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Numerical analysis of high-efficiency lead-free perovskite solar cell with NiO as hole transport material and PCBM as electron transport material

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CSI Transactions on ICT 2020年第2期8卷 111-116页

作者： T. R. Lenka A. C. Soibam K. Dey T. Maung F. Lin Microelectronics and VLSI Design Group Department of Electronics and Communication Engineering National Institute of Technology Silchar Silchar India Cavendish Laboratory Department of Physics University of Cambridge Cambridge UK Solar Energy Research Institute of Singapore National University of Singapore Singapore Singapore Department of Electrical and Computer Engineering National University of Singapore Singapore Singapore

In this work a lead free perovskite solar cell structure is proposed with NiO as the hole transport material (HTM), CH3NH3SnI3 as the perovskite absorber material and PCBM (phenyl C61 butyric acid methyl ester) as the electron transport material (ETM). Numerical analysis of the designed solar cell is performed using Solar Cell Capacitance Simulator (SCAPS-1D) program. The power conversion efficiency (PCE) of the optimized device stack is found to be above 29% with Voc = 0.98 V, Jsc = 34.86 mA/cm2, FF = 85.64%. The lead free perovskite solar cell with different HTM and ETM may be investigated for high PCE.

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Lightweight Task-Oriented Semantic Communication Empowered by Large-Scale AI Models

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IEEE Transactions on Vehicular Technology 2025年

作者： Liu, Chuanhong Guo, Caili Yang, Yang Chen, Mingzhe Quek, Tony Q. S. Beijing University of Posts and Telecommunications Beijing Key Laboratory of Network System Architecture and Convergence School of Information and Communication Engineering Beijing100876 China Beijing University of Posts and Telecommunications Beijing Laboratory of Advanced Information Networks School of Information and Communication Engineering Beijing100876 China University of Miami Department of Electrical and Computer Engineering Institute for Data Science and Computing Coral GablesFL United States Singapore University of Technology and Design Dept. of Information Systems Technology and Design 487372 Singapore

Recent studies have focused on leveraging large-scale artificial intelligence (LAI) models to improve semantic representation and compression capabilities. However, the substantial computational demands of LAI models pose significant challenges for real-time communication scenarios. To address this, this paper proposes utilizing knowledge distillation (KD) techniques to extract and condense knowledge from LAI models, effectively reducing model complexity and computation latency. Nevertheless, the inherent complexity of LAI models leads to prolonged inference times during distillation, while their lack of channel awareness compromises the distillation performance. These limitations make standard KD methods unsuitable for task-oriented semantic communication scenarios. To address these issues, we propose a fast distillation method featuring a pre-stored compression mechanism that eliminates the need for repetitive inference, significantly improving efficiency. Furthermore, a channel adaptive module is incorporated to dynamically adjust the transmitted semantic information based on varying channel conditions, enhancing communication reliability and adaptability. In addition, an information bottleneck-based loss function is derived to guide the fast distillation process. Simulation results verify that the proposed scheme outperform baselines in term of task accuracy, model size, computation latency, and training data requirements. © 1967-2012 IEEE.

关键词： NP-hard

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Ruddlesden-Popper chalcogenides push the limit of mechanical stiffness and glass-like thermal conductivity in single crystals

arXiv

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arXiv 2023年

作者： Hoque, Md Shafkat Bin Hoglund, Eric R. Zhao, Boyang Bao, De-Liang Zhou, Hao Thakur, Sandip Osei-Agyemang, Eric Hattar, Khalid Scott, Ethan A. Surendran, Mythili Tomko, John A. Gaskins, John T. Aryana, Kiumars Makarem, Sara Alwen, Adie Hodge, Andrea Balasubramanian, Ganesh Giri, Ashutosh Feng, Tianli Hachtel, Jordan A. Ravichandran, Jayakanth Pantelides, Sokrates T. Hopkins, Patrick E. Department of Mechanical and Aerospace Engineering University of Virginia CharlottesvilleVA22904 United States Department of Materials Science and Engineering University of Virginia CharlottesvilleVA22904 United States Center for Nanophase Materials Sciences Oak Ridge National Laboratory Oak RidgeTN37830 United States Mork Family Department of Chemical Engineering and Materials Science University of Southern California Los AngelesCA90089 United States Department of Physics and Astronomy Vanderbilt University NashvilleTN37235 United States Department of Mechanical Engineering University of Utah Salt Lake CityUT84112 United States Department of Mechanical Industrial and Systems Engineering University of Rhode Island KingstonRI02881 United States Department of Materials Design and Innovation University at Buffalo The State University of New York BuffaloNY14260 United States Department of Mechanical Engineering and Mechanics Lehigh University 19 Memorial Drive West BethlehemPA18015 United States Nuclear Engineering University of Tennessee KnoxvilleTN37996 United States Sandia National Laboratories AlbuquerqueNM87185 United States Laser thermal analysis CharlottesvilleVA22902 United States Department of Electrical and Computer Engineering Vanderbilt University NashvilleTN37235 United States Department of Physics University of Virginia CharlottesvilleVA22904 United States

Insulating materials featuring ultralow thermal conductivity for diverse applications also require robust mechanical properties. Conventional thinking, however, which correlates strong bonding with high atomic-vibration-mediated heat conduction, led to diverse weakly bonded materials that feature ultralow thermal conductivity and low elastic moduli. One must, therefore, search for strongly-bonded single crystals in which heat transport is impeded by other means. Here, we report intrinsic, glass-like, ultralow thermal conductivity and ultrahigh elastic-modulus/thermal-conductivity ratio in single-crystalline Ruddlesden-Popper Ban+1ZrnS3n+1, n = 2,3, which are derivatives of BaZrS3. Their key features are strong anharmonicity and intra-unit-cell rock-salt blocks. The latter produce strongly bonded intrinsic superlattices, impeding heat conduction by broadband reduction of phonon velocities and mean free paths and concomitant strong phonon localization. The present study initiates a paradigm of "mechanically stiff phonon glasses". © 2023, CC BY.

关键词： Single crystals

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Opportunities and challenges for monitoring terrestrial biodiversity in the robotics age

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Nature Ecology and Evolution 2025年第6期9卷 1031-1042页

作者： Pringle, Stephen Dallimer, Martin Goddard, Mark A. Le Goff, Léni K. Hart, Emma Langdale, Simon J. Fisher, Jessica C. Abad, Sara-Adela Ancrenaz, Marc Angeoletto, Fabio Auat Cheein, Fernando Austen, Gail E. Bailey, Joseph J. Baldock, Katherine C. R. Banin, Lindsay F. Banks-Leite, Cristina Barau, Aliyu S. Bashyal, Reshu Bates, Adam J. Bicknell, Jake E. Bielby, Jon Bosilj, Petra Bush, Emma R. Butler, Simon J. Carpenter, Dan Clements, Christopher F. Cully, Antoine Davies, Kendi F. Deere, Nicolas J. Dodd, Michael Drinkwater, Rosie Driscoll, Don A. Dutilleux, Guillaume Dyrmann, Mads Edwards, David P. Farhadinia, Mohammad S. Faruk, Aisyah Field, Richard Fletcher, Robert J. Foster, Chris W. Fox, Richard Francksen, Richard M. Franco, Aldina M. A. Gainsbury, Alison M. Gardner, Charlie J. Giorgi, Ioanna Griffiths, Richard A. Hamaza, Salua Hanheide, Marc Hayward, Matt W. Hedblom, Marcus Helgason, Thorunn Heon, Sui P. Hughes, Kevin A. Hunt, Edmund R. Ingram, Daniel J. Jackson-Mills, George Jowett, Kelly Keitt, Timothy H. Kloepper, Laura N. Kramer-Schadt, Stephanie Labisko, Jim Labrosse, Frédéric Lawson, Jenna Lecomte, Nicolas de Lima, Ricardo F. Littlewood, Nick A. Marshall, Harry H. Masala, Giovanni L. Maskell, Lindsay C. Matechou, Eleni Mazzolai, Barbara McConnell, Alistair Melbourne, Brett A. Miriyev, Aslan Nana, Eric Djomo Ossola, Alessandro Papworth, Sarah Parr, Catherine L. Payo-Payo, Ana Perry, Gad Pettorelli, Nathalie Pillay, Rajeev Potts, Simon G. Prendergast-Miller, Miranda T. Qie, Lan Rolley-Parnell, Persie Rossiter, Stephen J. Rowcliffe, Marcus Rumble, Heather Sadler, Jon P. Sandom, Christopher J. Sanyal, Asiem Schrodt, Franziska Sethi, Sarab S. Shabrani, Adi Siddall, Robert Smith, Simón C. Snep, Robbert P. H. Soulsbury, Carl D. Stanley, Margaret C. Stephens, Philip A. Stephenson, P.J. Struebig, Matthew J. Studley, Matthew Svátek, Martin Tang, Gilbert Taylor, Nicholas K. Umbers, Kate D. L. Ward, Robert J. White, Patrick J. C. Whittingham, Mark J. Wich, Serge Williams, Christopher D. Yakubu, Ibrahim B. Yoh, Natalie Durrell Institute of Conservation and Ecology (DICE) School of Natural Sciences University of Kent Canterbury United Kingdom Centre for Environmental Policy Imperial College London London United Kingdom Department of Geography and Environmental Sciences Northumbria University Newcastle upon Tyne United Kingdom School of Computing Engineering and the Built Environment Edinburgh Napier University Edinburgh United Kingdom Synthotech Ltd Milner Court Hornbeam Square Harrogate United Kingdom Mechanical Engineering Department University College London London United Kingdom HUTAN SWD Kota Kinabalu Malaysia Programa de Pós-Graduação em Gestão e Tecnologia Ambiental da Universidade Federal de Rondonópolis Rondonópolis Brazil Department of Engineering Harper Adams University Newport United Kingdom Applied Ecology Research Group School of Life Sciences Anglia Ruskin University Cambridge United Kingdom Centre for Ecology and Hydrology Penicuik United Kingdom Department of Life Sciences Imperial College London Silwood Park Campus Ascot United Kingdom Department of Urban and Regional Planning Faculty of Earth and Environmental Sciences Bayero University Kano Nigeria Greenhood Nepal Kathmandu Nepal Animal Rural & Environmental Sciences Nottingham Trent University Nottinghamshire United Kingdom School of Biological and Environmental Sciences Liverpool John Moores University Liverpool United Kingdom Lincoln Centre for Autonomous Systems University of Lincoln Lincoln United Kingdom Royal Botanic Garden Edinburgh Edinburgh United Kingdom School of Biological Sciences University of East Anglia Norwich Research Park Norwich United Kingdom Digital Ecology Limited Bristol United Kingdom School of Biological Sciences University of Bristol Bristol United Kingdom Department of Computing Imperial College London London United Kingdom Department of Ecology and Evolutionary Biology University of Colorado Boulder CO United States Faculty of Science Technology Engineering

With biodiversity loss escalating globally, a step change is needed in our capacity to accurately monitor species populations across ecosystems. Robotic and autonomous systems (RAS) offer technological solutions that may substantially advance terrestrial biodiversity monitoring, but this potential is yet to be considered systematically. We used a modified Delphi technique to synthesize knowledge from 98 biodiversity experts and 31 RAS experts, who identified the major methodological barriers that currently hinder monitoring, and explored the opportunities and challenges that RAS offer in overcoming these barriers. Biodiversity experts identified four barrier categories: site access, species and individual identification, data handling and storage, and power and network availability. Robotics experts highlighted technologies that could overcome these barriers and identified the developments needed to facilitate RAS-based autonomous biodiversity monitoring. Some existing RAS could be optimized relatively easily to survey species but would require development to be suitable for monitoring of more ‘difficult’ taxa and robust enough to work under uncontrolled conditions within ecosystems. Other nascent technologies (for instance, new sensors and biodegradable robots) need accelerated research. Overall, it was felt that RAS could lead to major progress in monitoring of terrestrial biodiversity by supplementing rather than supplanting existing methods. Transdisciplinarity needs to be fostered between biodiversity and RAS experts so that future ideas and technologies can be codeveloped effectively. © The Author(s) 2025.

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Geometric Filterless Photodetectors for Mid-infrared Spin Light

arXiv

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arXiv 2022年

作者： Wei, Jingxuan Chen, Yang Li, Ying Li, Wei Xie, Junsheng Lee, Chengkuo Novoselov, Kostya S. Qiu, Cheng-Wei Department of Electrical and Computer Engineering National University of Singapore Singapore117583 Singapore CAS Key Laboratory of Mechanical Behaviour and Design of Materials Department of Precision Machinery and Precision Instrumentation University of Science and Technology of China Hefei230026 China Interdisciplinary Center for Quantum Information State Key Laboratory of Modern Optical Instrumentation ZJU-Hangzhou Global Scientific and Technological Innovation Center Zhejiang University Hangzhou310027 China International Joint Innovation Center Key Lab of Advanced Micro/Nano Electronic Devices & Smart Systems of Zhejiang Zhejiang University Haining314400 China GPL Photonics Lab State Key Laboratory of Applied Optics Changchun Institute of Optics Fine Mechanics and Physics Chinese Academy of Sciences Changchun130033 China Center for Intelligent Sensors and MEMS National University of Singapore Singapore117608 Singapore Institute for Functional Intelligent Materials National University of Singapore Singapore117544 Singapore

Free-space circularly polarized light (CPL) detection, requiring polarizers and waveplates, has been well established, while such spatial degree of freedom is unfortunately absent in integrated on-chip optoelectronics. So far, those reported filterless CPL photodetectors suffer from the intrinsic small discrimination ratio, vulnerability to the non-CPL field components, and low responsivity. Here, we report a distinct paradigm of geometric photodetectors in mid-infrared exhibiting colossal discrimination ratio, close-to-perfect CPL-specific response, a zero-bias responsivity of 392 V/W at room temperature, and a detectivity of ellipticity down to 0.03o Hz−1/2. Our approach employs plasmonic nanostructures array with judiciously designed symmetry, assisted by graphene ribbons to electrically read their near-field optical information. This geometry-empowered recipe for infrared photodetectors provides a robust, direct, strict, and high-quality solution to on-chip filterless CPL detection and unlocks new opportunities for integrated functional optoelectronic devices. Copyright © 2022, The Authors. All rights reserved.

关键词： Photodetectors

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Consistent Discretization of a Class of Predefined-Time Stable systems

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IFAC-PapersOnLine 2020年第2期53卷 628-633页

作者： Esteban Jiménez-Rodríguez Rodrigo Aldana-López Juan D. Sánchez-Torres David Gómez-Gutiérrez Alexander G. Loukianov Relativity6 Inc. Computer Science & Artificial Intelligence Lab Jalisco 45040 México Department of Computer Science and Systems Engineering University of Zaragoza Zaragoza 50009 España Research Laboratory on Optimal Design Devices and Advanced Materials -OPTIMA- Department of Mathematics and Physics ITESO Jalisco 45604 México Multi-agent autonomous systems lab Intel Labs Intel Tecnología de México Jalisco 45019 Mexico Tecnologico de Monterrey Escuela de Ingeniería y Ciencias Jalisco 45138 Mexico Department of Electrical Engineering Cinvestav-Guadalajara Jalisco 45019 México

As the main contribution, this document provides a consistent discretization of a class of fixed-time stable systems, namely predefined-time stable systems. In the unperturbed case, the proposed approach allows obtaining not only a consistent but exact discretization of the considered class of predefined-time stable systems, whereas in the perturbed case, the consistent discretization preserves the predefined-time stability property. All the results are validated through simulations and compared with the conventional explicit Euler scheme, highlighting the advantages of this proposal.

关键词： Predefined-time stability Discrete-time systems Digital implementation Stability of nonlinear systems Fixed-time stability

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Consistent discretization of a class of predefined-time stable systems

arXiv

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arXiv 2020年

作者： Jiménez-Rodríguez, Esteban Aldana-López, Rodrigo Sánchez-Torres, Juan D. Gómez-Gutiérrez, David Loukianov, Alexander G. Department of Electrical Engineering Cinvestav-Guadalajara Jalisco45019 Mexico Department of Computer Science and Systems Engineering University of Zaragoza Zaragoza50009 Spain Research Laboratory on Optimal Design Devices and Advanced Materials -OPTIMA- Department of Mathematics and Physics ITESO Jalisco45604 Mexico Multi-agent autonomous systems lab Intel Labs Intel Tecnología de México Jalisco45019 Mexico Tecnologico de Monterrey Escuela de Ingeniería y Ciencias Jalisco45138 Mexico

关键词： Digital control systems

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EEG microstates: Functional significance and short-term test-retest reliability

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Neuroimage: Reports 2022年第2期2卷 100089-100089页

作者： Antonova, Elena Holding, Martin Suen, Ho Chak Sumich, Alex Maex, Reinoud Nehaniv, Chrystopher Division of Psychology Department of Life Sciences College of Health Medicine and Life Sciences & Centre for Cognitive Neuroscience Brunel University London Kingston Lane Uxbridge UB8 3PH United Kingdom Department of Psychology Institute of Psychiatry Psychology & Neuroscience King's College London De Crespigny Park London SE5 8AF United Kingdom Department of Psychology School of Social Sciences Nottingham Trent University 50 Shakespeare Street Nottingham NG1 4FQ United Kingdom Royal Society Wolfson Biocomputation Research Laboratory Centre for Computer Science and Informatics Research University of Hertfordshire College Lane Hatfield AL10 9AB United Kingdom Departments of Systems Design Engineering and Electrical & Computer Engineering University of Waterloo 200 University Avenue W Waterloo N2L 3G1 ON Canada

EEG microstates, reflecting discrete topographical organization of the EEG signal power, may have clinical relevance;however, their functional significance and test-retest reliability remain unclear. To investigate the functional significance of the canonical EEG microstate classes and their pairwise transitions, and to establish their within-session test-retest reliability, we recorded 36-channel EEGs in 20 healthy volunteers during three eyes-closed conditions: mind-wandering, verbalization (silently repeating the word ‘square’ every 2 s), and visualization (visualizing a square every 2 s). Each condition lasted 3 min and the sequence of three conditions was repeated four times (two runs of two sequence repetitions). The participants' alertness and their sense of effort during the experiment were rated using visual-analogue scales. The EEG data were 2–20 Hz bandpass-filtered and analysed into the four canonical microstate classes: A, B, C, and D. EEG microstate classes C and D were persistently more dominant than classes A and B in all conditions. Of the first-order microstate parameters, average microstate duration was most reliable. The duration of class D microstate was longer during mind-wandering (106.8 ms) than verbalization (102.2 ms) or visualization (99.8 ms), with a concomitantly higher coverage (36.4% vs. 34.7% and 35.2%), but otherwise there was no clear association of the four microstate classes to particular mental states. The test-retest reliability was higher at the beginning of each run, together with higher average alpha power and subjective ratings of alertness. Only the transitions between classes C and D (from C to D in particular) were significantly higher than what would be expected from the respective microstates' occurrences. The transition probabilities, however, did not distinguish between conditions, and their test-retest reliability was overall lower than that of the first-order parameters such as duration and coverage. Further studies

关键词： Biomarkers EEG microstates Mind-wandering Neuroimaging Resting-state EEG Resting-state networks

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Systematic Resource Allocation in Cloud RAN with Caching as a Service under Two Timescales

Systematic Resource Allocation in Cloud RAN with Caching as ...

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作者： Tang, Jianhua Quek, Tony Q. S. Chang, Tsung-Hui Shim, Byonghyo Hunan Provincial Key Laboratory of Intelligent Computing and Language Information Processing College of Information Science and Engineering Hunan Normal University Changsha410081 China Institute of New Media and Communications Department of Electrical and Computer Engineering Seoul National University Seoul08826 Korea Republic of Information Systems Technology and Design Pillar Singapore University of Technology and Design Singapore487372 Singapore Department of Electronic Engineering Kyung Hee University Yongin17104 Korea Republic of School of Science and Engineering Chinese University of Hong Kong Shenzhen518172 China Shenzhen Research Institute of Big Data Shenzhen518172 China Department of Electrical and Computer Engineering Institute of New Media and Communications Seoul National University Seoul08826 Korea Republic of

Recently, cloud radio access network (C-RAN) with caching as a service (CaaS) was proposed to merge the functionalities of communication, computing, and caching (CCC) together. In this paper, we dissect the interactions of CCC in C-RAN with CaaS from two dimensions: physical resource dimension and time dimension. In the physical resource dimension, we identify how to segment the baseband unit (BBU) pool resources (i.e., computation and storage) into different types of virtual machines (VMs). In the time dimension, we address how the long-term resource segmentation in the BBU pool impacts on the short-term transmit beamforming at the remote radio heads. We formulate the problem as a stochastic mixed-integer nonlinear programming (SMINLP) to minimize the system cost, including the server cost, VM cost and wireless transmission cost. After a series of approximation, including sample average approximation, successive convex approximation, and semidefinite relaxation, the SMINLP is approximated as a global consensus problem. The alternating direction method of multipliers (ADMM) is utilized to obtain the solution in a parallel fashion. Simulation results verify the convergence of our proposed algorithm, and also confirm that the proposed scheme is more cost-saving than that without considering the integration of CCC. © 1972-2012 IEEE.

关键词： Integer programming

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Smith-Purcell radiation from time grating

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Newton 2025年第2期1卷

作者： Juan-Feng Zhu Ayan Nussupbekov Yudi Fan Wenjie Zhou Zicheng Song Xuchen Wang Zi-Wen Zhang Chao-Hai Du Xianlong Wei Ping Bai Ching Eng Png Cheng-Wei Qiu Lin Wu Science Mathematics and Technology Singapore University of Technology and Design 8 Somapah Road Singapore 487372 Singapore Institute of High Performance Computing Agency for Science Technology and Research (A∗STAR) 1 Fusionopolis Way #16-16 Connexis Singapore 138632 Singapore Department of Electrical and Computer Engineering National University of Singapore 4 Engineering Drive 3 Singapore 117583 Singapore Center for Composite Materials and Structures School of Astronautics Harbin Institute of Technology Harbin China Institute of Nanotechnology Karlsruhe Institute of Technology Karlsruhe Germany Optical Communication Systems and Networks School of Electronics Peking University Beijing China Key Laboratory for the Physics and Chemistry of Nanodevices School of Electronics Peking University Beijing China

Smith-Purcell radiation (SPR) arises when an electron moves above a spatial grating, where fixed momentum compensation constrains the emission wavelength. In contrast, temporal SPR ( t -SPR) utilizes a time grating to leverage temporal periodicity for energy compensation, enabling more flexible radiation control. We introduce a generalized dispersion equation for t -SPR that predicts the interplay between radiation frequency, direction, electron velocity, modulation period, and harmonic orders. t -SPR offers several advantages over conventional SPR: robustness ( t -SPR maintains stable emission intensity without rapid decay as the electron moves away from the time grating), versatility ( t -SPR enables precise control via temporal modulation of period, amplitude, and waveform), and amplified emission (temporal modulation introduces additional energy channels, boosting emission). These features make t -SPR highly promising for advanced applications in on-chip light sources and electron accelerators.

关键词： Smith-Purcell radiation time grating photonic time crystal free-electron radiation

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