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Non-thermal plasma-catalytic processes for CO2 conversion toward circular economy: fundamentals, current status, and future challenges

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environmental science and Pollution Research 2024年 1-21页

作者： Mukhtar, Ahmad Saqib, Sidra Mohotti, Dinithi Ndeddy Aka, Robinson Jr. Hossain, Mokter Agyekum-Oduro, Ekow Wu, Sarah Department of Chemical and Biological Engineering University of Idaho MoscowID83843 United States Environmental Science Program University of Idaho MoscowID83844 United States

Practical and energy-efficient carbon dioxide (CO2) conversion to value-added and fuel-graded products and transitioning from fossil fuels are promising ways to cope with climate change and to enable the circular economy. The carbon circular economy aims to capture, utilize, and minimize CO2 emissions as much as possible. To cope with the thermodynamic stability and highly endothermic nature of CO2 conversion via conventional thermochemical process, the potential application of non-thermal plasma (NTP) with the catalyst, i.e., the hybrid plasma catalysis process to achieve the synergistic effects, in most cases, seems to promise alternatives under non-equilibrium conditions. This review focuses on the NTP fundamentals and comparison with conventional technologies. A critical review has been conducted on the CO2 reduction with water (H2O), methane (CH4) reduction with CO2 to syngas (CO + H2), CO2 dissociation to carbon monoxide (CO), CO2 hydrogenation, CO2 conversion to organic acids, and one-step CO2–CH4 reforming to the liquid chemicals. Finally, future challenges are discussed comprehensively, indicating that plasma catalysis has immense investigative areas. © The Author(s) 2024.

关键词： Circular economy

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Long-term performance: strength and metal encapsulation in alkali-activated iron ore tailings

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environmental science and Pollution Research 2024年第34期31卷 47071-47083页

作者： Levandoski, William Mateus Kubiaki Ferrazzo, Suéllen Tonatto Piovesan, Maria Alice Bruschi, Giovani Jordi Consoli, Nilo Cesar Korf, Eduardo Pavan Graduate Program in Environmental Science and Technology Universidade Federal da Fronteira Sul RS Erechim99700-970 Brazil Graduate Program in Civil Engineering Universidade Federal Do Rio Grande Do Sul RS Porto Alegre90035-190 Brazil Undergraduate Program in Environmental and Sanitary Engineering Universidade Federal da Fronteira Sul RS Erechim99700-970 Brazil

Understanding the strength behavior and leaching characteristics of mining tailings stabilized with alkali-activated cements in the short, medium, and long term is crucial for the feasibility of material applications. In this context, this study assessed the stabilization/solidification of iron ore tailings (IOT) using alkali-activated binder (AAB) composed of sugarcane bagasse ash and eggshell lime at curing times of 7, 28, 60, 90, 180, and 365 days. Additionally, leaching tests were conducted, along with the examination of possible changes in the chemical and mineralogical composition resulting from exposure to acidic environments. Tests included unconfined compression strength (UCS), leaching, X-ray diffraction, and Fourier-transform infrared spectroscopy for the IOT-AAB mixtures. The highest increase in UCS was observed between 7 and 60 days, reaching 6.47 MPa, with minimal variation thereafter. The AAB-bonded IOT exhibited no metal toxicity over time. Elements Ba, Mn, Pb, and Zn present in IOT and ash were encapsulated in the cemented matrix, with complete encapsulation of all metals observed from 90 days of curing time. The mineralogy of the stabilized/solidified tailings showed no changes resulting from leaching tests. Characteristic bands associated with the presence of N-A-S–H gel were identified in both pre-leaching and post-leaching samples for all curing times analyzed. Exposure to acidic environments altered bands related to carbonate bonds formed in the IOT-AAB mixture. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.

关键词： Lime

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Ethane integration project—a study for Egyptian NGLs plants and their economics

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Journal of engineering and Applied science 2024年第1期71卷 169页

作者： Elzohairy, Hamdy R. Ahmed, Tamer S. El-Marsafy, Sahar M. Chemical Engineering Department Faculty of Engineering Cairo University Giza12613 Egypt New Cairo Egypt Environmental Engineering Program Zewail City of Science and Technology 6th of October City Giza12578 Egypt

For Egypt, ethane is a vital chemical precursor, with the potential to significantly attract financial resources and drive economic growth. Enhancing its added value necessitates efficient recovery of ethane before it enters the national grid without processing. This research investigates the technical and economic feasibility of integrating natural gas liquids (NGLs) from three Egyptian NGLs plants—South Western Desert NGLs (SWD NGLs), North Western Desert NGLs (NWD NGLs), and East Mediterranean NGLs (EMD NGLs)—to improve ethane recovery from natural gas fields. The study focuses on revamping these NGLs plants using various NGLs recovery techniques, conducting a comprehensive comparison to identify the most effective methods for processing rich feed gas. Detailed design of the NGLs recovery processes was developed using HYSYS V.14 simulation software and supplementary calculation sheets. The design criteria encompass both technical and economic parameters to ensure a holistic approach in meeting project requirements. Results indicate a significant increase in ethane recovery: 16% for SWD NGLs, 10% for NWD NGLs (A, B, C), and 85% for EMD NGLs. This improvement will boost ethane feedstock for petrochemical companies from 2000 ton/day to 3500 ton/day, enabling increased polyethylene production. Economic analysis for the base case shows an expected internal rate of return (IRR) of 26%, a net present value (NPV) of USD 73 million, and a payback period of approximately 3 years. Sensitivity analysis on product prices, feed gas prices, and total capital investment confirms the project’s economic viability, with all cases showing feasibility (IRR ≥ 15%) except when product prices fall below USD 225/ton for propane, USD 215/ton for liquefied petroleum gas (LPG), and USD 25/bbl for condensate. This study highlights the potential for enhanced ethane recovery, offering substantial economic benefits and supporting the growth of Egypt’s petrochemical industry. © The Author(s) 202

关键词： Ethane

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Synergistic effect of silicon availability and salinity on metal adsorption in a common estuarine diatom

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Journal of environmental sciences 2025年第2期148卷 364-374页

作者： Fengyuan Chen Jie Ma Ke Pan SZU-HKUST Joint PhD Program in Marine Environmental Science Shenzhen UniversityShenzhen 518060China Shenzhen Key Laboratory of Marine Microbiome Engineering Institute for Advanced StudyShenzhen UniversityShenzhen 518060China Department of Ocean Science The Hong Kong University of Science and TechnologyHong Kong 999077China

Increasing nitrogen and phosphorus discharge and decreasing sediment input have made silicon(Si)a limiting element for diatoms in *** in nutrient structure and salinity fluctuation can greatly affect metal uptake by estuarine ***,the combined effects of Si and salinity on metal accumulation in these diatoms have not been *** this study,we aimed to investigate how salinity and Si availability combine to influence the adsorption of metals by a widely distributed diatom Phaeodactylum *** data indicate that replete Si and low salinity in seawater can enhance cadmium and copper adsorption onto the diatom *** the single-cell level,surface potential was a dominant factor determining metal adsorption,while surface roughness also contributed to the highermetal loading capacity at lower *** a combination of noninvasive micro-test technology,atomic force microscopy,X-ray photoelectron spectroscopy,and Fourier transform infrared spectroscopy,we demonstrate that the diversity and abundance of the functional groups embedded in diatom cell walls vary with salinity and Si *** results in a change in the cell surface potential and transient metal *** study provides novel mechanisms to explain the highly variable metal adsorption capacity of a model estuarine diatom.

关键词： Diatom Metal adsorption Silicon Salinity Functional group Surface potential

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Biosurfactant-Enhanced Remediation of Oil-Contaminated Groundwater

Biosurfactant-Enhanced Remediation of Oil-Contaminated Groun...

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2024 SPE Europe Energy Conference and Exhibition, EURO 2024

作者： Sanchez-Huerta, C. Hong, P.-Y. Zhang, S. Alahmari, M.M. Humam, A.A. Environmental Science and Engineering Program Biological and Environmental Science and Engineering Division King Abdullah University of Science and Technology Thuwal Saudi Arabia Saudi Aramco’s EXPEC Advanced Research Center Dhahran Saudi Arabia

ISBN: (纸本)9781959025399

Groundwater contaminated with hydrocarbons poses a serious hazard to the environment. Current oil-contaminated groundwater remediation techniques include physical, chemical, and biological approaches. Chemical surfactants have the potential of high toxicity due to their low biodegradability. Biosurfactants have demonstrated similar performance to that of chemical surfactants, with the added value of low toxicity. The use of surfactants directly over the top layer of crude oil-contaminating groundwater, where environmental conditions are different from that in above ground surfaces, have yet not been explored in depth. Therefore, this study aims to investigate the potential of four different surfactants for their ability to be deployed in conditions mimicking underground aquifer so as to enhance remediation of oil-contaminated groundwater. Selected surfactants comprised two chemical surfactants, referred to as A and B, and two biosurfactants, referred to as BS and C. Surfactants were evaluated for their ability (i) to reduce the crude oil layer thickness through facilitating oil dispersion, and (ii) the extent of natural biodegradation it can achieve. Experiments were performed in glass flasks containing synthetic groundwater and crude oil supplemented with surfactant added at the three different surfactants: oil ratios (S:O) 1:5, 1:10 and 1:50. Reduction of crude oil layer thickness, water turbidity, and bacterial cell count were continuously monitored for 60 days to observe the temporal variation of biosurfactant activity towards crude oil. The performance of surfactants A, C and BS in reducing oil layer thickness was influenced by temperature and S:O ratios. Overall, increase in temperature increased the performance of these three surfactants. S:O ratio was optimal at 1:10 for surfactants A and BS, and at 1:5 for surfactant C. Surfactants A and C reduced the oil layer thickness mainly by means of dispersion and less by biodegradation. In contrast, surfactant BS ex

关键词： Surface active agents

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Hybrid Solution to Remediate Groundwater Contaminated by Petroleum-Hydrocarbons

Hybrid Solution to Remediate Groundwater Contaminated by Pet...

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2024 SPE Water Lifecycle Management Conference and Exhibition, WLMC 2024

作者： Alahmari, M.M. Humam, A.A. Zefzafy, I.M. Sanchez-Huerta, C. Hong, P.-Y. Zhang, S. Saudi Aramco's EXPEC Advanced Research Center Dhahran Saudi Arabia Environmental Science and Engineering Program Biological and Environmental Science and Engineering Division King Abdullah University of Science and Technology Thuwal Saudi Arabia

ISBN: (纸本)9781959025320

Groundwater contamination by petroleum-hydrocarbons is a serious environmental problem. Crude oil is a complex mixture of hydrocarbons with serious environmental and health risks. Thus, remediation of groundwater from petroleum hydrocarbon contamination is an emerging priority. Current approaches to remediate hydrocarbon contamination include physical and chemical methods. However, most of these approaches have a limited application for in-situ groundwater remediation. This study aims to develop a sustainable hybrid solution for efficient restoration of groundwater polluted by crude oil, providing a source of high-quality groundwater stream. Hybrid solution compromises in-situ addition of biosurfactant followed by a flow through electrochemical reactor installed in the groundwater well. The proposed hybrid solution comprises a two-stage process evaluated through lab-scale experiments treating crude oil that was mixed with synthetic water, mimicking groundwater contamination by petroleum-hydrocarbons. For biosurfactant optimization, glass flasks containing synthetic groundwater and crude oil were supplemented with biosurfactant BS, and C added at the three surfactants: oil (S:O) ratios 1:5, 1:10, and 1:50. Two temperature (25-35 °C) conditions were analyzed to simulate groundwater environment. The change in the crude oil layer thickness total petroleum hydrocarbon concentration (TPH) was continuously monitored for 60 days. Electron Oxidation was carried out where Boron-dopped diamond (BDD) anode and titanium cathode plates, were fitted into a 1 L reactor containing groundwater, crude oil and biosurfactant. Kinetic analysis at three constant currents (20, 30 and 40 mA/cm2) was performed. Samples were collected at regular intervals along 120 min to determine changes in TPH, COD and pH. The performance of biosurfactant BS and C in reducing the thickness of crude oil layer was influenced by different parameters including temperature, and S:O ratio. The increase in temper

关键词： Groundwater

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Surface-modified Ag@Ru-P25 for photocatalytic CO_(2) conversion with high selectivity over CH_(4) formation at the solid–gas interface

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Carbon Energy 2024年第1期6卷 182-196页

作者： Chaitanya B.Hiragond Sohag Biswas Niket SPowar Junho Lee Eunhee Gong Hwapyong Kim Hong Soo Kim Jin-Woo Jung Chang-Hee Cho Bryan M.Wong Su-Il In Department of Energy Science&Engineering Daegu Gyeongbuk Institute of Science and Technology(DGIST)DaeguRepublic of Korea Department of Chemical&Environmental Engineering Materials Science&Engineering ProgramDepartment of ChemistryDepartment of Physics&AstronomyUniversity of California-RiversideRiversideCaliforniaUSA Department of Physics and Chemistry Daegu Gyeongbuk Institute of Science and Technology(DGIST)DaeguRepublic of Korea NiceScience Corporation DaeguRepublic of Korea

Systematic optimization of the photocatalyst and investigation of the role of each component is important to maximizing catalytic activity and comprehending the photocatalytic conversion of CO_(2) reduction to solar fuels.A surface-modified Ag@Ru-P25 photocatalyst with H_(2)O_(2) treatment was designed in this study to convert CO_(2) and H_(2)O vapor into highly selective *** doping followed by Ag nanoparticles(NPs)cocatalyst deposition on P25(TiO_(2))enhances visible light absorption and charge separation,whereas H_(2)O_(2) treatment modifies the surface of the photocatalyst with hydroxyl(–OH)groups and promotes CO_(2) ***-resonance transmission electron microscopy,X-ray photoelectron spectroscopy,X-ray absorption near-edge structure,and extended X-ray absorption fine structure techniques were used to analyze the surface and chemical composition of the photocatalyst,while thermogravimetric analysis,CO_(2) adsorption isotherm,and temperature programmed desorption study were performed to examine the significance of H_(2)O_(2) treatment in increasing CO_(2) reduction *** optimized Ag1.0@Ru1.0-P25 photocatalyst performed excellent CO_(2) reduction activity into CO,CH4,and C2H6 with a~95%selectivity of CH4,where the activity was~135 times higher than that of pristine TiO_(2)(P25).For the first time,this work explored the effect of H_(2)O_(2) treatment on the photocatalyst that dramatically increases CO_(2) reduction activity.

关键词： gas-phase CO_(2) reduction H_(2)O_(2) treatment plasmonic nanoparticles solar fuel photocatalyst surface modification

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Sorption-enhanced steam gasification of fine coal waste for fuel producing

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Journal of King Saud University - engineering sciences 2024年第2期36卷 81-88页

作者： Aprianti, Nabila Faizal, Muhammad Said, Muhammad Nasir, Subriyer Doctoral Program of Environmental Science Graduate School Universitas Sriwijaya South Sumatra Palembang30139 Indonesia Chemical Engineering Department Faculty of Engineering Universitas Sriwijaya South Sumatra Ogan Ilir30662 Indonesia

Improving the quality of syngas from fine coal waste using the sorption-enhanced gasification process is a novel technology in the production of H2. The effect of CaO on CO2 absorption and H2 increase in the steam fine coal gasification process was determined in a fixed bed gasifier. The steam gasification process took place at 650 °C using bentonite and CaO as catalysts and absorbents. Steam increased the H2 concentration in the syngas to 58 vol%. In-situ CO2 absorption is more effective with the addition of CaO. The maximum percentage of CO2 was absorbed when the Ca/C ratio 2 was 78.33 %. The H2 content in the syngas after the CO2 was absorbed increased rapidly to 75.80 vol% at a Ca-to-carbon-mole ratio (Ca/C) of 1.5 and a steam-to-feedstock ratio (S/F) of 1.5. CaO did not produce significant results for low heating value (LHV) or cold gas efficiency (CGE), with results of 12 MJ/Nm3 and 44.53 %. The dominant water gas shift reaction due to the influence of steam and CaO increased H2/CO up to 9.11, which made the syngas from this work suitable for Fischer–Tropsch synthesis. © 2022 The Authors

关键词： Carbon dioxide

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Efficient predictions of formation energies and convex hulls from density functional tight binding calculations

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Journal of Materials science & Technology 2023年第10期141卷 236-244页

作者： Anshuman Kumar Zulfikhar A.Ali Bryan M.Wong Materials Science&Engineering Program University of California-RiversideRiverside92521CAUSA Department of Physics&Astronomy University of California-RiversideRiverside92521CAUSA Materials Science&Engineering Program Department of Chemical&Environmental EngineeringDepartment of Physics&Astronomyand Department of ChemistryUniversity of California-RiversideRiverside92521CAUSA

Defects in materials significantly alter their electronic and structural properties,which affect the per-formance of electronic devices,structural alloys,and functional ***,calculating all the possible defects in complex materials with conventional Density Functional Theory(DFT)can be compu-tationally *** enhance the efficiency of these calculations,we interfaced Density Functional Tight Binding(DFTB)with the Clusters Approach to Statistical Mechanics(CASM)software package for the first *** SiC and ZnO as representative examples,we show that DFTB gives accurate results and can be used as an efficient computational approach for calculating and pre-screening formation ener-gies/convex *** DFTB+CASM implementation allows for an efficient exploration(up to an order of magnitude faster than DFT)of formation energies and convex hulls,which researchers can use to probe other complex systems.

关键词： CASM DFTB DFT Formation energy Convex hull

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Cationization of Cellulose Dissolved in TEAOH/urea Solvent and its Preparation of Cellulose Beads: Effect of Added Amount of GTAC

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Palpu Chongi Gisul/Journal of Korea Technical Association of the Pulp and Paper Industry 2022年第6期54卷 85-93页

作者： Kim, Younglae Jang, Minseok Cho, Byoung-Uk Department of Paper Science & Engineering College of Forest and Environmental Science Kangwon National University Korea Republic of Program of Paper Material Science & Engineering College of Forest and Environmental Science Kangwon National University Korea Republic of

To widen the applications, cationic cellulose beads were synthesized by adding glycidyltrimethylammonium chloride (GTAC) to cellulose fibers dissolved in a mixture of tetraethylammonium hydroxide and urea at room temperature for cationic modification, and dropping the cationic cellulose solution into an acetic acid solution. Herein, the effects of the added GTAC amount on the properties of cationic cellulose soultion and cellulose beads were investigated. It was observed that increasing the amount of GTAC increased the viscosity and surface tension of the cationically modified cellulose solution and increased the particle size of the cellulose beads. Furthermore, the zeta potential of the cellulose beads can be controlled by modifying the GTAC amount. © 2022 Korean Technical Assoc. of the Pulp and Paper Industry. All rights reserved.

关键词： Chemical modification

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