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Light tuning CO/H_(2)composition on Ag:Unraveling CO_(2)mass transfer and electron-phonon coupling in plasmon-enhanced electrocatalysis

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Nano Research 2025年第1期18卷 173-185页

作者： Rui Lin Dong Fan Luca MBerger Thomas Possmayer Yu Zhou Jiexin Zhu Xingbao Chen Wen Luo Lars Allmendinger Andreas Tittl Leonardo de Souza Menezes Guillaume Maurin Shihe Yang and Stefan AMaier Nanoinstitute Munich Faculty of PhysicsLudwig-Maximilians-Universität München80539 MunichGermany Institut Charles Gerhardt Montpellier UMR 5253 CNRS ENSCM UniversitéMontpellierPlace E.Bataillon34090 MontpellierFrance Guangdong Provincial Key Lab of Nano-Micro Material Research School of Advanced MaterialsPeking University Shenzhen Graduate SchoolShenzhen 518055China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Faculty of Chemistry and Pharmacy Ludwig-Maximilians-Universität München81377 MunichGermany Departamento de Física Universidade Federal de Pernambuco50670-901 Recife-PEBrazil School of Physics and Astronomy Monash University Clayton CampusMelbourneVictoria 3800Australia Department of Physics Imperial College LondonSW72AZ LondonUK

Plasmon-enhanced electrocatalysis(PEEC)is an emerging approach to mitigate CO_(2)*** mechanisms behind CO_(2)adsorption and reduction at the catalyst-electrolyte interface in PEEC still need to be further ***,we employ a well-defined Ag nanostructure to elucidate these pivotal *** shining light with wavelengths of 625,525,405 nm on Ag,an adjustable CO/H_(2)ratio from 35 to 1 can be *** reaction pathway changing under plasmonic excitation does not originate from the lowered CO_(2)mass transfer in the vicinity of Ag,as the electrochemical quartz crystal microbalance results unravel that a slightly elevated temperature in bulk electrolyte caused by light irradiation cannot weaken the CO_(2)adsorption at the Ag catalyst-electrolyte *** calculations reveal that optical excitation towards shorter wavelengths leads to a progressive lowered energy barrier for H_(2)formation together with an enhanced energy barrier for^(*)COOH *** thermodynamically suppressed,CO_(2)reduction can still be improved kinetically by optimizing the excitation wavelength and intensity,being accompanied with the enhanced *** absorption spectroscopy results further correlate the higher photocurrent with a prolonged electron-phonon coupling time,verifying that the improvement of CO_(2)reduction kinetics in PEEC can be realized by hot electron harnessing.

关键词： plasmonic catalysis photoelectrochemical CO_(2)reduction CO/H_(2)ratio hot electron generation electronphonon coupling thermal effect

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Microstructure and tribological properties of -oriented 3C-SiC by chemical vapor deposition

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Ceramics International 2025年

作者： Yang, Wenxuan Huang, Wei Li, Cuicui Wang, Chongjie Zhang, Chitengfei Tu, Rong Zhang, Song Hubei Longzhong Laboratory No.101 Luming Road Xiangyang441000 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Hubei Technology Innovation Center for Advanced Composites Wuhan430070 China

Highly -oriented 3C-SiC coatings were fabricated by chemical vapor deposition method at different temperatures. As deposition temperature increased from 1473 K to 1773 K, the surface structure of -oriented 3C-SiC transitioned from hexagonal structure with sixfold symmetry to hill-like structure, and finally to conical porous surface composed of stacked short rods. Owing to alteration of surface structure, the hardness of 3C-SiC coatings presented a trend of initially increasing and subsequently decreasing. The 3C-SiC coating deposited at 1673 K possessed the highest hardness, with a value of 42.08 GPa. The average friction coefficient for 3C-SiC/Si3N4 pair ranged from 0.258 to 0.569. The wear rate and hardness exhibited opposite trends. Compared with 3C-SiC coatings prepared at the other three temperatures, the 3C-SiC coating deposited at 1573 K exhibited the lowest wear rate under loads of 5 N, 10 N, and 15 N. Furthermore, the lowest wear rate, recorded at 15 N, was 4.1 × 10−6 mm3/Nm, attributed to high hardness and uniform grain size. The wear mechanism of -oriented 3C-SiC coatings during dry sliding primarily involved fracture, leading to fatigue and third-body wear. © 2025 Elsevier Ltd and Techna Group S.r.l.

关键词： Rockwell hardness

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NaTiOx-modified high-nickel layered oxide cathode for stable sodium-ion batteries

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Carbon Energy 2025年第1期7卷 283-291页

作者： Yingcong Liu Xing Zhou Dongwei He Xiaowei Liu Chao Yang Dawei Xu Meilong Wang Ruitao Sun Bin Zhang Jingjing Xie Jin Han Wen Chen Ya You State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Yibin Libode New Materials Co.Ltd SichuanChina International School of Materials Science and Engineering School of Materials Science and MicroelectronicsWuhan University of TechnologyWuhan 430070China

The O3-type layered cathode with high Ni content has attracted much attention because of its high capacity and simple synthesis ***,surface side reaction and O3-P3 phase transitions would occur during Na+insertion/extraction,resulting in unsatisfying electrochemical ***,O3-Na[Ni_(0.6)Co_(0.2)Mn_(0.2)]O_(2)(NNCM622)cathode is modified by a NaTiOx coating layer in a wet chemistry method,which reduces the parasitic reaction and facilitates Na+***,the partially doped Ti improves structural stability by restraining the irreversible multiple-phase *** a result,the modified NNCM622 cathode obtains a high specific capacity of 143.4 mAh g^(−1)and an improved capacity retention of 69%after 300 *** work offers new prospects for stabilizing the NNCM622 cathode with a feasible coating strategy.

关键词： cathode high-nickel layered oxides sodium-ion battery surface modification

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Spall Strength and the Study of Damage Mechanism of Pure-Al in Different Wave Systems

SSRN

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SSRN 2025年

作者： Zhang, Yang Sun, Yi Li, Peibo Zhang, Kaichang Zhao, GuiNan Luo, Guoqiang Shen, Qiang Hubei Longzhong Laboratory Hubei Xiangyang441000 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Qingdao University of Science and Technology China

To study the structural damage behavior of pure-Al under various shock wave profiles, this paper investigates the target using a light gas gun-driven density gradient material and a homogeneous material. It also conducts structural characterization and failure analysis of the postmortem target. The results indicate that spall strength increases with peak stress. At a strain rate of 103 s−1, the spall strength of the gradient material (approximately 0.502 GPa) is significantly higher than that of the homogeneous material (about 0.157 GPa). This difference is attributed to the temperature softening effect in the homogeneous material. The peak stress of the gradient material impacting pure Al is higher, leading to an increase in small-angle grain boundaries and a phenomenon of grain refinement. Here, the structural damage is primarily influenced by stress effects, resulting in higher spall strength. In contrast, the homogeneous material impacting pure Al exhibits a notable temperature rise, which significantly affects structural damage, making it more susceptible to the formation of pores and cracks, thus resulting in lower spall strength. Furthermore, there are differences in pore morphology under various wave regimes: the pores in the gradient material are elliptical, with the long axis perpendicular to the impact direction, while the pores in the homogeneous material are irregularly shaped. Additionally, the gradient material exhibits multiple spallation surfaces, whereas the homogeneous material shows only one spallation surface. By explaining the damage mechanisms of pure Al under different wave systems, this study aims to provide insights and guidance on the spallation behavior of aluminum matrix composites under complex conditions. © 2025, The Authors. All rights reserved.

关键词： Grain refinement

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Rodent enamel-inspired hydroxyapatite nanocomposites with Fe 3+ -rich amorphous intergranular phases

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Journal of materials Research and technology 2025年 36卷 7423-7432页

作者： Shenye Chen Zhengjian Su Bingyu Xue Benxi Xu Yafei Cheng Kun Wang Yidi Li Zhengyi Fu Hubei Longzhong Laboratory Xiangyang 441000 PR China School of Materials Science and Engineering Wuhan University of Technology Wuhan 430070 PR China State Key Laboratory of Precision Blasting Jianghan University Wuhan 430056 PR China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan 430070 PR China

Rodent enamel is primarily composed of hydroxyapatite (HAP) nanowires and Fe 3+ -rich amorphous intergranular phases (AIP). Inspired by rodent tooth enamel, this study successfully formed a layer of Fe 3+ -rich AIP on the outer layer of HAP nanowires by ion exchange between Fe 3+ and Ca 2+ within the HAP lattice. The thermal stability of Fe-HAP nanowires with Fe 3+ -rich AIP was enhanced. By bi-directional freezing of Fe-HAP nanowires with polyvinyl alcohol (PVA), rodent enamel-like nanocomposites (Fe-HEN) were obtained. Owing to the reinforcing and toughening effect of Fe 3+ -rich AIP, Fe-HEN exhibited a hardness of 1.66 ± 0.23 GPa, a Young's modulus of 48.8 ± 6.7 GPa in the longitudinal direction, as well as a hardness of 1.38 ± 0.16 GPa and a Young's modulus of 40.2 ± 3.0 GPa in the transversal direction. The flexural strength of the sample reached 153.5 ± 5.0 MPa, which is 2.9 times higher than that of samples without AIP, surpassing the performance of natural rodent enamel. The compressive strength reached 205 ± 4.3 MPa, representing a 1.5-fold increase over the sample without AIP and comparable to that of natural enamel. Compared to samples without AIP, Fe-HEN exhibits superior fracture toughness and crack deflection, better corrosion resistance, owing to the reinforcing effect of Fe 3+ -rich AIP at nanowire interfaces. This study demonstrates the incorporation of amorphous reinforced structures into the tooth enamel-like materials via ion exchange, offering a promising strategy for the development of high-performance multiscale composites.

关键词： Hydroxyapatite nanowires Amorphous intergranular phases Enamel-like nanocomposites Ion exchange Rodent enamel-inspired

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Large-scale manufacturing sulfide superionic conductor for advancing all-solid-state batteries

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Matter 2025年

作者： Wang, Shuo Lou, Chenjie Wu, Xinbin Lin, Jing Gautam, Ajay Li, Shenghao Huang, Jielei Cheng, Zhu Zhang, Shengnan Zhang, Xin Strauss, Florian Brezesinski, Torsten Luo, Guoqiang Tang, Mingxue Shen, Yang Lin, Yuanhua Nan, Ce-Wen Center of Smart Materials and Devices State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Material Science and Engineering Wuhan University of Technology Wuhan430070 China Center for High Pressure Science and Technology Advanced Research Beijing100094 China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and Engineering Tsinghua University Beijing100084 China Kaiserstr. 12 Karlsruhe76131 Germany Department of Radiation Science and Technology Delft University of Technology JB Delft2629 Netherlands

Lithium argyrodites with high ionic conductivities are favorable solid electrolytes (SEs) for all-solid-state batteries (ASSBs). However, their low preparation efficiency and poor cycling performance hinder their large-scale applications. In this work, we demonstrate successful large-scale production (over 1 kg per batch for the first time) of Li5.5PS4.5Cl0.75Br0.75 (LPSCB) by fast dry mixing followed by annealing, which presents high room temperature ionic conductivities of 13 mS cm−1 for cold-pressed and 25 mS cm−1 for sintered pellets. Combining neutron powder diffraction and 6Li → 7Li tracer-exchange nuclear magnetic resonance (NMR) spectroscopy measurements, we show that intercage jumps frequently occur through the 48h-16e-48h pathway in LPSCB, promoting the overall lithium conduction. The assembled ASSBs using LPSCB and a LiNi0.83Co0.11Mn0.06O2 electrode can be cycled for over 2,500 cycles at a 0.5 C rate and 1,800 cycles at a 2 C rate without any capacity degradation. Our results will accelerate the commercialization of sulfide SE for ASSBs. © 2025 Elsevier Inc.

关键词： Neutron powder diffraction

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Triphenylphosphine oxide additive regulates the growth of perovskite films by evaporation-spraying technique for high-efficiency large-area solar cell modules

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Journal of Energy Chemistry 2025年 108卷 468-476页

作者： Mingwei Zhu Danlin Ruan Xin Zhao Jiawei Song Jiahao Cheng Wenjian Shen Wangnan Li Guijie Liang Ying Liang Yong Peng Bin Li Yi-Bing Cheng Hubei Longzhong Laboratory Wuhan University of Technology (Xiangyang Demonstration Zone) Xiangyang 441000 Hubei China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan 430070 Hubei China Machine X Technology Co. Ltd. Jiaxing 314211 Zhejiang China Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices Hubei University of Arts and Science Xiangyang 441053 Hubei China State Key Laboratory of Advanced Processing and Recycling of Non-Ferrous Metals Lanzhou University of Technology Lanzhou 730050 Gansu China

Premature perovskite films rapidly form at the FAI/PbI 2 interface, inhibiting further reactions between FAI and PbI 2 during the fabrication of perovskite films via the evaporating-spraying hybrid method according to our previous research. In this research, triphenylphosphine oxide (TPPO) was proved to be an effective coordinator that reduces the reaction rate between FAI and PbI 2 at the initial stage, which can be attributed to the hydrogen (H) bonds between FA + and TPPO, and coordinate bonds between TPPO and PbI 2 . Additionally, the quality of perovskite films improved significantly: the trap state density decreased from 1.6 × 10 18 to 3.17 × 10 17 cm −3 , while the crystal size increased from 740 to 940 nm. The champion perovskite device achieved a remarkable efficiency of 20.93% (0.09 cm 2 ) and 16.75% (63.7 cm 2 ), marking one of the highest reported results for the evaporating-spraying hybrid method. Moreover, the perovskite solar cells retained over 80% of their initial performances after 600 h of storage at 60 °C in a nitrogen environment without encapsulation. It also maintained approximately 90% of its initial performance after continuous illumination at 25 °C for 1400 h under the same conditions.

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Achieving enhanced thermoelectric and mechanical performance in p-type bismuth telluride through constrained hot deformation

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Ceramics International 2025年

作者： Chen, Quansheng Ji, Chen Yu, Jian Hua, Lin Zhao, Wenyu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China School of Automotive Engineering Wuhan University of Technology Wuhan430070 China School of Materials Science and Engineering Jiujiang University Jiujiang332005 China Hubei Key Laboratory of Advanced Technology for Automobile Components Wuhan University of Technology Wuhan430070 China

Bi2Te3-based alloys remain the only commercially available thermoelectric (TE) materials. However, their practical applications are severely constrained by the inferior mechanical performance of the zone melting (ZM) ingot. Herein, a simple constrained hot deformation (CHD) technology was developed to prepare the p-type Bi0.5Sb1.5Te3 polycrystalline materials derived from ZM ingots. It was discovered that the deformation process has negligible impact on the phase composition, but can efficiently refine the grains to approximately 5 μm through the dynamic recrystallization and simultaneously introduce high-density dislocations. Although the donor-like effect induced by deformation would obviously deteriorate the electrical conductivity, the recovery effect triggered by high deformation temperature can effectively optimize the carrier concentration and thus alleviate the degradation of power factor. The material deformed at 773 K maintains a relatively high power factor ∼3.33 mW K−2 m−1 at 300 K, together with a significantly decreased lattice thermal conductivity ∼0.59 W m−1 K−1, and an improved zT ∼1.1 was obtained ultimately. More importantly, the deformed materials show a significant improvement in mechanical performance due to the grain refinement. A maximum average Vickers hardness of 0.67 GPa was achieved for the material deformed at 723 K, which is ∼40 % higher than that of the ZM ingot. Our work indicates the simple CHD is an efficient technology to synergistically enhance both TE and mechanical properties of Bi2Te3-based ZM ingot. © 2025 Elsevier Ltd and Techna Group S.r.l.

关键词： Polycrystalline materials

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Maximum Power Point Tracking Using a Multimode Hunter-Prey Optimization Algorithm for Gradually Varying Power in Centralized Thermoelectric Generation System

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Energy technology 2025年第0期

作者： Zhu, Wenchao Li, Peng Yang, Wenlong Xie, Changjun Li, Hao Yang, Yang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan430070 China School of Automation Wuhan University of Technology Wuhan430070 China Wuhan Industrial Technology Institute of Artificial Intelligence and New Energy Vehicles Wuhan430119 China Hubei Key Laboratory of Advanced Technology for Automotive Components Wuhan University of Technology Wuhan430070 China

The unstructured power outputs from thermoelectric generator (TEG) systems have precipitated the advancement of maximum power point tracking (MPPT) methods toward more intelligent solutions. This article concentrates on centralized TEG systems which work during nonuniform distribution of temperature cases and introduce the hunter-prey optimization algorithm with multimode updating (MMUHPO). Existing MPPT methods based on metaheuristic algorithms pay attention to improving tracking speed, efficiency, oscillation, and call frequency. However, in scenarios marked by gradual changes in power characteristics, the precision of MPPT algorithms can lead to frequent oscillatory searches and elevated computational demands. MMUHPO reduces power loss and simplifies algorithm complexity by improving the original mechanism and introducing termination mechanism and multimode update mechanism. Herein, the proposed algorithm is compared with several widely used MPPT algorithms based on metaheuristic algorithms under five different operating conditions. Remarkably, the MMUHPO algorithm demonstrates a substantial enhancement in energy collection efficiency, with the increase in efficiency reaching up to 109.8%. Finally, real-time data simulation experiments corroborate the exceptional tracking performance of the proposed algorithm. © 2025 Wiley-VCH GmbH.

关键词： Heuristic algorithms

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Improving the electrochemical performance of Prussian-Blue-analogue cathode by the co-doping of cobalt and nickel and its application in aqueous hybrid ions battery

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Electrochimica Acta 2025年 528卷

作者： Lin, Dian Hua, Ruiqing Yang, Hongwei Xu, Caiyun Yang, Sheng Chen, Jiajun Qu, Deyu Li, Xi Liu, Dan Department of Chemistry School of Chemistry Chemical Engineering and Life Science Wuhan University of Technology 122 Luoshi Road Hubei Wuhan430070 China State Key Laboratory of Advanced Technology for Material Synthesis and Processing School of Materials Science and Engineering Wuhan University of Technology 122 Luoshi Road Hubei Wuhan430070 China

Prussian blue and its analogues are promising electrode materials for the potassium ion batteries due to their large interstitial sites and three-dimensional porous framework. In this work, a series of Ni-co-doped Prussian blue analogues, Ni-Co hexacyanoferrate (NixCoyHCF), with various Ni/Co ratios are synthesized. Through the electrochemical investigation, the Prussian blue analogue with optimized ratio of Co and Ni coordinated with the CN, the NixCoyHCF materials exhibit enhanced performance as compared with that of the corresponding undoped counterparts. Specifically, the Ni1Co1HCF material delivers a high initial capacity of 101.6 mAh g-1 with a capacity retention of close to 100 % after 250 cycles, which reflects excellent cycle stability. Moreover, the Ni1Co1HCF material has excellent rate capability compared to NiHCF material. The capacity of the Ni1Co1HCF material under high current 2000 mA g-1 is >86.5 % of that under 50 mA g-1. After pairing with zeolite template carbon (ZTC) anode, the full cell provides an operational voltage of 1.60 V, a capacity of 54 mAh g-1 at 100 mA g-1, and 75.7 % capacity retention at 2000 mA g-1 along with the low self-discharge rate. © 2025

关键词： Semiconductor doping

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