Hybrid porous nanocomposites have received much attention during recent years because of their unique properties including well-controlled pore structures, high surface areas, and large and tunable pore sizes which fa...
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Hybrid porous nanocomposites have received much attention during recent years because of their unique properties including well-controlled pore structures, high surface areas, and large and tunable pore sizes which facilitate the diffusion of molecular entities inside the pores [1].Porous carbon-based nanocomposites are interesting owing to the potential applications as catalysts, electrodes and *** has been shown in the literature that the yields of hydrocarbons produced from FischerTropsch process can be improved by using catalytic materials with controlled nanostructure and particle size [2].
In the current work,the bulk ternary(0.85-x)BiFeO3-xBaTiO3-0.15PbTiO3(BF-BTx-PT,x=0.08-0.35)system has been studied as a potential high-temperature *** with various content of BT were prepared via solid-state route,an...
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In the current work,the bulk ternary(0.85-x)BiFeO3-xBaTiO3-0.15PbTiO3(BF-BTx-PT,x=0.08-0.35)system has been studied as a potential high-temperature *** with various content of BT were prepared via solid-state route,and pure perovskite phase was confirmed by X-ray *** temperature dependence of dielectric constants confirmed the decrease of Curie temperature with increasing BT *** was found that the morphotropic phase boundary(MPB)composition of BF-BTx-PT ceramics was in the vicinity of x=0.15,which exhibits optimal properties with piezoelectric constant d33 of 60 pC/N,high Curie temperature of 550℃,and low sintering temperature of 920℃.Measurements also showed that the depoling temperature was 300℃,about 150℃higher than that of commercialized PZT ceramics,which indicated good temperature ***-BTx-PT ceramics are promising candidates for high temperature applications.
Ag modified ZnO (Ag/ZnO) nanocrystals were prepared by a facile and low temperature wet chemical method. The phase structures, morphologies, and optical properties of the as-prepared samples were characterized by X-...
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Ag modified ZnO (Ag/ZnO) nanocrystals were prepared by a facile and low temperature wet chemical method. The phase structures, morphologies, and optical properties of the as-prepared samples were characterized by X-ray powder diffraction (XRD), field-emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM), the Brumauer-Emmett-Teller (BET) surface area, UV-vis diffuse reflectance spectroscopy and photoluminescence (PL) spectra, respectively. The photocatalytic performance of Ag/ZnO with diffent Ag contents was measured with the degradation of methyl orange (MO) at room temperature under UV light irradiation. The experimental results indicated that the well-crystalline ZnO nanopaticles with a size of ca. 4.5 nm exhibited a high photocatalytic activity for the degradation of MO with the apparent rate constant (k) of 1.57 ×10-2 min-1, and the photocatalytic activities of ZnO were further enhanced by modification with silver. When the Ag loading was 3mol%, Ag/ZnO showed the highest photocatalytic acitivity with a k value of 5.452×10-2 min-1, which is 3.5 and 2.5 time more than that of ZnO and commercial P25, respectively.
Nanoporous polymers, especially these presenting multimodal or multiscale porosity are of considerable interest because of their present advantages:hydrophobic surface, flexibility, biocompatiblity, easy functional mo...
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Nanoporous polymers, especially these presenting multimodal or multiscale porosity are of considerable interest because of their present advantages:hydrophobic surface, flexibility, biocompatiblity, easy functional modification, well regularity and so *** traditional templating techniques have been extented to fabricate the hierarchical structured polymer, such as breath figure, colloidal crystal, supercritical fluids, and emulsion templating.
Spray-drying was used to produce the high emissivity NiCr2O4 powders with a spinel structure. Preliminary investigations focused on fabricating the high emissivity powders for infrared radiation coatings and finding t...
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Spray-drying was used to produce the high emissivity NiCr2O4 powders with a spinel structure. Preliminary investigations focused on fabricating the high emissivity powders for infrared radiation coatings and finding the relationship between microstructure and emissivity. The NiCr2O4 powders were characterized for composition, microstructure, and infrared emissivity by X-ray diffraction (XRD), scanning electron microscopy (SEM), infrared radiant instrument, and Fourier transform infrared spectra (FT-IR). Thermogravimetry and differential thermal analysis show that the appropriate baking temperature for NiCr2O4 powder preparation is about 1200?C. The emissivity measurement and FT-IR spectra show that, because of the special spinel structure, the NiCr2O4 powders have a high emissivity about 0.91. Spray-drying is a suitable method to produce the high emissivity ceramic powders.
Recently, inverse opal structures, which have many potential applications in catalysts, separations, sensors, bioscience and photonics for their unique advantages such as highly ordered pore structure, large specific ...
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Recently, inverse opal structures, which have many potential applications in catalysts, separations, sensors, bioscience and photonics for their unique advantages such as highly ordered pore structure, large specific surface *** common synthesis strategy for inverse opal films is colloidal crystal templating method.
Air plasma spraying (APS) was used to produce high emissivity coatings with a NiCr204 spinel structure. The relationship between the emissivity and the crystal structure was investigated. X-ray diffraction (XRD) a...
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Air plasma spraying (APS) was used to produce high emissivity coatings with a NiCr204 spinel structure. The relationship between the emissivity and the crystal structure was investigated. X-ray diffraction (XRD) analyses show that NiCr204 spinel has been fabri- cated with the space group Fd3m. Scanning electron microscope (SEM) photographs show that the coating consists of a laminated structure with homogeneous grains and high porosity because of the unique feature of plasma spraying. The emissivity measurement and Fourier transformation infrared radiation (FT-IR) spectra show that NiCr204 has a high emissivity of about 0.91 because of its special spinel structure APS is a suitable method to produce high emissivity coatings.
The effects of microwave sintering on the properties, phases and microstructure of W-2OCu alloy, using composite powder fabricated by spray pyrolysis-continuous reduction technology, were investigated. Compared with t...
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The effects of microwave sintering on the properties, phases and microstructure of W-2OCu alloy, using composite powder fabricated by spray pyrolysis-continuous reduction technology, were investigated. Compared with the conventional hot-press sintering, microwave sintering to W-2OCu composites could be achieved with lower sintering temperature and shorter sintering time. Furthermore, microwave sintered W-Cu composites with high densification, homogenous microstructure and excellent properties were obtained. Microwave sintering could also result in finer microstructures. :~
An ultra-fast densification method based on high heating rate from the combustion reaction for producing carbon nanotubes (CNTs) reinforced alumina ceramics is reported. The heat generated by combustion reaction is ...
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An ultra-fast densification method based on high heating rate from the combustion reaction for producing carbon nanotubes (CNTs) reinforced alumina ceramics is reported. The heat generated by combustion reaction is adopted to act as a high temperature source to the sample, which results in a heating rate of 1660℃/min of the sample. Then a great mechanical pressure is applied to the sample when the sample gets the expected temperature. The densification process is finished in several minutes. The results indicate that the densification method is beneficial to protect the CNTs from destruction and creates good interracial combination between the nanotubes and the matrix. With the addition of 1 wt% CNTs, the fracture toughness of the ceramics prepared increases about 50%.
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