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Utilization of Basalt Saw Mud as a Spherical Porous Functional Aggregate for the Preparation of Ordinary Structure Concrete

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Journal of Wuhan University of technology(Materials Science) 2024年第2期39卷 364-375页

作者：周永祥关青锋 LENG Faguang WANG Jing LI Tianjun Faculty of Architecture Civil and Transportation EngineeringBeijing University of TechnologyBeijing 100124China Key Laboratory of Urban Security and Disaster Engineering of Ministry of Education Beijing University of TechnologyBeijing 100012China School of Materials Science and Engineering Southeast UniversityNanjing 211189China Institute of Building Materials China Academy of Building ResearchBeijing 100013China State Key Laboratory of Building Safety and Built Environment Beijing 100013China Zhejiang Chinavigor E.P.Technology Co. Ltd.Zhejiang 315043China

To promote the production and application of artificial aggregates,save natural sand resources and protect the ecological environment,we evaluated the feasibility of using spherical porous functional aggregates(SPFAs) formed by basalt saw mud under autoclave curing in ordinary structural *** our work,two types of prewetted functional aggregates were taken as replacements for natural aggregates with different volume substitution rates(0%,5%,10%,15%,20%,25%,and 30%) in the preparation of ordinary structural concrete with water-to-binder ratios(W/B) of 0.48 and *** effects of the functional aggregate properties and content,W/B,and curing age on the fluidity,density,mechanical properties and autogenous shrinkage of ordinary concrete were *** experimental results showed that the density of concrete declined at a rate of not more than 5%,and the 28 d compressive strength could reach 31.0-68.2 *** W/B,long curing age and high-quality functional aggregates were conducive to enhancing the mechanical properties of SPFAs *** the rolling effects,SPFAs can optimize the particle gradation of aggregate systems and improve the fluidity of concrete,and the water stored inside SPFAs provides an internal curing effect,which prolongs the cement hydration process and considerably reduces the autogenous shrinkage of *** exhibits high strength and high density,as well as being more cost-effective and ecological,and is expected to be widely employed in ordinary structural concrete.

关键词： lightweight concrete civil concrete building basalt saw mud fly ash internal curing environmentally friendly

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Modulating d-d orbitals coupling in PtPdCu medium-entropy alloy aerogels to boost pH-general methanol electrooxidation performance

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Chinese Chemical Letters 2025年第4期36卷 221-228页

作者： Kaili Wang Pengcheng Liu Mingzhe Wang Tianran Wei Jitao Lu Xingling Zhao Zaiyong Jiang Zhimin Yuan Xijun Liu Jia He School of Chemistry&Chemical Engineering and Environmental Engineering Weifang UniversityWeifang 261061China School of Chemistry and Chemical Engineering Tianjin University of TechnologyTianjin 300384China State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured MaterialsSchool of ResourcesEnvironment and MaterialsGuangxi UniversityNanning 530004China

Unraveling the essence of electronic structure effected by d-d orbital coupling of transition metal and methanol oxidation reaction(MOR)performance can fundamentally guide high efficient catalyst ***,density functional theory(DFT)calculations were performed at first to study the d–d orbital interaction of metallic Pt Pd Cu,revealing that the incorporation of Pd and Cu atoms into Pt system can enhance d-d electron interaction via capturing antibonding orbital electrons of Pt to fill the surrounding Pd and Cu *** the theoretical guidance,Pt Pd Cu medium entropy alloy aerogels(Pt Pd Cu MEAAs)catalysts have been designed and systematically screened for MOR under acid,alkaline and neutral ***,DFT calculation and in-situ fourier transform infrared spectroscopy analysis indicate that Pt Pd Cu MEAAs follow the direct pathway via formate as the reactive intermediate to be directly oxidized to CO_(2).For practical direct methanol fuel cells(DMFCs),the Pt Pd Cu MEAAs-integrated ultra-thin catalyst layer(4–5μm thickness)as anode exhibits higher peak power density of 35 m W/cm^(2) than commercial Pt/C of 20 m W/cm^(2)(~40μm thickness)under the similar noble metal loading and an impressive stability retention at a 50-m A/cm^(2) constant current for 10 *** work clearly proves that optimizing the intermediate adsorption capacity via d-d orbital coupling is an effective strategy to design highly efficient catalysts for DMFCs.

关键词： Medium-entropy alloys aerogels d-d Orbitals coupling pH-general Methanol oxidation reaction Ultra-thin catalyst layer

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Turbulent heat fluxes in the North Water Polynya and ice estimated based on ASRv2 data and their impact on cloud

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Advances in Climate Change Research 2024年第5期15卷 798-814页

作者： Hai-Yi REN Mohammed SHOKR Tian-Yu ZHANG Zhi-Lun ZHANG Feng-Ming HUI Xiao CHENG School of Geospatial Engineering and Science Sun Yat-sen UniversitySouthern Marine Science and Engineering Guangdong Laboratory(Zhuhai)Zhuhai 519082China Key Laboraory of Comprehensive Obseration of Polar Environment(Sun Yat-en University)Minisry of Education Zhuhai 519082 China State Key Laboratory of Remote Sensing Science Faculty of Geographical ScienceBeijing Normal UniversityBeijing 100875China State Key Laboratory of Space-Ground Integrated Information Technology Beijing Institute of Satllite Information Engineering Beijing 100086China Science and Technology Branch Environment CanadaToronto Ontario M3H5T4Canada

The presence or absence of sea ice introduces a substantial perturbation to surface-atmosphere energy *** the effect of varying sea ice cover on surface-atmosphere interactions is an important consideration for understanding the Arctic climate *** recurring North Water Polynya(NOW)serves as a natural laboratory for isolating cloud responses to a rapid,near-step perturbation in sea *** this study,we employed high-resolution Arctic System Reanalysis version 2(ASRv2)data to estimate turbulent heat fluxes over the NOW and nearby sea ice(NSI)area between 2005/2006 and 2015/*** results indicate that the average turbulent heat fluxes in the polynya are about 87%and 86%higher than in the NSI area over the 10 years during the entire duration of the polynya and during polar night,*** turbulent heat fluxes from the polynya tend to produce more low-level *** relationship between the polynya and low cloud in winter was examined based on Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations(CALIPSO).The low-cloud fraction(0-2 km)was about 7%-34%larger over the polynya than the NSI area,and the ice water content below 200 m was about 250%-413%higher over the former than the *** correlation between cloud fraction and turbulent heat fluxes in the polynya peaks around the altitude of 200-300 *** results suggest that the NOW affects the Arctic boundary layer cloudiness and structure in ***,higher horizontal resolution reanalysis data can advance our understanding of the cloud-polynya response.

关键词： The North Water Polynya Turbulent heat fluxes Cloud cover Ice water content ASRv2 CALIPSO

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Preparation of low cobalt-doped LiNiO2 materials by the spray pyrolysis method

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Progress in Natural Science:Materials International 2023年第4期33卷 425-432页

作者： Bianzheng You Zhixing Wang Ding Wang Gui Luo Duo Deng Guochun Yan Huajun Guo Xinhai Li Wenjie Peng Mingxia Dong Jiexi Wang National Key Laboratory of Energy Metal Resources and New Materials Engineering Research Center of the Ministry of Education for Advanced Battery Materials Hunan Provincial Key Laboratory of Nonferrous Value-Added Metallurgy School of Metallurgy and Environment Central South University National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Battery Materials of Yunnan Province Faculty of Metallurgical and Energy Engineering Kunming University of Science and Technology Research Institute BASF Shanshan Battery Materials Co LTD.

LiNiO2（LNO） is recognized as the most promising cathode material for next-generation lithium-ion batteries owing to its highest energy density and economic benefit in the layered oxide cathode materials ***, severe cation disordering, multiple phase transformations and poor lithium-ion diffusion kinetics,which result in rapid degradation of cycling stabilities and rate properties, hinder its further practical applications. Cobalt doping is an effective strategy to address such issues, but the influences of cobalt on LNO materials have not been figured out completely yet. Hence, a systematical investigation of cobalt doping for LiNiO2cathode materials prepared by spray pyrolysis is conducted. The addition of cobalt enhances the stabilities of layered structures and suppresses the cation disordering effectively. The multiple-phase transformations during cycling are also alleviated significantly. Furthermore, cobalt doping can decrease charge transfer resistances and improve lithium-ion diffusion kinetics, especially at high de-lithiation states. As a result, the electrochemical performances are improved comprehensively after cobalt doping. The LNO with optimal doping amount exhibits an improved capacity retention of 78.0% after 100 cycles as compared with 64.9% for pristine LNO, and an outstanding rate performance of 167.2 mA h g-1with the current density of 5 C(1 C = 200 mA g-1).

关键词： Lithium nickel oxides Spray pyrolysis Cobalt doping Phase transformations Lithium-ion diffusion kinetics

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Unraveling environmental influences on the spatial and temporal dynamics of cyanobacterial blooms in Lake Erhai during its early stage of eutrophication

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地球空间信息科学学报（英文版） 2024年第6期27卷中插14,1989-2007页

作者： Shangbo Yang Jianzhong Lu Xiaoling Chen Xuejiao Hou Zushuai Wei Jinru Wu State Key Laboratory of Information Engineering in Surveying Mappingand Remote SensingWuhan UniversityWuhanChina School of Environmental Science and Engineering Southern University of Science and TechnologyShenzhenChina State Key Laboratory of Information Engineering in Surveying Mappingand Remote SensingWuhan UniversityWuhanChina School of Geospatial Engineering and Science Sun Yat-Sen UniversityGuangzhouChina South China Institute of Environmental Sciences Ministry of Ecology and EnvironmentGuangzhouChina

Lake Erhai,a lake in the early stage of eutrophication,has been threatened by algal blooms(particularly the overproliferation of blue-green algae),which can have an impact on drinking water safety and the lake's *** the governing factors of cyanobacterial blooms is critical for taking timely and effective action during this key eutrophication-transition ***,long-term records of cyanobacterial bloom and its key dominating factors remain *** is,therefore,essential to understand the bloom dynamics and the driving forces before any control strategies can be *** investigated the cyanobacterial phycocyanin concentration variability based on satellite observations from 2003 to 2019,by using the empirical orthogonal function *** observed a decrease in the coverage of the dominant mode of variability in phycocyanin magnitudes compared to the period 2003 to 2011,with variations primarily occurring in the northern *** largest variability was identified to be predominant in July,and an apparent timing shift in variability was observed in December 2016 and *** 95％quantile regression model indicated a distinct upper boundary response in cyanobacteria proliferation to the joint Total Nitrogen(TN)and Total Phosphorus(TP)concentrations,which occurred in summer from 2003 to *** apparent response of cyanobacterial bloom to TP was observed during the winters from 2016 to ***,water level and TN:TP ratio played a central role in summer from 2003 to 2011,while from 2016 to 2019,TN:TP ratio was found to dominate in the summer *** winter,air temperature turned out to be a significant modulating factor compared to water *** results suggest that implementing a phosphorus reduction strategy,while controlling TN:TP ratio and suitable water level manipulation,should be considered to ensure the sustainability of Lake Erhai,especially under a consistent global warming scenario.

关键词： Cyanobacterial phycocyanin concentration spatio-temporal variability nutrient reduction remote sensing

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Release of Pb adsorbed on graphene oxide surfaces under conditions of Shewanella putrefaciens metabolism

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Journal of environmental Sciences 2022年第8期34卷 67-75页

作者： Jianfeng Zhang ShichangWei Zhenxing Liu Huang Tang Xiaoguang Meng Weihuang Zhu Shaanxi Key Laboratory of Environmental Engineering Key Laboratory of Northwest Water ResourceEnvironment and EcologyMOEXi’an University of Architecture and TechnologyXi’an 710055China Center for Environmental Systems Stevens Institute of TechnologyNJ 07030USA

In this study, Pb(Ⅱ) was used as a target heavy metal pollutant, and the metabolism of Shewanella putrefaciens(S. putrefaciens) was applied to achieve reducing conditions to study the effect of microbial reduction on lead that was preadsorbed on graphene oxide(GO) *** results showed that GO was transformed to its reduced form(r-GO) by bacteria, and this process induced the release of Pb(Ⅱ) adsorbed on the GO surfaces. After 72 hr of exposure in an S. putrefaciens system, 5.76% of the total adsorbed Pb(Ⅱ) was stably dispersed in solution in the form of a Pb(Ⅱ)-extracellular polymer substance(EPS) complex, while another portion of Pb(Ⅱ) released from GO-Pb(Ⅱ) was observed as lead phosphate hydroxide(Pb_(10)(PO_(4))_(6)(OH)_(2))precipitates or adsorbed species on the surface of the cell. Additionally, increasing pH induced the stripping of oxidative debris(OD) and elevated the content of dispersible Pb(Ⅱ)in aqueous solution under the conditions of S. putrefaciens metabolism. These research results provide valuable information regarding the migration of heavy metals adsorbed on GO under reducing conditions due to microbial metabolism.

关键词： Graphene oxide Pb(Ⅱ) Shewanella putrefaciens Extracellular polymeric substances Microbial reduction

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Design of supported CuCe catalysts with optimal pore size to promote low-temperature RWGS reactions

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International Journal of Hydrogen Energy 2025年 144卷 469-481页

作者： Xie, Hongmei Zhao, Shan Ouyang, Liu Zeng, Jia Chen, Shuang Zhou, Guilin Key Laboratory of Catalysis Science and Technology of Chongqing Education Commission College of Environment and Resources Chongqing Technology and Business University Chongqing400067 China Engineering Research Center for Waste Oil Recovery Technology and Equipment Ministry of Education Chongqing Technology and Business University Chongqing400067 China

CO2, as a cheap and abundant C1 resource, can be converted to an important basic chemical raw material CO through the RWGS reaction. Currently, the development of a catalyst with low-temperature and high-efficiency of RWGS is the key to achieving CO2 resource utilization. In this paper, mesoporous SiO2 with the same pore shape and different pore diameters were prepared and used as support to investigate the CO2 hydrogenation performance over CuCe/SiO2. The physicochemical properties of the prepared CuCe/SiO2 catalysts were investigated by using N2 adsorption/desorption, TEM/HRTEM, H2-TPR, H2-TPD, CO2-TPD, low-angle XRD, XRD, ICP, and N2O chemisorption, and the correlation between the physicochemical properties of the studied catalysts and the catalytic RWGS performances was established. It was found that the pore size had a significant effect on the RWGS performances, and the large specific surface area and well-developed mesoporous structure of the support SiO2 significantly promoted the high dispersion of the Cu and Ce components. This promotes the active centers to be formed on the catalyst surface and enhances the ability to adsorb and activate reactant molecules. The prepared CCS100 catalyst possesses a superior pore structure, large specific surface area, high ordering, good dispersion of active metal species, and superior adsorption/activation ability for reactant molecules, which results in good catalytic RWGS performances. At atmospheric pressure and a reaction temperature of 420 °C, the CO2 conversion and CO selectivity were achieved 41.34 % and 100 % over the CCS100 catalyst, respectively, and showed good CO2 hydrogenation recycling performance. © 2025 Hydrogen Energy Publications LLC

关键词： Mesoporous materials

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Insights into photocatalytic mechanism over a novel Cu_(2)WS_(4)/MoS_(2) S-scheme heterojunction

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Rare Metals 2024年第7期43卷 3118-3133页

作者： Wei Zhao Ji-Hui Cao Jun-Jie Liao Yun Liu Xiao-Jun Zeng Jun-Yu Shen Xue-Kun Hong Yang Guo He-Hua Zeng Ya-Zi Liu School of Materials Engineering Jiangsu Key Laboratory of Advanced Functional MaterialsSchool of Electronic and Information EngineeringChangshu Institute of TechnologyChangshu215500China School of Chemistry and Chemical Engineering Changji UniversityChangji 831100China State Environmental Protection Key Laboratory of Soil Environmental Management and Pollution Control Ministry of Ecology and EnvironmentNanjing Institute of Environmental SciencesNanjing 210023China School of Environment Jiangsu Engineering Lab of Water and Soil Eco-RemediationNanjing Normal UniversityNanjing 210023China Department of Chemical Engineering Curtin UniversityPerthWA6845Australia

A novel efficient Cu_(2)WS_(4)/MoS_(2) step-scheme(S-scheme)heterojunction photocatalyst was constructed for the first time and applied in the removal of environmental *** the as-prepared photocatalysts,the Cu_(2)WS_(4)/MoS_(2)-8%heterojunc tion photoc atalyst demonstrates the optimal photocatalytic performance,with the catalytic oxidation efficiency of tetracycline(TC)and the catalytic reduction efficiency of Cr^(6+)reaching 93.3%and 82.1%,*** excellent catalytic properties of Cu_(2)WS_(4)/MoS_(2) heterojunction photocatalysts are attributed to the effective separation pathways of charges and the presence of S-scheme heterojunctions,together with stronger redox *** is speculated that the photogenerated carrier migration path of the Cu_(2)WS_(4)/MoS_(2) catalyst follows the typical S-scheme photocatalytic mechanism,which is verified by the in-depth experimental study and simulated calculations including the electron paramagnetic resonance(EPR)analysis,free radical quenching experiments,charge density distribution,and simulated built-in electric field formation at the interface,which acts as driving force to promote the separation of photoinduced electrons and ***,the photocatalytic mechanism of S-scheme photogenerated carrier migration for the Cu_(2)WS_(4)/MoS_(2) catalyst is revealed based on the systematic experimental techniques and simulated calculations,accounting for its superior photocatalytic oxidation and reduction *** study provides inspiring implications to develop high-efficient S-scheme photocatalytic systems for versatile applications in solarenergy conversion.

关键词： Cu_(2)WS_(4)/MoS_(2) S-scheme Heterojunction Photocatalysis

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Adsorption of typical gasoline vapor emitted from service stations by commercial activated carbon:static/dynamic adsorption and kinetics simulation

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Frontiers of environmental Science & engineering 2025年第3期19卷 87-98页

作者： Wei Hu Quanming Liang Dan Lu Beibei Li Biqi Ren Qingye Luan Jia Liu Wenjun Liang Yuhu Huang National Engineering Research Center of Urban Environmental Pollution Control Beijing Key Laboratory of Urban Atmospheric Volatile Organic Compounds Control Technology and ApplicationsBeijing Municipal Research Institute of Eco-Environmental ProtectionBeijing 100037China Key Laboratory of Beijing on Regional Air Pollution Control Faculty of Environment and LifeBeijing University of TechnologyBeijing 100124China Institute of Urban Safety and Environmental Science Beijing Academy of Science and TechnologyBeijing 100054China

Gasoline vapor emissions from service stations significantly affect urban *** the research on the mechanisms and effectiveness of gasoline vapor removal is limited,this study innovatively investigates the static and dynamic adsorption of xylene—a typical gasoline vapor and one of the most active secondary organic aerosol(SOA)species—by commercial activated carbon(AC).The results showed that the saturation static adsorption capacity(Q_(e))of 12 ACs varied from 0.9 to 870.7 mg/g,which correlated with the specific surface area(SSA)and pore *** them,11#and 12#ACs were identified as the most effective adsorbents for typical gasoline vapor *** maximum dynamic Q_(e) increased from 301.5 to 414.3 mg/g when the initial xylene concentration rose from 918 to 2008 mg/m^(3) for 11#AC,and from 201.4 to 406.2 mg/g when the initial xylene concentration increased from 589 to 2120 mg/m^(3) for 12#*** findings implied a direct correlation between higher initial xylene concentrations and greater dynamic Q_(e) values,with static Q_(e) values surpassing dynamic *** adsorption kinetics simulation were analyzed by the pseudo-first-order(PFO)and pseudo-second-order(PSO)*** kinetics results demonstrated that the PFO was more effective in characterizing the adsorption of xylene onto ACs(R2>0.989),indicating that the adsorption of typical gasoline vapor by ACs primarily involves physical *** findings of static/dynamic adsorption and kinetics provide valuable guidance for practical applications of gasoline vapor removal in service stations.

关键词： Activated carbon Gasoline vapor Xylene Dynamic adsorption Breakthrough curve

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reliability Modeling and Evaluation of Circuit Boards Considering key Design Factors

Reliability Modeling and Evaluation of Circuit Boards Consid...

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International Symposium on System and Software reliability (ISSSR)

作者： Hailu Hu Jianguo Wu Ruihao Zhang Menlin Wen School of Reliability and Systems Engineering Beihang University Beijing China Science and Technology on Reliability and Environment Engineering Laboratory Beijing Institute of Structure and Environment Engineering Beijing China

ISBN: (数字)9798331501242

ISBN: (纸本)9798331501259

This paper examines the impact of key design factors on the failure time and reliability of circuit boards in thermal vibration environments. It proposes methodologies for constructing a surrogate model to predict failure time based on these design factors and for assessing the reliability of circuit boards. The research begins by analyzing the external influences and critical design factors affecting circuit board performance. An experimental design is implemented using the Latin hypercube sampling method to ensure comprehensive coverage of variable interactions. Next, finite element simulation is employed to perform thermal vibration analyses, and the resulting data is used to calculate the failure time of circuit boards. Following this, a Kriging surrogate model is developed to accurately fit the high-dimensional, nonlinear relationship between design factors and failure time. The model effectively captures the complex interactions among these variables. Subsequently, the uncertainty characteristics of the system are quantified and represented, enabling more precise parameter estimation of the lifetime distribution. This is achieved using the Monte Carlo method, which provides detailed insights into the reliability assessment. Finally, the feasibility and effectiveness of the proposed modeling and assessment methodologies are validated through case studies, demonstrating their practical applicability in engineering scenarios.

关键词： Vibrations Uncertainty Thermal factors Printed circuits reliability engineering Finite element analysis Topology Thermal analysis Integrated circuit reliability Integrated circuit modeling

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