It remains a big challenge to synthesize two-dimensional(2D)GaN material for applications in power *** synthetic methods require complex equipment and processes and time ***,we reported a two-step route to prepare pol...
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It remains a big challenge to synthesize two-dimensional(2D)GaN material for applications in power *** synthetic methods require complex equipment and processes and time ***,we reported a two-step route to prepare polycrystalline 2D GaN *** amorphous ultrathin Ga_(2)O_(3)film was first exfoliated from the surface of liquid *** a vapor phase reaction,2D Ga_(2)O_(3)film was then converted into 2D GaN film while maintaining the 2D *** and high-resolution transmission electron microscope(HRTEM)analysis implies the successful synthesis of wurtzite-type GaN ultrathin *** simple strategy proposed in this work will provide more opportunities for applications of GaN ultrathin film in many devices.
The piezoelectric strain of K_(0.5)Na_(0.5)NbO_(3)-based lead-free ceramic at different temperatures was *** Rayleigh analysis shows that the intrinsic and extrinsic contributions are increased at temperature from 173...
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The piezoelectric strain of K_(0.5)Na_(0.5)NbO_(3)-based lead-free ceramic at different temperatures was *** Rayleigh analysis shows that the intrinsic and extrinsic contributions are increased at temperature from 173 to 298 *** addition,a monoclinic phase structure was observed at 83 *** results of phase field simulation show that the temperature dependent microstructure evolution is a function of the local structure *** work contributes to understanding the structure and properties relationship of the multi-cations doped KNN-based piezoelectric ceramics as a function of temperature.
High resolution and full-color light-emitting diodes require precise and efficient patterning of light-emitting structures containing quantum dots or *** report light-induced inverted patterning of nanocrystals in gla...
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High resolution and full-color light-emitting diodes require precise and efficient patterning of light-emitting structures containing quantum dots or *** report light-induced inverted patterning of nanocrystals in glasses for micro-light-emitting *** laser pulse induces structural destruction and amorphization of nanocrystals in glasses,forming inverted luminescent ***-throughput patterning of micrometer-scale,thermally stable,and highly photoluminescent structures in nanocrystals embedded glass is *** patterning method provides a novel way to fabricate high-performance and ultrahigh-resolution color conversion layers for micrometer-scale light-emitting diodes.
Inspired by structures of natural shells,zirconia-carbon nanocomposites were obtained by using natural chitin from shrimp shells as templates via the sol-gel route in this *** was dispersed in the water and chelated w...
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Inspired by structures of natural shells,zirconia-carbon nanocomposites were obtained by using natural chitin from shrimp shells as templates via the sol-gel route in this *** was dispersed in the water and chelated with the zirconia precursors by *** a heat treatment for carbonization,nacre-like structures of carbon-zirconia nanocomposites were successfully *** to the toughening mechanism of tetragonal zirconia,the mechanical properties of carbon-zirconia composites are further *** as-received zirconia/carbon nanocomposite with best mechanical property has a hardness of 5.88GPa and an elastic modulus of 80.6 GPa,which is even stronger than natural *** work might facilitate a versatile platform for developing green nanocomposites with reasonably good mechanical properties.
The rhombohedralα-GeTe can be approximated as a slightly distorted rock-salt structure along its[111]direction and possesses superb thermoelectric ***,the role of such a ferroelectric-like structural distortion on it...
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The rhombohedralα-GeTe can be approximated as a slightly distorted rock-salt structure along its[111]direction and possesses superb thermoelectric ***,the role of such a ferroelectric-like structural distortion on its transport properties remains ***,we performed a systematic study on the crystal structure and electronic band structure evolutions of Ge_(1-x)Sn_(x)Te alloys where the degree of ferroelectric distortion is continuously *** is revealed that the band gap is maximized while multiple valence bands are converged at x=0.6,where the ferroelectric distortion is the least but still *** undistorted,the band gap is considerably reduced,and the valence bands are largely separated ***,near the ferro-to-paraelectric phase transition Curie temperature,the lattice thermal conductivity reaches its minima because of significant lattice softening enabled by ferroelectric *** predict a peak ZT value of 2.6 at 673 K inα-GeTe by use of proper dopants which are powerful in suppressing the excess hole concentrations but meanwhile exert little influence on the ferroelectric distortion.
Electrical stimulation(ES)can restore motor function after spinal cord injury(SCI).However,traditional intraspinal ES has many disadvantages,such as the need for a complex circuitry device,an external power source,and...
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Electrical stimulation(ES)can restore motor function after spinal cord injury(SCI).However,traditional intraspinal ES has many disadvantages,such as the need for a complex circuitry device,an external power source,and a second surgery to remove the *** materials have received increasing at-tention due to their potential to convert ambient mechanical energy into ES without an external power source or implantation of ***,a novel polydopamine(PDA)coated barium titanate(BaTiO_(3))nanoparticles(BaTiO_(3)@PDA)incorporated silk fibroin(SF)hydrogel(SFBT)was *** SFBT hy-drogel was crosslinked by horseradish peroxidase(HRP)/hydrogel peroxide(H_(2)O_(2))to integrate the piezo-electric potency of BaTiO_(3)with the thermal sensitivity of HRP/H_(2)O_(2)for SCI *** hydrogel con-taining 5%(w/v)BaTiO_(3)@PDA nanoparticles(SFBT-5),which was selected for in vivo study,exhibited a short gelation time(5 min),suitable storage modulus(925±35 Pa),and wireless ES(average current of 124 nA).Moreover,Basso-Beattie-Bresnahan(BBB)scores test and footprint analysis demonstrated that the SFBT-5 hydrogel successfully enhanced motor functional recovery of *** histopathological assess-ments,the SFBT-5 hydrogel significantly accelerated spinal cord healing,as indicated by smaller lesion cavities(∼16.7%of the SCI group).Meanwhile,the SFBT-5 hydrogel accelerated neurogenesis,facilitated axon regrowth and synapse formation,and promoted ***,this study highlights the potential of piezoelectric hydrogels for SCI regeneration.
Designing high cost-effective catalysts has been one of the core topics in energy conversion and *** to unique electronic structure and excellent comprehensive properties,Pt-group metal(PGM)based-materials occupy the ...
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Designing high cost-effective catalysts has been one of the core topics in energy conversion and *** to unique electronic structure and excellent comprehensive properties,Pt-group metal(PGM)based-materials occupy the top region of numerous volcanic curves and are currently difficult to be replaced by abundant tran-sition metal ***,we pay attention to the osmium(Os),as the cheapest and the least noticed PGM in the field of electrocatalysis,with promising application ***,the three main modification strategies(anion modulation,heterostructure construction,substrate engineering)of Os-based catalysts in hydrogen evolution reaction(HER),the structural advantages provided in oxygen evolution reaction(OER),and other energy-related electrocatalysis applications are discussed one by *** addition,we discuss the key problems and countermeasures faced in their further breakthroughs,and look forward to future development trends and ***,the insights in this work will promote the understanding and designation of Os-based catalysts.
Zn-air batteries(ZABs)as a class of promising energy storage setups are generally powered by efficient and robust catalysts at the oxygen-involving *** the existing non-noble catalysts have outperformed noble Pt bench...
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Zn-air batteries(ZABs)as a class of promising energy storage setups are generally powered by efficient and robust catalysts at the oxygen-involving *** the existing non-noble catalysts have outperformed noble Pt benchmark in the alkaline liquid-state ZABs,to the best of our knowledge few have excelled Pt in quasi-solid-state(QSS)***,we found that an integrated Mn-Co cathode derived from the bimetallic Mn/Co metal organic frameworks generates a 1.4-fold greater power density in the QSS ZABs than a Pt cathode while its power density in liquid-state ZABs is only 0.8-fold of the ***,such Mn-Co catalyst delivers high-rate oxygen reduction reaction(ORR)capability with half-wave potential of 0.84 *** in-depth characterizations and analyses have demonstrated that the Co and Mn species show the specific affinity towards H_(2)O and O_(2),respectively,synergizing the ORR process in the water-deficient environment of QSS *** work has enlightened the rational design of non-noble metal catalysts to improve the power density of QSS ZABs.
To satisfy the demand of zinc oxide（ZnO） with advanced muti-functional properties, significant efforts have been made in synthesizing ZnO with various structure and morphology. In particular, hydrothermal method has...
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To satisfy the demand of zinc oxide（ZnO） with advanced muti-functional properties, significant efforts have been made in synthesizing ZnO with various structure and morphology. In particular, hydrothermal method has attracted considerable attentions, in which Zn4CO3（OH）6·H2O（ZCHH） is commonly found as a metastable precursor. However, the formation and crystallization mechanisms of ZCHH are still lacking and urgently needed. In the present study, the crystallization pathway of ZCHH was systematically investigated, and the results demonstrate that the amorphous zinc carbonate（AZC） was an even more unstable precursor. AZC nanoparticles typically aggregated to form one-dimensional（1D） ZCHH nanorods, however, two-dimensional（2D） ZCHH nanofilms were obtained in the presence of a certain concentration of calcium ion. The results suggest that calcium ions could promote the partial dissolution of AZC and facilitate the aggregation of AZC nanoparticles to form crystalline nanofilm. Moreover, 2D ZnO nanofilms could be obtained by heat treatment of the ZCHH nanofilms. The calcium ion mediated nonclassical crystallization pathway provides inspiration for fabrication of ZnO with controlled morphology and offers new opportunities for inorganic regulated materialsynthesis.
The high energy density and long cycling life of zinc-based batteries are restricted by the single electro-chemical reaction *** improve the electrochemical performance of batteries,electrode materials,electrolytes an...
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The high energy density and long cycling life of zinc-based batteries are restricted by the single electro-chemical reaction *** improve the electrochemical performance of batteries,electrode materials,electrolytes and membranes are regularly modified,while the construction of battery systems is often ***,a multifunctional electrode was prepared via 3D printing,which successfully coupled the metal oxide/hydroxide-zinc battery(MZB)reaction and rechargeable zinc-air battery(RZAB)*** ultrathick hierarchical 3D electrode provided a tunable capacity for the MZB system,which enabled the possibility for feasible output regulation of this hybrid *** active material NiCoLDH was discov-ered to undergo structure reconstruction during cycling,which revealed the capacity fading *** delicate system design and discovery ensured a high-performance battery configuration and revealed the corresponding mechanism,opening a new avenue for developing high-performance zinc batteries.
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