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Micro-strain regulation strategy to stabilize perovskite lattice based on the categories and impact of strain on perovskite solar cells

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Journal of Energy Chemistry 2025年第1期100卷 578-604页

作者： Caixia Li Wenwu Liu Shiji Da Lingbin Kong Fen Ran State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals Lanzhou University of TechnologyLanzhou 730050GansuChina School of Materials Science and Engineering Lanzhou University of TechnologyLanzhou 730050GansuChina

Photovoltaic metal halide perovskite solar cells(PSCs) convert light to electricity more efficiently than crystalline silicon cells, and the cost of materials used to make them is lower than that of silicon *** efficiency is not a core issue affecting the application of perovskite solar cells in special *** present, stability is the major technical encounters that hinders its further commercial development. Microstrain in PSCs is currently a significant factor responsible for the device's instability. Strain-induced ion migration is widely believed to accelerate perovskite degradation even when external stimuli are ***, it is imperative to study strain to enhance the stability of PSCs. This paper reviews recent developments to understand strain's origin and effect mechanisms on performance of PSCs, including ion migration,failure behavior, defect formation, and its effect on photoelectric properties, stability, and ***, several well-known strain management strategies are systematically introduced based on the strain effect mechanism and strain engineering on the film, providing more clues for further preparation with increased stability. The manipulation of external physical strain applied from films to entire devices has been extensively studied. Furthermore, recommendations for future research directions and chemical approaches have been provided. It is emphasized that strain engineering plays a crucial role in improving the efficiency and longevity of PSCs. Tensile strain causes rapid degradation, while moderate compressive strain and external strain control could improve properties and stability. Efforts should focus on controlling compressive strain to mitigate residual tensile strain and introducing it in a controlled manner. Future research endeavors may focus on exploring these pathways to improve the efficiency and lifespan of PSCs.

关键词： Halide perovskite solar cells Strain origins Strain effects Strain management

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Al-F co-doping towards enhanced electrolyte-electrodes interface properties for halide and sulfide solid electrolytes

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Chinese Chemical Letters 2025年第1期36卷 610-617页

作者： Han Yan Jingming Yao Zhangran Ye Qiaoquan Lin Ziqi Zhang Shulin Li Dawei Song Zhenyu Wang Chuang Yu Long Zhang College of Physics and Energy Fujian Normal UniversityFuzhou 350117China Clean Nano Energy Center State Key Laboratory of Metastable Materials Science and TechnologyYanshan UniversityQinhuangdao 066004China Tianjin Key Laboratory for Photoelectric Materials and Devices School of Materials Science and EngineeringTianjin University of TechnologyTianjin 300384China Guilin Electrical Equipment Scientific Research Institute Co. Ltd.Guilin 541004China State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430000China

All-solid-state Li batteries(ASSLBs)using solid electrolytes(SEs)have gained significant attention in recent years considering the safety issue and their high energy *** these advantages,the commercialization of ASSLBs still faces challenges regarding the electrolyte/electrodes interfaces and growth of Li *** doping is an effective and direct method to enhance the performance of ***,we report an Al-F co-doping strategy to improve the overall properties including ion conductivity,high voltage stability,and cathode and anode ***,the Al-F co-doping enables the formation of a thin Li-Al alloy layer and fluoride interphases,thereby constructing a relatively stable interface and promoting uniform Li *** similar merits of Al-F co-doping are also revealed in the Li-argyrodite *** assembled with these optimized electrolytes gain good electrochemical performance,demonstrating the universality of Al-F co-doping towards advanced SEs.

关键词： Solid electrolytes Li halides Li_(2)ZrCl_(6) Li argyrodites Fluorine doping

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Enhanced rate capability and cycle stability of Ti2C MXene for sodium storage through an aniline molecules welding strategy

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Tungsten 2025年第1期7卷 161-171页

作者： Hao Chen Ya-Qin Wang Dong-Ting Zhang Bei Zhao Min-Peng Li Chen-Yang Li Tian-Peng Xu Mao-Cheng Liu State Key Laboratory of Advanced Processing and Recycling of Non-Ferrous Metals Lanzhou University of Technology School of Materials Science and Engineering Lanzhou University of Technology School of Computer and Communication Technology Lanzhou University of Technology

MXenes obtained significant attention in the field of energy storage devices due to their characteristic layered structure,modifiable surface functional groups,large electrochemically active surface,and regulable interlayer ***,the self-restacking and sluggish ions diffusion kinetics performance of MXenes during the alkali metal ions insertion/extraction process severely impedes their cycle stability and rate *** paper proposes an aniline molecule welding strategy for welding p-phenylenediamine（PPDA） into the interlayers of Ti2C through a dehydration condensation *** welded PPDA molecules can contribute pillar effect to the layered structure of *** pillar effect effectively maintains the structural stability during the sodium ions insertion/extraction process and effectively expands the interlayer spacing of Ti2C from 1.16 to 1.38 nm,thereby enhancing ions diffusion kinetics performance and improving the long-term cycle *** Ti2C-PPDA demonstrates outstanding Na+storage capability,exhibiting a specific capacity of 100.2 mAh·g-1at a current density of 0.1 A·g-1over 960 cycles and delivering a remarkable rate capability 81.2 mAh·g-1at a current density of 5 A·*** study demonstrates that expanding interlayer spacing is a promising strategy to enhance the Na+storage capacity and improve long-term cycling stability,which provides significant guidance for the design of two-dimensional Na+storage materials with high-rate capability and cycle stability.

关键词： Ti_2C Expanding interlayer spacing Sodium ions storage Diffusion kinetics Rate capability

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FPGA Real-Time Deployment of Low-Complexity Volterra Equalizer Based on Pruning and Non-Uniform Quantization

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Journal of Lightwave technology 2025年第9期43卷 4183-4192页

作者： Sun, Xinda Wang, Kaihui Zhu, Zonghui Zhang, Long Gou, Yumeng Meng, Yuanxiao Chen, Yun Yu, Jianjun Fudan University Department of Communication Science and Engineering State Key Laboratory of ASIC and System Key Laboratory for Information Science of Electromagnetic Waves School of Information Science and Technology Shanghai 200433 China Fudan University Shanghai200433 China

Electronic nonlinear equalization technology is a promising signal impairments compensation technique with great development potential and wide application scenarios. However, its high complexity makes it challenging to implement in field-programmable gate array (FPGA). We propose a low-complexity real-time nonlinear equalization scheme based on FPGA, which can provide similar performance as traditional schemes but only occupies very low digital signal processing (DSP) resources. With the help of this scheme, by using pruning and non-uniform quantization, the computational complexity of a Volterra equalizer with 15 linear taps and 25 nonlinear taps is comparable to that of a Volterra equalizer with 8 linear taps and 4 nonlinear taps. By non-uniformly quantizing the taps of the equalizer, the quantization accuracy can be saved compared to uniform quantization, and after the taps are quantized, complex multiplication can be replaced by simple shift operations, simplifying the complexity of multiplication operations. The scheme of weight pruning and non-uniform quantization significantly reduces the required hardware resources and power consumption. We verify the proposed scheme in a decision-directed Volterra (DD-Volterra) equalizer, The equalizer was successfully deployed in a 230.4 MHz xcvu9pflgb2104-2-I Xilinx FPGA and achieved real-time IM/DD transmission of 29.4912 Gbit/s PAM4 signals over 25 km standard single-mode fiber (SSMF), meeting the 3.8 × 10-3 hard-decision forward error correction (HD-FEC) standard. The results show that the proposed low-complexity Volterra equalizer scheme can reduce DSP resources by up to 75.3% and power consumption by 26.2%. © 1983-2012 IEEE.

关键词： Forward error correction

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Multi-scale dispersion strengthening for high-temperature titanium alloys:Strength preservation and softening mechanisms

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材料科学技术（英文版） 2025年第3期206卷 1-14页

作者： Xin Chen Lujun Huang Shuo Ma Fengbo Sun Shuai Wang Lin Geng School of Materials Science and Engineering Harbin Institute of TechnologyHarbin 150001China State Key Laboratory of Advanced Welding and Joining Harbin Institute of TechnologyHarbin 150001China School of Materials Science and Engineering Harbin Institute of TechnologyHarbin 150001China

The long-lasting expectation"the hotter the engine,the better"calls for the development of high-temperature metallic *** the high specific strengths of titanium alloys are compelling for such applications,their deleterious softening beyond 600 ℃ imposes serious *** has been known for decades regarding the phase metallurgy for precipitation strengthening design in titanium al-loys,however,the other facile strength promotion mechanism,dispersion strengthening,remains compar-atively less-explored and *** present research concerns the multi-scale dispersion strength-ening in titanium alloys,with mechanistic emphases on the critical plasticity micro-events that affect strength *** to the simultaneous introduction of intragranular dispersoids and intergran-ular reinforcers,the current titanium alloys present superior engineering tensile strength of 519 MPa at 700 ℃.Throughout the examined 25-800 ℃ temperature range,noticeable softening induced by the ther-mal activation occurs above 600 ℃,accompanied by evident strength *** temperature-dependence transition of dominated softening mechanisms from dynamic recovery to dynamic recrystallization has been clarified by theoretical ***,the strengthening effect of multi-scale architec-tures is underpinned as the enhanced dislocation strengthening owing to the introduction of thermally-stable heterointerfaces,which could generically guide the design of similar heat-resistant titanium alloys.

关键词： Titanium-based alloys Multi-scale architectures Mechanical properties Temperature dependence Dislocation strengthening

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Novel Inertia Control Method with Phase-Locked Error Feedforward in PLL for DFIG-Based WTs

Novel Inertia Control Method with Phase-Locked Error Feedfor...

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International Conference of Electrical, Electronic and Networked Energy Systems, EENES 2024

作者： Yu, Jiawei Zhu, Yihua Zhou, Yini Hu, Bo Li, Zheyu Li, Xiaoyu State Key Laboratory of HVDC Electric Power Research Institute China Southern Power Grid Guangzhou510663 China State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic Engineering Huazhong University of Science and Technology Wuhan430074 China

ISBN: (纸本)9789819620418

The large-scale access of wind power causes a significant reduction in the inertia of the power system, seriously threatening the security and stability of the system frequency. Inertia control methods based on the optimized PLLs provide a solution to the low inertia problem of doubly-fed inductance generator (DFIG)-based wind turbines (WTs), but they still suffer from poor dynamic performance and obvious phase-locked error in steady state. For this reason, a novel inertia control method for DFIG-based WTs is proposed in this paper to support the system frequency with better performance in all aspects. Firstly, an equivalent inertia model is deduced considering the dynamic of control and the reason why modifying PLL can realize inertia response of WT is analyzed. Then, the existing inertia control methods based on optimized PLL is introduced and a novel inertia control method with phase-locked error feed-forward in PLL (pefPLL) is proposed. After that, the inertia characteristics, dynamic performance, and steady state performance of pefPLL and other PLLs are compared. Finally, the superiority of the novel inertia control method with pefPLL is verified by simulations. © Beijing Paike Culture Commu. Co., Ltd. 2025.

关键词： Wind turbines

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Adsorption removal of mercury from flue gas by metal selenide:A review

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Journal of Environmental Sciences 2025年第2期148卷 420-436页

作者： Yang Zheng Guoliang Li Yi Xing Wenqing Xu Tao Yue School of Energy and Environmental Engineering University of Science and Technology BeijingBeijing 100083China State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China CAS Key Laboratory of Green Process and Engineering Institute of Process EngineeringInnovation Academy for Green ManufactureChinese Academy of SciencesBeijing 100190China

Mercury(Hg)pollution has been a global concern in recent decades,posing a significant threat to entire ecosystems and human health due to its cumulative toxicity,persistence,and transport in the *** intense interaction between mercury and selenium has opened up a new field for studying mercury removal from industrial flue gas *** the advantages of good Hg^(0) capture performance and lowsecondary pollution of the mineral selenium compounds,the most noteworthy is the relatively low regeneration temperature,allowing adsorbent regeneration with low energy consumption,thus reducing the utilization cost and enabling recovery of mercury *** paper reviews the recent progress of mineral selenium compounds in flue gas mercury removal,introduces in detail the different types ofmineral selenium compounds studied in the field ofmercury removal,reviews the adsorption performance of various mineral selenium compounds adsorbents on mercury and the influence of flue gas components,such as reaction temperature,air velocity,and other factors,and summarizes the adsorption mechanism of different fugitive forms of selenium *** on the current research progress,future studies should focus on the economic performance and the performance of different carriers and sizes of adsorbents for the removal of Hg^(0) and the correlation between the gas-particle flow characteristics and gas phase mass transfer with the performance of Hg^(0) removal in practical industrial *** addition,it remains a challenge to distinguish the oxidation and adsorption of Hg^(0) quantitatively.

关键词： Non-conventional pollutants Adsorbents Metal selenides Flue gas Mercury removal

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Microstructure and mechanical properties of high-pressure sintered B6O-SiC nanocomposites

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材料科学技术（英文版） 2025年第1期204卷 238-244页

作者： Bin Zhang Rongxin Sun Pan Ying Song Zhao Yitong Zou Lei Sun Zihe Li Yufei Gao Mengdong Ma Lingyu Liu Chao Liu Bo Xu Center for High Pressure Science(CHiPS) State Key Laboratory of Metastable Materials Science and TechnologyYanshan UniversityQinhuangdao 066004China National Key Laboratory of Advanced Casting Technologies MIIT Key Laboratory of Advanced Metallic and Intermetallic Materials TechnologyEngineering Research Center of Materials Behavior and DesignMinistry of Education Nanjing University of Science and TechnologyNanjing 210094China Key Laboratory of Materials and Surface Technology(Ministry of Education) School of Materials Science and EngineeringXihua UniversityChengdu 610039China School of Materials Science and Engineering Faculty of Materials Metallurgy and ChemistryJiangxi University of Science and TechnologyGanzhou 341000China

Boron suboxide(B6O)is recognized as a superhard material with a low mass density,high resistance to chemical wear,and excellent wear *** its desirable properties,the limited fracture tough-ness of B6O restricts its application in industrial *** study presents the structural and me-chanical characterization of B6O-SiC nanocomposites,which were synthesized via a high-pressure high-temperature sintering process of B6O powders and SiC *** sintering process induced fragmen-tation of SiC whiskers,resulting in the homogenous distribution of SiC fragments within the B6O *** increase in SiC content was observed to decrease the composite's hardness,while initially reducing then enhancing its *** nanocomposites containing 20 wt％and 30 wt％SiC whiskers exhibited significant improvements in fracture toughness,averaging 6.5 MPa m1/2 and 7.0 MPa m1/2,respectively-approximately threefold the toughness of polycrystalline B6O-while sustaining high hardness values of 36.3 GPa and 35.6 GPa on *** analyses revealed that the composites'superior me-chanical performance is due to the presence of strong grain boundaries,as well as a high density of nan-otwins and stacking *** findings demonstrate a viable method for producing B6O-based nanocom-posites with enhanced hardness and toughness,potentially expanding their industrial applicability.

关键词： B6O Ceramic nanocomposite Mechanical properties Microstructure

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Analysis of Three-Phase Short-Circuit Electromotive Force on Six Vacuum-Break Parallel-Type Generator Outlet Circuit Breakers 11th

Analysis of Three-Phase Short-Circuit Electromotive Force on...

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11th Frontier Academic Forum of Electrical engineering, FAFEE 2024

作者： Sun, Likang Chen, Lixue He, Yinghui Zou, Xinyang Li, Yingzhuo State Key Laboratory of Advanced Electromagnetic Technology Huazhong University of Science and Technology Wuhan430074 China Key Laboratory of Pulsed Power Technology Ministry of Education School of Electrical and Electronic Engineering Huazhong University of Science and Technology Wuhan430074 China

ISBN: (纸本)9789819787791

Currently, vacuum type generator outlet circuit breaker dominates the large-capacity generator circuit breaker. However, due to the large short-circuit current at the generator outlet end, the generator outlet circuit breaker needs to bear a great short-circuit electromotive force, thus affecting its dynamic stability. In this paper, COMSOL is used to construct a model of a six vacuum break parallel type outlet circuit breaker for the protection of a megawatt-level generator. Based on Maxwell's electromagnetic theory, the transient calculation of three-phase short-circuit electromotive force under different phases is carried out for the generator outlet vacuum circuit breaker, and the great values of short-circuit electromotive force under different phases are obtained for each phase. The results show that the main component of the short-circuit electromotive force is the electromotive force in the y-direction. And based on the maximum transient electromotive force, the influence of the material on the short-circuit electromotive force is studied, which provides theoretical support for the analysis of the short-circuit electromotive force of the generator outlet circuit breaker and the optimized design of the shell. © Beijing Paike Culture Commu. Co., Ltd. 2025.

关键词： Electric shielding

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A machine learning method approach for designing novel high strength and plasticity metastable β titanium alloys

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Progress in Natural Science:Materials International 2025年第1期35卷 156-165页

作者： Zhiduo Liu Haoyu Zhang Shuai Zhang Jun Cheng Yixuan He Ge Zhou Jiawei Liu Suping Song Lijia Chen School of Materials Science and Engineering Shenyang University of Technology Shenyang Key Laboratory of Advanced Structural Materials and Applications Shenyang University of Technology Northwest Institute for Nonferrous Metal Research Shaanxi Key Laboratory of Biomedical Metal Materials State Key Laboratory of Solidification Processing Northwestern Polytechnical University Ansteel Group Automation Co. Ltd

In order to improve efficiency and reduce costs, four machine learning models were established for the design of metastable β titanium alloys, including the Adaboost model, the LightGBM model, the Voting model, and the Stacking model. The accuracy of these models was evaluated, and all models exhibited excellent accuracy for tensile strength, yield strength, and elongation. The values of R-squared coefficients（R2） all greater than *** them, the LightGBM model showed the highest accuracy, with relatively smallest values of mean absolute error（MAE） and root mean square error（RMSE） and relatively largest value of R2. To further verify the accuracy of the model, a metastable β titanium alloy Ti-5.5Cr-5Al-4Mo-3Nb-2Zr was designed by the LightGBM model. The predicted values of the alloy's tensile strength, yield strength, and elongation under three heat treatment processes were in high agreement with the experimental values. The alloy exhibited optimal strength-plasticity matching after undergoing a solution treatment at 850°C for 0.5 h, followed by aging at 650°C for 8 h, with a tensile strength of 1317 MPa, an elongation of 11.17 %, and a strength-plasticity product of 14.711 GPa·%.

关键词： Machine learning Metastable β titanium alloy Microstructure Plasticity Strength

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