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Catalysis Today 2022年 405-406卷 82-91页

作者： Jia-Min Lyu Shen Yu Zhao Peng Jian Zhou Zhan Liu Xiao-Yun Li Yu-Li Li-Hua Chen Bao-Lian Su State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan 430070 Hubei China State Key Laboratory of Green Chemical Engineering and Industrial Catalysis Shanghai Research Institute of Petrochemical Technology SINOPEC Shanghai 201208 China State Key Laboratory of Silicate Materials for Architecture Wuhan University of Technology Wuhan 430070 Hubei China Laboratory of Inorganic Materials Chemistry (CMI) University of Namur Namur B-5000 Namur Belgium

Bifunctional catalysts are widely applied for many important reactions as the synergetic effect of two types of active sites remarkably improves catalysis performance. However, their bifunctionality has not been fully exploited since the proximity of bifunctional catalysts is hard to control. Herein, we demonstrate a bifunctional [email protected] 2 O 3 catalyst with a core-shell structure and a nano-scale proximity by in-situ growth of γ-Al 2 O 3 nanosheets on the surface of ZSM-5 crystals for methanol conversion. The nano-scale proximity endows the catalyst with higher reaction activity and C 2 –C 3 olefins yield (53 %) in comparison to the catalysts with micro-scale proximity (20 %) and millimeter-scale proximity (27 %), which can be attributed to the fluent transport of the reaction intermediates between two types of active sites. This strategy for constructing bifunctional catalysts with nano-scale proximity is conducive to understanding the relationship between proximity and catalytic performance in methanol conversion.

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Chemically Bonded Interface Construction of Covalent Organic Framework/CsPbBr3 Heterojunction for Efficient Photocatalytic CO2 Reduction Driven by Visible Light

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SSRN 2024年

作者： Zhou, Min Wang, Zhiqing Mei, Aohan Chen, Keqiang Zeng, Jianrong Liu, Yueli Chen, Wen State Key Laboratory of Silicate Materials for Architectures School of Materials Science and Engineering Wuhan University of Technology Wuhan430070 China Sanya Science and Education Innovation Park Wuhan University of Technology Sanya572024 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and Engineering Wuhan University of Technology Wuhan430070 China Faculty of Materials Science and Chemistry China University of Geosciences Wuhan430074 China Shanghai Synchrotron Radiation Facility Shanghai Institute of Applied Physics Chinese Academy of Sciences Shanghai201204 China

Effective interface interaction is the key factor to improve the photocatalytic performance due to its rapid interfacial charge transport. However, the complex organic synthesis environment and abundance surface ligands for most metal halide perovskites (MHPs) nanocrystals make it difficult to realize the strong interface interaction and rapid carrier transfer. Herein, the covalent organic framework (COF)/CsPbBr3 catalyst is constructed by in-situ growth method in HBr solvent. The Pb-N coordination acts as an electron delivery channel, guiding the transport of photogenerated carrier and enabling the effective separation of the photoexcited electron-hole pairs, thereby enhancing the performance of CO2 photoreduction. The photocatalytic efficiency of TpBpy/CsPbBr3 heterojunctions reaches up to 239.46 μmol·g–1 h–1 (CO) under the visible light irradiation, which is significantly higher than that of TpBpy and CsPbBr3 NCs. This work demonstrates a potential strategy for the construction of COF/MHPs heterojunction with strong interface interaction, which has great potential in various photocatalytic applications. © 2024, The Authors. All rights reserved.

关键词： Metal halides

Sulfur-doped g-C3N4/TiO2 S-scheme heterojunction photocatalyst for Congo Red photodegradation

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Chinese Journal of Catalysis 2021年第1期42卷 56-68页

作者： Juan Wang Guohong Wang Bei Cheng Jiaguo Yu Jiajie Fan Hubei Key Laboratory of Pollutant Analysis and Reuse Technology College of Chemistry and Chemical EngineeringInstitute for Advanced MaterialsHubei Normal UniversityHuangshi 435002HubeiChina State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina Material Science and Engineering School Zhengzhou UniversityZhengzhou 450001HenanChina

Constructing step-scheme(S-scheme)heterojunctions has been confirmed as a promising strategy for enhancing the photocatalytic activity of composite *** this work,a series of sulfur-doped g-C3N4(SCN)/TiO2 S-scheme photocatalysts were synthesized using electrospinning and calcination *** as-prepared SCN/TiO2 composites showed superior photocatalytic performance than pure TiO2 and SCN in the photocatalytic degradation of Congo Red(CR)aqueous *** significant enhancement in photocatalytic activity benefited not only from the 1D well-distributed nanostructure,but also from the S-scheme ***,the XPS analyses and DFT calculations demonstrated that electrons were transferred from SCN to TiO2 across the interface of the SCN/TiO2 *** built-in electric field,band edge bending,and Coulomb interaction synergistically facilitated the recombination of relatively useless electrons and holes in hybrid when the interface was irradiated by simulated solar ***,the remaining electrons and holes with higher reducibility and oxidizability endowed the composite with supreme redox *** results were adequately verified by radical trapping experiments,ESR tests,and in situ XPS analyses,suggesting that the electron immigration in the photocatalyst followed the S-scheme heterojunction *** work can enrich our knowledge of the design and fabrication of novel S-scheme heterojunction photocatalysts and provide a promising strategy for solving environmental pollution in the future.

关键词： TiO2 nanofiber Sulfur-doped g-C3N4 Step-scheme heterojunction photocatalysis In situ XPS S-scheme mechanism

Novel hollow Ni0.33Co0.67Se nanoprisms for high capacity lithium storage

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Nano Research 2019年第6期12卷 1371-1374页

作者： Shaohua Zhu Cheng Chen Pan He Shuangshuang Tan Fangyu Xiong Ziang Liu Zhuo Peng Qinyou An Liqiang Mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

In this work,homogeneous Ni0.33Co0.67Se hollow nanoprisms were synthesized successfully in virtue of Kirkendall *** is the first time for bimetallic Ni-Co compounds Ni0.33Co0.67Se to be used in lithium-ion batteries (LIBs).Impressively,the Ni0.33Co0.67Se hollow nanoprisms show superior specific capacity (1,575 mAh/g at the current density of 100 mA/g) and outstanding rate performance (850 mAh/g at 2,000 mA/g) as anode material for *** work proves the potential of bimetallic chalcogenide compounds as high performance anode materials for LIBs.

关键词： Ni0.33Co0.87Se hollow nanoprisms anodehigh capacity lithium-ion batteries

Metal-organic frameworks enable broad strategies for lithium-sulfur batteries

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National Science Review 2021年第12期8卷 104-121页

作者： Cheng Zhou Zhaohuai Li Xu Xu Liqiang Mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology International Schoo of Materials Science and Engineering Wuhan University of Technology Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory

The lithium-sulfur(Li-S) battery is considered to be a potential next-generation power battery system,however, it is urgent that suitable materials are found in order to solve a series of challenges, such as the shuttle effect and lithium dendrite growth. As a multifunctional porous material, metal-organic frameworks(MOFs) can be used in different parts of Li-S batteries. In recent years, the application of MOFs in Li-S batteries has been developed rapidly. This review summarizes the milestone works and recent advances of MOFs in various aspects of Li-S batteries, including cathode, separator and electrolyte. The factors affecting the performance of MOFs and the working mechanisms of MOFs in these different parts are also discussed in detail. Finally, the opportunities and challenges for the application of MOFs in Li-S batteries are proposed. We also put forward feasible solutions to related problems. This review will provide better guidance for the rational design of novel MOF-based materials for Li-S batteries.

关键词： metal-organic frameworks lithium-sulfur batteries cathode separator electrolyte

Improvement of Sic Deposition Uniformity in Cvd Reactor by Showerhead with Baffle

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SSRN 2023年

作者： Li, Qizhong Zhang, Yixuan Ji, Baifeng Zhang, Song Tu, Rong Hubei Key Laboratory of Advanced Technology for Automotive Components Wuhan University of Technology Wuhan430070 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China School of Civil Engineering and Architecture Wuhan University of Technology Wuhan430070 China Chaozhou Branch of Chemistry and Chemical Engineering Guangdong Laboratory Chaozhou521000 China Wuhan University of Technology Advanced Engineering Technology Research Institute of Zhongshan City Guangdong Zhongshan528400 China

The deposition rate distribution during halide chemical vapour deposition of silicon carbide (SiC) is influenced by equipment structure, and a uniform film can be obtained by optimising the chamber structure. A detailed chemical reaction mechanism was incorporated into a reaction chamber model to verify the SiC deposition kinetics model. We studied the influence of spray hole size, baffle size, and baffle positioning on the deposition rate uniformity. The results show that reducing the size of the spray holes leads to a "double peak" in the deposition rate across the substrate from the edge to both sides, which first increases and then decreases. The "double peak" disappears when the spray hole size is reduced. With an increase in baffle size, the uniformity of the deposition rate first increased and then decreased. Moreover, the baffle displacement had little effect on the deposition rate when the baffle-to-spray plate distance was at least 45 mm. Meanwhile, the deposition uniformity gradually worsened when the baffle distance was reduced. The spray plate and baffle reduced the extreme difference in deposition rates across the effective deposition area by improving the velocity field of the reaction chamber. A uniform SiC film can be obtained using the proposed optimisation method. © 2023, The Authors. All rights reserved.

关键词： Structural optimization

Interfacial Microstructure and Mechanical Behavior of Low-Temperature Diffusion Bonded Mo/SS304 Joints Using Ni xCu 1-x Interlayers

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SSRN 2021年

作者： Jia, Mingyong Chen, Fei Zhang, Lei Huang, Zhifeng Shen, Qiang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China

To join dissimilar metals with large differences in characteristics, such as molybdenum (Mo) and stainless steels (SS), is essential to take full advantage of their combined performances. In this work, Mo and SS304 have been jointed with Ni interlayer by using a diffusion bonding technique at different bonding temperatures. The results show that a MoNi brittle intermetallic compound is easy to form in the interface of the Mo/SS304 joint with increasing the bonding temperature, which will reduce the shear strength of the joint because a crack is easy to form between Mo and the intermetallic compounds. Meanwhile, Mo/SS304 joints have also been prepared by using NixCu1-x (x=0.45, 0.24, or 0) as an interlayer. The result shows that reducing Ni content can avoid the formation of intermetallic compounds, and the fracture occurs between the interlayer and Mo diffusion zone far away from the Mo side. This work shows that the fracture properties of the Mo/SS304 joint can be modified by changing the composition of the interlayer. The best shear strength of the Mo/SS304 joint is 140 MPa. This work is important for providing an effective approach to join Mo and SS304 using a low-temperature diffusion bonding method. © 2021, The Authors. All rights reserved.

关键词： Intermetallics

Operando Selenium Treatment Towards Enhanced Cyclic Stability for Single-Crystal Ni-Rich Cathode at Ultra-High Voltage of 4.7 V

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SSRN 2023年

作者： Zhang, Zhi Ding, Xiang He, Xinyou Gong, Yang Xiao, Biaobiao Shen, Jixue Ou, Xing Hunan Provincial Key Laboratory of Water Treatment Functional Materials Hunan Provincial Key Laboratory for Control Technology of Distributed Electric Propulsion Aircraf College of Chemistry and Materials Engineering Hunan University of Arts and Science Changde415000 China Engineering Research Center of the Ministry of Education for Advanced Battery Materials School of Metallurgy and Environment Central South University Changsha410083 China Institute of Advanced Battery Materials and Devices Faculty of Materials and Manufacturing Beijing University of Technology Beijing100124 China Tianmu Lake Institute of Advanced Energy Storage Technologies Co. Ltd Liyang213300 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China

Developing high-voltage (≥4.3 V vs Li/Li+) single-crystal Ni-rich LiNixCoyMn1-x-yO2 offers an enticing strategy to achieve high energy density for lithium-ion batteries. However, at high-voltage operation, the cathode will be vulnerable to induce the intrinsic Oα- (α 0.6Co0.1Mn0.3O2 (SC-NCM) cathode materials by introducing the surface Se element, exhibiting an "anti-aging" effect of inhibiting the escape of oxygen on SC-NCM particles during the ultra-high voltage (4.7 V) cycling. Both theoretical calculation and experimental results confirm that the outside-in nanostructure would substitute some mobile Oα- at the surface of highly charged SC-NCM particle, stabilizing the oxygen lattice and suppressing O2 release during long-term cycling. Meanwhile, the surface modification of thin Se layer will alleviate the parasitic reactions and improve the electronic conductivity. Under the synergistic strategy of surface modification and interface doping, the obtained SC-NCM exhibits boosted cyclic stability in coin half-cell and pouch full-cell simultaneously. Therefore, the reversible capacity of LiNi0.6Co0.1Mn0.3O2 at high voltage is competitive with comercial LiNixCoyMn1-x-yO2 (x ≥ 0.8), demonstrating more superior safety ability and cyclic property. It provides an effective approach for improving the long-term performance of Ni-rich cathode materials for practical application under ultra-high working voltage. © 2023, The Authors. All rights reserved.

关键词： Single crystals

Tuning Ferroelectrics to Antiferroelectrics in Multiferroic LaxSr1-xFe12O19 Ceramics

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arXiv

arXiv 2021年

作者： Duan, Cong-Cong Tan, Guo-Long State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China

The combination of antiferroelectricity (AFE) and ferromagnetism (FM) in one structure would allow the development of new type of multiferroic candidates, which be applicable not only in magnetoelectric memories but also in novel energy storage devices. Here we propose a novel type of multiferroic candidate LaxSr1-xFe12O19, whose room temperature state could betuned from ferroelectrics (FE) to antiferroelectrics by changing x from 0 to 0.5. The emphasis of this paper will be focused on the La0.5Sr0.5Fe12O19 system, in which full AFE and FM coexist. The pure antiferroelectric behavior in La0.5Sr0.5Fe12O19 ceramics is demonstrated by double polarization-electric field (P-E) hysteresis loops, which are fully separated by a linear antiferroelectric AFE component with zero net polarization. The material of La0.2Sr0.7Fe12O19 with the intermediate composition exhibits a hybrid ferroelectric/antiferroelectric state. The recoverable energy density of the antiferroelectric La0.5Sr0.5Fe12O19 phase reaches Ure∼14.3 J/cm3. This material demonstrates strong magnetoelectric coupling and giant magnetoresistance (GMR) effect. A 1.1T magnetic field generates electronic polarization up to 0.95μC/cm2, reduce the resistance by 117%, enhances dielectric constants by 540% and right shifts the maximum dielectric loss peak by 208 kHz. The combined functional responses provide an opportunity to develop novel multifunctional electric and energy storage devices. © 2021, CC BY.

关键词： Energy storage

Double-Layer Phosphates Coated Mn-Based Oxide Cathodes for Highly Stable Potassium-Ion Batteries

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SSRN 2023年

作者： Wang, Hong Peng, Haoyang Xiao, Zhitong Yu, Ruohan Liua, Fang Zhua, Zhu Zhou, Liang Wu, Jinsong State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and Engineering Wuhan University of Technology Wuhan430070 China School of Mathematics and Physics Jingchu University of Technology Jingmen448000 China Wuhan University of Technology Wuhan430070 China Shenzhen Institute of Wuhan University of Technology Guangdong Shenzhen518000 China

Manganese rich oxides with layered structure are now being developed as cathodes for potassium ion batteries (PIBs). Nevertheless, poor cycling stability and sluggish electrochemical kinetics have hindered their practical applications. Here, we construct a thin K3PO4/MnPO4 layer, which has high conductivity of both electron and potassium-ion, on the surface of K0.5Mn0.8Co0.2O2 (KMCO) and achieve improved cycling stability and capacity rate when the composite is used as cathodes in PIBs. Comparing to the pure KMCO, the K3PO4/MnPO4-coated K0.5Mn0.8Co0.2O2 (P-KMCO) has higher electron and K-ion conductivity, less surficial oxygen loss and layered-to-spinel-to-rock salt tri-phase transition, and less internal lattice expansion and contraction in cycling, as studied by aberration-corrected scanning transmission electron microscopy and in-situ X-ray diffraction. The synthesized P-KMCO exhibits a highly reversible specific capacity (101.3 mAh g-1 at 0.1 A g-1), excellent rate performance and stellar capacity retention of 80% after 500 cycles at 1 A g-1 compared to pure KMCO (78.6 mAh g-1 at 0.1 A g-1 with 67.3% capacity retention). The P-KMCO electrode shows also a supreme electrochemical performance when assembled in pouch cells. First-principal calculations imply that the surface modification can effectively prevent TM ions dissolution and oxygen release while cycling. Like those developed in lithium-ion batteries, this work demonstrates the appropriate surface engineering is also an effective approach to development stable cathodes of PIBs. © 2023, The Authors. All rights reserved.

关键词： Cathodes