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Propagation properties and spatial-mode UWOC performance of quasi-perfect optical vortex beam in an improved oceanic channel

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Optics and Laser technology 2025年 188卷

作者： Xiao, Zhiwei Zhou, Jian Wang, Lin Liu, Guizhen Ding, Zhongjun State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China School of Information Engineering Wuhan University of Technology Wuhan430070 China Hubei Key Laboratory of Broadband Wireless Communication and Sensor Networks Wuhan University of Technology Wuhan430070 China National Deep Sea Center Qingdao266237 China

In this study, the Quasi-perfect optical vortex (Quasi-POV) beam with topological charge-independence radial distribution is investigated to enhance the performance of underwater wireless optical communication (UWOC) system based on spatial modes. Additionally, the oceanic channel model is modified to obtain more reliable simulation results. The propagation and communication performance of perfect optical vortex (POV) beam and Quasi-POV beam are compared and analyzed through the modified model. With the optimization of beam's parameters, Quasi-POV beam achieves lower bit-error rate (BER) and higher average capacity in multiple phase shift keying (M−PSK) modulated UWOC system. The results indicate that Quasi-POV beam receives higher normalized intensity and lower crosstalk probability than the POV beam, the average simulation results for the three topologic charge cases show that the BER of Quasi-POV beam at 100 m reduced by approximately 52%, the average capacity of Quasi-POV beam increased by approximately 13.3%. The Quasi-POV beam has better performance than the POV beam in Spatial-Mode UWOC system according to the simulation results, which is more suitable for UWOC system based on spatial modes with smaller values of topologic charge. © 2025 Elsevier Ltd

关键词： Vortex flow

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Polyoxometalated metal-organic framework superstructure for stable water oxidation

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Science (New York, N.Y.) 2025年第6745期388卷 430-436页

作者： Yue, Kaihang Lu, Ruihu Gao, Mingbin Song, Fei Dai, Yao Xia, Chenfeng Mei, Bingbao Dong, Hongliang Qi, Ruijuan Zhang, Daliang Zhang, Jiangwei Wang, Ziyun Huang, Fuqiang Xia, Bao Yu Yan, Ya State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences Shanghai China School of Chemistry and Chemical Engineering State Key Laboratory of Materials Processing and Die & Mould Technology Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education) Hubei Key Laboratory of Material Chemistry and Service Failure Wuhan National Laboratory for Optoelectronics Huazhong University of Science and Technology (HUST) Wuhan China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing China School of Chemical Sciences University of Auckland Auckland New Zealand National Engineering Laboratory for Methanol to Olefins Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian China Shanghai Advanced Research Institute Chinese Academy of Sciences Shanghai Synchrotron Radiation Facility Shanghai China Center for High Pressure Science and Technology Advanced Research Shanghai China Key Laboratory of Polar Materials and Devices (MOE) Department of Electronics East China Normal University Shanghai China Multiscale Porous Materials Center Institute of Advanced Interdisciplinary Studies and School of Chemistry and Chemical Engineering Chongqing University Chongqing China College of Energy Material and Chemistry Inner Mongolia Key Laboratory of Low Carbon Catalysis Inner Mongolia University Hohhot China State Key Lab of Metal Matrix Composites School of Materials Science and Engineering Shanghai Jiao Tong University Shanghai China Center for Next-Generation Energy Materials and School of Chemical Engineering Sungkyunkwan University (SKKU) Seobu-ro Jangan-guGyeonggi-do Suwon South Korea

Stable, nonprecious catalysts are vital for large-scale alkaline water electrolysis. Here, we report a grafted superstructure, MOF@POM, formed by self-assembling a metal-organic framework (MOF) with polyoxometalate (POM). In situ electrochemical transformation converts MOF into active metal (oxy)hydroxides to produce a catalyst with a low overpotential of 178 millivolts at 10 milliamperes per square centimeter in alkaline electrolyte. An anion exchange membrane water electrolyzer incorporating this catalyst achieves 3 amperes per square centimeter at 1.78 volts at 80°C and stable operation at 2 amperes per square centimeter for 5140 hours at room temperature. In situ electrochemical spectroscopy and theoretical studies reveal that the synergistic interactions between metal atoms create a fast electron-transfer channel from catalytic iron and cobalt sites, nickel, and tungsten in the polyoxometalate to the electrode, stabilizing the metal sites and preventing dissolution.

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Molecular dynamics study on nano sliding behavior at DLC/AISI 304 interface

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Carbon 2025年 240卷

作者： Huang, Tao Yang, Mai Su, Yibing Han, Yuzhe Li, Qizhong Zhang, Song Goto, Takashi Tu, Rong Zhang, Lianmeng Chaozhou Branch of Chemistry and Chemical Engineering Guangdong Laboratory Chaozhou521000 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Hubei Technology Innovation Center for Advanced Composites Wuhan University of Technology Wuhan430070 China New Industry Creation Hatchery Center Tohoku University Sendai980-8579 Japan

Diamond-like carbon (DLC) serves as a prevalent protective coating for stainless steel in various applications, including automotive engines and medical devices, to combat wear and corrosion. This investigation delves into the nanoscale interface friction and mechanical behavior between DLC and polycrystalline austenitic stainless steel. Molecular dynamics simulations were employed to model the sliding interface structure's evolution and friction performance under differing contact pressures and graphitization states. In the friction sliding process, carbon atoms predominantly experience surface structural reorganization with minimal diffusion. The displacement of stainless steel's internal atoms is chiefly driven by deformation rather than diffusion. The study also examines the synergistic impacts of external pressure, structural transformations, and interfacial compounds on the system's friction mechanism. At low contact pressures (≤8 GPa), austenite deformation and recrystallization triggered by friction were noted. Conversely, at high junction pressures (>8 GPa), the interplay of stress and strain induces martensitic transformation in stainless steel and amplifies mechanical mixing with DLC. The α′-martensite proportion correlates positively with contact pressure and friction duration. An uptick in martensite content escalates the system's friction force;however, when the system's friction is governed entirely by martensite, it manifests a stable low friction force. Furthermore, under varied carbon atom hybridization conditions, systems characterized by high sp3 hybridization display increased strain and friction. These insights provide valuable perspectives for improving the research on DLC and stainless steel nano micro interfaces. © 2025

关键词： Austenitic stainless steel

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Simultaneous optimization of lattice and spin configurations in atomic scale simulation of magnetic materials

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Physical Review B 2025年第13期111卷 134412-134412页

作者： Zhengtao Huang Teng Yang Hanxing Liu Ben Xu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Center for Smart Materials and Device Integration School of Material Science and Engineering Wuhan University of Technology Wuhan 430070 People's Republic of China Graduate School of China Academy of Engineering Physics Beijing 100088 People's Republic of China School of Materials Science and Engineering Tsinghua University Beijing 100084 People's Republic of China

Large scale atomistic simulations involving spin-lattice coupling are at the forefront of research in condensed matter physics and materials science. A key challenge lies in determining the ground state configurations of spins and lattices given this strong coupling, complicated by their evolution adherence to distinct governing equations. Unlike first-principles calculations, where the magnetic configuration is naturally determined by minimizing the electronic energy, no existing algorithm can simultaneously optimize both lattice and spin degrees of freedom at the atomic scale. This paper introduces a synergistic optimization framework for lattice and spin optimization in magnetic materials, overcoming the conventional separation approach. Employing a “pseudoatomic” method, the simultaneous optimization of atomic and spin configurations enhances accuracy and speed, enabling both atomic scale precision and large scale calculations. Applied to face-centered-cubic iron and BiFeO3, this approach demonstrates effective convergence, offering a robust tool for complex spin-lattice coupling problems, which paves a path for addressing high-dimensional optimization problems.

关键词： Atoms

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Enhanced oxygen evolution reaction activity of iridium oxide supported on tantalum-doped tin oxide for acidic water electrolysis

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International Journal of Electrochemical Science 2025年第7期20卷

作者： Tian, Juanjuan Li, Shang Zhu, Zuobiao Tan, Jinting Pan, Mu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Luoshi Road 122# Wuhan 430070 China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen China Hubei Key Laboratory of Fuel Cells Wuhan University of Technology Wuhan 430070 China

In the research process of proton exchange membrane electrolysis, Ir-based catalysts exhibit sluggish dynamics of reaction and the poor durability in strongly acidic medium, as well as the high cost greatly limit their commercialization. In this paper, in order to decrease the Ir amount and improve precious metal utilization, Ta-doped tin oxide (SnO₂) was prepared by sol-gel method in this paper as a support and loaded with iridium dioxide (IrO₂). The results indicate that the Ta doping increased conductivity of SnO₂ by two orders of magnitude and inhibited particle size growth. The introduction of 2Ta-SnO₂ supports improved the electric charge transfer dynamics during the catalytic reaction process, and the mass activity of the 40 wt% IrO₂/2Ta-SnO₂ catalyst reached 835.39 A g⁻¹ IrO₂, which was 3.6 times higher than that of commercial IrO₂. The overpotential of the 40 wt% IrO₂/2Ta-SnO₂ catalyst was 264 mV at a current density of 10 mA cm⁻², which is due to the prominent dispersion effect of the support as well as the interaction of the support surface with the active substance. Its stability is better than that of commercial IrO₂ in a stability test over 20,000 s. Therefore, Ta-doped SnO₂ supported IrO₂ catalysts have a promising application by reducing the cost of precious metal catalysts and enhancing the electrocatalytic properties of OER catalysts. © 2025 The Authors

关键词： Catalyst support OER catalyst Proton exchange membrane electrolysis Ta-doped SnO2

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Compatible matching and synergy operation optimization of hydrogen-electric hybrid energy storage system in DC microgrid

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Energy Conversion and Management: X 2025年 26卷

作者： Du, Banghua Peng, Yanyu Li, Yang Xie, Changjun Zhu, Shihao Zhu, Wenchao Yang, Yang You, Li Zhang, Leiqi Zhao, Bo Hubei Key Laboratory of Advanced Technology for Automotive Components Wuhan University of Technology Wuhan430070 China School of Automation Wuhan University of Technology Wuhan430070 China Department of Electrical Engineering Chalmers University of Technology Gothenburg41258 Sweden State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan430070 China State Grid Hubei Electric Power Research Institute Wuhan430077 China State Grid Zhejiang Electric Power Research Institute Hangzhou310014 China

Hydrogen energy storage (HES) systems could balanced source-load mismatches in DC microgrids. By combining HES with electrical energy storage (EES), the start-up delay and rapid degradation of HES under fluctuating inputs can be mitigated, enhancing system adaptability. However, without proper power allocation and operational optimization, system efficiency and the lifespan of HES and EES decrease. Accordingly, this paper proposes a compatible matching and synergy operation optimization for hydrogen-electric hybrid energy storage systems (H-E HESS). Firstly, Complete Ensemble Empirical Mode Decomposition with Adaptive Noise (CEEMDAN) is developed to decompose power fluctuation signals into frequency components, and the Hilbert transform calculates the energy value to determine high- and low-frequency dividing points. Next, a system power allocation strategy is formulated through the fast response of the EES to compensate for the delay in the start-up of the HES. A multi-objective optimization model is then developed to balance efficiency and lifespan, which is solved by the NSGA-III algorithm. Finally, case studies show that the proposed strategy improves efficiency by 17.95 % and 8.34 %, reduces degradation rates by 1 % and 0.71 %, and shortens system response time in 1 s, compared to Schemes I and II. The strategy's effectiveness is also validated through an experimental platform in a hydrogen-electric coupled DC microgrid demonstration project. © 2025 The Author(s)

关键词： Hydrogen storage

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Sym- and Asym-Expanded Heterohelicene Isomers Featuring Extended Multi-Resonance Skeleton for Narrowband Deep-Blue Fluorescence

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Angewandte Chemie - International Edition 2025年第13期64卷

作者： Zeng, Xuan Luo, Xiaofeng Meng, Guoyun Wang, Xuewen Zhang, Dongdong Duan, Lian School of Chemistry Chemical Engineering and Life Science State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Key Lab of Organic Optoelectronics and Molecular Engineering of Ministry of Education Department of Chemistry Tsinghua University Beijing100084 China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu hydrogen Valley Foshan528200 China Center for Flexible Electronics Technology Tsinghua University Beijing100084 China

Expanded heterohelicenes composed of alternating linearly and angularly fused multi-resonance (MR) skeletons have gained wide interest owing to their promising narrowband emissions. Herein, a pair of sym- and asym-expanded heterohelicene isomers was obtained by merging boron/oxygen (B/O)-embedded MR triangulene and indolo[3,2,1-jk]carbazole units via one-pot synthesis. Owing to their fully resonating extended helical skeleton, the target heterohelicenes exhibit a significantly narrowed spectra bandwidth while emission red-shifting, thus affording deep-blue narrowband emission with a peak at approximately 460 nm, full-width-at-half-maximum (FWHM) of only 18 nm, and near-unity photoluminescence quantum yields. In comparison to the symmetrical structure, the asym-expanded heterohelicene displays suppressed aggregation within doped films, thereby showing superior narrowband electroluminescence in devices with CIE coordinates of (0.12, 0.18) and a high external quantum efficiency of up to 25 %, which retains 18.1 % even at a high luminance of 10,000 cd m−1. Overall, this work provides a novel paradigm for the development of narrowband expanded heterohelicenes. © 2025 Wiley-VCH GmbH.

关键词： Electroluminescence

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Boosting oxygen evolution of LiCoO2 electrocatalysts via lithium defect

Materials Today Catalysis

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materials Today Catalysis 2025年 8卷

作者： Li, Huamei Li, Mengyuan Liao, Lingling Yang, Han Xiang, Kun Luo, Guoqiang Xie, Mingjiang School of Chemistry and Environmental Engineering Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education Wuhan Institute of Technology Wuhan430205 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Hubei Key Lab for Processing and Application of Catalytic Materials College of Chemical Engineering Huanggang Normal University Huanggang438000 China

The challenge of the complex oxygen evolution reaction (OER) currently impedes the efficient production of hydrogen via electrolytic water splitting. To address this issue, the development and improvement of effective electrocatalysts are required. LiCoO2, a key material in lithium-ion batteries, has shown promising potential as an electrocatalyst for electrochemical energy conversion. However, OER catalysts derived from LiCoO2 have faced obstacles such as high overpotential and a complicated preparation process. In this study, the preparation method is adjusted to optimize the synthesis of Li1-xCoO2 with a defective structure, resulting in an impressive overpotential of only 290 mV at a current density of 100 mA cm−2 and a remarkable Tafel slope of 15.2 mV dec−1. The exceptional catalytic activity of Li1-xCoO2 can be attributed to the absence of Li, which triggers oxidative alterations in the electronic structure of Co. Density functional theory (DFT) calculations reveal that Li defects can influence the d-band center of active Co sites, enhancing the adsorption capabilities of Co sites towards *OOH intermediates and increasing the conductivity of the electrocatalyst during the OER process. These alterations improve the velocity of the crucial step in the reaction, ultimately boosting the catalyst's overall performance and efficiency. © 2024 The Authors

关键词： Lithium-ion batteries

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Ionic liquid-grafted MXene composite polymer electrolytes for high-performance solid-state batteries

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Chemical Engineering Journal 2025年 514卷

作者： Qian, Zhi Qiu, Zhao-Dong Wang, Rui-Qing Wei, Mei-Tong Fei, An-Min Hu, Zhi-Yi Mohamed, Hemdan S.H. Chen, Li-Hua Li, Yu Su, Bao-Lian State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Wuhan University of Technology Wuhan430070 China Physics Department Faculty of Science Fayoum University El Gomhoria Street Fayoum63514 Egypt University of Namur NamurB-5000 Belgium

All-solid-state batteries (ASSBs) have obtained much attention due to the high energy density and security. At present, PEO-based solid-state batteries are considered to be one of the most promising candidates for high-performance ASSBs due to the excellent processability and good interfacial stability. However, low ionic conductivity and Li+ transference number seriously hinder their progress in practical applications. Here, a novel filler is developed by embedding ionic liquid (IL) grafted onto the surface of MXene to improve the electrochemical performance of PEO-based solid composite polymer electrolyte (MXene-IL-SPE) for ASSBs. The 2D MXene can significantly reduce the crystallinity of PEO, and the presence of IL not only enhances the dispersion of MXene in the polymer matrix, but also promotes the dissociation of lithium salts and anchors anions. As a result, the MXene-IL-SPE possesses high ionic conductivity (7.19 × 10−4 S cm−1) and Li+ transference number (0.51), together with wide electrochemical window (5.2 V) at 60 °C. The assembled LiFePO4|MXene-IL-SPE|Li full cell exhibits remarkable rate capability and exceptional capacity of 154.8 mAh g−1 over 120 cycles with an impressive 95.3 % capacity retention at 0.5 C. This design opens up a new way to prepare high performance CPEs for ASSBs. © 2025 Elsevier B.V.

关键词： Solid-state Batteries

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Lattice Boltzmann simulation of droplet dynamics in proton exchange membrane fuel cell channel with mechanical vibration

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Chemical Engineering Research and Design 2025年 218卷 302-311页

作者： Zijian Zhou Shuai Zhai Xunchen Liu Yuan Fang Mingzhang Chen Ju Zhang Shanyue Guan Hubei Longzhong Laboratory Wuhan University of Technology Xiangyang Hubei 441000 China School of Automotive Engineering Wuhan University of Technology Wuhan 430070 China Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education College of Chemistry and Materials Science South-central University for Nationalities Wuhan 430074 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan 430070 China School of Vehicle Engineering Hubei University of Automotive Technology Shiyan 442002 China

Handling water is a critical challenge for proton exchange membrane (PEM) fuel cells, significantly impacting their lifespan and reliability. While most PEM cells operate in vibrational environments, no studies have examined how mechanical vibrations affect water handling. This research investigates water droplet behavior in a vibrating airflow channel and proposes a new design featuring a hydrophilic band to enhance water management. key findings include: (1) an optimal hydrophilic band width of 0.6 that facilitates droplet movement; (2) a decrease in droplet velocity from 0.107 to 0.024 m s −1 as amplitude increases from 5 mm to 20 mm; and (3) an increase in velocity from 0.0669 to 0.15 m s −1 with higher frequency, highlighting the significant effects of vibration on droplet dynamics and overall water management in PEM fuel cells.

关键词： Machine vibrations

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