Surface sulfurization activating hematite nanorods for efficient photoelectrochemical water splitting

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Science Bulletin 2019年第17期64卷 1262-1271页

作者： Lianlian Mao Yu-Cheng Huang Yanming Fu Chung-Li Dong Shaohua Shen International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China Department of Physics Tamkang University Tamsui 25137 Taiwan China

Surface treatment is an effective method to improve the photoelectrochemical(PEC) performance of photoelectrodes. Herein, we introduced a novel strategy of surface sulfurization to modify hematite(a-Fe2 O3)nanorods grown in an aqueous solution, which triggered encouraging improvement in PEC *** comparison to the solution-grown pristine a-Fe2 O3 nanorod photoanode that is PEC inefficient and always needs high temperature(>600 °C) activation, the surface sulfurized a-Fe2 O3 nanorods show photocurrent density increased by orders of magnitude, reaching 0.46 mA cmà2 at 1.23 V vs. RHE(reversible hydrogen electrode) under simulated solar illumination. This improvement in PEC performances should be attributed to the synergy of the increased carrier density, the reduced surface charge carrier recombination and the accelerated water oxidation kinetics at the a-Fe2 O3/electrolyte interface, as induced by the incorporation of S ions and the formation of multi-state S species(Fe-Sx-Oy) at the surface of a-Fe2 O3 nanorods. This study paves a new and facile approach to activate a-Fe2 O3 and even other metal oxides as photoelectrodes for improved PEC water splitting performances, by engineering the surface structure to relieve the bottlenecks of charge transfer dynamics and redox reaction kinetics at the electrode/electrolyte interface.

关键词： Photoelectrochemical Water splitting Hematite nanorods Photoanodes Surface sulfurization

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