检索结果-内蒙古大学图书馆

Effect of Y:Zn ratio on microstructure and emission of Er^(3+)/Yb^(3+) codoped Y_(2)O_(3)-ZnO ceramic phosphors

Journal of Rare Earths 2023年第12期41卷 1883-1894,I0003页

作者： Boxu Xu Chao Song Jie Song Rui Huang Shaomin Lin Zhenxu Lin Yi Zhang Dejian Hou Jun Song School of Materials Science and Engineering Hanshan Normal UniversityChaozhou521041China Key Laboratory of Optoelectronic Devices and Systemsof MinistryofEducation and Guangdong Province College of Optoelectronic EngineeringShenzhen UniversityShenzhen518060China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan430070China

In this study,Er^(3+)/Yb^(3+)codoped Y_(2)O_(3)-ZnO ceramic phosphors were prepared by sol-gel *** samples had two emission bands,namely,green(535 nm) and red(660 nm),which are attributed to Er^(3+):^(2)H_(11/2)(^(4)S_(3/2))→^(4)I_(15/2)and Er^(3+):^(4)F_(9/2)→^(4)I_(15/2)radiative transitions,*** samples exhibited green-and red-emission intensity enhancement by 1.728 and 2.286 times that of the pure Y2O3host,respectively and by 514.468 and 214.341 times that of the pure ZnO *** emission intensities are first enhanced by lattice *** the change of Y:Zn ratio,the high surface energy is converted into low crystal surface resulting in the change of asymmetry crystal field for *** the intensity of the asymmetric crystal field reaches maximum,both emissions are further *** the high surface energy transforms into crystal surface energy,the microstructure changes into a compact mesoporous ***,the chemical stability of the samples improves significantly,and the final emission band of the three samples with mesoporous structures is continuously red.

关键词： Mesoporous Y_(2)0_(3) Zno Luminescence Rare earths Ceramic phosphors

来源：评论

学校读者我要写书评

暂无评论

synthesis Approach and Adsorption Properties of SiOC Nanocomposite by Chitin Templating

引用

Journal of Wuhan University of technology(materials Science) 2022年第6期37卷 1041-1047页

作者： HUANG Yaoxuan PING Hang WANG Kun FU Zhengyi State Key Laboratory of Silicate Materials for Architectures Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Using chitin as the templating material,we obtained layered nanocomposites like shrimp or crab shells via a sol-gel self-assembly *** images show a layered structure and XRD patterns present a typical peak of chitin,which indicates the templating role of chitin in the as-received hybrid ***,the layer spacing of chitin/silica hybrid materials is reduced with increasing content of *** the heat treatment for carbonization,layered SiOC nanocomposites with mesoporous structures were obtained and showed good dye adsorption *** present study demonstrates a reliable and self-assembly synthesis technique for the development of advanced high-performance nanocomposites with biomimetic nanostructures.

关键词： chitin sol-gel method self-assembly biomimetic structure SiOC nanocomposite

来源：评论

学校读者我要写书评

暂无评论

Reshaping Electrolyte Solvation Structure for High-Energy Aqueous Batteries

引用

Energy & Environmental materials 2022年第3期5卷 686-687页

作者： Shuailei Liu Jinping Liu School of Chemistry Chemical Engineering and Life ScienceState Key Laboratory of Advanced Technology for Materials Synthesis and ProcessingWuhan University of TechnologyWuhan 430070China

A highlight on reshaping aqueous electrolyte solvation structure for highenergy batteries is ***,the recent key design routes for regulating solvation structure to widen electrochemical stability window(ESW)of aqueous electrolyte are briefly ***,the groundbreaking work of Wang et *** reshaping electrolyte structure using urea as the diluent is ***,the significance of Wang's work is highlighted.

关键词： aqueous electrolyte structure CO(NH_2)_2 electrochemical stability window energy density

来源：评论

学校读者我要写书评

暂无评论

Probing the Nucleation and Growth Kinetics of Bismuth Nanoparticles via In-situ Transmission Electron Microscopy

引用

Journal of Wuhan University of technology(materials Science) 2024年第4期39卷 877-887页

作者：王浪李超凡 RAN Maojin YUAN Manman 胡执一 LI Yu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Nanostructure Research Centre(NRC) Wuhan University of TechnologyWuhan 430070China Institute of Chemistry Henan Academy of SciencesZhengzhou 450002China Henan Academy of Sciences Zhengzhou 450046China

The nucleation and growth mechanism of nanoparticles is an important theory,which can guide the preparation of ***,it is still lacking in direct observation on the details of the evolution of intermediate state structure during nucleation and *** this work,the evolution process of bismuth nanoparticles induced by electron beam was revealed by in-situ transmission electron microscopy(TEM)at atomic *** experimental results demonstrate that the size,stable surface and crystallographic defect have important influences on the growth of Bi *** non-classical growth paths including single crystal growth and polycrystalline combined growth,as well as,corresponding layer-by-layer growth mechanism along{012}stable crystal plane of Bi nanoparticles with dodecahedron structure were revealed by in-situ TEM *** results provide important guidance and a new approach for in-depth understanding of the nucleation and growth kinetics of nanoparticles.

关键词： bismuth nanoparticles crystal growth transmission electron microscopy in-situ electron microscopy

来源：评论

学校读者我要写书评

暂无评论

Achieving asymmetric redox chemistry for oxygen evolution reaction through strong metal-support interactions

引用

Journal of Energy Chemistry 2024年第9期96卷 526-535页

作者： Shihao Wang Meiling Fan Hongfei Pan Jiahui Lyu Jinsong Wu Haolin Tang Haining Zhang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina National Energy Key Laboratory for New Hydrogen-Ammonia Energy Technologies Foshan Xianhu LaboratoryFoshan 528200GuangdongChina International School of Materials Science and Engineering(School of Materials and Microelectronics) Wuhan University of TechnologyWuhan 430070HubeiChina Nanostructure Research Centre Wuhan University of TechnologyWuhan 430070HubeiChina Hubei Key Laboratory of Fuel Cell Wuhan University of TechnologyWuhan 430070HubeiChina

Water electrolysis poses a significant challenge for balancing catalytic activity and stability of oxygen evolution reaction(OER)*** this study,we address this challenge by constructing asymmetric redox chemistry through elaborate surface OO–Ru–OH and bulk Ru–O–Ni/Fe coordination moieties within single-atom Ru-decorated defective NiFe LDH nanosheets(Ru@d-NiFe LDH)in conjunction with strong metal-support interactions(SMSI).Rigorous spectroscopic characterization and theoretical calculations indicate that single-atom Ru can delocalize the O 2p electrons on the surface and optimize d-electron configurations of metal atoms in bulk through ***^(18)O isotope labeling experiment based on operando differential electrochemical mass spectrometry(DEMS),chemical probe experiments,and theoretical calculations confirm the encouraged surface lattice oxygen,stabilized bulk lattice oxygen,and enhanced adsorption of oxygen-containing intermediates for bulk metals in Ru@d-NiFe LDH,leading to asymmetric redox chemistry for *** Ru@d-NiFe LDH electrocatalyst exhibits exceptional performance with an overpotential of 230 mV to achieve 10 mA cm^(−2)and maintains high robustness under industrial current *** approach for achieving asymmetric redox chemistry through SMSI presents a new avenue for developing high-performance electrocatalysts and instills confidence in its industrial applicability.

关键词： Reaction redox chemistry Strong metal-support interactions Layered double hydroxides Electrocatalysts Water electrolysis

来源：评论

学校读者我要写书评

暂无评论

In Situ-Constructed Li_(x)MoS_(2)with Highly Exposed Interface Boosting High-Loading and Long-Life Cathode for All-Solid-State Li-S Batteries

引用

Energy & Environmental materials 2024年第4期7卷 163-174页

作者： Hao Li Rui Wang Jiangping Song Dan Liu Hongyang Gao Yimin Chao Haolin Tang A State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Department of Chemistry Chemical Engineeringand Life ScienceWuhan University of TechnologyWuhan 430070China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen ValleyFoshan 528200China School of Chemistry University of East AngliaNorwich NR47TJUK

As the persistent concerns regarding sluggish reaction kinetics and insufficient conductivities of sulfur cathodes in all-solid-state Li-S batteries(ASSLSBs),numerous carbon additives and solid-state electrolytes(SSEs)have been incorporated into the cathode to facilitate ion/electron pathways around ***,this has resulted in a reduced capacity and decomposition of ***,it is worth exploring neotype sulfur hosts with electronic/ionic conductivity in the ***,we present a hybrid cathode composed of few-layered S/MoS_(2)/C nanosheets(<5 layers)that exhibits high-loading and long-life performance without the need of additional carbon additives in advanced *** multifunctional MoS_(2)/C host exposes the abundant surface for intimate contacting sites,in situ-formed LixMoS_(2)during discharging as mixed ion/electron conductive network improves the S/Li2S conversion,and contributes extra capacity for the part of active *** a high active material content(S+MoS_(2)/C)of 60 wt%in the S/MoS_(2)/C/Li_(6)PS_(5)Cl cathode composite(the carbon content is only~3.97 wt%),the S/MoS_(2)/C electrode delivers excellent electrochemical performance,with a high reversible discharge capacity of 980.3 mAh g^(-1)(588.2 mAh g^(-1)based on the whole cathode weight)after 100 cycles at 100 mA g^(-1).The stable cycling performance is observed over 3500 cycles with a Coulombic efficiency of 98.5%at 600 mA g^(-1),while a high areal capacity of 10.4 mAh cm^(-2)is achieved with active material loading of 12.8 mg cm^(-2).

关键词： all-solid-state lithium-sulfur batteries conversion/intercalation high-loading and long-life low carbon content mixed ionic/electronic conductivities

来源：评论

学校读者我要写书评

暂无评论

Dynamic reconstruction of Ni-Zn alloy solid-electrolyte interface for highly stable Zn anode

引用

Nano Research 2023年第9期16卷 11604-11611页

作者： Qian Zhang Yuhang Dai Kangning Zhao Chengyi Zhang Ruihu Lu Jinghao Li Shuhan Jin Lei Zhang Qinyou An Liqiang Mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Department of Physical Science and Technology School of ScienceWuhan University of TechnologyWuhan 430070China Hainan Institute Wuhan University of TechnologySanya 572000China

Aqueous zinc ion batteries(AZIBs)are ideal candidates for large-scale battery storage,with a high theoretical specific capacity,ecological friendliness,and extremely low cost but are strongly hindered by zinc dendrite ***,Ni-Zn alloy is artificially constructed as a solid-electrolyte interface(SEI)for Zn anodes by electrodeposition and *** Ni-Zn alloy layer acts as a dynamic shield at the electrode/electrolyte ***,the zinc atoms migrate out of the electrode body during zinc stripping while merging into the electrode body during the *** this way,the Ni-Zn alloy is able to guide the zinc deposition in the horizontal direction,thereby suppressing the formation of *** from those,the Ni-Zn alloy symmetric cell shows a greatly improved cycle life and is able to operate stably for 1,900 h at a current density of 0.5 mA·cm^(−2).The present study is a strategy for negative electrode protection of AZIBs.

关键词： zinc ion batteries Zn anodes Ni-Zn alloy migration mechanism

来源：评论

学校读者我要写书评

暂无评论

The role of γ/γ interfacial spacing on the tensile behavior in lamellar TiAl alloy via molecular dynamics simulations

引用

Acta Mechanica Sinica 2025年第2期41卷 1-6页

作者： Xiong Zhou Shiping Wang Zhongtao Lu Xiege Huang Xiaobin Feng Jiayi Fu Wenjuan Li Pengcheng Zhai Guodong Li Hubei Key Laboratory of Theory and Application of Advanced Materials Mechanics School of ScienceWuhan University of TechnologyWuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

The lamellar microstructure is one of the most typical microstructures of TiAl *** are threeγ/γinterfaces with different microstructures in lamellarγ-TiAl *** this work,we investigated the deformation processes of lamellarγ-TiAl alloys with different interfacial spacing(λ)via uniaxial tensile loading using molecular dynamics simulations,including true twin(TT),pseudo-twin(PT),rotational boundary(RB),and the mixed structure(TT∥PT∥RB).The results show that in all lamellarγ-TiAl samples,the Shockley partial dislocation prefers to nucleate in the region between two neighboring ***,dislocations move towards,crossing theγ/γ***,the dislocation slippage leads to the destruction of the interface,resulting in cracks and structural *** the decrease ofλ,the ultimate strength slightly increases in the TT or PT structure ofγ-TiAl,which follows the Hall-Petch *** in general,the interfacial spacing has a slight effect on the ultimate strengths of these four structures ofγ-TiAl.

关键词： Lamellarγ-TiAl alloys γ/γinterface Ultimate strength Interfacial spacing

来源：评论

学校读者我要写书评

暂无评论

CdS decorated resorcinol-formaldehyde spheres as an inorganic/organic S-scheme photocatalyst for enhanced H_(2)O_(2)production

引用

Journal of materials Science & technology 2023年第31期162卷 90-98页

作者： Bicheng Zhu Jingjing Liu Jian Sun Fei Xie Haiyan Tan Bei Cheng Jianjun Zhang Laboratory of Solar Fuel Faculty of Materials Science and ChemistryChina University of GeosciencesWuhan 430078China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China School of Chemistry and Environmental Engineering Hubei University for NationalitiesEnshi 445000China

Photocatalytic H_(2)O_(2)production provides a clean and sustainable strategy for artificial ***,an inorganic/organic composite photocatalyst was fabricated by in-situ growth of CdS nanoparticles on the surface of resorcinol-formaldehyde(RF)resin *** spheres played multiple roles:(i)acting as a substrate for the growth of CdS and constructing a core-shell structure with seamless con-tact;(ⅱ)improving visible light absorption of CdS;(ⅲ)forming an S-scheme heterojunction with CdS and promoting the charge separation and ***,under visible light illumination,CdS/RF composite presented remarkably enhanced H_(2)O_(2)production *** H_(2)O_(2)yield in 60 min was 801μmol L^(-1),which was 5.2 and 1.5 times higher than that of RF spheres and CdS hollow spheres,*** charge migration between CdS and RF followed the S-scheme photocatalytic mechanism,which was verified by work function measurement,ex-situ and in-situ irradiated X-ray photoelectron *** work brings a novel insight into designing RF-based inorganic/organic S-scheme heterojunction pho-tocatalysts for efficient H_(2)O_(2)production.

关键词： Photocatalysis Step-scheme heterojunction Resorcinol-formaldehyde Hydrogen peroxide in-situ irradiated XPS

来源：评论

学校读者我要写书评

暂无评论

Formation mechanisms of Ti_(3)(Si,Al)C_(2)/Al_(2)O_(3) composites from Ti_(3)AlC_(2) and SiO via low-temperature sintering

引用

Journal of advanced Ceramics 2023年第1期12卷 93-110页

作者： Zhenyu ZHANG Jun JI Yingying CHEN Deli MA Sique CHEN Hailing YANG Guopu SHI Zhi WANG Mengyong SUN Fei CHEN Shifeng HUANG Qinggang LI Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials University of JinanJinan 250022China School of Materials Science and Engineering University of JinanJinan 250022China Institute of China North Industries Group Yantai 264003China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Ti_(3)SiC_(2)/Al_(2)O_(3) composites have attracted attention due to their excellent mechanical and electromagnetic properties,but the high temperatures(≥1400℃)required for the densification of aluminum oxide(Al_(2)O_(3))leads to the decomposition of Ti_(3)SiC_(2).To address this issue,Ti_(3)(Si_(x)Al_(1−x))C2/Al_(2)O_(3)(x represents the Si content)composites were synthesized for the first time via hot-pressing(HP)sintering and current-assisted sintering(CAS)of mixed Ti_(3)AlC_(2) and silicon monoxide(SiO)powders at 1300 and 1200℃,*** approaches produced composites with x values greater than 0.9,indicating that the compositions of the prepared composites were similar to those of Ti_(3)SiC_(2)/Al_(2)O_(3) *** synthetic mechanism involved substitution and continuous interdiffusion of Al and Si *** composite prepared by CAS at 1200℃ was compacted,whereas the composite prepared by HP had a low *** low-temperature densification mechanism is attributed to the combined effects of amorphous SiO,liquid Al,and the high heating rates for *** flexural strength and hardness of the composite prepared by CAS were also comparable to those of compacted Ti_(3)SiC_(2)/Al_(2)O_(3) composites.

关键词： aluminum oxide(Al_(2)O_(3)) current-assisted sintering(CAS) silicon monoxide(SiO) Ti_(3)(Si Al)C_(2)

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：