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Revised Control Strategy for Coal-Fired power Plants During Transient Processes Considering Heat Transfer Deterioration of Cooling Wall: Flexibility Enhancement and Security Operation

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SSRN 2024年

作者： Wang, Dengliang Zhao, Yongliang Gao, Wei Chen, Weixiong Wang, Chaoyang Yan, Junjie State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

Increasing share of power generation from intermittent renewable energy has resulted in an expanding demand for deep peaking and operational flexibility of thermal power plants. Under this circumstance, it causes an enormous threat to the safe operation of the boiler, especially cooling wall. So it is crucial to focus on the thermo-hydraulic performance of the cooling wall during transient processes. In this paper, a 1100 MW ultra-supercritical thermal power plant is used as the research object. A one-dimensional dynamic model of the cooling wall is constructed based on the conservation of mass, conservation of momentum, conservation of energy, state, metal heat storage and heat transfer equations. The temperature distributions of working fluid, inner and outer wall along the height direction of the cooling wall are obtained. Dry-out phenomenon of the cooling wall during the load cycling process is observed. It is found that heat transfer deterioration is a key reason for metal wall temperature intermittent fluctuation. When the load cycling rates are 2.5% Pe/min and 3.0% Pe/min, the maximum temperatures of metal tube wall during the loading up process reach 527.9°C and 557.3°C, respectively. Furthermore, a revised control strategy is proposed based on the heat transfer deterioration characteristics of the cooling wall. During the loading up process, the highest wall temperature is significantly reduced from 557.3°C to 502.2°C at 3.0% Pe/min. The maximum power ramp rate is increased from 2.5% Pe/min to 3.0% Pe/min when the revised control strategy is adopted. © 2024, The Authors. All rights reserved.

关键词： Fossil fuel power plants

Thermodynamic Modeling and Analysis of the Hydrogen and Combustible Gas Production in Supercritical Water Partial Oxidation System of Coal

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SSRN 2024年

作者： Li, Yifeng Xing, Guowei Liu, Shi Guo, Shenghui Ge, Zhiwei Guo, Liejin State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

Supercritical water partial oxidation (SCWPO) is an eco-friendly coal treatment technology that lowers the temperature needed for complete gasification of coal, promotes hydrogen output, enables targeted regulation of gaseous product composition, and eliminates gaseous pollutants. Current researches mainly focus on experiments and numerical simulations, with limited exploration in thermodynamics. he present study establishes an auto-thermal SCWPO cogeneration system for Hongliulin coal, employs sensitivity analysis to refine system parameters, and utilizes Life Cycle Assessment to evaluate environmental impact of hydrogen production system. As the outlet temperature of the reactor increases and the preheating water flow and equivalence ratio (ER) increase, the fraction of hydrogen in the gas product rises;conversely, the fraction of the combustible gas (CH4+CO+H2) rises. The SCWPO system can be precisely tailored to yield high-purity hydrogen or combustible gas by modulating the amount of oxygen input. The system of combustible gas production is capable of generating 241.67 GJ·h-1 of energy and attaining a cold gas efficiency of 81.62% when the ER is 0.25. The hydrogen production system can produce 1004.38 kg·h-1 of hydrogen and 206 t·h-1 of heated water at 0.5 MPa and 150℃ for an ER of 0.6. The optimum hydrogen production system achieved an energy efficiency of 90.97%, showing an improvement of 11.12% to 46.76% compared to previous hydrogen production systems. The standard Global Warming Potential of the system through carbon capture technology is 0.0087. The system developed in this paper benefits the industrial application of SCWPO and the optimization of subsequent processes. © 2024, The Authors. All rights reserved.

关键词： Thermolysis

Thermodynamic Analysis of a Supercritical Water Partial Oxidation Autothermal Cogeneration System of Coal

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SSRN 2024年

作者： Xing, Guowei Li, Yifeng Ren, Changyifan Ge, Zhiwei Guo, Liejin State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

Supercritical water partial oxidation (SCWPO) is a very efficient technology for the environmentally sound treatment of resources. Currently, there are few thermodynamic studies of SCWPO cogeneration system. In this study, a new supercritical water partial oxidation autothermal cogeneration system of coal is proposed. The system was evaluated for energy and exergy under typical operating conditions. The efficiencies achieved were 86% for energy and 47.6% for exergy. Due to the mixed working fluid is a mixture of H2O and CO2, the CO2 is very easy to capture. The exergy analysis revealed that the most significant exergy loss within the system occurred in the SCWPO reactor, which accounted for 78.2%% of the total exergy loss. Further sensitivity analysis of the system indicates that optimum values identified for both back pressure and carbon capture and storage unit (CCS) first stage pressure (PV-pump1), which are 8.5 kPa and 0.03 MPa. Additionally, increasing both the flow rate and temperature of preheated water can significantly enhance system efficiency. An increase in the flow rate of preheated water can lead to a reduction of the maximum system temperature;however, an elevation in the temperature of preheated water may cause a significant rise of the maximum system temperature, which is not conducive to the stable operation of the system. Finally, this paper compares the proposed system with the systems that have been reported in the literature. The results show that the system represents an innovative cogeneration solution with considerable advantages. © 2024, The Authors. All rights reserved.

关键词： Exergy

Heat Transfer Enhancement of Air flow Through New Types of Perforated Dimple/Protrusion Fins

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SSRN 2024年

作者： Sen, Palash Chen, Mengjie Bai, Bofeng State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

Heat transfer enhancement technologies of air flow are of critical to energy conservation and emission reduction in industrial applications. This paper explores the numerical simulation analysis of 18 kinds of perforated dimple/protrusion fins. The wind speed varies within the range of 2~6m/s, and the investigation delves into the impact of different structural parameters on strengthening factor Nu/Nu0, resistance factor f/f0 and other comprehensive evaluation factor performance evaluation criteria (PEC) of perforated dimple/protrusion fins. The study specifically explores the influence of structural parameters, including intercepting perforated dimple/protrusion height (S0), aperture (D), hole structure offset (a), and the arrangement of perforated dimple/protrusion structure, on heat transfer performance. The overall heat transfer performance of the perforated dimple/protrusion fins rises with height under the same operating conditions. It first increases and then declines with the increasing aperture, and first drops and then increases with the increasing offset. The hole structure offset is better on the inflowing leeward side than on the inflowing side. The fins with both perforated dimple and perforated protrusion structures have advantages over the one with either of two structures, and the alignment arrangements are identified as the optimal configuration. © 2024, The Authors. All rights reserved.

关键词： Air

Calcium Looping Sorption-Enhanced Electrified Steam Methane Reforming for Efficient Hydrogen Production with Short- and Long-Duration Cooperative Energy Storage

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SSRN 2024年

作者： Song, Huchao Zhang, Xinyue Lin, Xiaolong Bian, Hao Liu, Yinhe State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

Currently, the dominant hydrogen production technology is steam methane reforming, but both the reforming reaction and the combustion for driving the reaction produce significant CO2 emissions. Sorption-enhanced methane reforming enables the in-situ removal of CO2 produced by the reforming reaction and promotes higher hydrogen yields, however, CO2 emissions from combustion cannot be avoided. Renewable electricity instead of combustion for reaction heating can eliminate combustion carbon emissions and flue gas heat loss, but its dependence on renewable electricity supply prevents continuous and stable operation. This study proposes a sorption-enhanced electrified steam methane reforming technology based on short- and long-duration cooperative energy storage and calcium looping carbon capture. This technology utilizes the CO2 adsorption and energy storage property of the absorbent to absorb CO2 in situ in the reformer and transform renewable electricity to chemical and thermal energy in the regenerator as short- duration energy storage. The energy stored in the absorbent can be used to drive the methane reforming reaction and transformed into chemical energy in hydrogen continuously as long- duration energy storage. Through First law and Second law analysis, this study has found that the novel process improves thermal efficiency by 8.5 percentage points and reduces the exergy loss of the overall process by 53.2% compared with the sorption-enhanced steam methane reforming process. Based on current fuel prices in China, the novel process is more economical than the other steam methane reforming processes simulated in this study. Sensitivity analysis has found that low electricity and high methane prices benefit the economic performance of the novel process. This study may provide a stable, efficient, and economical way of clean hydrogen energy production. © 2024, The Authors. All rights reserved.

关键词： Hydrogen production

Experimental and Numerical Study on Co-combustion Behaviors and NO_(x) Emission Characteristics of Semi-coke and Coal in a Tangentially Fired Utility Boiler

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Journal of Thermal Science 2021年第4期30卷 1116-1131页

作者： WANG Chang’an FENG Qinqin JIN Liyan WANG Zhichao YAO Wei WANGPengqian DU Yongbo ZHANG Xilai YANG Zhongcan CHE Defu State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power EngineeringXi’an Jiaotong UniversityXi’an 710049China Xi’an Thermal Power Research Institute Co. LTD.Xi’an 710054China

The utilization of powdery semi-coke as a power fuel in pulverized coal-fired power plants has become a new and potential technique to consume the excess powdery *** characteristic of low volatile results in poor combustion performance and high NO_(x) emission,and to co-fire with bituminous coal is a practical strategy to address this ***,the co-combustion characteristics and the inherent interaction between semi-coke and coal remain insufficiently *** addition,the influences of secondary air arrangement,the boiler operation load,and the fuel type on co-combustion process are still unclear,which is urgent to be further *** the present study,experiments and numerical simulations were jointly utilized to inquire into the co-combustion behaviors and NO_(x) emission features of semi-coke and *** results demonstrated that the"out-furnace method"was a suitable choice for small-capacity boiler when the proportion of semi-coke was 33%,due to the limited combinations of the semi-coke injection *** was recommended that semi-coke was preferred to be injected from the middle layers of the furnace under the"in-furnace method"to improve the overall co-combustion *** critical value of the separated over fire air ratio in this study was 27.5%,over which a slight drop of carbon content in fly ash could come ***,the elevation in the proportion of separated over fire air gave rise to the significant decline of NO_(x) *** constricted secondary air arrangement was preferred to be employed due to the high boiler *** separated over fire air and the surrounding air needed to maintain a wide-open degree to prevent the increase of NO_(x) emissions and the coking of *** the load reduction regulation method adopted in this study,the NO_(x) concentration first rose and then dropped,while the burnout ratio decreased obviously as the operation load was *** combinations of coa

关键词： semi-coke numerical simulation co-combustion NOx emission blending method

Eco-friendly calcium alginate microspheres enable enhanced profile control and oil displacement

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Petroleum Science 2024年第3期21卷 1928-1943页

作者： Xiao-Han Zhang Chang-Jing Zhou Yuan-Xiang Xiao Bo Hui Yong-Gang Xie Yu-Bin Su Xin-Ru Li Jie Huang Mao-Chang Liu International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi'an Jiaotong UniversityXi'an710049ShaanxiPR.China Shaanxi Key Laboratory of Advanced Stimulation Technology for Oil&Gas Reservoirs School of Petroleum EngineeringXi'an Shiyou UniversityXi'an 710065ShaanxiPR.China Oil&Gas Technology Research Institute Changqing Oilfield Branch CompanyPetroChinaXi'an710021ShaanxiPR China Suzhou Academy of Xi'an Jiaotong University Suzhou215123JiangsuPR China

Polymer microspheres(PMs),such as polyacrylamide,have been widely applied for enhanced oil recovery(EOR),yet with environmental ***,we report a microfluid displacement technology containing a bio-based eco-friendly material,i.e.,calcium alginate(CaAlg)microspheres for *** dominant mechanisms responsible for EOR over Ca Alg fluid have been verified,including the microscopic oil displacement efficacy augmented by regulating capillary force(determined by the joint action of interfacial tension and wettability between different phases)and macroscopic sweep volume increment through profile control and mobility ratio *** comprehensive effectiveness can be further impacted when the CaAlg microsphere is embellished ulteriorly by using appropriate amount of sodium dodecyl sulfonate(SDS).The core flooding and nuclear magnetic resonance(NMR)tests demonstrate that CaAlg-SDS microsphere can balance the interphase property regulation(wettability alteration and IFT reduction)and rheology properties,enabling simultaneous profile control and oil *** introduction of SDS will have a negative impact on rheological properties,which is not favored for *** results show that the involvement of 4-m M SDS will provide the best behavior,with an EOR rate of 34.38%.This cost-effective and environmentally-friendly bio-microspherebased microfluidic displacement technology is expected to achieve“green”oil recovery in future oilfield exploitation.

关键词： Calcium alginate microspheres Wettability Interfacial tension Rheology Viscoelasticity Enhanced oil recovery(EOR)

High Concentration of CO and CO2 Inhibits Coal Gasification in Supercritical Water

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SSRN 2024年

作者： Zhang, Rui Zhao, Shuaiqi Huang, Han Zhao, Kunpeng Bai, Bofeng State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

Supercritical water gasification technology achieves efficient resource utilization of lignite and produces H2, CO and CO2. In this study, we experimentally investigated the impact of gas product generated from high concentration (>30 wt%) formic acid decomposition on the gasification of Tiebei lignite in the supercritical water. H2 promotes the pyrolysis of carbon structures, the increase in CO promotes CO2 generation through the water-gas shift reactions, and the enrichment of CO2 hinders gas diffusion. We found that high concentration of formic acid(H2, CO and CO2) inhibits the gasification of Tiebei lignite in the supercritical water. Compared with coal gasification in the supercritical water without formic acid, 30wt% formic acid reduces the carbon efficiency of lignite by 7.66%, and the mass conversion of coal by 3.97%. When the concentration of formic acid is 30wt% to 70wt%, the higher concentration of formic acid(H2, CO and CO2), the worse gasification performance of Tiebei lignite. © 2024, The Authors. All rights reserved.

关键词： Water gas shift

Experimental Study on flow Boiling and Circumferential Non-Uniform Heat Transfer Characteristics in Helically-Coiled Tube Under Coupled Heat Transfer Conditions

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SSRN 2024年

作者： Wang, Hengyuan Xuan, Qiyu Lei, Hailin Li, Xi Li, Zhibin Li, Huixiong State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an710049 China

Because of its compact structure and high energy conversion efficiency, helically-coiled tube steam generator has been widely used in nuclear reactor, energy power, petrochemical and other systems. In the liquid metal reactor, the liquid metal on the primary side of the helically-coiled tube steam generator washes the helically-coiled tube bundles, and exchanges heat with the water on the secondary side. Due to the coupled heat transfer between liquid metal and water, the distribution of the wall temperature or heat transfer coefficient of helically-coiled tube are significant different in the circumference direction of the tube cross-section. An experimental system of helically-coiled tube steam generator was set up in this paper. The non-uniform heat transfer characteristics of secondary side fluid of helically-coiled tube steam generator were studied under the coupled heat transfer conditions between the heat transfer of primary side and secondary sides fluid. It was found the local wall temperature or local heat transfer coefficient in the circumferential direction of the tube cross-section was significantly different, and they showed different change trends with the change of the parameters such as subcooling degree, mass flux of the secondary side fluid, system pressure of secondary side fluid, heating temperature of primary side fluid, etc. Secondly, ηt and ηh were defined to represent the degree of local non-uniformity of local wall temperature or local heat transfer coefficient in the circumferential distribution of the tube cross-section, respectively. δt and δh were defined to characterize the degree of overall non-uniformity of wall temperature or heat transfer coefficient in the circumferential distribution of the tube cross-section, respectively. The variation rules of ηt and ηh, δt and δh with subcooling degree、system pressure、mass flux of primary side fluid、mass flux of secondary side fluid and heating temperature of primary side fluid were obtained.

关键词： Steam generators