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Isotropic sintering shrinkage of 3D glass-ceramic nanolattices:backbone preforming and mechanical enhancement

International Journal of Extreme Manufacturing 2024年第2期6卷 418-426页

作者： Nianyao Chai Yunfan Yue Xiangyu Chen Zhongle Zeng Sheng Li Xuewen Wang Center of Femtosecond Laser Manufacturing for Advanced Materials and Devices State Key Laboratory of Advanced Technology for Materials Synthesis and ProcessingWuhan University of TechnologyWuhan 430070People’s Republic of China National Energy Key Laboratory for New Hydrogen-Ammonia Energy Technologies Foshan Xianhu LaboratoryFoshan 528000People’s Republic of China International School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070People’s Republic of China

There is a perpetual pursuit for free-form glasses and ceramics featuring outstanding mechanical properties as well as chemical and thermal *** is a promising idea to shape inorganic materials in three-dimensional(3D)forms to reduce their weight while maintaining high mechanical properties.A popular strategy for the preparation of 3D inorganic materials is to mold the organic–inorganic hybrid photoresists into 3D micro-and nano-structures and remove the organic components by subsequent ***,due to the discrete arrangement of inorganic components in the organic-inorganic hybrid photoresists,it remains a huge challenge to attain isotropic shrinkage during ***,we demonstrate the isotropic sintering shrinkage by forming the consecutive–Si–O–Si–O–Zr–O–inorganic backbone in photoresists and fabricating 3D glass–ceramic nanolattices with enhanced mechanical *** femtosecond(fs)laser is used in two-photon polymerization(TPP)to fabricate 3D green body *** subsequent sintering at 1000℃,high-quality 3D glass–ceramic microstructures can be obtained with perfectly intact and smooth ***-suit compression experiments and finite-element simulations reveal that octahedral-truss(oct-truss)lattices possess remarkable adeptness in bearing stress concentration and maintain the structural integrity to resist rod bending,indicating that this structure is a candidate for preparing lightweight and high stiffness glass–ceramic nanolattices.3D printing of such glasses and ceramics has significant implications in a number of industrial applications,including metamaterials,microelectromechanical systems,photonic crystals,and damage-tolerant lightweight materials.

关键词： 3D printing isotropic shrinkage femtosecond laser two-photon polymerization structural glass-ceramics

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Enhancing proton exchange membrane water electrolysis by building electron/proton pathways

Advanced Powder Materials

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advanced Powder materials 2024年第4期3卷 103-112页

作者： Liyan Zhu Hao Zhang Aojie Zhang Tian Tian Yuhan Shen Mingjuan Wu Neng Li Haolin Tang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing State Key Laboratory of Silicate Materials for ArchitecturesWuhan University of TechnologyWuhan 430070China National Energy Key Laboratory for New Hydrogen-ammonia Energy Technologies Foshan Xianhu LaboratoryFoshan 528200China Hubei Key Laboratory of Fuel Cell Wuhan 430070China

Proton exchange membrane water electrolysis(PEMWE)plays a critical role in practical hydrogen *** for the electrode activities,the widespread deployment of PEMWE is severely obstructed by the poor electron-proton permeability across the catalyst layer(CL)and the inefficient transport *** this work,the PEDOT:F(Poly(3,4-ethylenedioxythiophene):perfluorosulfonic acid)ionomers with mixed proton-electron conductor(MPEC)were fabricated,which allows for a homogeneous anodic CL structure and the construction of a highly efficient triple-phase *** PEDOT:F exhibits strong perfluorosulfonic acid(PFSA)side chain extensibility,enabling the formation of large hydrophilic ion clusters that form proton-electron transport channels within the CL networks,thus contributing to the surface reactant water *** PEMWE device employing membrane electrode assembly(MEA)prepared by PEDOT:F-2 demonstrates a competitive voltage of 1.713 V under a water-splitting current of 2 A cm^(-2)(1.746 V at 2A cm^(-2) for MEA prepared by Nafion D520),along with exceptional long-term ***,the MEA prepared by PEDOT:F-2 also exhibits lower ohmic resistance,which is reduced by 23.4%and 17.6%at 0.1 A cm^(-2) and 1.5 A cm^(-2),respectively,as compared to the MEA prepared by *** augmentation can be ascribed to the superior proton and electron conductivity inherent in PEDOT:F,coupled with its remarkable structural *** characteristic enables expeditious mass transfer during electrolytic reactions,thereby enhancing the performance of PEMWE devices.

关键词： Proton exchange membrane water electrolysis Oxygen evolution reaction Mixed proton-electron conductivity Triple-phase boundaries Membrane electrode assembly

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4D printing for future manufacturing

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Science China materials 2023年第11期66卷 4517-4518页

作者： Chaolin Tan Ji Zou Zhengyi Fu Singapore Institute of Manufacturing Technology(SIMTech) Agency for ScienceTechnology and Research(A*STAR)Singapore 636732Singapore State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Additive manufacturing(AM),also called three-dimensional(3D)printing,offers disruptive design freedom and manufacturing flexibility due to the layer-wise incremental formation manner of *** in AM techniques provide unique advantages and feasibilities for overcoming challenges arising from fabricating parts with complexities in geometry,materials,and properties.

关键词： printing properties freedom

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Pt–C interactions in carbon-supported Pt-based electrocatalysts

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Frontiers of Chemical Science and Engineering 2023年第11期17卷 1677-1697页

作者： Yu-Xuan Xiao Jie Ying Hong-Wei Liu Xiao-Yu Yang School of Chemical Engineering and Technology Sun Yat-sen UniversityZhuhai 519082China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing&Shenzhen Research Institute&Joint Laboratory for Marine Advanced Materials in Pilot National Laboratory for Marine Science and Technology(Qingdao) Wuhan University of TechnologyWuhan 430070China

Carbon-supported Pt-based materials are highly promising *** carbon support plays an important role in the Pt-based catalysts by remarkably influencing the growth,particle size,morphology,dispersion,electronic structure,physiochemical property and function of *** review summarizes recent progress made in the development of carbon-supported Pt-based catalysts,with special emphasis being given to how activity and stability enhancements are related to Pt–C interactions in various carbon supports,including porous carbon,heteroatom doped carbon,carbon-based binary support,and their corresponding electrocatalytic ***,the current challenges and future prospects in the development of carbon-supported Pt-based catalysts are discussed.

关键词： Pt-C interactions Pt-based materials carbon support electrocatalysis

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Mitigating the capacity fading of Si nanoparticles through V_(2)O_(3) and carbon dual coatings

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Journal of materials Science & technology 2024年第24期191卷 17-22页

作者： Ruhan He Hao Li Aoyuan Chen Liqiang Mai Liang Zhou State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China International School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China Hubei Longzhong Laboratory Wuhan University of Technology(Xiangyang Demonstration Zone)Xiangyang 441000China Hainan Institute Wuhan University of TechnologySanya 572000China

Nano-structured silicon(Si)has demonstrated high capacity for lithium storage;however,it suffers from unsatisfactory cycling stability caused by large volume change and poor interface ***,it is very important to construct functional coatings on nano-structured Si to buffer the volume change and improve the interface ***,we successfully construct V_(2)O_(3) and carbon(C)dual-layer coatings on Si nanoparticles with ultrathin and uniform thickness using a facile spray drying and chemical vapour deposition *** as-prepared Si@V_(2)O_(3)@C manifests a high specific capacity of 2230 mAh g^(-1) after 100 cycles under the current density of 200 mA g^(-1),showing its promising application prospect in lithium *** situ electrochemical impedance spectroscopy(EIS)results at different lithiation states and different cycles show a more stable interface resistance of Si@V_(2)O_(3)@C than pristine *** V_(2)O_(3) and C dual coating layers not only ensure the Si nanoparticles with high structural stability by buffering volume expansion and preventing electrolyte penetration,but also guarantee a superior electron transport rate because of the metallic V_(2)O_(3) as well as the highly conductive carbon layers.

关键词： Lithium-ion batteries Silicon anode Vanadium(Ⅲ)oxide Spray drying SEI layer

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Revealing structural degradation in layered structure oxides cathode of lithium ion batteries via in-situ transmission electron microscopy

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Journal of materials Science & technology 2023年第23期154卷 189-201页

作者： Fanjie Xia Weihao Zeng Haoyang Peng Hong Wang Congli Sun Ji Zou Jinsong Wu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and Engineering Wuhan University of Technology Wuhan 430070 China Nanostructural Research Center (NRC) Wuhan University of Technology Wuhan 430070 China Hubei Longzhong Laboratory Xiangyang 441000 China

Transition metal oxides with layered structure have been widely used as cathode materials for lithium-ion batteries(LIBs)which have relatively high energy density,large capacity and long ***,in the long-term electrochemical cycle,the inevitable degradation of performance of LIBs due to structural degradation in cathodes severely restricts their large-scale practical *** the underlying mechanism of structural degradation is the most critical scientific ***,in situ transmission electron microscopy(TEM)has become a useful tool to study the structural and compositional evolutions at atomic scale in electrochemical reactions,which provided a unique and in-depth understanding of the structural *** this review,we discuss the recent advances in the in situ TEM,focusing on its role in revealing the structural degradation mechanisms in the four key places:(1)the interface between the cathodes and electrolyte;(2)the cathode surface;(3)the particle interior and(4)those induced by thermal *** insight gained by the in-situ TEM which is still developing at its fast pace is unique and expected to provide guidance for designing better layered cathode materials.

关键词： Li-ion battery Layered cathodes Structural degradations Electron microscopy In-situ

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Ultraviolet Photodetector based on Sr_(2)Nb_(3)O_(10) Perovskite Nanosheets

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Journal of Wuhan University of technology(materials Science) 2024年第2期39卷 282-287页

作者：张斌斌 JIA Mengmeng LIANG Qi WU Jinsong ZHAI Junyi 李宝文 School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China CAS Center for Excellence in Nanoscience Beijing Institute of Nanoenergy and NanosystemsChinese Academy of SciencesBeijin 100083China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Liquid-phase exfoliation was employed to synthesize Sr_(2)Nb_(3)O_(10) perovskite nanosheets with thicknesses down to 1.76 *** electron microscopy(TEM),atomic force microscope(AFM),X-ray photoelectron spectrometer(XPS),and other characterization techniques were used to evaluate the atomic structure and chemical composition of the exfoliated nanosheets.A UV photodetector based on individual Sr_(2)Nb_(3)O_(10) nanosheets was prepared to demonstrate the application of an ultraviolet(UV) *** UV photodetector exhibited outstanding photocurrent and responsivity with a responsivity of 3×10^(5) A·W^(-1) at 5 V bias under 280 nm illumination,a photocurrent of 60 nA,and an on/off ratio of 3×10^(2).

关键词： perovskite nanosheets liquid-phase exfoliation ultraviolet photodetector

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Metal-nitrogen-doped hybrid ionic/electronic conduction triple-phase interfaces for high-performance all-solid-state lithium-sulfur batteries

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Nano Research 2023年第8期16卷 10956-10965页

作者： Hao Li Jiangping Song Fanglin Wu Rui Wang Dan Liu Haolin Tang A State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Department of Chemistry School of ChemistryChemical Engineering and Life SciencesWuhan University of TechnologyWuhan 430070China

The point-to-point contact mechanism in all-solid-state Li-S batteries(ASSLSBs)is not as efficient as a liquid electrolyte which has superior mobility in the electrode,resulting in a slower reaction kinetics and inadequate ionic/electronic conduction network between the S(or Li_(2)S),conductive carbon,and solid-state electrolytes(SSEs)for achieving a swift(dis)charge ***,a series of hybrid ionic/electronic conduction triple-phase interfaces with transition metal and nitrogen co-doping were *** graphitic ordered mesoporous carbon frameworks(TM-N-OMCs;TM=Fe,Co,Ni,and Cu)serve as hosts for Li_(2)S and Li_(6)PS_(5)Cl(LPSC)and provide abundant reaction sites on the triple *** from both experimental and computational research display that the combination of Cu-N co-dopants can promote the Li-ion diffusion for rapid transformation of Li_(2)S with adequate ionic(6.73×10^(−4)S·cm^(−1))/electronic conductivities(1.77×10^(−2)S·cm^(−1))at 25℃.The as-acquired Li_(2)S/Cu-N-OMC/LPSC electrode exhibits a high reversible capacity(1147.7 mAh·g^(−1))at 0.1 C,excellent capacity retention(99.5%)after 500 cycles at 0.5 C,and high areal capacity(7.08 mAh·cm^(−2)).

关键词： all-solid-state lithium-sulfur batteries triple-phase interfaces ordered mesoporous carbons mixed ion/electron conductivities Li_(6)PS_(5)Cl solid electrolyte

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In situ generated layered NiFe-LDH/MOF heterostructure nanosheet arrays with abundant defects for efficient alkaline and seawater oxidation

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Nano Research 2023年第7期16卷 8945-8952页

作者： Manjie Xiao Can Wu Jiawei Zhu Chengtian Zhang Yan Li Jiahui Lyu Weihao Zeng Haiwen Li Lei Chen Shichun Mu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Foshan Xianhu Laboratory Foshan 528200China Science and Technology Institute of Advanced Technology Wuhan 430051China Hefei General Machinery Research Institute Hefei 230031China

As the main limiting step of overall water splitting,oxygen evolution reaction(OER)is urgent to be enhanced by developing efficient catalysts to promote the process of electrolytic *** on theoretical analysis,the Ni-metal-organic framework(Ni-MOF)and NiFe-layered double hydroxide(NiFe-LDH)(NiFe-LDH/MOF)heterostructure can optimize the energy barrier of the OER process and decrease the adsorption energy of oxygen-containing intermediates,effectively accelerating the OER ***,layered NiFe-LDH/MOF heterostructures are in situ constructed through a facile two-step reaction process,with substantial oxygen defects and lattice defects that further improve the catalytic *** a result,only 208 and 275 mV OER overpotentials are needed for NiFe-LDH/MOF to drive the current densities of 20 and 100 mA·cm^(-2)in 1 M KOH solutions,and even maintain catalytic stability of 100 h at 20 mA·cm^(-2).When applied to seawater oxidation,only 235 and 307 mV OER overpotentials are required to achieve the current densities of 20 and 100 mA·cm^(-2),respectively,with almost no attenuation for 100 h stability test at 20 mA·cm^(-2),all better than commercial RuO_(2).This work provides the theoretical and experimental basis and a new idea for efficiently driving fresh water and seawater cracking by heterostructure and defect coupling design toward catalysts.

关键词： oxygen evolution reaction defects seawater electrolysis catalyst

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3D ordered macroporous sulfur-doped g-C_(3)N_(4)/TiO_(2)S-scheme photocatalysts for efficient H_(2)O_(2)production in pure water

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Journal of materials Science & technology 2023年第31期162卷 1-10页

作者： Zicong Jiang Qing Long Bei Cheng Rongan He Linxi Wang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Hunan Key Laboratory of Applied Environmental Photocatalysis Changsha UniversityChangsha 410022China Laboratory of Solar Fuel Faculty of Materials Science and ChemistryChina University of GeosciencesWuhan 430074China

Photocatalytic hydrogen peroxide(H_(2)O_(2))production offers a clean and cost-efficient alternative to the traditional anthraquinone oxidation ***,a step-scheme(S-scheme)heterojunction photocat-alyst is fabricated by coupling TiO_(2)with three dimensionally ordered macroporous sulfur-doped graphitic carbon nitride(3DOM SCN/T)by electrostatic *** optimized photocatalyst achieved a high photocatalytic H_(2)O_(2)production activity with a yield of 2128μmol h^(−1)g^(−1)without the addition of hole *** remarkable performance was attributed to the synergy between the 3DOM framework and the S-scheme *** former enhances light harvesting and provides abundant active sites for surface reactions,while the latter promotes the spatial separation of photogenerated carriers and enhances the redox ***,the mechanism of photocatalytic H_(2)O_(2)production over the 3DOM SCN/T S-scheme composite is *** work provides novel insights into the development of effi-cient photocatalysts for H_(2)O_(2)production from water and O_(2).

关键词： Photocatalysis Step-scheme heterojunction Three dimensionally ordered macroporous Hydrogen peroxide O_(2)reduction reaction

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