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Ionic liquid engineering enabled in-plane orientated 1D perovskite nanorods for efficient mixed-dimensional perovskite photovoltaics

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InfoMat 2023年第8期5卷 81-93页

作者： Fei Wang Dawei Duan Kang Zhou YZBXue Xiao Liang Xianfang Zhou Chuangye Ge Chao Zhou Jin Xiang Jiajie Zhu Quanyao Zhu Haoran Lin Yumeng Shi Yonghua Chen Gang Li Hanlin Hu Hoffmann Institute of Advanced Materials Shenzhen PolytechnicShenzhenthe People's Republic of China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhanthe People's Republic of China Oxford Instruments Technology(Shanghai)Co.Ltd. Shanghaithe People's Republic of China International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education Institute of Microscale OptoelectronicsShenzhen UniversityShenzhenthe People's Republic of China School of Physics Science and Engineering Tongji UniversityShanghaithe People's Republic of China Key Laboratory of Flexible Electronics(KLoFE)&Institute of Advanced Materials(IAM) School of Flexible Electronics(Future Technologies)Nanjing Tech University(NanjingTech)Nanjingthe People's Republic of China Department of Electronic and Information Engineering Research Institute for Smart Energy(RISE)The Hong Kong Polytechnic UniversityKowloonHong Kongthe People's Republic of China

Mixed-dimensional engineering of perovskite material has been demonstrated as a facile and promising strategy to improve both photovoltaic performance and long-term stability of perovskite solar cells(PSCs).In this study,we report an in-plane preferred orientation of 1D perovskite induced by an ionic liquid(IL)of 1-(3-cyanopropyl)-3-methylimidazolium chloride(CPMIMCl)for the first time via sequential deposition approach,leading to a mixed dimensional perovskite thin *** generated one-dimensional(1D)CPMIMPbI3 with in-plane orientation resides at the grain boundaries of three-dimensional(3D)perovskite can be appreciably observed from the morphology level,leading to creation of high-quality films with large grain size with more efficient defect ***,the dispersion of IL in the bulk phase of perovskite material allows for the formation of 1D perovskite for multiple level passivation to inhibit non-radiative recombination and optimize carrier *** IL engineering strategy not only yields a mixed-dimensional perovskite heterostructure with in-plane orientation 1D perovskite nano-rods but also significantly improves the opto-electronic property with suppressed trap *** a result,the CPMIMCl-treated PSCs show an enhanced photovoltaic performance with a champion power conversion efficiency(PCE)up to 24.13%.More importantly,benefiting from the hydrophobicity of formed 1D perovskite and defects suppression,the corresponding PSC demonstrates an excellent longterm stability and maintain 97.1%of its pristine PCE at 25C under 50%RH condition over 1000 *** research provides an innovative perspective for employing the low dimensional engineering to optimize the performance and stability of photovoltaic devices.

关键词： 1D/3D perovskite ionic liquid perovskite solar cells stability

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Designing polymer nanocomposites with high energy density using machine learning

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npj Computational materials 2021年第1期7卷 999-1007页

作者： Zhong-Hui Shen Zhi-Wei Bao Xiao-Xing Cheng Bao-Wen Li Han-Xing Liu Yang Shen Long-Qing Chen Xiao-Guang Li Ce-Wen Nan State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Center of Smart Materials and DevicesWuhan University of TechnologyWuhanChina International School of Materials Science and Engineering Wuhan University of TechnologyWuhanChina Hefei National Laboratory for Physical Sciences at the Microscale Department of Physics and CAS Key Laboratory of Strongly-Coupled Quantum Matter Physics University of Science and Technology of China HefeiChina Department of Materials Science and Engineering The Pennsylvania State UniversityUniversity ParkPAUnited States School of Materials Science and Engineering State Key Lab of New Ceramics and Fine ProcessingTsinghua UniversityBeijingChina

Addressing microstructure-property relations of polymer nanocomposites is vital for designing advanced dielectrics for electrostatic energy ***,we develop an integrated phase-field model to simulate the dielectric response,charge transport,and breakdown process of polymer ***,based on 6615 high-throughput calculation results,a machine learning strategy is schemed to evaluate the capability of energy *** find that parallel perovskite nanosheets prefer to block and then drive charges to migrate along with the interfaces in x-y plane,which could significantly improve the breakdown strength of polymer *** verify our predictions,we fabricate a polymer nanocomposite P(VDF-HFP)/Ca_(2)Nb_(3)O_(10),whose highest discharged energy density almost doubles to 35.9 J cm^(−3) compared with the pristine polymer,mainly benefit from the improved breakdown strength of 853 MVm^(−1).This work opens a horizon to exploit the great potential of 2D perovskite nanosheets for a wide range of applications of flexible dielectrics with the requirement of high voltage endurance.

关键词： polymer energy perovskite

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Phosphorus-doped NiS_(2)electrocatalyst with a hybrid structure for hydrogen evolution

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Science China(Technological Sciences) 2022年第7期65卷 1506-1512页

作者： ZHOU Qi LIU HaoRui JIAO SunZhi FENG ChenChen State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals Lanzhou University of TechnologyLanzhou 730050China School of Materials Science and Engineering Lanzhou University of TechnologyLanzhou 730050China College of Mechanical Engineering Longdong UniversityQingyang 745000China

In this article,P-NiS_(2)/Ni_(x)P electrocatalysts were synthesized by dealloying the Ni-Al precursor followed by phosphosulfide *** found that the hybrid structure of P-NiS_(2)/Ni_(x)P provides rich active sites for the surface hydrogen evolution reaction (HER),and the doping of P enhances the electronic conductivity of *** particular,the obtained electrode shows a low overpotential of 196 mV at 10 mA cm^(-2)and a small Tafel slope of only 110 mV dec^(-1)in the ***,longterm constant current electrolysis test experiments indicate that P-NiS_(2)/Ni_(x)P has good service *** research will help to open a new window on the design and fabrication of HER electrocatalysts.

关键词： nickle phosphosulfides hybrid structure hydrogen evolution reaction dealloying

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Ultralow Interfacial Thermal Resistance of Graphene Thermal Interface materials with Surface Metal Liquefaction

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Nano-Micro Letters 2023年第1期15卷 183-196页

作者： Wen Dai Xing-Jie Ren Qingwei Yan Shengding Wang Mingyang Yang Le Lv Junfeng Ying Lu Chen Peidi Tao Liwen Sun Chen Xue Jinhong Yu Chengyi Song Kazuhito Nishimura Nan Jiang Cheng-Te Lin Key Laboratory of Marine Materials and Related Technologies Zhejiang Key Laboratory of Marine Materials and Protective TechnologiesNingbo Institute of Materials Technology and Engineering(NIMTE)Chinese Academy of SciencesNingbo 315201People’s Republic of China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049People’s Republic of China Institute of Advanced Technology Shandong UniversityJinan 250100People’s Republic of China Ningbo Institute of Materials Technology and Engineering(NIMTE) Chinese Academy of SciencesNingbo 315201People’s Republic of China The State Key Laboratory of Metal Matrix Composites School of Materials Science and EngineeringShanghai Jiao Tong University800 Dong Chuan RoadShanghai 200240People’s Republic of China Advanced Nano-Processing Engineering Lab Mechanical Systems EngineeringKogakuin UniversityTokyo 192-0015Japan

Developing advanced thermal interface materials(TIMs)to bridge heat-generating chip and heat sink for constructing an efficient heat transfer interface is the key technology to solve the thermal management issue of high-power semiconductor *** on the ultra-high basal-plane thermal conductivity,graphene is an ideal candidate for preparing high-performance TIMs,preferably to form a vertically aligned structure so that the basal-plane of graphene is consistent with the heat transfer direction of ***,the actual interfacial heat transfer efficiency of currently reported vertically aligned graphene TIMs is far from *** addition to the fact that the thermal conductivity of the vertically aligned TIMs can be further improved,another critical factor is the limited actual contact area leading to relatively high contact thermal resistance(20-30 K mm^(2) W^(−1))of the“solid-solid”mating interface formed by the vertical graphene and the rough chip/heat *** solve this common problem faced by vertically aligned graphene,in this work,we combined mechanical orientation and surface modification strategy to construct a three-tiered TIM composed of mainly vertically aligned graphene in the middle and micrometer-thick liquid metal as a cap layer on upper and lower *** on rational graphene orientation regulation in the middle tier,the resultant graphene-based TIM exhibited an ultra-high thermal conductivity of 176 W m^(−1) K^(−1).Additionally,we demonstrated that the liquid metal cap layer in contact with the chip/heat sink forms a“liquid-solid”mating interface,significantly increasing the effective heat transfer area and giving a low contact thermal con-ductivity of 4-6 K mm^(2) W^(−1) under packaging *** finding provides valuable guidance for the design of high-performance TIMs based on two-dimensional materials and improves the possibility of their practical application in electronic thermal management.

关键词： Vertically aligned graphene Liquid metal Surface modification Thermal interface materials

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High-entropy alloy nanocrystals boosting photocatalytic hydrogen evolution coupled with selective oxidation of cinnamyl alcohol

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Chinese Journal of Catalysis 2025年第1期68卷 326-335页

作者： Xianglin Xiang Bei Cheng Bicheng Zhu Chuanjia Jiang Guijie Liang Faculty of Materials Science and Engineering Kunming University of Science and TechnologyKunming 650093YunnanChina State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina Laboratory of Solar Fuel Faculty of Materials Science and ChemistryChina University of GeosciencesWuhan 430078HubeiChina College of Environmental Science and Engineering Nankai UniversityTianjin 300350China Hubei Key Laboratory of Low Dimensional Arts and Science Hubei University of Arts and ScienceXiangyang 441053HubeiChina

Photocatalysis provides a promising solution to the worldwide shortages of energy and industrially important raw materials by utilizing sunlight for coupled hydrogen(H_(2))production with controllable organic ***,we demonstrate that PtFeNiCoCu high-entropy alloy(HEA)nanocrystals can act as efficient cocatalysts for H_(2)evolution coupled with selective oxidation of cinnamyl alcohol to cinnamaldehyde by cubic cadmium sulfide(CdS)quantum dots(QDs)with uniform sizes of 4.0±0.5 *** nanocrystals were prepared via a simple solvothermal approach,and were successfully integrated with CdS QDs by an electrostatic self-assembly method to construct HEA/CdS *** optimized HEA/CdS sample presented an enhanced photocatalytic H_(2)production rate of 7.15 mmol g^(-1)h^(-1),which was 13 times that of pure CdS ***,a cinnamyl alcohol conversion of 96.2%with cinnamaldehyde selectivity of 99.5%was achieved after photoreaction for 3 *** integration of HEA with CdS QDs extended the optical absorption edge from 475 to 484 *** d-band center analysis,Pt atoms in the HEA are the active sites for H_(2)evolution,exhibiting higher catalytic activity than pure ***,the band structure of the CdS QDs enables the oxidative transformation of cinnamyl alcohol to cinnamaldehyde with high ***,femtosecond transient absorption spectroscopy shows that HEA can significantly promote the separation of photogenerated carriers in CdS,which is vital for achieving enhanced photocatalytic *** work inspires atomic-level design of photocatalytic materials for coordinated production of green energy carriers and value-added products.

关键词： Artificial photosynthesis d-Band center Photocatalytic hydrogen evolution Quantum dots Value-added organic synthesis

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A new strategy to access Co/N co-doped carbon nanotubes as oxygen reduction reaction catalysts

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Chinese Chemical Letters 2021年第1期32卷 535-538页

作者： Bingshuai Liu Huang Zhou Huihui Jin Jiawei Zhu Zhe Wang Chenxi Hu Lvhan Liang Shichun Mu Daping He State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Hubei Engineering Research Center of RF-Microwave Technology and Application Wuhan University of TechnologyWuhan 430070China

Carbon nanotubes(CNTs),as one-dimensional nanomaterials,show great potential in energy conversion and storage due to their efficient electrical conductivity and mass ***,the security risks,time-consuming and high cost of the preparation process hinder its further ***,we develop that a negative pressure rather than a following gas environment can promote the generation of cobalt and nitrogen co-doped CNTs(Co/N-CNTs) by using cobalt zeolitic imidazolate framework(ZIF-67) as a precursor,in which the negative pressure plays a key role in adjusting the size of cobalt nanoparticles and stimulating the rearragement of carbon atoms for forming ***,the obtained Co/N-CNTs,with high content of pyridinic nitrogen and abundant graphitized structure,exhibit superior catalytic activity for oxygen reduction reaction(ORR) with half-wave potential(E_(1/2)) of 0.85 V and durability in terms of the minimum current loss(2%) after the 30,000 s *** development provides a new pathway for large-scale and cost-effective preparation of metal-doped CNTs for various applications.

关键词： Negative pressure Cobalt zeolitic imidazolate framework Cobalt and nitrogen co-doped Carbon nanotubes Oxygen reduction reaction

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Fabrication and Property of SiC Ceramic with Large Thickness/Diameter Ratios

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Journal of Wuhan University of technology(materials Science) 2020年第3期35卷 506-513页

作者： TAN Lin HE Qianglong HU Lanxin TIAN Tian WANG Weimin State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Silicon carbide ceramics with different thicknesses/diameter ratios were prepared by using ultra-fine silicon carbide powder with the sintering additives of 1.0 wt% boron and 1.5 wt% carbon. The influence of thickness/diameter ratio on the microstructure and density of SiC ceramics was investigated in detail. The experimental results show that the addition of boron and carbon sintering aids can promote the densification process of SiC ceramic, leading to the low sintering temperature and improve mechanical properties. At 1950 ℃, SiC ceramic with a density of 99% exhibits Young's modulus, hardness, and flexural strength of 476 MPa, 28.3 GPa, and 334 MPa, respectively. It is found that long holding time has a positive effect on the uniformity of the microstructure and density distribution of SiC ceramics with large thickness/diameter ratios. Additionally, the sintering additive of boron can solid-solve into SiC, and then facilitate the phase transformation of SiC to form 6H-SiC and 4H-SiC composite ceramics.

关键词： SiC large thickness/diameter ratios mechanical properties uniformity

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Fabrication and Characterization of Pressure Sensors Based on Xanthan Gum and Pullulan 16

Fabrication and Characterization of Pressure Sensors Based o...

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16th Textile Bioengineering and Informatics Symposium, TBIS 2023

作者： Zhang, Ya-Qi Liu, Shi-Yao Tao, Yong-Zhen State Key Laboratory for Textile Materials and Advanced Processing Technology Wuhan Textile University Wuhan China College of Material Science and Engineering Wuhan Textile University Wuhan China

ISBN: (纸本)9781713879473

Conductive hydrogels based on biopolymers have potential applications in the field of wearable devices, implantable devices, and human-machine interfaces due to their biocompatibility as well as conductivity. However, hydrogels are prone to water loss under dry atmospheres. In this paper, a biopolymer-based pressure sensor with water retention was designed. Xanthan gum (XG) and pullulan (P) were cross-linked with sodium trimetaphosphate (STMP) to prepare XG5-P-STMP, and polyethylene glycol with a molecular weight of 200 (PEG200) was added into hydrogels to improve moisture retention. The mechanical properties of the hydrogels were investigated by rheologic measurements such as time sweep, frequency sweep, and strain sweep. The results showed that the addition of PEG200 enhanced strength and moisture retention of the hydrogels, and high PEG200 content hindered the recovery property of the hydrogels. Furthermore, the XG5-P-PEG-STMP hydrogel with ionic conductivity and recoverability was explored as a pressure sensor, and the resistance change ratio exhibited repeatable profile. This work provides some valuable information for further applications of natural polysaccharides as intelligent flexible elections. © TBIS 2023. All rights reserved.

关键词： Hydrogels

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Structure stability, electronic property and voltage profile of LiFe_(1-n)NnP_(1-m)M_(m)O_(4) olivine cathode material

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Rare Metals 2021年第12期40卷 3512-3519页

作者： Zhi-Hong Cui Xue-Feng Lu Jian-Hua Luo Xin Guo Hong-Tao Xue Fu-Ling Tang State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metal Department of Materials Science and EngineeringLanzhou University of TechnologyLanzhou 730050China

First-principles computational studies under density functional theory(DFT) framework were used to investigate the structural stability, conductivity and voltage profile of LiFe_(1-n)NnP_(1-m)M_(m)O_(4)(N, M = Si or S) electrode materials. It is found that the Li FeP_(7/8)Si_(1/8)O_(4) system has the most stable structure. After doping, the band gap values of the systems decrease gradually, and LiFe_(7/8)S_(1/8)PO_(4) system has a minimum band gap of 1.553 e V, attributed to the hybridization of the Fe-d and S-p orbital electrons. The Li Fe P7/8 S1/8 O4 system demonstrates the characteristic of n-type semiconductor, and other doping systems have the feature of p-type semiconductor. Charge density difference maps show that the covalent property of Si-O bond is enhanced in the Li FeP_(7/8)Si_(1/8)O_(4) system. The average distance of Li and O atoms in the S doping systems increases from 0.21026 to 0.21486 and 0.21129 nm, respectively,indicating that doping broadens significantly the channel of Li ion de-intercalation in LiFe_(7/8)S_(1/8)PO_(4) and LiFeP_(7/8)S_(1/8)O_(4). Additionally, the results of lithium intercalation potential imply that the voltages of the doping systems fallinto the range of 2.23-2.86 V.

关键词： Energy storage materials First principles Battery cathode LiFePO_(4) Doping Electronic properties

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Flame-retardant Cotton Fabric based on Electrostatic Layer-by-layer Assembly of Vermiculite 16

Flame-retardant Cotton Fabric based on Electrostatic Layer-b...

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16th Textile Bioengineering and Informatics Symposium, TBIS 2023

作者： Cheng, Hong-Bin Liu, Xiao-Shu Xiao, Shi-Li School of Textile Science and Engineering Wuhan Textile University Wuhan430200 China State Key Laboratory of New Textile Materials & Advanced Processing Technology Wuhan430200 China

ISBN: (纸本)9781713879473

Flame-retardant cotton fabric, in clothing and decoration, can reduce the damage in a fire. This study reports a facile way to prepare vermiculite-assembled cotton fabrics using layer by layer assemble technique. The vermiculite-assembled cotton fabrics synthesized are characterized by SEM, FTIR, Instron and a vertical inflammability test. The results show that vermiculite assembled on cotton fabrics could improve the mechanical property and endow the fabric with the good flame-retardant property. © TBIS 2023. All rights reserved.

关键词： Cotton fabrics

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