The isomerization of endo-tetrahydrodicyclopentadiene (THDCPD) to exo-THDCPD over AlCl 3 catalyst has been studied in a batch reactor. The effects of temperature, catalyst loading, and the type and amount of solvent ...
详细信息
The isomerization of endo-tetrahydrodicyclopentadiene (THDCPD) to exo-THDCPD over AlCl 3 catalyst has been studied in a batch reactor. The effects of temperature, catalyst loading, and the type and amount of solvent on the isomerization rate were investigated. Under the conditions of removing both internal and external diffusion effects, a kinetic model was established and the model parameters were developed. The results showed that the endo- to exo- isomerization of THDCPD can be treated as a first-order reaction. The activation energy E 0 and pre-exponential factor obtained from Arrhenius plot are 116 kJ I mol and 3.39x10 13 respectively. The simulation results agreed well with the experimental data.
An effective way to boost natural gas production from low pressure gas field was introduced in the paper. The supersonic ejector used the energy of high pressure gas wells, which was generally wasted through the choke...
详细信息
An effective way to boost natural gas production from low pressure gas field was introduced in the paper. The supersonic ejector used the energy of high pressure gas wells, which was generally wasted through the choke valve, as its power supply to boost the low pressure gas production. The field experiment of the natural gas ejector was carried out, and the performance of the ejector was also presented. Moreover, the production of low pressure natural gas well was compared when the natural gas ejector was used or not. The economic analysis shows that the recovery period of the capital was less than several months.
Experimental investigation was conducted on the cooling tower test device using the outlet water temperature as evaluation index. The experimental results indicated that: the outlet water temperature decreased with th...
详细信息
Experimental investigation was conducted on the cooling tower test device using the outlet water temperature as evaluation index. The experimental results indicated that: the outlet water temperature decreased with the increase of air-to-water ratio, but the trend was decreasing gradually. The limit air-to-water ratio existed during the decrease of outlet water temperature. The outlet water temperature had little change when the air-to-water ratio was up to this value. The limit air-to-water ratio decreased with the increase of inlet air dry bulb temperature and wet bulb temperature, and increased with the increase of inlet water temperature. And the limit air-to-water ratio decreased with the increase of the flow rate of circulating water. Such conclusions may be advantageously used in guiding the design and operation of cooling tower.
The viscous and pressure gradient terms, which can be solved by Green Function method theoretically, are calculated separately in MPS method. Through the analysis of kernel function, an accuracy condition of viscous t...
详细信息
The viscous and pressure gradient terms, which can be solved by Green Function method theoretically, are calculated separately in MPS method. Through the analysis of kernel function, an accuracy condition of viscous term is proposed and the reasonable match between spatial and time step will increase the accuracy and stability of MPS method. Poiseuille flow is simulated and the accuracy condition is validated. In the analysis of the source term of Pressure Poisson equation, the particle number density (PND), which is very sensitive to the relative configuration of particles, yields the deviation of velocity profile from the theoretical solution. It is the fluctuation in PND that causes the spurious fluctuation of pressure.
The heat exchange tube with inner and outer fins has been widely applied in industry in order to enhance the performance of heat exchangers. When it is used in high temperature environment, the security must be consid...
详细信息
A two-dimensional two-phase non-isothermal mass transport model is developed in this paper for the air breathing direct methanol fuel cell(DMFC). The self-made computer code is used to simulate the heat and mass trans...
详细信息
The optical model of the volumetric solar receiver has been built and corresponding solar radiation propagation process within the receiver is simulated by the Monte Carlo ray tracing method(MCRT). In the computation,...
详细信息
Experimental study of air natural convection in horizontally-positioned copper metallic foams with open cells was conducted. Temperature distributions on the heating surface were tested under different heating power f...
详细信息
ISBN:
(纸本)9781612847498
Experimental study of air natural convection in horizontally-positioned copper metallic foams with open cells was conducted. Temperature distributions on the heating surface were tested under different heating power for foam samples having different porosities and pore densities. The effects of porosity and pore density on the total thermal resistance of the foam sample were quantified. It is found that the porous surface can enhance the natural convection and reduce the thermal resistance by about 20% in comparison with a smooth surface. The surface area density and mass flow rate in natural convection are affected by porosity and pore density simultaneously. When the porosity is relative small (ε = 90%), there exits a critical value of the Gr number (turning point) for two pore densities (10ppi and 40ppi). When the Gr number is less than this critical value, the foam with a higher pore density has the lower total thermal resistance, whereas when the Gr number exceeds the turning point value, the opposite holds. If the porosity is increased to ε = 95%, the foam with a higher pore density has the lower thermal resistance in the whole experimental range. When the porosity and pore density is the same, the foam with smaller size has the higher thermal resistance in the whole experimental range. If the size is relatively small (100×100×50mm), for the two pore densities studied (20ppi and 80ppi), there exits a critical value of the Gr number (turning point). The foam with a lower porosity (ε = 90%) has the lower thermal resistance and the decrease is more obvious for the case of 80ppi. If the size is relatively big(100×100×80mm), there exists a critical value of the Gr number (turning point) only for the case of 10ppi. When the Gr number is less than this critical value, the foam with a higher porosity (ε = 95%) has the higher total thermal resistance, the opposite holds. While for the other two pore densities (20ppi and 40ppi), there is no turning point. The foam with
This paper studies the projectile electron loss cross sections of C^3+ colliding with atomic hydrogen in the frame work of extended over-barrier model at intermediate velocities (25 keV/u-600 keV/u). The electron l...
详细信息
This paper studies the projectile electron loss cross sections of C^3+ colliding with atomic hydrogen in the frame work of extended over-barrier model at intermediate velocities (25 keV/u-600 keV/u). The electron loss is calculated in terms of the interaction between the screened target nucleus and the active projectile electron and of the interaction between projectile electron and target electron. Compared with the convergent close-coupling calculations, screening and anti-screening calculations, this model satisfactorily reproduces the experimentally obtained energy dependence of the electron-impact ionisation cross sections and the single electron loss cross sections over the energy range investigated here.
The laminar burning velocity of iso-butanol-air mixtures was measured under different initial pressures,initial temperatures and equivalence ratios using high-speed schlieren photography and outwardly propagation flam...
详细信息
The laminar burning velocity of iso-butanol-air mixtures was measured under different initial pressures,initial temperatures and equivalence ratios using high-speed schlieren photography and outwardly propagation flame in a constant volume combustion *** on the analysis of stretched flame propagation speed and stretch rate,the laminar burning velocities and Markstein lengths of iso-butanol-air flames are *** accordance,with photos of flame,an analysis of flame stability and the influencing factors is carried *** results show that the laminar burning velocity is decreased with the increase of initial pressure and is increased with the increase of initial *** maximum value of laminar burning velocity is presented at the equivalence ratio of *** Markstein length is decreased with the increase of equivalence *** specified equivalence ratio,the Markstein length is decreased with the increase of initial temperature and initial ***,the flame instability is increased with the increase of equivalence ratio,initial temperature and initial pressure.
暂无评论