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Vapor-phase conversion of waste silicon powders to silicon nanowires for ultrahigh and ultra-stable energy storage performance

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Journal of Energy Chemistry 2025年第3期102卷 27-36页

作者： Hao Li Qiushi Chen Lili Feng Yueling Zou Xuzhong Gong Zhi Wang Junhao Liu CAS Key Laboratory of Green Process and Engineering and National Engineering Research Center of Green Recycling for Strategic Metal Resources Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China School of Chemical&Environmental Engineering China University of Mining&TechnologyBeijing 100083China University of Chinese Academy of Sciences Beijing 100049China

Silicon nanowires(SiNWs)have been used in a wide variety of applications over the past few decades due to their excellent material *** only drawback is the high production cost of *** preparation of SiNWs from photovoltaic waste silicon(WSi)powders,which are high-volume industrial wastes,not only avoids the secondary energy consumption and environmental pollution caused by complicated recycling methods,but also realizes its high-value ***,we present a method to rapidly convert photovoltaic WSi powders into SiNWs *** flash heating and quenching provided by carbothermal shock induce the production of free silicon atoms from the WSi powders,which are rapidly reorganized and assembled into SiNWs during the vapor-phase *** method allows for the one-step composite of SiNWs and carbon cloth(CC)and the formation of SiC at the interface of the silicon(Si)and carbon(C)contact to create a stable chemical *** obtained SiNWs-CC(SiNWs@CC)composites can be directly used as lithium anodes,exhibiting high initial coulombic efficiency(86.4%)and stable cycling specific capacity(2437.4 mA h g^(-1)at 0.5 A g^(-1)after 165 cycles).In addition,various SiNWs@C composite electrodes are easily prepared using this method.

关键词： Photovoltaicwastesilicon powders Silicon nanowires Vapor-phaseconversion Lithium-ion batteries Silicon-carbon anode electrode

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Characterization of nonlinear spectral linewidth and light shift in diffuse laser-cooled atoms

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Chinese Physics B 2025年第2期34卷 250-255页

作者： Yiran Yin An-Ning Xu Jin Peng Bei Liu Key Laboratory of Laser and Infrared System Ministry of EducationCenter for Optics Research and Engineering(CORE)Shandong UniversityQingdao 266237China

We demonstrate an integrating sphere to cool~(87)Rb atoms and measure the recoil-induced resonance and electromagnetically induced absorption *** measure the relationship between their linewidth and light shift with variation of the detuning and power of the cooling laser and study the performance of the diffuse laser cooling mechanism by the absorption linewidth radio?ν_E/?ν_R and light shift|?_R-?_E|using nonlinear ***,when?ν_E/?ν_R reaches a value of 1.57,the temperature and number of cold atoms achieve the optimal cooling *** characterization of absorption linewidth and light shift will provide a method to estimate whether diffuse light cooling achieves the best cooling effect,contributing to the future development of isotropic laser cooling for application in quantum sensing.

关键词： nonlinear spectrum diffuse laser cooling temperature measurement

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Lithium Salt Combining Fluoroethylene Carbonate Initiates Methyl Methacrylate Polymerization Enabling Dendrite-Free Solid-State Lithium Metal Battery

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Energy & Environmental Materials 2024年第6期7卷 50-59页

作者： Xue Ye Jianneng Liang Baorong Du Yongliang Li Xiangzhong Ren Dazhuan Wu Xiaoping Ouyang Qianling Zhang Jianhong Liu Institute of Process Equipment College of Energy EngineeringZhejiang UniversityHangzhou310000 China Graphene Composite Research Center College of Chemistry and Environmental EngineeringShenzhen UniversityShenzhen518061 China

This work demonstrates a novel polymerization-derived polymer electrolyte consisting of methyl methacrylate,lithium bis(trifluoromethanesulfonyl)imide and fluoroethylene *** polymerization of MMA was initiated by the amino compounds following an anionic catalytic *** plays both roles including the initiator and Li ion source in the polymer ***,lithium bis(trifluoromethanesulfonyl)imide has difficulty in initiating the polymerization reaction of methyl methacrylate monomer,a very high concentration of lithium bis(trifluoromethanesulfonyl)imide is needed for initiating the ***,the fluoroethylene carbonate additive can work as a supporter to facilitate the degree of dissociation of lithium bis(trifluoromethanesulfonyl)imide and increase its initiator capacity due to the high dielectric *** as-prepared poly-methyl methacrylate-based polymer electrolyte has a high ionic conductivity(1.19×10^(−3)S cm^(−1)),a wide electrochemical stability window(5 V vs Li^(+)/Li),and a high Li ion transference number(t_(Li^(+)))of 0.74 at room temperature(RT).Moreover,this polymerization-derived polymer electrolyte can effectively work as an artificial protective layer on Li metal anode,which enabled the Li symmetric cell to achieve a long-term cycling performance at 0.2 mAh cm^(−2)for 2800 *** LiFePO_(4)battery with polymerization-derived polymer electrolyte-modified Li metal anode shows a capacity retention of 91.17%after 800 cycles at 0.5 *** work provides a facile and accessible approach to manufacturing poly-methyl methacrylate-based polymerization-derived polymer electrolyte and shows great potential as an interphase in Li metal batteries.

关键词： in situ polymerization lithium anode polymer electrolyte solid-state lithium batteries

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Reconstruction and recovery of anatase TiO_(2) from spent selective catalytic reduction catalyst by Na OH hydrothermal method

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Chinese Journal of Chemical engineering 2023年第8期60卷 53-60页

作者： Jinlong Liu Chenye Wang Xingrui Wang Chen Zhao Huiquan Li Ganyu Zhu Jianbo Zhang CAS Key Laboratory of Green Process and Engineering National Engineering Research Center of Green Recycling for Strategic Metal ResourcesInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China School of Chemical Engineering University of Chinese Academy of SciencesBeijing 100049China

The improper disposal of spent selective catalytic reduction (SCR) catalysts causes environmental pollution and metal resource waste.A novel process to recover anatase titanium dioxide (TiO_(2)) from spent SCR catalysts was *** process included alkali (NaOH) hydrothermal treatment,sulfuric acid washing,and *** TiO_(2) in spent SCR catalyst was reconstructed by forming Na_(2)Ti_(2)O_(4)(OH)_(2) nanosheet during NaOH hydrothermal treatment and H_(2)Ti_(2)O_(4)(OH)_(2) during sulfuric acid *** TiO_(2) was recovered by decomposing H_(2)Ti_(2)O_(4)(OH)_(2) during *** surface pore properties of the recovered anatase TiO_(2) were adequately improved,and its specific surface area (SSA) and pore volume (PV) were 85 m^(2)·g^(-1)and 0.40 cm^(3)·g^(-1),*** elements affecting catalytic abilities(arsenic and sodium) were also *** SCR catalyst was resynthesized using the recovered TiO_(2) as raw material,and its catalytic performance in NO selective reduction was comparable with that of commercial SCR *** study realized the sustainable recycling of anatase TiO_(2) from spent SCR catalyst.

关键词： TiO_(2)reconstruction Anatase TiO_(2)recovery Pore properties Spent V_(2)O_(5)-WO_(3)/TiO_(2)catalyst

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Strategically designing and fabricating nitrogen and sulfur Co-doped g-C3N4 for accelerating photocatalytic H2 evolution

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材料科学技术（英文版） 2025年第5期208卷 111-119页

作者： Haitao Wang Lianglang Yu Jiahe Peng Jing Zou Jizhou Jiang School of Chemistry and Environmental Engineering School of Environmental Ecology and Biological EngineeringKey Laboratory of Green Chemical Engineering Process of Ministry of EducationEngineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationNovel Catalytic Materials of Hubei Engineering Research CenterWuhan Institute of TechnologyWuhan 430205China State Key Laboratory of Silicate Materials for Architectures Wuhan University of TechnologyWuhan 430070China

Doping engineering is an effective strategy for graphitic carbon nitride(g-C3N4)to improve its photocat-alytic hydrogen evolution reaction(HER)*** this work,a novel nitrogen and sulfur co-doped g-C3N4(N,S-g-C3N4)is elaborately designed on the basis of theoretical predictions of first-principle density functional theory(DFT).The calculated Gibbs free energy of adsorbed hydrogen(ΔGH·)for N,S-g-C3N4 at the N-doping active sites is extremely close to zero(0.01 eV).Inspired by the theoretical predictions,the N,S-g-C3N4 is successfully fabricated through ammonia-rich pyrolysis synthesis strategy,in which ammonia is in-situ obtained by pyrolyzing *** characterizations indicate that the N,S-g-C3N4 possesses high specific surface area,outstanding light utilization,good hydrophilicity,and efficient carrier transfer ***,the N,S-g-C3N4 displays an extremely high H2 evolution rate of 8269.9 μmol g-1 h-1,achieves an apparent quantum efficiency(AQE)of 3.24％,and also possesses outsatnding *** calculations further demonstrate that N and S dopants can not only introduce doping energy level to reduce the band gap,but also induce charge redistribution to facilitate hydrogen adsorption,thus promoting the photocatalytic HER ***,femtosecond transient absorption(fs-TA)spectroscopy further corroborates the efficient photogenerated carrier transport of N,*** research highlights a promising and reliable strategy to achieve superior photocatalytic activity,and exhibits significant guidance for precise designing high-efficiency photocatalysts.

关键词： Theoretical predictions g-C3N4 N and S co-doping Photocatalytic H2 evolution

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Piezoelectric-enhanced BiOBr/UiO-66-NH2（Hf） photocatalysts for purification of mixed pollutants

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Science China Technological Sciences 2025年第5期68卷 91-105页

作者： Tingting YU Chenyu YANG Ran DENG Yonghang ZHANG Jiajun LI Tao YANG Jizhou JIANG School of Environmental and Chemical Engineering Jiangsu Ocean University School of Materials Science and Engineering Key Laboratory of Green Chemical Engineering Process of Ministry of EducationEngineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationWuhan Institute of Technology

The simultaneous purification of multiple mixed pollutants holds significant practical value in addressing the growing environmental challenges of today. In this work, UiO-66-NH2（Hf） octahedrons were successfully synthesized and grown on BiOBr nanosheets to form a novel heterojunction, BiOBr/UiO-66-NH2（Hf）. This BiOBr/UiO-66-NH2（Hf） heterojunction exhibits enhanced photocatalytic degradation and reduction activities. Specifically, the degradation rate of tetracycline hydrochloride（TC） reached 84.8%, while the reduction efficiency of Cr（Ⅵ） approached 100%, demonstrating the material's effectiveness in simultaneously purifying mixed pollutants. Furthermore, when ultrasonic force was applied, the degradation rate of TC increased from 57.1% to 84.8%, and the reduction rate of Cr（Ⅵ） improved from 73.5% to 100%. These results highlight the material's excellent piezoelectric properties, which were confirmed through density functional theory calculations and piezoresponse force microscopy. This work introduces a novel piezoelectric-coupled photocatalyst that offers a new strategy for the efficient purification of mixed pollutants. Additionally, it demonstrates that TC can promote the reduction of Cr（Ⅵ） in place of hole quenchers, while simultaneously undergoing degradation. This approach reveals promising prospects for the effective removal of mixed pollutants.

关键词： piezoelectric effect tetracycline hydrochloride photocatalytic degradation Cr(VI) reduction mixed pollutant purification

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Secure Speculation via Speculative Secret Flow Tracking

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Journal of Computer Science & Technology 2023年第2期38卷 422-438页

作者：崔宏伟杨春程旭 School of Computer Science Engineering Research Center of Microprocessor and System Peking UniversityBeijing 100871China

Speculative execution attacks can leak arbitrary program data under malicious speculation,presenting a severe security *** on two key observations,this paper presents a software-transparent defense mechanism called speculative secret flow tracking(SSFT),which is capable of defending against all cache-based speculative execution attacks with a low performance ***,we observe that the attacker must use array or pointer variables in the victim code to access arbitrary memory ***,we propose a strict definition of secret data to reduce the amount of data to be ***,if the load is not data-dependent and control-dependent on secrets,its speculative execution will not leak any ***,this paper introduces the concept of speculative secret flow to analyze how secret data are obtained and propagated during speculative *** tracking speculative secret flow in hardware,SSFT can identify all unsafe speculative loads(USLs)that are dependent on ***,SSFT exploits three different methods to constrain USLs’speculative execution and prevent them from leaking secrets into the cache and translation lookaside buffer(TLB)*** paper evaluates the performance of SSFT on the SPEC CPU 2006 workloads,and the results show that SSFT is effective and its performance overhead is very *** defend against all speculative execution attack variants,SSFT only incurs an average slowdown of 4.5%(Delay USL-L1Miss)or 3.8%(Invisible USLs)compared to a non-secure *** analysis also shows that SSFT maintains a low hardware overhead.

关键词： cache side channel attack hardware speculative execution attack security

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Built-in electric field intensified by photothermoelectric effect drives charge separation over Z-scheme 3D/2D In_(2)Se_(3)/PCN heterojunction for high-efficiency photocatalytic CO_(2) reduction

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Journal of Materials Science & Technology 2024年第12期179卷 251-261页

作者： Hongjun Dong Lei Tong Pingfan Zhang Daqiang Zhu Jizhou Jiang Chunmei Li Institute of Green Chemistry and Chemical Technology School of Chemistry and Chemical EngineeringJiangsu UniversityZhenjiang 212013China School of Environmental Ecology and Biological Engineering Key Laboratory of Green Chemical Engineering Process of Ministry of EducationEngineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationNovel Catalytic Materials of Hubei Engineering Research CenterWuhan Institute of TechnologyWuhan 430205China

It is a challenging issue to further drive charge separation through the oriented design of Z-scheme het-erojunction in the exploitation of cost-effective photocatalytic *** this contribution,the unique Z-scheme 3D/2D In_(2)Se_(3)/PCN heterojunction is developed through implanting In_(2)Se_(3) microspheres on PCN nanosheets using an in situ growth technique,which acquires the effective CO generation activity from photocatalytic CO_(2) reduction(CO_(2)R).The CO yield of 4 h in the CO_(2)R reaction over the optimal In_(2)Se_(3)/PCN-15 sample reaches up to 11.40 and 2.41 times higher than that of individual PCN and In_(2)Se_(3),*** greatly enhanced photocatalytic performance is primarily the improvement of photo-generated carrier separation *** be more specific,the formed built-in electric field is signifi-cantly intensified by producing the temperature difference potential between In_(2)Se_(3) and PCN owing to the photothermoelectric effect of In_(2)Se_(3),which actuates the high-efficiency separation of photogenerated charge carriers along the Z-scheme transfer path in the In_(2)Se_(3)/PCN *** effective strat-egy of enhancing the built-in electric field to drive photogenerated charge separation proposed in this work opens up an innovative avenue to design Z-scheme heterojunction applied to high-efficiency pho-tocatalytic reactions,such as hydrogen generation from water splitting,CO_(2)R,and degradation of organic pollutants.

关键词： In_(2)Se_(3)/PCN Z-scheme heterojunction Photocatalytic CO_(2) reduction Enhanced built-in electric field Photothermoelectric effect

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Effects of sulfur on variations in the chemical speciation of heavy metals from fly ash glass

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Frontiers of Environmental Science & engineering 2023年第10期17卷 133-145页

作者： Yali Chang Jianwei Cao Wenfeng Song Zhi Wang Chenyang Xu Mengzhuo Long School of Mechanical Electronic and Information Engineering China University of Mining and TechnologyBeijing 100083China CAS Key Laboratory of Green Process and Engineering National Engineering Research Center of Green Recycling for Strategic Metal ResourcesInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China

This work designed a new CaO-Al_(2)O_(3)-SiO_(2)-SO3 glass for the immobilization of multiple heavy metals found in dechlorinated fly ash having high amounts of calcium and sulfur. Increasing the (CaO + SO3)/SiO_(2) mass ratio (M(CS/S)) from 0.28 to 0.85 was found to lower the proportions of Mn, Ni and Zn in an unstable state, while an M(CS/S) ratio of 0.51 gave the lowest proportions of unstable Cr and Pb. Decreasing the degree of polymerization of the glassy network increased the proportions of Mn, Cr, Ni, Pb and Zn in the carbonate bound state. The leaching out of metals in this state was the primary cause of degradation of Q^(3) structural units in the glassy network. The amount of Mn in the iron-manganese oxide bound state was increased by increasing the number of Q^(2) units in the silicate network. Decreasing the CaO/SiO_(2) mass ratio (M(C/S)) raised the proportions of Mn, Ni and Zn in the unstable state. An M(C/S) value of 0.43 lowered the proportions of unstable Cr and Pb. A principal components analysis determined that the leaching of toxic heavy metals from the glass was primarily related to the proportions of these metals in the unstable state while there were no evident correlations between leaching and the proportions in stable states.

关键词： Dechlorinated fly ash SO_(3) Heavy metal Chemical speciation Glass solidification

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Structure-phase transformation of bismuth oxide to BiOCl/Bi_(24)O_(31)Cl_(10)shoulder-by-shoulder heterojunctions for efficient photocatalytic removal of antibiotic

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Journal of Environmental Sciences 2025年第3期149卷 149-163页

作者： Man Yang Zhenzhen Shi Shaodong Sun Bian Yang Jie Cui Jianing Li Daqin Yun Nian Lei Engineering Research Center of Conducting Materials and Composite Technology Ministry of EducationShaanxi Engineering Research Center of Metal-Based Heterogeneous Materials and Advanced Manufacturing TechnologyShaanxi Province Key Laboratory for Electrical Materials and Infiltration TechnologySchool of Materials Science and EngineeringXi’an University of TechnologyXi’an 710048China College of Energy Xiamen UniversityXiamen 361005China Beijing Key Laboratory of Ionic Liquids Clean Process Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China

Developing heterojunction photocatalyst with well-matched interfaces andmultiple charge transfer paths is vital to boost carrier separation efficiency for photocatalytic antibiotics removal,but still remains a great *** present work,a new strategy of chloride anion intercalation in Bi_(2)O_(3)via one-pot hydrothermal process is *** as-prepared Ta-BiOCl/Bi_(24)O_(31)Cl_(10)(TBB)heterojunctions are featured with Ta-Bi_(24)O_(31)Cl_(10)and Ta-BiOCl lined shoulder-by-shouleder via semi-coherent *** this TBB heterojunctions,the well-matched semi-coherent interfaces and shoulder-by-shoulder structures provide fast electron transfer andmultiple transfer paths,respectively,leading to enhanced visible light response and improved photogenerated charge ***,a type-II heterojunction for photocharge separation has been obtained,in which photogenerated electrons are drove from the CB(conduction band)of Ta-Bi_(24)O_(31)Cl_(10)to the both of bilateral empty CB of Ta-BiOCl and gathered on the CB of Ta-BiOCl,while the photogenerated holes are left on the VB(valence band)of Ta-Bi_(24)O_(31)Cl_(10),effectively hindering the recombination of photogenerated electron-hole ***,the separated electrons can effectively activate dissolved oxygen for the generation of reactive oxygen species(·O_(2)^(−)).Such TBB heterojunctions exhibit remarkably superior photocatalytic degradation activity for tetracycline hydrochloride(TCH)solution to Bi_(2)O_(3),Ta-BiOCl and Ta-Bi_(24)O_(31)Cl_(10).This work not only proposes a Ta-BiOCl/Bi_(24)O_(31)Cl_(10)shoulder-by-shoulder micro-ribbon architectures with semi-coherent interfaces and successive type-Ⅱheterojunction for highly efficient photocatalytic activity,but offers a new insight into the design of highly efficient heterojunction through phasestructure synergistic transformation strategy.

关键词： Heterojunction Bismuth oxide Charge separation/transfer Photocatalytic degradation Catalytic mechanism

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